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Isaac B. Bersuker

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Isaac B. Bersuker
Isaac B. Bersuker in 2008
Isaac B. Bersuker in 2008
Born
Isaac Borukhovich Bersuker

(1928-02-12) February 12, 1928 (age 96)
Chișinău, Kingdom of Romania
NationalityKingdom of Romania
CitizenshipUnited States
Moldova
Alma materMoldova State University (M.Sc.)
Leningrad State University (Ph.D.)
Known forTunneling splitting in polyatomic systems with Jahn–Teller effect and pseudo Jahn–Teller effect
Vibronic theory of ferroelectricity and related properties of cubic perovskites
Theory of core polarization in Rydberg atoms
Quantum chemistry of coordination complexes
Electron-conformational approach to drug design and fragrance activity.
Spouse
Lilia B. Bersuker
​
(m. 1951)​
ChildrenSon: Gennadi B. Bersuker (b. 1953)
AwardsMoldavian SSR State Prize in Science and Technology (1979)
Order of Honour (Moldova) (2004)
The Medal "Scientific Merit", I class (Moldova) (2021)
Scientific career
FieldsChemical Physics and Physical Chemistry, Theoretical Chemistry, Theoretical Physics, Condensed Matter Physics
InstitutionsThe University of Texas at Austin
Academy of Sciences of Moldova

Isaac B. Bersuker (Russian: Исаáк Бóрухович (Бори́сович) Берсýкер; born February 12, 1928) is a Romanian-born Soviet-Moldоvan-American theoretical physicist and quantum chemist whose principal research is in chemical physics, solid-state physics, and theoretical chemistry. Known for his "life-long years of experience in theoretical chemistry"[1] working on the electronic structure and properties of coordination compounds, Isaac B. Bersuker is “one of the most widely recognized authorities”[2] in the theory of the Jahn–Teller effect (JTE) and the pseudo-Jahn–Teller effect (PJTE). His accomplishments include explaining the polarization of the atomic core in Rydberg atoms, the effect of tunneling splitting in molecules and solids with a strong JTE, and the discovery of the PJTE origen of ferroelectricity in cubic perovskites. Known as the leading expert in JTE and PJTE, Bersuker is the permanent chairman of the international steering committee of the Jahn–Teller symposia.[3] His present affiliation is with the Oden Institute for Computational Engineering and Science of the Department of Chemistry of the University of Texas at Austin.

Early life, education, and career

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Isaac (Izya) Bersuker was born on February 12, 1928, in Chișinău, then part of Greater Romania, to a low-income family of Bessarabian Jewish descent. His father Boruch Bersuker was a carpenter, and his mother Bella Bersuker (Russian: Бéлла Хáймовна Берсýкер, 1896–1981) was a housewife with five kids. As a boy in a family of a modest background, Isaac got his elementary school education in Talmud Torah and ORT.  He was 13 years old when the tragic events of World War II forced his Jewish family to run from the Nazis to an Azerbaijan village.[4] Deprived of the traditional middle and high-school education, he spent four years farming in Azerbaijan kolkhoz.[5] However, he never gave up his dream of getting a higher education and becoming an intellectual. After the war, native Romanian, he barely spoke Russian. Yet, in a self-education way, in а two-year term, he managed to complete a four-year high-school program in a Russian school and enrolled at Chișinău State University.[5] In the best meaning of this expression, Isaac is a self-made man.[4] A fascinating autobiographical section in [5] describes "his scientific ascent, starting from a Jewish childhood in Bessarabia and frequently hampered by antisemitic state directives under the Stalin regime."[6] Dedicated to the study of theoretical physics, in 1952, just six years after being an illiterate boy shepherding sheep, Bersuker graduated from this university with a master's degree in physics. He began his scientific research in atomic spectroscopy as a post-graduate student at Leningrad State University, working under Mikhail G. Veselov[7] at the Division of Quantum Mechanics[8] led by its Chair Vladimir A. Fock. Here, in 1957, Bersuker received his doctorate (Kandidat of science, Russian: Кандидáт наýк) and in 1964 his habilitation degree (Doctor of science, Russian: Дóктор наýк). From 1964 to 1993, back in Chișinău, Bersuker continued his scientific research at the Institute of Chemistry[9] of the Moldavian branch of the USSR Academy of Sciences. Organizationally, Bersuker's success was the creation in 1964, and the leadership of the Laboratory of Quantum Chemistry[10] also dubbed ‘‘the Chișinău school of the Jahn–Teller effect.’’[6]  Elected as a Corresponding Member of this academy in 1972 and a full Member[11] in 1989, Isaac B. Bersuker moved to the United States In 1993. He became a senior research scientist and professor of the department of chemistry[12] at the University of Texas at Austin. Isaac B. Bersuker served as a doctoral and habilitation supervisor for 31 post-graduate students and post-docs. According to K. Alex Müller, Bersuker was and still is "in full swing at the university, writing books, discussing with great wit, and quick to understand ‒ as I had known him for well over thirty years."[13] In the late 1980s, owing to Bersuker's high motivating role, leadership, and creative ingenuity, Bersuker's school was called "the capital of the Jahn–Teller effect" by some.[4] Bersuker's academic publications have a high impact on the scientific community. According to Google Scholar,[14] since 1993 when he moved to the United States, Bersuker's papers were cited 10428 times, his h-index is 41, and his i10-index is 141.

