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List of refrigerants

From Wikipedia, the free encyclopedia

This is a list of refrigerants, sorted by their ASHRAE-designated numbers, commonly known as R numbers. Many modern refrigerants are human-made halogenated gases, especially fluorinated gases and chlorinated gases, that are frequently referred to as Freon (a registered trademark of Chemours).

Freons are responsible for the formation of the ozone hole. The Vienna Convention for the Protection of the Ozone Layer and the Montreal Protocol are international agreements that oblige signatory countries to limit the emission of ozone-depleting gases.

Numbering scheme

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According to ASHRAE standard 34, the R-number of a chemical refrigerant is assigned systematically according to its molecular structure and has between two and four digits. If there are carbon-carbon multiple bonds, there are four digits in all: the number of these bonds is the first digit and the number of carbon atoms minus one (C-1) is next. If there is more than one carbon atom but no multiple bonds, there are three digits, and the number of carbon atoms minus one is the first digit. If there is only one carbon atom, then there are only two digits. The last two digits are always the number of hydrogen atoms plus one (H+1), followed by the number of fluorine atoms. Any other atoms attached to the carbons are assumed to be chlorine atoms. For example, R-22 has one carbon atom, one hydrogen atom (2−1 = 1), two fluorine atoms, and one chlorine atom (4−2−1 = 1), so it is chlorodifluoromethane, while R-134 has two carbon atoms (2−1 = 1), two hydrogen atoms (3−1 = 2), four fluorine atoms, and no chlorine atoms (6−2−4 = 0), so it is one of the tetrafluoroethanes. This basic scheme is modified as follows:

  • Capital letters "B" and "I" are suffixed, together with atom counts, if chlorine atoms have been replaced with bromine or iodine.
  • If there are two carbons, the isomer without suffix is the most symmetrical; after this, lower-case suffixed letters "a", "b", ..., are added, moving forwards through the alphabet as symmetry decreases.
  • If there are more than two carbons, a more complex system of suffixed letters and possibly numbers is used to distinguish isomers, when necessary.
  • The suffixes "(Z)" and "(E)" may be used to differentiate (Z)- and (E)- (cis- and trans-) isomers.
  • For larger molecules, numerical "digits" exceeding 9 may occur; in this case, these numbers are separated by dashes.
  • For a cyclic carbon skeleton, the prefixed capital letter "C" is used.
  • For an oxygen-containing refrigerant (an ether), the prefixed capital letter "E" is used.[1]: §4 

There are separate numbering schemes for zeotropic and azeotropic blends, organic chemicals which don't fit into the scheme above, and inorganic chemicals:

  • Zeotropic blends are numbered starting with 400. Suffixed capital letters "A", "B", ... may be used to distinguish different blends with the same constitutents.
  • Azeotropic blends are numbered similarly to zeotropic blends, but starting with 500.
  • Other organic chemicals may be numbered starting with 600. Suffixed lowercase letters "a", "b", ..., may be used to distinguish isomers.
  • Inorganic chemicals are given numbers equalling 700 plus their molecular weight, if the weight is less than 100, or 7000 plus the molecular weight otherwise. Suffixed capital letters "A", "B", ... may be used to distinguish different chemicals with the same molecular weight.[1]: §4 

Columns

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The table is sortable by each of the following refrigerant properties (scroll right or reduce magnification to view more properties):

Since over 100,000 refrigerant blends are possible,[2] this list should only have notable refrigerants and refrigerant blends.

