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D-D Transitions and Selection Rule

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1K views11 pages

D-D Transitions and Selection Rule

Uploaded by

placard.ind
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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D-D TRANSITIONS AND

SELECTION RULE
ROMI SHARMA
3RD YEAR
HOW DOES IT HAPPEN?
• when spilliting of degenerate orbital take place when ligands
approaches these orbitals
• Degenerate orbital splits into two sets.
• The set at higher energy is eg and the set at lower energy is teg.
D-D TRANSITION

•THE ELECTRONS IN TEG ABSORBS


THE REQUIRED ENERGY AND JUMP
FROM THE LOWER ENERGY
ORBITAL TO THE HIGHER ENERGY
SETS.
PRINCIPLE OF D-D TRANSITION
It works on the principle of quantization of energy.
The energy needed for the ground state electrons to jump into the
excited state is fixed.
When white light falls on the metalcomplex
 Some are aborbed .
 Others are transmitted.
D-ORBITAL ENERGIES BY AN
OCTAHEDRAL FIELD OF LIGANDS
D-ORBITAL ENERGIES BY AN
TETRAHEDRAL FIELD OF LIGANDS
SELECTION RULE

It tells about the possible transition of system from one quantum state
to another.
Allowed transition- When electronic. transition occur according to
selection rule.
Forbidden transition - when electronic transition -occur according to
selection rule.
TYPES OF SELECTION RULE

• Spin selection rule


• Laporte selection rule
SPIN SELECTION RULE

Transition may occur only between two energy same spin multiplicity.
LAPORTE SELECTION RULE
A rule that explains the intensities of absorption
spectra for chemical species.
THANKS

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