Research

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Atomic spectroscopy

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In his Ph.D. thesis, Bersuker developed the theory of core polarization and its effect on optical transitions in Rydberg atoms.[15] At the time, this was a puzzling problem in absorption spectroscopy. The absorption of light by alkali atoms appeared to violate the electric dipole sum rule. According to Bersuker, the solution to the problem is in the instantaneous polarization of the atomic core by the incident electromagnetic wave creating an additional perturbation to the excitation of the valence electron. Related to this problem, he worked out the adiabatic separation of motion of the valence and the atomic core electrons in electronic structure calculations of atoms.[16][17] First introduced in 1957, still, decades later, Bersuker's ideas of electron polarization by the incident electromagnetic wave and of the atomic core polarization by the valence electron is used and further explored in atomic spectroscopy.[18]

Jahn–Teller and pseudo Jahn–Teller effects

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Bersuker's contributions to the JTE and PJTE theory with applications to physical and chemical phenomena are reflected in his several monographs (some of them written and published with the assistance and involvement of other authors) and major reviews on this subject (see the latest in[19][20][21][22][23][24][25]). First published in 1961–1962, his contributions to the theory of the JTE predicted the tunneling splitting of the vibronic energy levels of the systems with the JTE,[26][27] later confirmed experimentally. The splitting is due to the tunneling transitions between the equivalent wells on the multiminimum adiabatic potential energy surface produced by this effect. In 1976, "The phenomenon of tunneling splitting of energy levels of polyatomic systems in the state of electronic degeneracy" was qualified as a scientific discovery and registered in the State Register of the USSR (Diploma No. 202).[28] In addition, Bersuker is known for revealing the significance of the PJTE and showing that it may take place at any energy gaps between entangled electronic states. Most important, he proved that the JTE and PJTE are the only sources of structural instability and spontaneous symmetry breaking (SSB) in polyatomic systems.[19][20][29] Thus, according to Bersuker, if a polyatomic system has broken symmetry properties, undoubtedly, they are of JTE or PJTE origen. This conclusion elevates the two effects from their assumed earlier rare particular features to general tools for exploring molecular and solid-state properties.[19][20][21][22][30][23][25]

The generality of this result was challenged by the existence of some molecular systems with SSB. For example, in the ozone O3 molecule, neither the JTE nor the PJTE is seen explicitly in the high-symmetry configuration. Bersuker eliminated this controversy by revealing the hidden JTE and PJTE.[31] They take place in the excited states of the system but, being strong enough, penetrate the ground state of the high-symmetry configuration and form an additional, coexisting equilibrium state with lower symmetry. The latter may also have a different spin state leading to an interesting phenomenon of spin-crossover and magnetic-dielectric bistability.[32] Involving excited states, Bersuker also showed that the PJTE is instrumental in explaining the origen of chemical activation and sudden polarization in photochemical reactions.[33][34] Revealed by Bersuker, other applications of the JTE and PJTE are briefly mentioned below.

Solid-state problems: ferroelectricity and multiferroicity

[edit]

Another fundamental contribution of Isaac B. Bersuker to the early developments of this field was applying the PJTE to explain the origen of ferroelectricity in perovskite-type crystals.[35] This first application of the PJTE to solve an important solid-state problem led to developing a whole trend in the studies of local and cooperative properties in crystals. The origen of crystals' temperature-controlled spontaneous dielectric polarization was the subject of discussion for many decades involving high-rank physicists at the time. However, with the development of the experimental technics, the "displacive theories" encountered increasing controversies that had no explanation.