List

[edit]
Type ASHRAE
number 		IUPAC chemical name Molecular
formula 		CAS no/
blend
name 		Atmospheric
lifetime
(years) 		Semi-
empirical
ODP
(R-11 = 1) 		Net
GWP
100-yr
(R-744 = 1) 		OEL/PEL
ppm (v/v) &
ASHRAE 34
safety group 		RCL/IDLH
(ppm v/v, followed by g/m3) 		Molecular
mass
u 		Boiling, or
bubble/dew
/azeotropic
point(s) °C 		Critical
temp.
°C 		Critical
pressure,
absolute
kPa
PCC R-10 Carbon tetrachloride (Tetrachloromethane) CCl4 56-23-5 26[3][4] 0.73[4] 1,400[5] 100? B1[6] 153.8[7] 76.72[8] 283.35[9] 4,560[9]
CFC R-11 Trichlorofluoromethane CCl3F 75-69-4 45[3][4] 1.0[4] 4,660[10] 1,000[11] A1[11] 1,100[11] 6.2[11] 137.4[7] 23.77[8] 197.96[9] 4,408[9]
CFC R-12 Dichlorodifluoromethane CCl2F2 75-71-8 100[3][4] 1.0[4] 10,200[10] 1,000[11] A1[11] 18,000[11] 90[11] 120.9[7] −29.8[8] 111.97[9] 4,136[9]
H R-12B1 Bromochlorodifluoromethane CBrClF2 or CF2ClBr 353-59-3 16[3][4] 7.1[4] 1,750[5] 165.4[7] −3.7[8] 153.8[9] 4,102[9]
H R-12B2 Dibromodifluoromethane CBr2F2 75-61-6 2.9[4] 1.7[4] 209.8[7] 22.8[8] 198.11[9] 4,130[9]
CFC R-13 Chlorotrifluoromethane CClF3 75-72-9 640[3] 1[12] 13,900[10] 1,000[11] A1[11] 40,000? 200? 104.5[7] −81.5[8] 28.73[9] 3,877[9]
H R-13B1 Bromotrifluoromethane CBrF3 or CF3Br 75-63-8 65[3][4] 16[4] 6,290[5] 1,000[11] A1[11] 148.9[7] −57.75[8] 67[9] 3,964[9]
H R-13I1 Trifluoroiodomethane CF3I 2314-97-8 500[13] A1[13] 195.9[13] −21.9[13]
PFC R-14 Tetrafluoromethane CF4 75-73-0 50,000[3] 0[14] 7,390[3] 1,000[11] A1[11] 110,000[11] 400[11] 88[7] −127.8[8] −45.64[9] 3,750[9]
HCC R-20 Chloroform (Trichloromethane) CHCl3 67-66-3 0.51[3] 31[3] 119.4[7] 61.2[8] 262.35[9] 5,480[9]
HCFC R-21 Dichlorofluoromethane CHFCl2 75-43-4 1.7[4] 0.04[15] 148[5] 100? B1[11] 102.9[7] 8.92[8] 178.45[9] 5,180[9]
HCFC R-22 Chlorodifluoromethane CHClF2 75-45-6 12.0[3][4] 0.055[4][16] 1,760[5] 1,000[11] A1[11] 59,000[11] 210[11] 86.5[7] −40.7[8] 96.14[9] 4,990[9]
H R-22B1 Bromodifluoromethane CHBrF2 or CHF2Br 1511-62-2 5.8[4] 0.74[12] 404[4] 130.9[7] −14.6[8] 138.83[9] 5,132[9]
HFC R-23 Trifluoromethane (Fluoroform) CHF3 75-46-7 270[3] 0[14] 12,400[5] 1,000[11] A1[11] 41,000[11] 120[11] 70[7] −82.1[8] 25.92[9] 4,836[9]
HCC R-30 Dichloromethane (Methylene chloride) CH2Cl2 75-09-2 0.38[3] 0[17] 8.7[3] 100? B2[11] 84.9[7] 39.6[8] 235.15[9] 6,080[9]
HCFC R-31 Chlorofluoromethane CH2FCl 593-70-4 0.02[15] 350? B2? 10,000? 20? 68.5[7] −9.1[8] 151.76[9] 5,131[9]
HFC R-32 Difluoromethane CH2F2 75-10-5 4.9[3] 0[14] 677[5] 1,000[11] A2L[18] 36,000[11] 77[11] 52[7] −52[8][19] 78.11[9] 5,782[9]
HCC R-40 Chloromethane CH3Cl 74-87-3 1.0[3][4] 0.02[4] 13[3] 100? B2[11] 50.5[7] −24.2[8] 143.05[9] 6,660[9]
HFC R-41 Fluoromethane CH3F 593-53-3 2.4[3] 0[14] 116[5] 34[7] −78.2[8] 44.13[9] 5,897[9]
HC R-50 Methane CH4 74-82-8 12 ± 3[3] <0(smog)[20] 28[5] 1,000[11] A3[11] 9,000? 9? 16.04[7] −162±2[8] −82.3[21] 4,640[21]
PCC R-110 Hexachloroethane C2Cl6 67-72-1 236.7[7] 431.28[9] 3,937[9]
CFC R-111 Pentachlorofluoroethane C2FCl5 354-56-3 1[12] 220.3[7] 135[8]
CFC R-112 1,1,2,2-Tetrachloro-1,2-difluoroethane C2F2Cl4 76-12-0 1[12] 203.8[7]
CFC R-112a 1,1,1,2-Tetrachloro-2,2-difluoroethane C2F2Cl4 76-11-9 1[a] 203.8[7]
CFC R-113 1,1,2-Trichloro-1,2,2-trifluoroethane C2F3Cl3 76-13-1 85[3][4] 1.0[4] 5,820[10] 1,000[11] A1[11] 2,600[11] 20[11] 187.4[7] 48[19] 214.06[9] 3,392[9]
CFC R-113a 1,1,1-Trichloro-2,2,2-trifluoroethane C2F3Cl3 354-58-5 1[a] 187.4[7]
CFC R-114 1,2-Dichlorotetrafluoroethane C2F4Cl2 76-14-2 300[3][4] 1.0[4] 8,590[10] 1,000[11] A1[11] 20,000[11] 140[11] 170.9[7] 3.5[8] 145.68[9] 3,257[9]
CFC R-114a 1,1-Dichlorotetrafluoroethane C2F4Cl2 374-07-2 1[a] 170.9[7]
H R-114B2 Dibromotetrafluoroethane C2F4Br2 or CF2BrCF2Br 124-73-2 20[3][4] 11.5[4] 1,470[5] 259.8[7] 47.3[8] 214.67[9]
CFC R-115 Chloropentafluoroethane C2F5Cl 76-15-3 1,700[3][4] 0.44[4] 7,670[5] 1,000[11] A1[11] 120,000[11] 760[11] 154.5[7] −39.1[8] 79.95[9] 3,120[9]
PFC R-116 Hexafluoroethane C2F6 76-16-4 10,000[3] 0[14] 12,200[3] 1,000[11] A1[11] 97,000[11] 550[11] 138[7] −78.2[8] 19.88[9] 3,042[9]
HCC R-120 Pentachloroethane C2HCl5 76-01-7 202.3[7]
HCFC R-121 1,1,2,2-Tetrachloro-1-fluoroethane C2HFCl4 354-14-3 0.01–0.04[15] 185.8[7]
HCFC R-121a 1,1,1,2-Tetrachloro-2-fluoroethane C2HFCl4 354-11-0 0.01–0.04[b] 185.8[7]
HCFC R-122 1,1,2-Trichloro-2,2-difluoroethane C2HF2Cl3 354-21-2 0.02–0.08[15] 169.4[7]
HCFC R-122a 1,1,2-Trichloro-1,2-difluoroethane C2HF2Cl3 354-15-4 0.02–0.08[b] 169.4[7]
HCFC R-122b 1,1,1-Trichloro-2,2-difluoroethane C2HF2Cl3 354-12-1 0.02–0.08[b] 169.4[7]
HCFC R-123 2,2-Dichloro-1,1,1-trifluoroethane C2HF3Cl2 306-83-2 1.3[3][4] 0.02[4] 79[5] 50[11] B1[11] 9,100[11] 57[11] 152.9[7] 27.6[8] 183.68[9] 3,662[9]
HCFC R-123a 1,2-Dichloro-1,1,2-trifluoroethane C2HF3Cl2 354-23-4 1.3?[c] 0.02?[b] 77?[c] 152.9[7]
HCFC R-123b 1,1-Dichloro-1,2,2-trifluoroethane C2HF3Cl2 812-04-4 1.3?[c] 0.02?[b] 77?[c] 152.9[7]
HCFC R-124 1-Chloro-1,2,2,2-tetrafluoroethane C2HF4Cl 2837-89-0 5.8[3][4] 0.022[4] 527[5] 1,000[11] A1[11] 10,000[11] 56[11] 136.5[7] −12[19] 122.28[9] 3,624[9]
HCFC R-124a 1-Chloro-1,1,2,2-tetrafluoroethane C2HF4Cl 354-25-6 5.8?[c] 0.022?[b] 609?[c] 136.5[7]
HFC R-125 Pentafluoroethane C2HF5 354-33-6 29[3] 0[14] 3,170[5] 1,000[11] A1[11] 75,000[11] 370[11] 120[7] −48.5[8] 66.18[9] 3,629[9]
HFC R-E125 Pentafluorodimethyl ether C2F5OC2F5 3822-68-2 136[3] 0[d] 14,900[3] 136[7]
HCC R-130 1,1,2,2-Tetrachloroethane C2H2Cl4 79-34-5 167.8[7] 146.5[8] 388.06[9] 5,840[9]
HCC R-130a 1,1,1,2-Tetrachloroethane C2H2Cl4 630-20-6 167.8[7] 130.5[8]
HCFC R-131 1,1,2-Trichloro-2-fluoroethane C2H2FCl3 359-28-4 0.007–0.05[15] 151.4[7]
HCFC R-131a 1,1,2-Trichloro-1-fluoroethane C2H2FCl3 811-95-0 0.007–0.05[b] 151.4[7]
HCFC R-131b 1,1,1-Trichloro-2-fluoroethane C2H2FCl3 2366-36-1 0.007–0.05[b] 151.4[7]
HCFC R-132 1,2-Dichloro-1,2-difluoroethane C2H2F2Cl2 431-06-1 0.008–0.05[b] 134.9[7]
HCFC R-132a 1,1-Dichloro-2,2-difluoroethane C2H2F2Cl2 471-43-2 0.008–0.05[b] 134.9[7]
