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Catalyst Preparation Methods-G1

Precipitation and co-precipitation are commonly used methods to prepare catalysts. Precipitation involves forming a solid catalyst from a supersaturated metal solution. Co-precipitation simultaneously precipitates more than one compound from a solution to form mixed oxide catalysts. Examples of catalysts prepared through these methods include SiO2-Al2O3 via precipitation and ZnCrO, V-Mo oxide, Cu-Cr oxides via co-precipitation which are used for reactions like methanol synthesis and selective oxidation. Key factors to consider include choice of base, metal salt, pH, and cation ratio.

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0% found this document useful (0 votes)
115 views

Catalyst Preparation Methods-G1

Precipitation and co-precipitation are commonly used methods to prepare catalysts. Precipitation involves forming a solid catalyst from a supersaturated metal solution. Co-precipitation simultaneously precipitates more than one compound from a solution to form mixed oxide catalysts. Examples of catalysts prepared through these methods include SiO2-Al2O3 via precipitation and ZnCrO, V-Mo oxide, Cu-Cr oxides via co-precipitation which are used for reactions like methanol synthesis and selective oxidation. Key factors to consider include choice of base, metal salt, pH, and cation ratio.

Uploaded by

Ankomah Kwame
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PPTX, PDF, TXT or read online on Scribd
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CATALYST PREPARATION BY

PRECIPITATION AND CO-


PRECIPITATION

GROUP 1
 Process Description
 Type of Catalyst prepared by the
method
OUTLINE  Examples of Catalyst prepared by
the method
 Application of Catalysts prepared
by the method.
 Precipitation is the formation of a
desired solid Catalyst from a
supersaturated metal solution.
PRECIPITATION
 It is a traditional and the most
widely used catalyst preparation
method.
 Usually facile and economic
 Method is however demanding
PRECIPITAT since it requires product separation
TION after precipitation and large
(CONT.D) volumes of salt containing
solutions.
Precipitation method involves 4
main stages;
 Liquid Mixing/ Supersaturation
PROCESS  Nucleation
DESCRIPTIO
N  Crystal growth from primary
products
 Aggregation of the primary
particles
TYPE OF  Precipitation is mostly used in the
PREPARED BY preparation of Bulk and Support
PRECIPITATI catalysts.
ON
EXAMPLE OF CATALYST PROCESS EMPLOYED IN

SiO2-Al2O3 Acid-catalyzed reaction e.g.,


FCC isomerization

EXAMPLES OF
CATLYSTS ZrO2-SO42- Strong acid reaction

PREPARED BY TiO2 A major component of DeNOx


PRECIPITATION catalysts
 It is the simultaneous precipitation
of more than one compound from a
CO-
PRECIPITATI solution.
ON
 Co-precipitation is a method used
for the synthesis of mixed oxide.
catalysts and catalyst precursors are
prepared as precipitates from basic
 Constant pH method
METHODS
FOR CO-
PRECIPITATI  Variable pH method
ON
 Choice of base.

FACTORS TO  Choice of metal salt.


CONSIDER  Choice of pH.
DURING
PREPARATION  Variation of cation ratio.
METHOD
 Ageing.
CATALYST APPLICATION

ZnCrO Conversion of syngas (CO/H2) into methanol and


other chemicals.

EXAMPLES OF V-Mo oxide Selective oxidation of acrolein to acrylic acid

CATLYST Cu-Cr oxides Combustion reactions


PREPARED BY
Ni/Al2O3 for steam reforming,
CO-
PRECIPITATION Cu-ZnO/Al2O3 for methanol Synthesis.

AlPO4 Acid catalysed reactions, polymerisation

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