Using perovskite crystals as an example, Bersuker showed (first in 1964, published in 1966[35]) that the PJTE produces a spontaneous symmetry breaking resulting under certain conditions in local dipolar instability. It exists in all the crystal phases, and the spontaneous polarization results from the order-disorder interaction between these PJTE-induced local dipolar distortions. Performed in the local octahedral TiO6 center in the BaTiO3 crystal (taken as an example), where vibronic coupling mixes ground 1A1g and close in energy exited 1T1u states of opposite parity (but same multiplicity), detailed analysis with calculations proved the PJTE to produce the dipolar distortion. Thus, it shows that Bersuker's PJTE theory of ferroelectricity agrees with the available empirical data and predicts new properties,[25][36] confirmed experimentally.

From the fact that PJTE does not entangle states with different spin multiplicity, Bersuker deduced conditions and predicted possible multiferroics in some cubic perovskites.[37]  According to Bersuker, only the dn cations with the close-energy ground and excited states of opposite parity, but with the same multiplicity, may meet the necessary conditions of ferroelectricity in the presence of unpaired spins.[37]

Novel solid-state property: orientational polarization

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Under external unipolar perturbations, polar gases and liquids manifest two kinds of polarization, displacive and orientational. The latter is by orders of magnitude larger than the former. So far, solids were known to undergo only displacive polarization. Bersuker showed that in ABO3 type perovskites, dipolar distortions are due to the PJTE.[38][36][39][40] Similar to the other cases of the JTE and PJTE,[35] the adiabatic potential energy surface of the metallic B center has eight equivalent wells positioned along the eight diagonals of the cube, meaning eight symmetry-equivalent positions of the PJTE-induced dipole moment with small barriers between them. As a result, these dipoles can rotate under external perturbations realizing orientational polarization.[39][40] Predicted more than a century ago by P. Debye, solids with intrinsic dipoles behave like polar liquids with orientational polarization. However, enhanced polarizability of such solids was not well understood until Bersuker's works[35][38][39][40] (see also in[25][36]). As shown by Bersuker, experimentally observed giant flexoelectricity, permittivity, and electrostriction result from PJTE-induced orientational polarization.[25][36][39][40]

Molecular puckering (buckling) and its suppression

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Given that the PJTE is the unique source of structural instability, Bersuker applied this idea to planar configurations of some molecules in nondegenerate states. Bersuker was the first to demonstrate that the puckering (or buckling) of planar two-dimensional systems is of PJTE origen.[19][20][21] Hence, following Bersuker, their planarity can be driven by external influence targeting the PJTE parameters.[41] As the starting example, he suggested hemoglobin oxygenation. The out-of-plane displacement of the iron atom was shown to be due to the PJTE. At the same time, the coordination of the oxygen atom violates the condition of the PJTE instability, thus restoring the planar configuration.[42] In a more general setup, such manipulations became more critical recently because of the applications of two-dimensional molecular systems in electronics. According to Bersuker, planarity can be operated by targeted redox perturbations, coordination with other atomic groups, and chemical substitutions.[41] A similar modification of a crystal lattice by redox influencing its local JTE centers was also realized.[43]

Other problems

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There is quite a list of other theoretical chemistry, chemical physics, and quantum chemistry fields with a remarkable Bersuker's contribution. In a number of his seminal papers, Bersuker introduced and developed theoretical models of vibronic mechanisms in redox properties, electron-conformational effects,[44] chemical reactivity, and catalysis.[45][46] He is known for revealing the role of JTE and PJTE in the properties of mixed-valence compounds.[47] In addition, he discovered the effect of coordination covalent bonding and the JTE in the "plasticity effect".[48] Also, Bersuker worked out a quantum mechanics/molecular mechanics method of electronic structure calculations of large organometallic systems when there is charge transfer between the QM and MM parts.[49] The name of Bersuker is associated with the semiempirical approach to relativistic electronic structure calculations[50][51] and a method of estimating molecular-orbital parameters from Mossbauer spectra.[52][53] In another series of publications, he created and applied the electron-conformational method to computer-aided drug design and toxicology.[54][55][56] Within this methodology, the chemical origen of odorant activity was also revealed, including the source of musk odor.[57]

Selected books

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Isaac B. Bersuker wrote 15 books, first in 1962, and more than 400 academic papers.[14][58][59][60][61] His books on the JTE and PJTE, published in 1984,[62] 1989,[20] and 2006,[19] were most influential.[63][64][6][65][66] According to Google Scholar,[14] cumulatively, these three monographs were cited more than 3000 times.