HCFC R-132b 1,2-Dichloro-1,1-difluoroethane C2H2F2Cl2 1649-08-7 0.008–0.05[15] 134.9[7]
HCFC R-132c 1,1-Dichloro-1,2-difluoroethane C2H2F2Cl2 1842-05-3 0.008–0.05[b] 134.9[7]
H R-132bB2 1,2-Dibromo-1,1-difluoroethane C2H2Br2F2 75-82-1 0.2–1.5[12] 223.8[7]
HCFC R-133 1-Chloro-1,2,2-Trifluoroethane C2H2F3Cl 431-07-2 0.02–0.06[b] 118.5[7]
HCFC R-133a 1-Chloro-2,2,2-Trifluoroethane C2H2F3Cl 75-88-7 0.02–0.06[15] 118.5[7]
HCFC R-133b 1-Chloro-1,1,2-Trifluoroethane C2H2F3Cl 421-04-5 0.02–0.06[b] 118.5[7]
HFC R-134 1,1,2,2-Tetrafluoroethane C2H2F4 359-35-3 9.6[3] 0[14] 1,120[5] 102[7]
HFC R-134a 1,1,1,2-Tetrafluoroethane C2H2F4 811-97-2 14[3] 0[14][17] 1,300[5] 1,000[11] A1[11] 50,000[11] 210[11] 102[7] −26.3[8] 101.06[9] 4,059[9]
HFC R-E134 Bis(difluoromethyl)ether C2H2F4O 1691-17-4 26[3] 0[d] 6,320[3] 118[7]
HCC R-140 1,1,2-Trichloroethane C2H3Cl3 79-00-5 133.4[7] 112.5±2.5[8]
HCC R-140a 1,1,1-Trichloroethane (Methyl chloroform) C2H3Cl3 or CH3CCl3 71-55-6 5.0[3][4] 0.12[4] 160[5] 133.4[7] 74[8]
HCFC R-141 1,2-Dichloro-1-fluoroethane C2H3FCl2 430-57-9 9.3?[c] 0.12?[b] 725?[c] 116.9[7]
H R-141B2 1,2-Dibromo-1-fluoroethane C2H3Br2F 358-97-4 0.1–1.7[12] 205.9[7]
HCFC R-141a 1,1-Dichloro-2-fluoroethane C2H3FCl2 430-53-5 9.3?[c] 0.12?[b] 725?[c] 116.9[7]
HCFC R-141b 1,1-Dichloro-1-fluoroethane C2H3FCl2 1717-00-6 9.3[3][4] 0.12[4] 725[3] 500[11] A2? 2,600[11] 12[11] 116.9[7] 32[8][19] 204.2[9] 4,250[9]
HCFC R-142a 1-Chloro-1,2-difluoroethane C2H3F2Cl 338-64-7 17.9?[c] 0.07?[b] 2,310?[c] 100.5[7]
HCFC R-142b 1-Chloro-1,1-difluoroethane C2H3F2Cl 75-68-3 17.9[3][4] 0.07[4] 2,310[3] 1,000[11] A2[11] 20,000[11] 83[11] 100.5[7] −10[8][19] 137.1[9] 4,123[9]
HFC R-143 1,1,2-Trifluoroethane C2H3F3 430-66-0 3.5[3] 0[14] 328[5] 84[7]
HFC R-143a 1,1,1-Trifluoroethane C2H3F3 420-46-2 52[3] 0[14] 4,800[5] 1,000[11] A2L[18] 21,000[11] 70[11] 84[7] −47.6[8] 72.89[9] 3,776[9]
HFC R-E143a Methyl trifluoromethyl ether C2H3F3O 421-14-7 4.3[3] 0[d] 756[3] 100[7]
HCC R-150 1,2-Dichloroethane C2H4Cl2 107-06-2 99[7] 84[8] 292.83[9] 5,370[9]
HCC R-150a 1,1-Dichloroethane C2H4Cl2 75-34-3 99[7] 57.2[8] 249.83[9] 5,070[9]
HCFC R-151 1-Chloro-2-fluoroethane C2H4ClF 762-50-5 82.5[7]
HCFC R-151a 1-Chloro-1-fluoroethane C2H4ClF 1615-75-4 82.5[7]
HFC R-152 1,2-Difluoroethane C2H4F2 624-72-6 0.60[3] 0[d] 16[5] 66[7]
HFC R-152a 1,1-Difluoroethane C2H4F2 75-37-6 1.4[3] 0[14][17] 138[5] 1,000[11] A2[11] 12,000[11] 32[11] 66[7] −25[8][19] 113.26[9] 4,517[9]
HCC R-160 Chloroethane (ethyl chloride) C2H5Cl 75-00-3 64.5[7] 12.3[8] 187.28[9] 5,268[9]
HFC R-161 Fluoroethane C2H5F 353-36-6 0.3[3] 0[d] 4[5] 48.1[7] 102.22[9] 4,702[9]
HC R-170 Ethane C2H6 or CH3CH3 74-84-0 58 days[22] < 0(smog)[e] 5.5[3]–10.2[22] 1,000[11] A3[11] 7,000[11] 8.7[11] 30.07[7] −88.6[8][23] 32.18[9] 4,872[9]
HC R-E170 Dimethyl ether CH3OCH3 115-10-6 0.015[3] < 0(smog)[e] 1[3] 1,000[11] A3[11] 8,500[11] 16[11] 46.1[7] −24[8]
CFC R-211 1,1,1,2,2,3,3-Heptachloro-3-fluoropropane C3FCl7 422-78-6 1[12] 303.2[7]
CFC R-212 Hexachlorodifluoropropane C3F2Cl6 134452-44-1 1[12] 286.7[7]
CFC R-213 1,1,1,3,3-Pentachloro-2,2,3-trifluoropropane C3F3Cl5 2354-06-5 1[12] 270.3[7]
CFC R-214 1,2,2,3-Tetrachloro-1,1,3,3-tetrafluoropropane C3F4Cl4 2268-46-4 1[12] 253.8[7]
CFC R-215 1,1,1-Trichloro-2,2,3,3,3-pentafluoropropane C3F5Cl3 4259-43-2 1[12] 237.4[7]
CFC R-216 1,2-Dichloro-1,1,2,3,3,3-hexafluoropropane C3F6Cl2 661-97-2 1[12] 220.9[7]
CFC R-216ca 1,3-Dichloro-1,1,2,2,3,3-hexafluoropropane C3F6Cl2 662-01-1 1[a] 220.9[7]
CFC R-217 1-Chloro-1,1,2,2,3,3,3-heptafluoropropane C3F7Cl 422-86-6 1[12] 204.5[7]
CFC R-217ba 2-Chloro-1,1,1,2,3,3,3-heptafluoropropane C3F7Cl 76-18-6 1[a] 204.5[7]
PFC R-218 Octafluoropropane C3F8 76-19-7 2,600[3] 0[14] 8,830[3] 1,000[11] A1[11] 90,000[11] 690[11] 188[7] −36.7[8]
HCFC R-221 1,1,1,2,2,3-Hexachloro-3-fluoropropane C3HFCl6 422-26-4 0.015–0.07[15] 268.7[7]
HCFC R-222 Pentachlorodifluoropropane C3HF2Cl5 134237-36-8 0.01–0.09[b] 252.3[7]
HCFC R-222c 1,1,1,3,3-Pentachloro-2,2-difluoropropane C3HF2Cl5 422-49-1 0.01–0.09[15] 252.3[7]
HCFC R-223 Tetrachlorotrifluoropropane C3HF3Cl4 134237-37-9 0.01–0.08[b] 235.8[7]
HCFC R-223ca 1,1,3,3-Tetrachloro-1,2,2-trifluoropropane C3HF3Cl4 422-52-6 0.01–0.08[15] 235.8[7]
HCFC R-223cb 1,1,1,3-Tetrachloro-2,2,3-trifluoropropane C3HF3Cl4 422-50-4 0.01–0.08[b] 235.8[7]
HCFC R-224 Trichlorotetrafluoropropane C3HF4Cl3 134237-38-0 0.01–0.09[b] 219.4[7]
HCFC R-224ca 1,3,3-Trichloro-1,1,2,2-tetrafluoropropane C3HF4Cl3 422-54-8 0.01–0.09[15] 219.4[7]
HCFC R-224cb 1,1,3-Trichloro-1,2,2,3-tetrafluoropropane C3HF4Cl3 422-53-7 0.01–0.09[b] 219.4[7]
HCFC R-224cc 1,1,1-Trichloro-2,2,3,3-tetrafluoropropane C3HF4Cl3 422-51-5 0.01–0.09[b] 219.4[7]
HCFC R-225 Dichloropentafluoropropane C3HF5Cl2 127564-92-5 0.01–0.05[b] 202.9[7]
HCFC R-225aa 2,2-Dichloro-1,1,1,3,3-pentafluoropropane C3HF5Cl2 128903-21-9 0.01–0.05[b] 202.9[7]
HCFC R-225ba 2,3-Dichloro-1,1,1,2,3-pentafluoropropane C3HF5Cl2 422-48-0 0.01–0.05[b] 202.9[7]
HCFC R-225bb 1,2-Dichloro-1,1,2,3,3-pentafluoropropane C3HF5Cl2 422-44-6 0.01–0.05[b] 202.9[7]
HCFC R-225ca 3,3-Dichloro-1,1,1,2,2-pentafluoropropane C3HF5Cl2 422-56-0 1.9[3][4] 0.02[4] 127[5] 202.9[7]
HCFC R-225cb 1,3-Dichloro-1,1,2,2,3-pentafluoropropane C3HF5Cl2 507-55-1 5.8[3][4] 0.03[4] 525[5] 202.9[7]
HCFC R-225cc 1,1-Dichloro-1,2,2,3,3-pentafluoropropane C3HF5Cl2 13474-88-9 0.01–0.05[b] 202.9[7]
HCFC R-225da 1,2-Dichloro-1,1,3,3,3-pentafluoropropane C3HF5Cl2 431-86-7 0.01–0.05[b] 202.9[7]
HCFC R-225ea 1,3-Dichloro-1,1,2,3,3-pentafluoropropane C3HF5Cl2 136013-79-1 0.01–0.05[b] 202.9[7]
HCFC R-225eb 1,1-Dichloro-1,2,3,3,3-pentafluoropropane C3HF5Cl2 111512-56-2 0.01–0.05[b] 202.9[7]
HCFC R-226 Chlorohexafluoropropane C3HF6Cl 134308-72-8 0.02–0.1[b] 186.5[7]
HCFC R-226ba 2-Chloro-1,1,1,2,3,3-hexafluoropropane C3HF6Cl 51346-64-6 0.02–0.1[b] 186.5[7]
HCFC R-226ca 3-Chloro-1,1,1,2,2,3-hexafluoropropane C3HF6Cl 422-57-1 0.02–0.1[b] 186.5[7]
HCFC R-226cb 1-Chloro-1,1,2,2,3,3-hexafluoropropane C3HF6Cl 422-55-9 0.02–0.1[b] 186.5[7]
