Borate phosphate
| Identifiers | |
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3D model (JSmol)
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| ChemSpider |
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| Properties | |
| BO7P−6 | |
| Molar mass | 153.78 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Borate phosphates are mixed anion compounds containing separate borate and phosphate anions. They are distinct from the borophosphates where the borate is linked to a phosphate via a common oxygen atom. The borate phosphates have a higher ratio of cations to number of borates and phosphates, as compared to the borophosphates.[1]
There are also organic esters of both borate and phosphate, e.g. NADH-borate.[2]
Production
[edit]In the high temperature method, ingredients are heated together at atmospheric pressure. Products are anhydrous, and production or borophosphates is likely.[3]
The boron flux method involves dissolving ingredients such as an ammonium phosphate and metal carbonate in an excess of molten boric acid.[3]
Use
[edit]Borate phosphates are of research interest for their optical, electrooptical or magnetic properties.[3]
List
[edit]| chem | mw | crystal system | space group | unit cell Å | volume | density | comment | references | |
|---|---|---|---|---|---|---|---|---|---|
| Be3(BO3)(PO4) | hexagonal | SHG | [1][4] | ||||||
| α-Mg3[BPO7] | orthorhombic | Immm | a=8·495, b=4·886, c=12·565 Z=4 | [5] | |||||
| Mg3[BPO7] | monoclinic | Cm | [3] | ||||||
| Mg3[BPO7] | hexagonal | P6_2m | [3] | ||||||
| Lüneburgite | Mg3[B2(OH)6](PO4)2 · 6H2O | triclinic | 2.05 | Biaxial (-) nα = 1.520 – 1.522 nβ = 1.540 – 1.541 nγ = 1.545 – 1.548
2V 52° to 60° Max birefringence δ = 0.025 – 0.026 |
[6][7] | ||||
| Ca3[BPO7] | monoclinic | a=8.602 b=4.891 c=12.806 β=102.30 | [5] | ||||||
| Seamanite | Mn2+3[B(OH)4](PO4)(OH)2 | orthorhombic | Pbnm | a = 7.81 Å, b = 15.11 Å, c = 6.69 Å Z=4 | 789.48 | 3.08 | Biaxial (+) nα = 1.640 nβ = 1.663 nγ = 1.665
2V 40° Max birefringence δ = 0.025 |
[8][9] | |
| Laptevite-(Ce) | Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11 | trigonal | R3m | a = 10.804, c = 27.726 Z=3 | 2802.6 | 4.61 | Uniaxial (-) nω = 1.741 nε = 1.720
Max birefringence δ = 0.021 |
[10] | |
| (CoPO4)4, B5O6(OH)4N(CH3)4(CH3NH3) | 1036.10 | orthorhombic | I222 | a=6.7601 b=7.5422 c=34.822 Z=2 | 1775.4 | 1.938 | red | [11] | |
| Co3[BPO7] | monoclinic | Cm | a=9.774, b=12.688, c=4.9057, β=119.749°; Z=4 | 528.2 | purple | [3] | |||
| α-Zn3[BPO7] | 349.89 | orthorhombic | a=8.438 b=4.884 c=12.558 | [5] | |||||
| α-Zn3[BPO7] | 349.89 | monoclinic | Cm | a=9.725 b=12.720 c=4.874 β=119.80 Z=4 | [3][12] | ||||
| β-Zn3[BPO7] | 349.89 | hexagonal | P-6 | a=8.4624 c=13.0690 Z=6 | 810.51 | 4.301 | colourless | [3][13] | |
| α-Sr3[BPO7] | orthorhombic | a=9.0561, b=9.7984, c=13.9531 | [14] | ||||||
| Sr10[(PO4)5.5(BO4)0.5](BO2) | P3_ | a=9.7973, c=7.3056, Z=1 | 607.29 | [15] | |||||
| SrCo2(BO3)(PO4) | 359.26 | monoclinic | P21/c | a=6.485 b=9.270 c=10.066 β=111.14 Z=4 | 548.7 | 4.349 | red | [1][16] | |