  • Bersuker I. B. and Ablov A. V., (1962) Chemical Bonds in Complex Compounds, [in Russian], AN MoldavSSR, Chișinău, 208 p., ASIN: B072L33R79
  • Bersuker I. B. (1971) ''Structure and Properties of Coordination Compounds'' [in Russian], Khimia, Leningrad, ASIN: B0725HWXD4
  • Bersuker I. B., (1984) ''The Jahn–Teller Effect and Vibronic Interactions in Modern Chemistry'', Plenum, New York, 320 p., ISBN 978-1-4612-9654-6
  • Bersuker I. B. and Polinger V. Z. (1989), Vibronic Interactions in Molecules and Crystals, Springer-Verlag, Berlin-Heidelberg-New York, ISBN 978-3-642-83481-3
  • Bersuker I. B. (2006), The Jahn–Teller Effect, Cambridge University Press, Cambridge (UK), 2006; ISBN 978-0-521-82212-1
  • Bersuker I. B. (2010). Electronic Structure and Properties of Transition Metal Compounds: Introduction to the theory (2nd ed.), Wiley, Hoboken, NJ, 759 p., ISBN 978-0470180235

Awards and honors

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Personal life

[edit]

Isaac B. Bersuker was married in 1951 to Liliya Bersuker (Russian: Ли́лия Бори́совна Берсýкер, 1930–2003), a chemist. He has one son, Gennadi B. Bersuker[67] (born 1953), a theoretical physicist, and two grandsons, Eugene G. Bersuker (born 1979) and Kirill G. Bersuker[68] (born 1985), a molecular biologist.