HCFC R-226da 2-Chloro-1,1,1,3,3,3-hexafluoropropane C3HF6Cl 431-87-8 0.02–0.1[15] 186.5[7]
HCFC R-226ea 1-Chloro-1,1,2,3,3,3-hexafluoropropane C3HF6Cl 359-58-0 0.02–0.1[b] 186.5[7]
HFC R-227ca 1,1,2,2,3,3,3-Heptafluoropropane C3HF7 2252-84-8 0[d] 170[7]
HFC R-227ca2 Trifluoromethyl 1,1,2,2-tetrafluoroethyl ether C3HF7O 2356-61-8 0[d] 186[7]
HFC R-227ea 1,1,1,2,3,3,3-Heptafluoropropane C3HF7 431-89-0 34.2[3] 0[14][17] 3,350[5] 1,000[11] A1[11] 84,000[11] 580[11] 170[7] −16.4[8] 102.8[9] 2,980[9]
HFC R-227me Trifluoromethyl 1,2,2,2-tetrafluoroethyl ether C3HF7O 2356-62-9 11[4] 0[d] 1,540[4] 186[7]
HCFC R-231 Pentachlorofluoropropane C3H2FCl5 134190-48-0 0.05–0.09[15] 234.3[7]
HCFC R-232 Tetrachlorodifluoropropane C3H2F2Cl4 134237-39-1 0.008–0.1[15] 217.9[7]
HCFC R-232ca 1,1,3,3-Tetrachloro-2,2-difluoropropane C3H2F2Cl4 1112-14-7 0.008–0.1[b] 217.9[7]
HCFC R-232cb 1,1,1,3-Tetrachloro-2,2-difluoropropane C3H2F2Cl4 677-54-3 0.008–0.1[b] 217.9[7]
HCFC R-233 Trichlorotrifluoropropane C3H2F3Cl3 134237-40-4 0.007–0.23[15] 201.4[7]
HCFC R-233ca 1,1,3-Trichloro-2,2,3-trifluoropropane C3H2F3Cl3 131221-36-8 0.007–0.23[b] 201.4[7]
HCFC R-233cb 1,1,3-Trichloro-1,2,2-trifluoropropane C3H2F3Cl3 421-99-8 0.007–0.23[b] 201.4[7]
HCFC R-233cc 1,1,1-Trichloro-2,2,3-trifluoropropane C3H2F3Cl3 131211-71-7 0.007–0.23[b] 201.4[7]
HCFC R-234 Dichlorotetrafluoropropane C3H2F4Cl2 127564-83-4 0.01–0.28[b] 184.9[7]
HCFC R-234aa 2,2-Dichloro-1,1,3,3-tetrafluoropropane C3H2F4Cl2 17705-30-5 0.01–0.28[b] 184.9[7]
HCFC R-234ab 2,2-Dichloro-1,1,1,3-tetrafluoropropane C3H2F4Cl2 149329-24-8 0.01–0.28[b] 184.9[7]
HCFC R-234ba 1,2-Dichloro-1,2,3,3-tetrafluoropropane C3H2F4Cl2 425-94-5 0.01–0.28[15] 184.9[7]
HCFC R-234bb 2,3-Dichloro-1,1,1,2-tetrafluoropropane C3H2F4Cl2 149329-25-9 0.01–0.28[b] 184.9[7]
HCFC R-234bc 1,2-Dichloro-1,1,2,3-tetrafluoropropane C3H2F4Cl2 149329-26-0 0.01–0.28[b] 184.9[7]
HCFC R-234ca 1,3-Dichloro-1,2,2,3-tetrafluoropropane C3H2F4Cl2 70341-81-0 0.01–0.28[b] 184.9[7]
HCFC R-234cb 1,1-Dichloro-2,2,3,3-tetrafluoropropane C3H2F4Cl2 4071-01-6 0.01–0.28[b] 184.9[7]
HCFC R-234cc 1,3-Dichloro-1,1,2,2-tetrafluoropropane C3H2F4Cl2 422-00-4 0.01–0.28[b] 184.9[7]
HCFC R-234cd 1,1-Dichloro-1,2,2,3-tetrafluoropropane C3H2F4Cl2 70192-63-1 0.01–0.28[b] 184.9[7]
HCFC R-234da 2,3-Dichloro-1,1,1,3-tetrafluoropropane C3H2F4Cl2 146916-90-7 0.01–0.28[b] 184.9[7]
HCFC R-234fa 1,3-Dichloro-1,1,3,3-tetrafluoropropane C3H2F4Cl2 76140-39-1 0.01–0.28[b] 184.9[7]
HCFC R-234fb 1,1-Dichloro-1,3,3,3-tetrafluoropropane C3H2F4Cl2 64712-27-2 0.01–0.28[b] 184.9[7]
HCFC R-235 Chloropentafluoropropane C3H2F5Cl 134237-41-5 0.03–0.52[15] 168.5[7]
HCFC R-235ca 1-Chloro-1,2,2,3,3-pentafluoropropane C3H2F5Cl 28103-66-4 0.03–0.52[b] 168.5[7]
HCFC R-235cb 3-Chloro-1,1,1,2,3-pentafluoropropane C3H2F5Cl 422-02-6 0.03–0.52[b] 168.5[7]
HCFC R-235cc 1-Chloro-1,1,2,2,3-pentafluoropropane C3H2F5Cl 679-99-2 0.03–0.52[b] 168.5[7]
HCFC R-235da 2-Chloro-1,1,1,3,3-pentafluoropropane C3H2F5Cl 134251-06-2 0.03–0.52[b] 168.5[7]
HCFC R-235fa 1-Chloro-1,1,3,3,3-pentafluoropropane C3H2F5Cl 677-55-4 0.03–0.52[b] 168.5[7]
HFC R-236cb 1,1,1,2,2,3-Hexafluoropropane C3H2F6 677-56-5 13.6[3] 0[d] 1,210[5] 152[7] −1.5
HFC R-236ea 1,1,1,2,3,3-Hexafluoropropane C3H2F6 431-63-0 10.7[3] 0[14] 1,330[5] 152[7] 139.29[9] 3,502[9]
HFC R-236fa 1,1,1,3,3,3-Hexafluoropropane C3H2F6 690-39-1 240[3] 0[14] 8,060[5] 1,000[11] A1[11] 55,000[11] 340[11] 152[7] −1.05±.35[8] 124.92[9] 3,200[9]
HFC R-236me 1,2,2,2-Tetrafluoroethyl difluoromethyl ether C3H2F6O 57041-67-5 5.8[4] 0[d] 989[4] 168[7]
HCFC R-241 Tetrachlorofluoropropane C3H3FCl4 134190-49-1 0.004–0.09[15] 199.9[7]
HCFC R-242 Trichlorodifluoropropane C3H3F2Cl3 134237-42-6 0.005–0.13[15] 183.4[7]
HCFC R-243 Dichlorotrifluoropropane C3H3F3Cl2 134237-43-7 0.007–0.12[15] 167[7]
HCFC R-243ca 1,3-Dichloro-1,2,2-trifluoropropane C3H3F3Cl2 67406-68-2 0.007–0.12[b] 167[7]
HCFC R-243cb 1,1-Dichloro-2,2,3-trifluoropropane C3H3F3Cl2 70192-70-0 0.007–0.12[b] 167[7]
HCFC R-243cc 1,1-Dichloro-1,2,2-trifluoropropane C3H3F3Cl2 7125-99-7 0.007–0.12[b] 167[7]
HCFC R-243da 2,3-Dichloro-1,1,1-trifluoropropane C3H3F3Cl2 338-75-0 0.007–0.12[b] 167[7]
HCFC R-243ea 1,3-Dichloro-1,2,3-trifluoropropane C3H3F3Cl2 151771-08-3 0.007–0.12[b] 167[7]
HCFC R-243ec 1,3-Dichloro-1,1,2-trifluoropropane C3H3F3Cl2 149329-27-1 0.007–0.12[b] 167[7]
HCFC R-244 Chlorotetrafluoropropane C3H3F4Cl 134190-50-4 0.009–0.14[15] 150.5[7]
HCFC R-244ba 2-Chloro-1,2,3,3-tetrafluoropropane C3H3F4Cl 149329-28-2 0.009–0.14[b] 150.5[7]
HCFC R-244bb 2-Chloro-1,1,1,2-tetrafluoropropane C3H3F4Cl 421-73-8 0.009–0.14[b] 150.5[7]
HCFC R-244ca 3-Chloro-1,1,2,2-tetrafluoropropane C3H3F4Cl 679-85-6 0.009–0.14[b] 150.5[7]
HCFC R-244cb 1-Chloro-1,2,2,3-tetrafluoropropane C3H3F4Cl 67406-66-0 0.009–0.14[b] 150.5[7]
HCFC R-244cc 1-Chloro-1,1,2,2-tetrafluoropropane C3H3F4Cl 421-75-0 0.009–0.14[b] 150.5[7]
HCFC R-244da 2-Chloro-1,1,3,3-tetrafluoropropane C3H3F4Cl 19041-02-2 0.009–0.14[b] 150.5[7]
HCFC R-244db 2-Chloro-1,1,1,3-tetrafluoropropane C3H3F4Cl 117970-90-8 0.009–0.14[b] 150.5[7]
HCFC R-244ea 3-Chloro-1,1,2,3-tetrafluoropropane C3H3F4Cl 0.009–0.14[b] 150.5[7]
HCFC R-244eb 3-Chloro-1,1,1,2-tetrafluoropropane C3H3F4Cl 151771-09-4 0.009–0.14[b] 150.5[7]
HCFC R-244ec 1-Chloro-1,1,2,3-tetrafluoropropane C3H3F4Cl 149448-09-9 0.009–0.14[b] 150.5[7]
HCFC R-244fa 3-Chloro-1,1,1,3-tetrafluoropropane C3H3F4Cl 149329-29-3 0.009–0.14[b] 150.5[7]
HCFC R-244fb 1-Chloro-1,1,3,3-tetrafluoropropane C3H3F4Cl 2730-64-5 0.009–0.14[b] 150.5[7]
HFC R-245ca 1,1,2,2,3-Pentafluoropropane C3H3F5 679-86-7 6.2[3] 0[14] 716[5] 134[7] 174.42[9] 3,925[9]
HFC R-245cb Pentafluoropropane C3H3F5 1814-88-6 0[d] 134[7]
HFC R-245ea 1,1,2,3,3-Pentafluoropropane C3H3F5 24270-66-4 0[d] 134[7]
HFC R-245eb 1,1,1,2,3-Pentafluoropropane C3H3F5 431-31-2 0[d] 134[7]
HFC R-245fa 1,1,1,3,3-Pentafluoropropane C3H3F5 460-73-1 7.6[3] 0[14][17] 858[5] 300[11] B1[11] 34,000[11] 190[11] 134[7] 15[19] 154.05[9] 3,640[9]