| Byzantievite | Ba5(Ca,REE,Y)22(Ti,Nb)18(SiO4)4[(PO4, SiO4)]4(BO3)9O22[(OH),F]43(H2O)1.5 | trigonal | R3 | a = 9.1202, c = 102.145 | 7,357.9 | 4.10 | Uniaxial (-) nω = 1.940 nε = 1.860
Max birefringence δ = 0.080 16 different layers in structure |
[17][18] | |
| Rhabdoborite | Mg12(V5+,Mo6+,W6+)1 · 5O6{[BO3]6-x[(P,As)O4]xF2-x} (x < 1) | hexagonal | P63 | a = 10.6314, c = 4.5661 | 446.95 | [19] | |||
| CsNa2Y2(BO3)(PO4)2 | 605.46 | orthorhombic | Cmcm | a=6.9491 b=14.907 c=10.6201 Z=4 | 1100.2 | 3.655 | colourless | [20] | |
| CsZn4(BO3)(PO4)2 | 679.30 | orthorhombic | Pbca | a=14.49 b=10.02 c=16.45 Z=8 | 2388 | 3.779 | colourless | [21] | |
| Ba3(BO3)(PO4) | hexagonal | P63mc | a=5.4898, c=14.7551, Z=2 | [1][22] | |||||
| Ba3(BO3)(PO4) | monoclinic | P2/m | a = 11.7947, b = 9.6135, c = 12.9548, β= 111.25° | 1369.08 | [23] | ||||
| Ba11B26O44(PO4)2(OH)6 | monoclinic | P21/c | a=6.891, b=13.629, c=25.851, β=90.04° | [24] | |||||
| Ba3(ZnB5O10)PO4 | 786.41 | orthorhombic | Pnm21 | a = 10.399 b = 7.064 c = 8.204 Z=2 | 602.6 | 4.334 | [25] | ||
| La7O6(BO3)(PO4)2 | monoclinic | a=7.019 b=17.915 c=12.653 β=97.52 | 1577.27 | [1][26] | |||||
| Pr7O6(BO3)(PO4)2 | monoclinic | P121/n1 | a=6.8939 b=17.662 c=12.442 β=97.24 Z=4 | 1502.9 | green | [1][27] | |||
| Nd7O6(BO3)(PO4)2 | monoclinic | a=6.862 b=17.591 c=12.375 β=97.18 | 1482.12 | [1][26] | |||||
| Sm7O6(BO3)(PO4)2 | monoclinic | P121/n1 | a=6.778 b=17.396 c=12.218 β=96.96 Z=4 | 1430.0 | yellow | [1][27] | |||
| CsNa2Sm2(BO3)(PO4)2 | 728.34 | orthorhombic | Cmcm | a=7.0631 b=15.288 c=10.725 Z=4 | 1158.1 | 4.177 | colourless | [28] | |
| CsNa2Ho2(BO3)(PO4)2 | [29] | ||||||||
| CsNa2Er2(BO3)(PO4)2 | [29] | ||||||||
| CsNa2Tm2(BO3)(PO4)2 | [29] | ||||||||
| Gd7O6(BO3)(PO4)2 | monoclinic | a=6.704 b=17.299 c=12.100 β=96.94 | 1393.11 | [1][26] | |||||
| Dy7O6(BO3)(PO4)2 | monoclinic | a=6.623 b=17.172 c=11.960 β=96.76 | 1350.84 | [1][26] | |||||
| K3Yb[OB(OH)2]2[HOPO3]2 | R3_ | a=5.6809, c=36.594 Z=3 | 1022.8 | [1][30] | |||||
| CsNa2Yb2(BO3)(PO4)2 | [29] | ||||||||
| K3Lu[OB(OH)2]2[HOPO3]2 | R3_ | a=5.6668, c=36.692 Z=3 | 1020.4 | [1][30] | |||||
| CsNa2Lu2(BO3)(PO4)2 | 777.58 | orthorhombic | Cmcm | a = 6.8750 b = 14.6919 c = 10.5581 | 1066.44 | 4.843 | |||
| Pb4O(BO3)(PO4) | 998.54 | monoclinic | P21/c | a=10.202 b=7.005 c=12.92 β=113.057 Z=4 | 849.6 | 7.807 | colourless | [31] | |
| LiPb4(BO3)(PO4)2 | 1084.85 | orthorhombic | Pbca | a=12.613 b=6.551 c=25.63 Z=8 | 2095 | 6.875 | colourless | [1] | |
| Bi4O3(BO3)(PO4) | 1037.70 | orthorhombic | Pbca | a=5.536 b=14.10 c=22.62 Z=8 | 1766 | 7.807 | colourless | [31] | |
| Th2[BO4][PO4] | monoclinic | P21/c | a=8.4665, b=7.9552, c=8.2297, β= 103.746° Z = 4 | [32] | |||||
| Ba5[(UO2)(PO4)3(B5O9)]·nH2O | interlocking nanotubes; absorbs water from air | [33] | |||||||
| U2[BO4][PO4] | 645.84 | monoclinic | P21/c | a = 8.546, b = 7.753, c = 8.163 β = 102.52° Z=4 | 528.0 | 8.12 | generated at 12.5 GPa + 1000 °C; emerald green | [34] | |
| [Sr8(PO4)2][(UO2)(PO4)2(B5O9)2] | 1746.97 | monoclinic | P21/n | a = 6.5014, b =22.4302, c =9.7964 β = 90.241° Z=2 | 1428.57 | 4.061 | orange | [35] |
References
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