See also

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References

[edit]
Wikimedia Commons has media related to Isaac B. Bersuker.
  1. ^ Lever, A. B. P. (1999-05-01). "Electronic Structure and Properties of Transition Metal Compounds: Introduction to the Theory By Isaac B. Bersuker (The University of Texas at Austin). John Wiley: New York. 1996. ISBN 0-471-13079-6". Journal of the American Chemical Society. 121 (18): 4544. doi:10.1021/ja975564q. ISSN 0002-7863.
  2. ^ Kaplan, Michael D. (2006-08-01). "The Jahn−Teller Effect By Isaac B. Bersuker (University of Texas at Austin). Cambridge University Press: Cambridge. 2006. xvi + 616 pp. $185.00. ISBN 0-521-82212-2". Journal of the American Chemical Society. 128 (32): 10631–10632. doi:10.1021/ja069734n. ISSN 0002-7863.
  3. ^ "Fullerene Theory - University of Nottingham". www.nottingham.ac.uk. Retrieved 2021-12-23.
  4. ^ a b c Borshch, Serguei; Polinger, Victor (2003). "Anniversary Isaac Bersuker 75". In Ceulemans, Arnout; et al. (eds.). Advances in Quantum Chemistry. Manifestations of Vibronic Coupling in Chemistry and Physics. Vol. 44. San Diego, CA: Elsevier Ltd. pp. xxxiii–xxxv. doi:10.1016/S0065-3276(03)44048-3. ISBN 978-0-12-034844-2.
  5. ^ a b c Boggs, James E.; Polinger, Victor Z., eds. (2008). The Jahn–Teller Effect and Beyond. Selected works of Isaac Bersuker with Commentaries. Chișinău, Moldova: The Acad. of Sciences of Moldova and The University of Texas at Austin (published December 17, 2008). pp. 10–31. ISBN 978-9975-62-212-7.
  6. ^ a b c Englman, Robert (2009-04-01). "Book Review". Structural Chemistry. 20 (2): 351–353. doi:10.1007/s11224-009-9438-8. ISSN 1572-9001. S2CID 195068521.
  7. ^ Veselov, M. G. "Division of Quantum Mechanics". fock.phys.spbu.ru. Retrieved 2021-12-23.
  8. ^ "Division of Quantum Mechanics". fock.phys.spbu.ru. Retrieved 2021-12-23.
  9. ^ "Home | Institute of Chemistry". ichem.md. Retrieved 2021-12-23.
  10. ^ "Laboratory Physical and Quantum Chemistry | Institute of Chemistry". www.ichem.md. Retrieved 2021-12-23.
  11. ^ "Academia de Științe a Moldovei". www.asm.md. Retrieved 2021-12-23.
  12. ^ "Department of Chemistry, University of Texas at Austin". cm.utexas.edu. Retrieved 2021-12-23.
  13. ^ Müller, K. Alex (2003). "Encounters with Isaac Bersuker". In Ceulemans, Arnout; et al. (eds.). Advances in Quantum Chemistry. Manifestations of Vibronic Coupling in Chemistry and Physics. Vol. 44. San Diego, CA: Elsevier Science. pp. xxxv–xxxvi. ISBN 0-12-034844-6.
  14. ^ a b c "Bersuker I. B." Google Scholar.
  15. ^ Bersuker, I. B. (1957-03-01). "On the total summation rule for oscillator strengths of alkali metals". Soviet Phys. (Doklady). 2: 167–169. ISSN 0038-5689. OCLC 1023153322. OSTI 4331475 – via ISBN 978-9975-62-212-7, pp.57-59.
  16. ^ Veselov, M. G.; Bersuker, I. B. (1958). "Adiabatic approximation in quantum theory of atoms". Izvestija Akademii Nauk SSSR. Ser. Fizicheskaia (in Russian). 22 (6): 662–663. Bibcode:1958IzSSR..22..662V.
  17. ^ Veselov, M. G.; Bersuker, I. B. (1962). "Calculation of the lithium atom in the adiabatic approximation and computation of its nuclear magnetic moment". Opt. Spectr. (USSR) (English Transl.). 13 (3): 167–169. Bibcode:1962OptSp..13..167V. ISSN 0030-4034. OSTI 4719250.
  18. ^ Hansen, Jørgen E.; Laughlin, Cecil; Hart, Hugo W. van der; Verbockhaven, Gilles (1999). "Energy levels, wavefunction compositions and electric dipole transitions in neutral Ca". Journal of Physics B: Atomic, Molecular and Optical Physics. 32 (9): 2099–2137. Bibcode:1999JPhB...32.2099H. doi:10.1088/0953-4075/32/9/305. ISSN 0953-4075. S2CID 250830221.
  19. ^ a b c d e Bersuker, Isaac B. (2006). The Jahn–Teller Effect. Cambridge, UK: Cambridge University Press. doi:10.1017/CBO9780511524769. ISBN 978-0-521-82212-1.
  20. ^ a b c d e Bersuker, Isaac B.; Polinger, Victor Z. (1989). Vibronic Interactions in Molecules and Crystals. Springer Series in Chemical Physics. Vol. 49. Berlin, Heidelberg: Springer-Verlag. doi:10.1007/978-3-642-83479-0. hdl:10821/3407. ISBN 978-3-540-19259-6. ISSN 0172-6218.