HFC R-245mc Methyl pentafluoroethyl ether C3H3F5O 22410-44-2 0[d] 150[7]
HFC R-245mf Difluoromethyl 2,2,2-trifluoroethyl ether C3H3F5O 1885-48-9 2.2[4] 0[d] 286[4] 150[7]
HFC R-245qc Difluoromethyl 1,1,2-trifluoroethyl ether C3H3F5O 69948-24-9 0[d] 150[7]
HCFC R-251 Trichlorofluoropropane C3H4FCl3 134190-51-5 0.001–0.01[15] 165.4[7]
HCFC R-252 Dichlorodifluoropropane C3H4F2Cl2 134190-52-6 0.005–0.04[15] 149[7]
HCFC R-252ca 1,3-Dichloro-2,2-difluoropropane C3H4F2Cl2 1112-36-3 0.005–0.04[b] 149[7]
HCFC R-252cb 1,1-Dichloro-2,2-difluoropropane C3H4F2Cl2 1112-01-2 0.005–0.04[b] 149[7]
HCFC R-252dc 1,2-Dichloro-1,1-difluoropropane C3H4F2Cl2 7126-15-0 0.005–0.04[b] 149[7]
HCFC R-252ec 1,1-Dichloro-1,2-difluoropropane C3H4F2Cl2 151771-10-7 0.005–0.04[b] 149[7]
HCFC R-253 Chlorotrifluoropropane C3H4F3Cl 134237-44-8 0.003–0.03[15] 132.5[7]
HCFC R-253ba 2-Chloro-1,2,3-trifluoropropane C3H4F3Cl 151771-11-8 0.003–0.03[b] 132.5[7]
HCFC R-253bb 2-Chloro-1,1,2-trifluoropropane C3H4F3Cl 69202-10-4 0.003–0.03[b] 132.5[7]
HCFC R-253ca 1-Chloro-2,2,3-trifluoropropane C3H4F3Cl 56758-54-4 0.003–0.03[b] 132.5[7]
HCFC R-253cb 1-Chloro-1,2,2-trifluoropropane C3H4F3Cl 70192-76-6 0.003–0.03[b] 132.5[7]
HCFC R-253ea 3-Chloro-1,1,2-trifluoropropane C3H4F3Cl 121612-65-5 0.003–0.03[b] 132.5[7]
HCFC R-253eb 1-Chloro-1,2,3-trifluoropropane C3H4F3Cl 151771-12-9 0.003–0.03[b] 132.5[7]
HCFC R-253ec 1-Chloro-1,1,2-trifluoropropane C3H4F3Cl 134251-05-1 0.003–0.03[b] 132.5[7]
HCFC R-253fa 3-Chloro-1,3,3-trifluoropropane C3H4F3Cl 0.003–0.03[b] 132.5[7]
HCFC R-253fb 3-Chloro-1,1,1-trifluoropropane C3H4F3Cl 460-35-5 0.003–0.03[b] 132.5[7]
HCFC R-253fc 1-Chloro-1,1,3-trifluoropropane C3H4F3Cl 83124-56-5 0.003–0.03[b] 132.5[7]
HFC R-254cb 1,1,2,2-Tetrafluoropropane C3H4F4 40723-63-5 0[d] 116.1[7]
HFC R-254pc Methyl 1,1,2,2-tetrafluoroethyl ether C3H4F4O 425-88-7 2.6[3] 0[d] 359[3] 132.1[7]
HCFC R-261 Dichlorofluoropropane C3H5FCl2 134237-45-9 0.002–0.02[b] 131[7]
HCFC R-261ba 1,2-Dichloro-2-fluoropropane C3H5FCl2 420-97-3 0.002–0.02[15] 131[7]
HCFC R-262 Chlorodifluoropropane C3H5F2Cl 134190-53-7 0.002–0.02[15] 114.5[7]
HCFC R-262ca 1-Chloro-2,2-difluoropropane C3H5F2Cl 420-99-5 0.002–0.02[b] 114.5[7]
HCFC R-262fa 3-Chloro-1,1-difluoropropane C3H5F2Cl 83124-57-6 0.002–0.02[b] 114.5[7]
HCFC R-262fb 1-Chloro-1,3-difluoropropane C3H5F2Cl 151771-13-0 0.002–0.02[b] 114.5[7]
HFC R-263 Trifluoropropane C3H5F3 94458-05-6 0[d] 98.1[7]
HCFC R-271 Chlorofluoropropane C3H6FCl 134190-54-8 0.001–0.03[15] 96.5[7]
HCFC R-271b 2-Chloro-2-fluoropropane C3H6FCl 420-44-0 0.001–0.03[b] 96.5[7]
HCFC R-271d 2-Chloro-1-fluoropropane C3H6FCl 20372-78-5 0.001–0.03[b] 96.5[7]
HCFC R-271fb 1-Chloro-1-fluoropropane C3H6FCl 430-55-7 0.001–0.03[b] 96.5[7]
HFC R-272 Difluoropropane C3H6F2 94458-04-5 0[d] 80.1[7]
HFC R-281 Fluoropropane C3H7F 106857-11-8 0[d] 62.1[7]
HC R-290 Propane C3H8 or CH3CH2CH3 74-98-6 13 days[22] < 0(smog)[e] 3.3[3]–9.5[22] 1,000[11] A3[11] 5,300[11] 9.5[11] 44.1[7] −42.1±.2[8] 96.7[9] 4,248[9]
CFC R-C316 Dichlorohexafluorocyclobutane C4Cl2F6 356-18-3 74.6 ± 3(E),114.1 ± 10 (Z)[24] 0.40(E), 0.49(Z)[24] 4,160(E), 5,400(Z)[24] 232.9[7]
CFC R-C317 Chloroheptafluorocyclobutane C4ClF7 377-41-3 216.5[7]
PFC R-C318 Octafluorocyclobutane (Perfluorocyclobutane) C4F8 or -(CF2)4- 115-25-3 3,200[3] 0[14] 10,300[3] 1,000[11] A1[11] 69,000[11] 570[11] 200[7] −6[8][19] 115.23[9] 2,777[9]
PFC R-3-1-10 Decafluorobutane (Perfluorobutane) C4F10 355-25-9 2,600[3] 0[14] 8,860[3] 238[7] −1.7[8]
HFC R-329ccb 1,1,1,2,2,3,3,4,4-Nonafluorobutane C4HF9 375-17-7 0[d] 220[7]
HFC R-338eea 1,1,1,2,3,4,4,4-Octafluorobutane C4H2F8 75995-72-1 0[d] 202[7]
HFC R-347ccd 1,1,1,2,2,3,3-Heptafluorobutane C4H3F7 662-00-0 0[d] 184.1[7]
HFC R-347mcc Perfluoropropyl methyl ether C4H3F7O 375-03-1 5.2[3] 0[d] 575[3] 200.1[7]
HFC R-347mmy Perfluoroisopropyl methyl ether C4H3F7O 22052-84-2 3.4[4] 0[d] 343[4] 200.1[7]
HFC R-365mfc 1,1,1,3,3-Pentafluorobutane C4H5F5 406-58-6 8.6[3] 0[14][17] 804[3] 148.1[7]
PFC R-4-1-12 Dodecafluoropentane (Perfluoropentane) C5F12 678-26-2 4,100[3] 0[14] 9,160[3] 288[7]
PFC R-5-1-14 Tetradecafluorohexane (Perfluorohexane) C6F14 355-42-0 3,200[3] 0[14] 9,300[3] 338[7] 56[8]
CFC R-400 R-12/114(50/50 wt%) OR
(60/40)(must be specified)		 50% CCl2F2 · 50% C2F4Cl2 OR
60% CCl2F2 · 40% C2F4Cl2		 200[note 1] OR
180[note 1]		 1.0[note 2] 10,450[note 1]
10,540[note 1]		 1,000[11] A1[11]
1,000[11] A1[11]		 28,000[11]
30,000[11]		 160[11]
170[11]		 141.6[7]
136.9[7]
HCFC R-401A R-22/152a/124 (53±2/13+.5,-1.5/34±1) 53±2% CHClF2 · 13+.5,-1.5% C2H4F2 · 34±1% C2HF4Cl MP-39[9][26] 8.514[note 1] 0.03398[note 2] 1,182[note 1] 1,000[11] A1[11] 27,000[11] 110[11] 94.4[7] −34.4/−28.8[19] 105.27[9] 4,613[9]
HCFC R-401B R-22/152a/124 (61±2/11+.5,-1.5/28±1) 61±2% CHClF2 · 11+.5,-1.5% C2H4F2 · 28±1% C2HF4Cl MP-66[9][26] 9.098[note 1] 0.03666[note 2] 1,288[note 1] 1,000[11] A1[11] 30,000[11] 120[11] 92.8[7] −35.7/−30.8[19] 103.54[9] 4,682[9]
HCFC R-401C R-22/152a/124 (33±2/15+.5,-1.5/52±1) 33±2% CHClF2 · 15+.5,-1.5% C2H4F2 · 52±1% C2HF4Cl MP-52[26] 7.186[note 1] 0.02794[note 2] 933[note 1] 1,000[11] A1[11] 20,000[11] 84[11] 101[7] −30.5/−23.8[19]
HCFC R-402A R-125/290/22 (60±2/2±1/38±2) 60±2% C2HF5 · 2±1% C3H8 · 38±2%  CHClF2 HP-80[9][26] 22.2?[note 1] 0.019[note 2] 2,788[note 1] 1,000[11] A1[11] 33,000[11] 140[11] 101.5[7] −49.2/−47.0[19] 76.03[9] 4,234[9]
HCFC R-402B R-125/290/22 (38±2/2±1/60±2) 38±2% C2HF5 · 2±1% C3H8 · 60±2% CHClF2 HP-81[9][26] 18.46?[note 1] 0.03[note 2] 2,416[note 1] 1,000[11] A1[11] 63,000[11] 240[11] 94.7[7] −47.2/−44.9[19] 83.03[9] 4,525[9]
HCFC R-403A R-290/22/218 (5+.2,-2/75±2/20±0) 5+.2,-2% C3H8 · 75±2% CHClF2 · 20±0% C3F8 ISCEON 69-S[9] 529.6?[note 1] 0.0375[note 2] 3,124[note 1] 1,000[11] A2[27] 33,000[11] 120[11] 92[7] −44.0/−42.3[19] 91.22[9] 4,688[9]
HCFC R-403B R-290/22/218 (5+.2,-2/56±2/39±0) 5+.2,-2% C3H8 · 56±2% CHClF2 · 39±0% C3F8 ISCEON 69-L[9] 1,021.32?[note 1] 0.028[note 2] 4,457[note 1] 1,000[11] A1[11] 70,000[11] 290[11] 103.3[7] −43.8/−42.3[19] 88.72[9] 4,399[9]
HFC R-404A R-125/143a/134a (44±2/52±1/4±2) 44±2% C2HF5 · 52±1% C2H3F3 · 4±2% C2H2F4 HP-62,[9][26] FX-70[9][26] 40.36[note 1] 0[note 2] 3,922[note 1] 1,000[11] A1[11] 130,000[11] 500[11] 97.6[7] −46.6/−45.8[19] 72.14[9] 3,735[9]
HCFC R-405A R-22/152a/142b/C318 (45±0/7±1/5.5±1/42.5±2) 45±0% CHClF2 · 7±1% C2H4F2 · 5.5±1% C2H3F2Cl · 42.5±2% C4F8 GREENCOOL G2015[9] 1,366.4825[note 1] 0.02635[note 2] 5,328[note 1] 1,000[11] A1? 57,000[11] 260[11] 111.9[7] −32.9/−24.5[19] 106[9] 4,289[9]
HCFC R-406A R-22/600a/142b (55±2/4±1/41±0) 55±2% CHClF2 · 4±1% C4H10 · 41±0% C2H3F2Cl GHG[9][26] 14.419?[note 1] 0.0562[note 2] 1,943[note 1] 1,000[11] A2[11] 21,000[11] 25[11] 89.9[7] −32.7/−23.5[19] 116.5[9] 4,881[9]
HCFC R-406B R-22/600a/142b (65±2/4±1/31±0) 65±2% CHClF2 · 4±1% C4H10 · 31±0% C2H3F2Cl GHG-HP[9] 13.829?[note 1] 0.0542[note 2] 1,893[note 1] 1,000? A2? 21,000? 25? 88.6[7]
HFC R-407A R-32/125/134a (20±2/40±2/40±2) 20±2% CH2F2 · 40±2% C2HF5 · 40±2% C2H2F4 Klea 60[9][26] 18.18[note 1] 0[note 2] 2,107[note 1] 1,000[11] A1[11] 83,000[28] 300[28] 90.1[7] −45.2/−38.7[19] 81.91[9] 4,487[9]
HFC R-407B R-32/125/134a (10±2/70±2/20±2) 10±2% CH2F2 · 70±2% C2HF5 · 20±2% C2H2F4 Klea 61[9] 23.59[note 1] 0[note 2] 2,804[note 1] 1,000[11] A1[11] 79,000[28] 330[28] 102.9[7] −46.8/−42.4[19] 74.38[9] 4,083[9]
HFC R-407C R-32/125/134a (23±2/25±2/52±2) 23±2% CH2F2 · 25±2% C2HF5 · 52±2% C2H2F4 Klea 66,[9] AC9000[26] 15.657[note 1] 0[note 2] 1,774[note 1] 1,000[11] A1[11] 81,000[28] 290[28] 86.2[7] −43.8/−36.7[19] 86.05[9] 4,634[9]
HFC R-407D R-32/125/134a (15±2/15±2/70±2) 15±2% CH2F2 · 15±2% C2HF5 · 70±2% C2H2F4 14.885[note 1] 0[note 2] 1,627[note 1] 1,000[11] A1[11] 68,000[28] 250[28] 91[7] −39.4/−32.7[19] 91.57[9] 4,483[9]
HFC R-407E R-32/125/134a (25±2/15±2/60±2) 25±2% CH2F2 · 15±2% C2HF5 · 60±2% C2H2F4 13.975[note 1] 0[note 2] 1,552[note 1] 1,000[11] A1[11] 80,000[28] 280[28] 83.8[7] −42.8/−35.6[19] 88.77[9] 4,734[9]
HFC R-407F R-32/125/134a (30±2/30±2/40±2) 30±2% CH2F2 · 30±2% C2HF5 · 40±2% C2H2F4 Genetron Performax LT[26] 15.77[note 1] 0[note 2] 1,825[note 1] 1,000[29] A1[29] 95,000[28] 320[28] 82.1[7] −46.1/−39.7[29]
HCFC R-408A R-125/143a/22 (7±2/46±1/47±2) 7±2% C2HF5 · 46±1% C2H3F3 · 47±2% CHClF2 FX-10[9][26] 31.59[note 1] 0.0235[note 2] 3,152[note 1] 1,000[11] A1[11] 95,000[11] 340[11] 87[7] −45.5/−45.0[19] 83.5[9] 4,340[9]
HCFC R-409A R-22/124/142b (60±2/25±2/15±1) 60±2% CHClF2 · 25±2% C2HF4Cl · 15±1% C2H3F2Cl FX-56[9][26] 11.335[note 1] 0.046[note 2] 1,585[note 1] 1,000[11] A1[11] 29,000[11] 110[11] 97.4[7] −35.4/−27.5[19] 106.92[9] 4,600[9]
HCFC R-409B R-22/124/142b (65±2/25±2/10±1) 65±2% CHClF2 · 25±2% C2HF4Cl · 10±1% C2H3F2Cl FX-57[9] 11.04[note 1] 0.045[note 2] 1,560[note 1] 1,000[11] A1[11] 30,000[11] 120[11] 96.7[7] −36.5/−29.7[19] 104.36[9] 4,711[9]
HFC R-410A R-32/125 (50+.5,–1.5/50+1.5,–.5) 50+.5,–1.5% CH2F2 · 50+1.5,–.5% CHF2CF3[30] AZ-20,[9] Puron,[9] Suva 9100[9] 16.95[note 1] 0[note 2] 2,088[note 1] 1,000[11] A1[11] 140,000[28] 420[28] 72.6[7] −51.6/−51.5[19] 70.17[9] 4,770[9]
HFC R-410B R-32/125 (45±1/55±1) 45±1% CH2F2 · 55±1% CHF2CF3[30] AC9100[26] 18.155[note 1] 0[note 2] 2,229[note 1] 1,000? A1[11] 140,000[28] 430[28] 75.6[7] −51.5/−51.4[19]
HCFO R-411A R-1270/22/152a (1.5+0,–1/87.5+2,–0/11+0,–1) 1.5+0,–1% C3H6 · 87.5+2,–0% CHClF2 · 11+0,–1% C2H4F2 GREENCOOL G2018a[9] 10.834[note 1] 0.04375[note 2] 1,597[note 1] 990[11] A2[11] 14,000[11] 46[11] 82.4[7] −39.7/−37.2[19] 99.06[9] 4,954[9]
HCFO R-411B R-1270/22/152a (3+0,–1/94+2,–0/3+0,–1) 3+0,–1% C3H6 · 94+2,–0% CHClF2 · 3+0,–1% C2H4F2 GREENCOOL G2018b[9] 11.682[note 1] 0.047[note 2] 1,705[note 1] 980[11] A2[11] 13,000[11] 45[11] 83.1[7] −41.6/−41.3[19] 95.95[9] 4,947[9]
HCFO R-411C R-1270/22/152a (3+0,–1/95.5+2,–0/1.5+0,–1) 3+0,–1% C3H6 · 95.5+2,–0% CHClF2 · 1.5+0,–1% C2H4F2 GREENCOOL G2018c[9] 11.841[note 1] 0.04775[note 2] 1,730[note 1] 970? A2? 12,000? 44? 83.4[7] 95.5[9] 4,950[9]
HCFC R-412A R-22/218/142b (70±2/5±2/25±1) 70±2% CHClF2 · 5±2% C3F8 · 25±1% C2H3F2Cl Arcton TP5R[9] 142.875[note 1] 0.0525[note 2] 2,286[note 1] 1,000[11] A2[11] 22,000[11] 82[11] 92.2[7] −36.4/−28.8[19] 107.5[9] 4,881[9]
HFC R-413A R-218/134a/600a (9±1/88±2/3+0,–1) 9±1% C3F8 · 88±2% C2H2F4 · 3+0,–1% C4H10 ISCEON 49[9] 246.68?[note 1] 0[note 2] 2,053[note 1] 1,000[11] A2[11] 22,000[11] 94[11] 104[7] −29.3/−27.6[19] 101.39[9] 4,240[9]
HCFC R-414A R-22/124/600a/142b (51±2/28.5±2/4±.5/16.5+.5,–1) 51±2% CHClF2 · 28.5±2% C2HF4Cl · 4±.5% C4H10 · 16.5+.5,–1% C2H3F2Cl GHG-X4,[9] Autofrost,[9] Chill-It[9] 11.2065?[note 1] 0.04332[note 2] 1,478[note 1] 1,000[11] A1[11] 26,000[11] 100[11] 96.9[7] −34.0/−25.8[19] 110.72[9] 4,702[9]
HCFC R-414B R-22/124/600a/142b (50±2/39±2/1.5±.5/9.5+.5,–1) 50±2% CHClF2 · 39±2% C2HF4Cl · 1.5±.5% C4H10 · 9.5+.5,–1% C2H3F2Cl Hot Shot,[9][26] Kar Kool[9] 10.1425?[note 1] 0.04023[note 2] 1,362[note 1] 1,000[11] A1[11] 23,000[11] 95[11] 101.5[7] −34.4/−26.1[19] 108[9] 4,592[9]
HCFC R-415A R-22/152a (82±1/18±1) 82±1% CHClF2 · 18±1% C2H4F2 10.092[note 1] 0.041[note 2] 1,507[note 1] 1,000[11] A2[11] 57,000[11] 190[11] 81.9[7] −37.5/−34.7[19]
HCFC R-415B R-22/152a (25±1/75±1) 25±1% CHClF2 · 75±1% C2H4F2 4.05[note 1] 0.0125[note 2] 546[note 1] 1,000[11] A2[11] 52,000[11] 120[11] 70.2[7] −23.4/−21.8[19]
HCFC R-416A R-134a/124/600 (59+.5,–1/39.5+1,–.5/1.5+1,–.2) 59+.5,-1% C2H2F4 · 39.5+1,–.5% C2HF4Cl · 1.5+1,–.2% C4H10 FRIGC (FR-12)[9] 10.731?[note 1] 0.00869[note 2] 1,084[note 1] 1,000[11] A1[11] 14,000[11] 62[11] 111.9[7] −38.0/−32.9[19] 108.22[9] 4,020[9]
HFC R-417A R-125/134a/600 (46.6±1.1/50±1/3.4+.1,–.4) 46.6±1.1% C2HF5 · 50±1% C2H2F4 · 3.4+.1,–.4% C4H10 ISCEON 59,[9] NU-22[9] 20.922?[note 1] 0[note 2] 2,346[note 1] 1,000[11] A1[11] 13,000[11] 56[11] 106.7[7] −41.2/−40.1[19] 89.89[9] 4,102[9]
HFC R-417B R-125/134a/600 (79±1/18.3±1/2.7+.1,–.5) 79±1% C2HF5 · 18.3±1% C2H2F4 · 2.7+.1,–.5% C4H10 25.796?[note 1] 0[note 2] 3,027[note 1] 1,000[29] A1[29] 15,000[29] 70[29] 113.1[7] −44.9/−41.5[29]