  21. ^ a b c Bersuker, Isaac B. (2021). "Jahn–Teller and Pseudo-Jahn–Teller Effects: From Particular Features to General Tools in Exploring Molecular and Solid State Properties". Chemical Reviews. 121 (3): 1463–1512. doi:10.1021/acs.chemrev.0c00718. ISSN 0009-2665. PMID 33353296. S2CID 229690173.
  22. ^ a b Bersuker, Isaac B. (2016). "Spontaneous Symmetry Breaking in Matter Induced by Degeneracies and Pseudodegeneracies". In Rice, Stuart A.; Dinner, Aaron R. (eds.). Advances in Chemical Physics. Vol. 160. John Wiley & Sons, Inc. pp. 159–208. doi:10.1002/9781119165156.ch3. ISBN 978-1-119-16515-6. ISSN 1934-4791.
  23. ^ a b Bersuker, I. B. (2017). "The Jahn–Teller and pseudo Jahn–Teller effect in materials science". Journal of Physics: Conference Series. 833 (1): 012001. Bibcode:2017JPhCS.833a2001B. doi:10.1088/1742-6596/833/1/012001. ISSN 1742-6596. S2CID 136171872.
  24. ^ Bersuker, Isaac B. (2013-03-13). "Pseudo-Jahn–Teller Effect—A Two-State Paradigm in Formation, Deformation, and Transformation of Molecular Systems and Solids". Chemical Reviews. 113 (3): 1351–1390. doi:10.1021/cr300279n. ISSN 0009-2665. PMID 23301718.
  25. ^ a b c d e Bersuker, I. B. (2018-11-18). "Vibronic (pseudo Jahn–Teller) theory of ferroelectricity: Novel aspects and applications". Ferroelectrics. 536 (1): 1–59. Bibcode:2018Fer...536....1B. doi:10.1080/00150193.2018.1528919. ISSN 0015-0193. S2CID 126940116.
  26. ^ Bersuker, I. B. (1963). "Inversion splitting of levels in free complexes of transition metals" (PDF). Soviet Physics JETP. 16 (4): 933–938. Bibcode:1963JETP...16..933B. ISSN 0038-5646. OCLC 1128379287.
  27. ^ Bersuker, I. B.; Vekhter, B. J.; Ogurtsov, I. Ya. (1975). "Tunnel effects in polyatomic systems with electronic degeneracy and pseudodegeneracy". Sov. Phys. Usp. 18 (8): 569–587. doi:10.1070/PU1975v018n08ABEH004913. ISSN 0038-5670. OCLC 960772943.
  28. ^ "Discovery: The phenomenon of tunneling splitting of energy levels of polyatomic systems in the state of electronic degeneracy (Author: Academician, Professor Isaac Bersuker)".
  29. ^ Bersuker, Isaac B.; Gorinchoi, Natalia N.; Polinger, Victor Z. (1984-05-01). "On the origen of dynamic instability of molecular systems". Theoretica Chimica Acta. 66 (3): 161–172. doi:10.1007/BF00549666. ISSN 1432-2234. S2CID 98728524.
  30. ^ Bersuker, I. B. (2010). Electronic structure and properties of transition metal compounds : introduction to the theory (Second ed.). Hoboken, N.J.: Wiley. ISBN 978-0-470-57305-1. OCLC 632158142.
  31. ^ Bersuker, Isaac B. (2009), Köppel, Horst; Yarkony, David R.; Barentzen, Heinz (eds.), "Recent Developments in the Jahn–Teller Effect Theory: The Hidden Jahn–Teller Effect", The Jahn–Teller Effect: Fundamentals and Implications for Physics and Chemistry, Springer Series in Chemical Physics, vol. 97, Berlin, Heidelberg: Springer, pp. 3–23, doi:10.1007/978-3-642-03432-9_1, ISBN 978-3-642-03432-9, retrieved 2021-12-14
  32. ^ Bersuker, Isaac B. (2020). "Spin Crossover and Magnetic-Dielectric Bistability Induced by Hidden Pseudo-Jahn–Teller Effect". Magnetochemistry. 6 (4): 64. doi:10.3390/magnetochemistry6040064.
  33. ^ BERSUKER, I. B. (1980). "Are activated complexes of chemical reactions experimentally observable ones?". Nouv. J. Chim. 4 (3). Cambridge: Royal Society of Chemistry: 139–145. ISSN 0398-9836. https://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=PASCAL8060250194.
  34. ^ Wang, Ya; Liu, Yang; Bersuker, Isaac B. (2019-05-22). "Sudden polarization and zwitterion formation as a pseudo-Jahn–Teller effect: a new insight into the photochemistry of alkenes". Physical Chemistry Chemical Physics. 21 (20): 10677–10692. Bibcode:2019PCCP...2110677W. doi:10.1039/C9CP01023H. ISSN 1463-9084. PMID 31086864. S2CID 149779106.