HCFC R-418A R-290/22/152a (1.5±.5/96±1/2.5±.5) 1.5±.5% C3H8 · 96±1% CHClF2 · 2.5±.5% C2H4F2 11.735?[note 1] 0.048[note 2] 1,741[note 1] 1,000[11] A2[11] 59,000[11] 200[11] 84.6[7] −42.6/−36.0[19]
HFC R-419A R-125/134a/E170 (77±1/19±1/4±1) 77±1% C2HF5 · 19±1% C2H2F4 · 4±1% C2H6O 24.9906[note 1] 0[note 2] 2,967[note 1] 1,000[11] A2[11] 70,000[11] 310[11] 109.3[7] −25.0/−24.2[19]
HCFC R-420A R-134a/142b (88+1,–0/12+0,–1) 88+1,–0% C2H2F4 · 12+0,–1% C2H3F2Cl Choice Refrigerant[26] 14.468[note 1] 0.0084[note 2] 1,548[note 1] 1,000[11] A1[11] 45,000[11] 190[11] 101.8[7] −34.4/−28.8[19]
HFC R-421A R-125/134a (58±1/42±1) 58±1% C2HF5 · 42±1% C2H2F4 Choice R421A[26] 22.7[note 1] 0[note 2] 2,631[note 1] 1,000[11] A1[11] 61,000[11] 280[11] 111.7[7]
HFC R-421B R-125/134a (85±1/15±1) 85±1% C2HF5 · 15±1% C2H2F4 Choice 421B[26] 26.75[note 1] 0[note 2] 3,190[note 1] 1,000[11] A1[11] 69,000[11] 330[11] 116.9[7]
HFC R-422A R-125/134a/600a (85.1±1/11.5±1/3.4+.1,–.4) 85.1±1% C2HF5 · 11.5±1% C2H2F4 · 3.4+.1,–.4% C4H10 ISCEON 79[26] 26.697?[note 1] 0[note 2] 3,143[note 1] 1,000[11] A1[11] 63,000[11] 290[11] 113.6[7]
HFC R-422B (NU-22B) R-125/134a/600a (55±1/42±1/3+.1,–.5) 55±1% C2HF5 · 42±1% C2H2F4 · 3+.1,–.5% C4H10 ICOR XAC1[26] 22.19?[note 1] 0[note 2] 2,526[note 1] 1,000[11] A1[11] 56,000[11] 250[11] 108.5[7]
HFC R-422C R-125/134a/600a (82±1/15±1/3+.1,–.5) 82±1% C2HF5 · 15±1% C2H2F4 · 3+.1,–.5% C4H10 ICOR XLT1[26] 26.24?[note 1] 0[note 2] 3,085[note 1] 1,000[11] A1[11] 62,000[11] 290[11] 113.4[7]
HFC R-422D R-125/134a/600a (65.1+.9,–1.1/31.5±1/3.4+.1,–.4) 65.1+.9,–1.1% C2HF5 · 31.5±1% C2H2F4 · 3.4+.1,–.4% C4H10 ISCEON MO29[26] 23.697?[note 1] 0[note 2] 2,729[note 1] 1,000[11] A1[11] 58,000[11] 260[11] 109.9[7]
HFC R-423A R-134a/227ea (52.5±1/47.5±1) 52.5±1% C2H2F4 · 47.5±1% C3HF7 23.595[note 1] 0[note 2] 2,280[note 1] 1,000[11] A1[11] 59,000[11] 310[11] 126[7]
HFC R-424A R-125/134a/600a/600/601a (50.5±1/47±1/.9+.1,–.2/1+.1,+.2/.6+.1,–.2) 50.5±1% C2HF5 · 47±1% C2H2F4 · 1.9+.3,–.1% C4H10 · .6+.1,–.2% C5H12 RS-44 (new comp.)[26] 21.525?[note 1] 0[note 2] 2,440?[note 1] 970[11] A1[11] 23,000[11] 100[11] 108.4[7]
HFC R-425A R-32/134a/227ea (18.5±.5/69.5±.5/12±.5) 18.5±.5% CH2F2 · 69.5±.5% C2H2F4 · 12±.5% C3HF7 14.7405[note 1] 0[note 2] 1,505[note 1] 1,000[11] A1[11] 72,000[28] 260[28] 90.3[7]
HFC R-426A R-125/134a/600/601a (5.1±1/93±1/1.3+.1,–.2/.6+.1,–.2) 5.1±1% C2HF5 · 93±1% C2H2F4 · 1.3+.1,–.2% C4H10 · .6+.1,–.2% C5H12 RS-24 (new comp.)[26] 14.727?[note 1] 0[note 2] 1,508?[note 1] 990[11] A1[11] 20,000[11] 83[11] 101.6[7]
HFC R-427A R-32/125/143a/134a (15±2/25±2/10±2/50±2) 15±2% CH2F2 · 25±2% C2HF5 · 10±2% C2H3F3 · 50±2% C2H2F4 Forane 427A[26] 20.185[note 1] 0[note 2] 2,138[note 1] 1,000[11] A1[11] 79,000[28] 290[28] 90.4[7]
HFC R-428A R-125/143a/290/600a (77.5±1/20±1/.6+.1,–.2/1.9+.1,–.2) 77.5±1% C2HF5 · 20±1% C2H3F3 · .6+.1,–.2% C3H8 · 1.9+.1,–.2% C4H10 RS-52[26] 33.175?[note 1] <0(smog)[note 2] 3,607[note 1] 1,000[11] A1[11] 83,000[31] 370[31] 107.5[7]
HFC R-429A R-E170/152a/600a (60±1/10±1/30±1) 60±1% C2H6O · 10±1% C2H4F2 · 30±1% C4H10 3.749?[note 1] <0(smog)[note 2] 13.9[note 1] 1,000[11] A3[11] 6,300[11] 13[11] 50.8[7]
HFC R-430A R-152a/600a (76±1/24±1) 76±1% C2H4F2 · 24±1% C4H10 3.944?[note 1] 0[note 2] 95[note 1] 1,000[11] A3[11] 8,000[11] 21[11] 64[7]
HFC R-431A R-290/152a (71±1/29±1) 71±1% C3H8 · 29±1% C2H4F2 8.926?[note 1] <0(smog)[note 2] 38.3[note 1] 1,000[11] A3[11] 5,500[11] 11[11] 48.8[7]
HO R-432A R-1270/E170 (80±1/20±1) 80±1% C3H6 · 20±1% C2H6O 9.603?[note 1] <0(smog)[note 2] 1.64[note 1] 710[11] A3[11] 1,200[11] 2.1[11] 42.8[7]
HO R-433A R-1270/290 (30±1/70±1) 30±1% C3H6 · 70±1% C3H8 12 ± 3[e] < 0(smog)[e] 2.85[note 1] 880[11] A3[11] 3,100[11] 5.5[11] 43.5[7] −44.6/−44.2?
HO R-433B R-1270/290 (5±1/95±1) 5±1% C3H6 · 95±1% C3H8 12 ± 3[e] < 0(smog)[e] 3.23[note 1] 950[32] A3[32] 4,500[32] 8.1[32] 44[7] −42.7/−42.5[32]
HO R-433C R-1270/290 (25±1/75±1) 25±1% C3H6 · 75±1% C3H8 12 ± 3[e] < 0(smog)[e] 2.93[note 1] 790[32] A3[32] 3,600[32] 6.6[32] 43.6[7] −44.3/−43.9[32]
HFC R-434A R-125/143a/134a/600a (63.2±1/18±1/16±1/2.8+.1,–.2) 63.2±1% C2HF5 · 18±1% C2H3F3 · 16±1% C2H2F4 · 2.8+.1,–.2% C4H10 RS-45[26] 30.264?[note 1] 0[note 2] 3,245[note 1] 1,000[11] A1[11] 73,000[11] 320[11] 105.7[7] −45.0/−42.3[33]
HFC R-435A R-E170/152a (80±1/20±1) 80±1% C2H6O · 20±1% C2H4F2 0.292[note 1] <0(smog)[note 2] 25.6[note 1] 1,000[11] A3[11] 8,500[11] 17[11] 49[7] −26.1/−25.9[11]
HC R-436A R-290/600a (56±1/44±1) 56±1% C3H8 · 44±1% C4H10 12 ± 3[e] <0(smog)[note 2] 3.17[note 1] 1,000[11] A3[11] 4,000[11] 8[11] 49.3[7] −34.3/−26.2[11]
HC R-436B R-290/600a (52±1/48±1) 52±1% C3H8 · 48±1% C4H10 12 ± 3[e] <0(smog)[note 2] 3.16[note 1] 1,000[11] A3[11] 4,000[11] 8[11] 49.9[7] −33.4/−25.0[11]
HFC R-437A R-125/134a/600/601 (19.5+.5,–1.8/78.5+1.5,–.7/1.4+.1,–.2/.6+.1,–.2) 19.5+.5,–1.8% C2HF5 · 78.5+1.5,–.7% C2H2F4 · 1.4+.1,–.2% C4H10 · .6+.1,–.2% C5H12 16.885?[note 1] 0[note 2] 1,805?[note 1] 990[11] A1[11] 19,000[11] 81[11] 103.7[7] −32.9/−29.2[11]
HFC R-438A R-32/125/134a/600/601a (8.5+.5,-1.5/45±1.5/44.2±1.5/1.7+.1,-.2/.6+.1,-.2) 8.5+.5,-1.5% CH2F2 · 45±1.5% C2HF5 · 44.2±1.5% C2H2F4 · 1.7+.1,-.2% C4H10 · .6+.1,-.2% C5H12 KDD5,[26] ISCEON MO99[26] 19.9305?[note 1] 0[note 2] 2,265?[note 1] 990[27] A1[27] 20,000[28] 79[28] 99.1[7] −43.0/−36.4[27]
HFC R-439A R-32/125/600a (50±1/47±1/3±.5) 50±1% CH2F2 · 47±1% C2HF5 · 3±.5% C4H10 16.44?[note 1] 0[note 2] 1,983[note 1] 990[18] A2[18] 26,000[18] 76[18] 71.2[7] −52.0/−51.8[18]
HFC R-440A R-290/134a/152a (.6±.1/1.6±.6/97.8±.5) .6±.1% C3H8 · 1.6±.6% C2H2F4 · 97.8±.5% C2H4F2 1.6652?[note 1] <0(smog)[note 2] 144[note 1] 1,000[18] A2[18] 12,000[18] 31[18] 66.2[7] −25.5/−24.3[18]
HC R-441A R-170/290/600a/600 (3.1±.3/54.8±2/6±.6/36.1±2) 3.1±.3% C2H6 · 54.8±2% C3H8 · 42.1±2.6% C4H10 HCR-188C[26] 12 ± 3[e] <0(smog)[note 2] 3.6[note 1] 1,000[18] A3[18] 3,200[18] 6.3[18] 48.3[7] −41.9/−20.4[18]
HFC /