  35. ^ a b c d Bersuker, I. B. (1966-04-01). "On the origen of ferroelectricity in perovskite-type crystals". Physics Letters. 20 (6): 589–590. Bibcode:1966PhL....20..589B. doi:10.1016/0031-9163(66)91127-9. ISSN 0031-9163.
  36. ^ a b c d Bersuker, Isaac B.; Polinger, Victor (2020). "Perovskite Crystals: Unique Pseudo-Jahn–Teller Origin of Ferroelectricity, Multiferroicity, Permittivity, Flexoelectricity, and Polar Nanoregions". Condensed Matter. 5 (4): 68. Bibcode:2020CondM...5...68B. doi:10.3390/condmat5040068.
  37. ^ a b Garcia-Fernandez, Pablo; Bersuker, Isaac B. (2011-06-17). "Class of Molecular and Solid State Systems with Correlated Magnetic and Dielectric Bistabilities Induced by the Pseudo Jahn–Teller Effect". Physical Review Letters. 106 (24): 246406. Bibcode:2011PhRvL.106x6406G. doi:10.1103/PhysRevLett.106.246406. hdl:10902/26489. PMID 21770587.
  38. ^ a b Bersuker, I.B. (1966-04-01). "On the origen of ferroelectricity in perovskite-type crystals". Physics Letters. 20 (6): 589–590. Bibcode:1966PhL....20..589B. doi:10.1016/0031-9163(66)91127-9. ISSN 0031-9163.
  39. ^ a b c d Bersuker, I. B. (2015-01-12). "Pseudo Jahn–Teller effect in the origen of enhanced flexoelectricity". Applied Physics Letters. 106 (2): 022903. Bibcode:2015ApPhL.106b2903B. doi:10.1063/1.4905679. hdl:2152/31050. ISSN 0003-6951. S2CID 119788341.
  40. ^ a b c d Bersuker, Isaac B. (2015-11-16). "Giant permittivity and electrostriction induced by dynamic Jahn–Teller and pseudo Jahn–Teller effects". Applied Physics Letters. 107 (20): 202904. Bibcode:2015ApPhL.107t2904B. doi:10.1063/1.4936190. ISSN 0003-6951.
  41. ^ a b Bersuker, I. B. (2017). "Manipulation of structure and properties of two-dimensional systems employing the pseudo Jahn–Teller effect". FlatChem. 6: 11–27. doi:10.1016/j.flatc.2017.10.001. ISSN 2452-2627.
  42. ^ Bersuker, I. B.; Stavrov, S. S. (1988). "Structure and properties of metalloporphyrins and hemoproteins: the vibronic approach". Coordination Chemistry Reviews. 88: 1–68. doi:10.1016/0010-8545(88)80001-8. ISSN 0010-8545.
  43. ^ Gudkov, V. V.; Sarychev, M. N.; Zherlitsyn, S.; Zhevstovskikh, I. V.; Averkiev, N. S.; Vinnik, D. A.; Gudkova, S. A.; Niewa, R.; Dressel, M.; Alyabyeva, L. N.; Gorshunov, B. P. (2020). "Sub-lattice of Jahn–Teller centers in hexaferrite crystal". Scientific Reports. 10 (1): 7076. Bibcode:2020NatSR..10.7076G. doi:10.1038/s41598-020-63915-7. ISSN 2045-2322. PMC 7184747. PMID 32341430.
  44. ^ Bersuker, Isaac B. (2010). "Electron Transfer, Redox Properties, and Electron-Conformational Effects". Electronic Structure and Properties of Transition Metal Compounds: Introduction to the Theory (2-nd ed.). Hoboken, NJ: John Wiley & Sons, Inc. pp. 579–622. ISBN 978-0-470-18023-5. {{cite book}}: |work= ignored (help)
  45. ^ Bersuker, I. B. (1984). "Activation Mechanisms in Chemical Reactions and Catalysis". The Jahn–Teller Effect and Vibronic Interactions in Modern Chemistry. New York: Plenum Press. pp. 251–290. ISBN 978-0-306-41319-3. {{cite book}}: |work= ignored (help)
  46. ^ Bersuker, Isaac B. (2010). "Reactivity and Catalytic Action.". Electronic Structure and Properties of Transition Metal Compounds: Introduction to the Theory (2-nd ed.). Hoboken, NJ: John Wiley & Sons, Inc. pp. 623–691. ISBN 978-0-470-18023-5. {{cite book}}: |work= ignored (help)
  47. ^ Bersuker, I. B; Borshch, S. A. (1992). "Vibronic interactions in polynuclear mixed-valence clusters". Adv. Chem. Phys. Advances in Chemical Physics. 81: 703–782. doi:10.1002/9780470141380.ch6. ISBN 978-0-471-54570-5. ISSN 0065-2385.
  48. ^ Gazo, J.; Bersuker, I. B.; Garaj, J.; Kabesova, M.; Kohout, J.; Langfelderova, H.; Melnik, M.; Serator, M.; Valach, F. (1976). "Plasticity of the coordination sphere of copper(II) complexes, its manifestation and causes". Coordination Chemistry Reviews. 19 (3): 253–297. doi:10.1016/S0010-8545(00)80317-3. ISSN 0010-8545.
  49. ^ Bersuker, Isaac B. (2001-08-01), "Methods of Combined Quantum/Classical (QM/MM) Modeling for Large Organometallic and Metallobiochemical Systems", Computational Chemistry: Reviews of Current Trends, vol. 6, WORLD SCIENTIFIC, pp. 69–135, doi:10.1142/9789812799937_0003, ISBN 978-981-02-4660-0, retrieved 2021-09-20
  50. ^ Bersuker, I. B.; Budnikov, S. S.; Leizerov, B. A. (1972). "Quasi-relativistic approximation in the SCF-MO-LCAO method". International Journal of Quantum Chemistry. 6 (5): 849–858. doi:10.1002/qua.560060505. ISSN 1097-461X.
  51. ^ Bersuker, I. B.; Budnikov, S. S.; Leizerov, B. A. (1977). "Semi-quantitative and semi-empirical versions in the quasi-relativistic SCF-MO-LCAO methods: Numerical calculations for (PtCl6)2−". International Journal of Quantum Chemistry. 11 (4): 543–559. doi:10.1002/qua.560110403. ISSN 1097-461X.
  52. ^ Ablov, A. V.; Bersuker, I. B.; Gol'danskii, V. I. (1964) [October 21, 1963]. "Interpretation of the resonance absorption of gamma-quanta by a number of complex iron compounds on taking into account the covalency of the bond and inductive effects". Doklady Physical Chemistry: Proceedings of the Academy of Sciences of the USSR, Physical Chemistry Sections. 152 (1–6): 934–937. ISSN 0012-5016.
  53. ^ Bersuker, I. B. (1967). "Derivation of molecular-orbital parameters from Mossbauer spectra". Theoretical and Experimental Chemistry. 1 (5): 450–452. doi:10.1007/BF00525389. ISSN 1573-935X. S2CID 93989324.
  54. ^ Bersuker, I. B.; Dimoglo, A. S. (1991), "The Electron-Topological Approach to the QSAR Problem", Reviews in Computational Chemistry, John Wiley & Sons, Ltd, pp. 423–460, doi:10.1002/9780470125793.ch10, ISBN 978-0-470-12579-3, retrieved 2021-09-20
  55. ^ Bersuker, I. B. (2003). "Pharmacophore Identification and Quantitative Bioactivity Prediction Using the Electron-Conformational Method". Current Pharmaceutical Design (Review). 9 (20). Bentham Science: 1575–1606. doi:10.2174/1381612033454586. eISSN 1873-4286. ISSN 1381-6128. PMID 12871060.
  56. ^ Bersuker, Isaac B. (2008). "QSAR without arbitrary descriptors: the electron-conformational method". Journal of Computer-Aided Molecular Design. 22 (6): 423–430. Bibcode:2008JCAMD..22..423B. doi:10.1007/s10822-008-9191-x. ISSN 1573-4951. PMID 18283420. S2CID 7037356.
  57. ^ Bersuker, I. B; Dimoglo, A. S.; Gorbachov, M. Y.; Vlad, P. F.; Pesaro, M. (1987). "Origin of musk fragrance activity: the electron-topologic approach". New Journal of Chemistry. 15 (5). CNRS, Paris/Roy. Soc. Chem., Cambridge: 307–320. ISSN 1144-0546.
  58. ^ "Bersuker Isaac B." Scopus. Elsevier.
  59. ^ "Bersuker Isaac B". Academia.
  60. ^ "Isaac B Bersuker". ResearchGate.
  61. ^ "Bersuker, Isaak Boruhovich". Math-Net.Ru.
  62. ^ Bersuker, I. B. (1984). The Jahn–Teller effect and vibronic interactions in modern chemistry. New York: Plenum Press. ISBN 0-306-41319-1. OCLC 9829216.
  63. ^ Profeta, S. Jr.; Eckhardt, Craig (1991). "Bersuker and Polinger Book Explores Role of Vibronic Coupling in Molecules and Crystals". Chem. Des. Autom. News. 6 (11): 20–23.
  64. ^ Schmidtke, H.-H. (1990). "I. B. Bersuker, V. Z. Polinger: Vibronic Interactions in Molecules and Crystals, Vol. 49 aus: Springer Series in Chemical Physics. Springer-Verlag Berlin, Heidelberg, New York, London, Paris, Tokyo 1989. 422 Seiten, Preis: DM 178,—". Berichte der Bunsengesellschaft für physikalische Chemie. 94 (8): 896–897. doi:10.1002/bbpc.19900940819. ISSN 0005-9021.
  65. ^ Borshch, Serguei A. (2006). "The Jahn–Teller Effect. By Isaac B. Bersuker". ChemPhysChem. 7 (11): 2434–2435. doi:10.1002/cphc.200600417. ISSN 1439-7641.
  66. ^ Tsukerblat, Boris (2006). "The Jahn–Teller Effect. Von Isaac B. Bersuker". Angewandte Chemie. 118 (48): 8268–8269. Bibcode:2006AngCh.118.8268T. doi:10.1002/ange.200685413. ISSN 1521-3757.
  67. ^ Bersuker, Gennadi I. "Scopus preview - Bersuker, Gernnadi I. - Author details - Scopus". www.scopus.com. Retrieved 2021-12-23.
  68. ^ Bersuker, Kirill G. "Calico Life Sciences".
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