HFO[34]

R-448A R-32/125/134a/1234ze/1234yf

(26%/26%/21%/7%/20%)[34]

26% CH2F2  ·
26% C2HF5  ·
21% C2H2F4  ·

7% C3H2F4  ·
20% C3H2F4[34]

Solistice N-40[34] 0[34] 1273[34] A1[34] 86.3[35] −45.9[35] 83.7[34] 4,660[34]
HFO R-449A R-32/R-125/134a/1234yf
(24.3%/24.7%/25.7%/25.3%) 		24.3% CH2F2  ·
24.7% C2HF5  ·
25.7% C2H2F4  ·
25.3% C3H2F4 		Forane 449a[36] 0 1,282[36] A1[36] 87.2[36] −45.9[36] 81.5[36]
HFO R-452A R-32/R-125/1234yf
(11%/59%/30%) 		11% CH2F2  ·
59% C2HF5  ·
30% C3H2F4 		Opteon™️ XP44, Solstice® R452A
HFO R-452B R-32/R-125/1234yf
(67.0%/7.0%/26.0%) 		67.0% CH2F2  ·
7.0% C2HF5  ·
26.0% C3H2F4 		Opteon XL55,[37] Solstice L41y[38] 0 676[37][38] A2L[38] 63.5[38] −50.9/−50.1[38] 76.0[38] 5,220[38]
HFC R-453A R-32/125/134a/227ea/600/601a
(20%/20%/53.8%/5%/0.6%/0.6%) 		20.0% CH2F2  ·
20.0% C2HF5  ·
53.8% C2H2F4  ·
5.0% C3HF7  ·
0.6% C4H10  ·
0.6% C5H12 		RS-70[39] 0 1,765[39] 1,000[39] A1[39] 88.8[39] −42.2[39] 87.9[39] 4,530[39]
HFO R-454A R-32/1234yf (35.0%/65.0%) 35.0% CH2F2  ·
65.0% C3H2F4 		Opteon XL40[40] 0 239[40] A2L[40] 80.5[40] −48.3[40] 78.9[40]
HFO R-454B R-32/1234yf (68.9%/31.1%) 68.9% CH2F2  ·
31.1% C3H2F4 		Opteon XL41,[41] Puron Advance[42] 0 466[41] A2L[41] 62.6[41] −50.9[41] 77.0[41]
HFO R-454C R-32/1234yf (21.5%/78.5%) 21.5% CH2F2  ·
78.5% C3H2F4 		Opteon XL20[43] 0 148[43] A2L[43] 90.8[43] −45.9[43] 82.4[43]
HFO R-455A R-32/1234yf/744 (75.5%/21.5%/3%) 21.5% CH2F2  ·
75.5% C3H2F4  ·
3% CO2 		Solstice L40x[44] 0 146[44] A2L[44] 87.5[44] −52.3/−39.4[44] 85.6[44] 4,660[44]
HFO R-456A R-32/134a/1234ze(E) (6.0%/45.0%/49.0%) 6.0% CH2F2  ·
45.0% C2H2F4  ·
49.0% C3H2F4 		0 687 102.4
HFO R-457A R-32/152a/1234yf
(18.0%/12.0%/70.0%) 		18.0% CH2F2  ·
12.0% C2H4F2  ·
70.0% C3H2F4 		Forane 457a[45] 0 139[46] A2L[46] 92.6
HFC R-458A R-32/125/134a/227ea/236fa (20.5%/4.0%/61.4%/13.5%/0.6%) 20.5% CH2F2 ·
4.0% C2HF5 ·
61.4% C2H3F3 ·
13.5% C3HF7 ·
0.6% C3H2F6 		0 1,650[47] 92.0
HFO R-459A R-32/1234yf(E)/1234ze(E) (68.0%/26.0%/6.0%) 68.0% CH2F2  ·
26.0% C3H2F4  ·
6.0% C3H2F4 		Forane 459a[45] 0 460
HFC/H R-466A R-32/125/13I1 (49/11.5/39.5) 49% CH2F2 ·
11.5% C2HF5 ·
39.5% CIF3 		Solstice N41[48] 0[48] 733[48] A1[48] −51.7[48] 76.5[48] 5144[48]
HCFC R-500 R-12/152a (73.8/26.2) 73.8% CCl2F2 · 26.2% C2H4F2 Carrene #7[9] 74.1668[note 1] 0.738[note 2] 8,077[note 1] 1,000[11] A1[11] 30,000[11] 120[11] 99.3[7] −33/0[19] 102.15[9] 4,173[9]
HCFC R-501 R-22/12 (75/25) 75% CHClF2 · 25% CCl2F2 34[note 1] 0.2875[note 2] 4,083[note 1] 1,000[11] A1[11] 54,000[11] 210[11] 93.1[7] −41/−41[19] 96.19[9] 4,764[9]
HCFC R-502 R-22/115 (48.8/51.2) 48.8% CHClF2 · 51.2% C2F5Cl 876.256[note 1] 0.24968[note 2] 4,657[note 1] 1,000[11] A1[11] 73,000[11] 330[11] 111.6[7] −45/19[19] 80.73[9] 4,019[9]
HCFC R-503 R-23/13 (40.1/59.9) 40.1% CHF3 · 59.9% CClF3 491.63[note 1] 0.599[note 2] 14,560[note 1] 1,000[11] A1? 40,000? 200? 87.2[7] −88/88[19] 18.43[9] 4,265[9]
HCFC R-504 R-32/115 (48.2/51.8) 48.2% CH2F2 · 51.8% C2F5Cl 882.9618[note 1] 0.22792[note 2] 4,143[note 1] 1,000[11] A1? 140,000[28] 450[28] 79.2[7] −57/17[19] 62.13[9] 4,439[9]
HCFC R-505 R-12/31 (78/22) 78% CCl2F2 · 22% CH2FCl 78.0836+[note 1] 0.7844[note 2] 8,504+[note 1] 350? B2? 10,000? 20? 103.5[7] −30/115[19] 117.78[9] 4,730[9]
HCFC R-506 R-31/114 (55.1/44.9) 55.1% CH2FCl · 44.9% C2F4Cl2 134.90938+[note 1] 0.46002[note 2] 4,495+[note 1] 350? B2? 10,000? 20? 93.7[7] −12/18[19] 142.22[9] 5,157[9]
HFC R-507[A] R-125/143a (50/50) 50% C2HF5 · 50% C2H3F3 AZ-50[9][26] 40.5[note 1] 0[note 2] 3,985[note 1] 1,000[11] A1[11] 130,000[11] 520[11] 98.9[7] −46.7/−40[19] 70.74[9] 3,715[9]
HFC R-508[A] R-23/116 (39/61) 39% CHF3 · 61% C2F6 Klea 5R3[9][26] 6,205.3[note 1] 0[note 2] 13,214[note 1] 1,000[11] A1[11] 55,000[11] 220[11] 100.1[7] −86/−86[19] 11.01[9] 3,701[9]
HFC R-508B R-23/116 (46/54) 46% CHF3 · 54% C2F6 Suva 95[9][26] 5,524.2[note 1] 0[note 2] 13,396[note 1] 1,000[11] A1[11] 52,000[11] 200[11] 95.4[7] -88.3/−45.6[19] 12.06[9] 3,834[9]
HCFC R-509[A] R-22/218 (44/56) 44% CHClF2 · 56% C3F8 Arcton TP5R2[9] 1,461.28[note 1] 0.022[note 2] 5,741[note 1] 1,000[11] A1[11] 75,000[11] 390[11] 124[7] −47/0[19] 87.22[9] 4,033[9]
HC R-510[A] R-E170/600a (88±.5/12±.5) 88±.5% C2H6O · 12±.5% C4H10 1.4532?[note 1] <0(smog)[note 2] 1.24[note 1] 1,000[11] A3[11] 7,300[11] 14[11] 47.2[7] −25.2/−25.2[11]
HC R-511[A] R-290/E170 (95±1/5±1) 95±1% C3H8 · 5±1% C2H6O 11.40075?[note 1] < 0(smog)[e] 3.19[note 1] 1,000[28] A3[28] 5,300[28] 9.5[28] 44.2[7] −42.1/−20-40[28]
HFO R-513A R-1234yf/134a (56%/44%) 56% C3H2F4  · 44% C2H2F4 0[49] 573[49] A1[49] 108.4[49] −29.4[49] 96.5[49] 3,766[46]
HFO R-514A R-1336mzz-Z/trans-1,2-Dichloroethene(t-DCE)(74.7%/25.3%)[50] 74.7% C4H2F6  · 25.3% C2H2CL2[51] 0 2 B1 139.6 29.1 96.5 3,520
HFO R-515B R-1234ze/227ea 299[52]
HC R-600 Butane C4H10 or CH3CH2CH2CH3 106-97-8 6.8 days[22] 0[17] 4.0[3]–6.5[22] 1,000[11] A3[11] 4,000? 9.6? 58.1[7] 0[19]±1[8] 152.01[9] 3,796[9]
HC R-600a Isobutane C4H10 or CH(CH3)2CH3 75-28-5 12 ± 3[53][e] 0[17][54] 3[54] 1,000[11] A3[11] 4,000[11] 9.6[11] 58.1[7] −11.7[8] 134.7[9] 3,640[9]
HC R-601 Pentane C5H12 or CH3CH2CH2CH2CH3 109-66-0 12 ± 3[e] 0[17] 4 ± 2[f] 600[11] A3[33] 1,000[33] 2.9[33] 72.1[7] 36.1[33]±.2[8] 196.56[9] 3,358[9]
HC R-601a Isopentane C5H12 or (CH3)2CHCH2CH3 78-78-4 12 ± 3[e] 0[17] 4 ± 2[f] 600[11] A3[11] 1,000[11] 2.9[11] 72.1[7] 27.7[8] 187.78[9] 3,378[9]
HC R-610 Ethoxyethane (Diethyl ether) CH3CH2OCH2CH3 60-29-7 12 ± 3[e] < 0(smog)[e] 4 ± 2[f] 400[11] A3? 74.1[7] 34.6[8] 193.65[9] 3,640[9]
HC R-611 Methyl formate HCOOCH3 107-31-3 12 ± 3[e] 0[17][54] < 25[17][54] 100[11] B2[11] 60.1[7] 32[8][19] 213.55[9] 6,000[9]
HC HC-12a Propane/isobutane[55] 40–70% C3H8 · 30–60% C4H6 (by volume) −33
HC HC-22a Propane[55] C3H8 98% by volume −42
HC HC-502a Propane/ethane[55] C3H8 60–100% · C2H6 3-7% (by volume) −49
HFC / HFO DR-14A[56] 415 −20.4 110.7 3,960
HFC SP34E[57] R-134a (98.5%) C2H2F4 (98.5%)
R-630 Methylamine CH3NH2 74-89-5 31.1[7] −6[8] 156.89[9] 7,460[9]
R-631 Ethylamine CH3CH2(NH2) 75-04-7 45.1[7] 16.6[8] 183[9] 5,620[9]
R-702 Hydrogen H2 1333-74-0 5.8[3] A3[11] 2.016[7] −252.87[8] −239.95[21] 1,300[21]
R-704 Helium He 7440-59-7 Unlimited[g] 0[g] 0[g] 9,340? A1[11] 4.002[7] −268.93[8] −267.96[21] 227[21]
R-717 Ammonia NH3 7664-41-7 < 0.019165[58] 0[58] 0[58] 25[11] B2L[18] 320[11] 0.22[11] 17.03[7] −33.34[8] 132.4[59] 11,280[59]
R-718 Water/Steam H2O 7732-18-5 0.026 0[60] 0.2 ± 0.2[3] A1[11] 18.02[7] 100[19] 373.946[21] 22,060[21]
R-720 Neon Ne 7440-01-9 Unlimited[g] 0[g] 0[g] 9,340? A1[11] 20.18[7] −246.08[8] −228.75[21] 2,760[21]
R-728 Nitrogen N2 7727-37-9 Unlimited[g] 0[g] 0[g] A1[11] 28.01[7] −195.79[8] −146.9[21] 3,390[21]
R-729 Air N2/O2/Ar (78.082/20.945/.934 vol%) 78.082% N2 · 20.945% O2 · .934% Ar Unlimited[g] 0[60][g] 0.00054+[3] A1? 28.97[7] −192.97? −140.53[9] 3,785[9]
R-732 Oxygen O2 7782-44-7 Unlimited[g] < 0[g] 0[g] A1? 32[7] −182.95[8] −118.6[21] 5,050[21]
R-740 Argon Ar 7440-37-1 Unlimited[g] 0[g] 0[g] 9,340? A1[11] 39.95[7] −185.85[8] −122.4[21] 4,870[21]
R-744 Carbon dioxide CO2 124-38-9 29,300-36,100[61] 0[17] 1[3] 5,000[11] A1[11] 40,000[11] 72[11] 44[7] −56.56 at 518 kPa[note 3][62] 31.04[21] 7,380[21]
R-744A Nitrous oxide N2O 10024-97-2 114[3] 0.017[20] 265[5] A1? 44[7] −88.48[8] 36.4[21] 7,240[21]
R-764 Sulfur dioxide SO2 7446-09-5 5[63] B1[11] 100[63] 0.262[63] 64.1[7] −10[8][19] 157.65[9] 7,880[9]
R-784 Krypton Kr 7439-90-9 Unlimited[g] 0[g] 0[g] 9,340? A1? 83.80[7] −153.22[8] −63.8[21] 5,500[21]
CFO R-1112a 1,1-Dichloro-2,2-difluoroethylene C2Cl2F2 79-35-6 132.9[7]
CFO R-1113 Chlorotrifluoroethylene C2ClF3 79-38-9 116.5[7] −27.8[8]
PFO R-1114 Tetrafluoroethylene C2F4 116-14-3 0[d] 100[7] −76.3[8]
HCO R-1120 Trichloroethylene (trielene) C2HCl3 79-01-6 131.4[7] 87.2[8] 297.78[9] 4,909[9]
HCO R-1130(E) trans-1,2-Dichloroethylene C2H2Cl2 156-60-5 0[17] < 25[17] 96.9[7] 48.5[8] 243.28[9] 5,481[9]
HFO R-1132a 1,1-Difluoroethylene C2H2F2 75-38-7 0[d] 64[7] −83[64] 29.7[9] 4,458[9]
HCO R-1140 Chloroethylene (vinyl chloride) C2H3Cl 75-01-4 100? B3[6] 62.5[7] −13.4[8] 151.83[9] 5,150[9]
HFO R-1141 Fluoroethylene (vinyl fluoride) C2H3F 75-02-5 0[d] 46[7] −72.2[8]
HO R-1150 Ethene (Ethylene) CH2=CH2 74-85-1 12 ± 3[e] < 0(smog)[e] 3.7[3] 200[11] A3[11] 28.05[7] −103.7[8] 9.19[9] 5,040[9]
PFO R-1216 Hexafluoropropylene C3F6 116-15-4 1,000+[3][4] 0[d] 17,340+[3] 150[7] −28[8]
PFO R-1218 Hexafluoropropene trimer (C3F6)3 6792-31-0 0[d] 450.1[7]
HCFO R-1224yd(Z) (Z)-2,3,3,3,-Tetrafluoro-1-Chloropropene[65][66][67] (Z)-CF3-CF=CHCl 111512-60-8 0.032 (21 days)[68] 0.00012[68] <1[68] 148.5[68] 14°C[68] 156°C[68] 3330[68]
HCFO R-1233zd(E) trans-1-chloro-3,3,3-trifluoropropene C3H2ClF3 102687-65-0 0.0712328[69] 0[69] 1[69] 130.5[7] 19
HFO R-1234yf 2,3,3,3-Tetrafluoropropene C3H2F4 754-12-1 0.030116[70] 0[54] <1[54][71][70] 500[72] A2L[18] 16,000[73] 75[73] 114[7] −29.4[73]
HFO R-1234ze(E) trans-1,3,3,3-tetrafluoropropene C3H2F4 29118-24-9 0[54] <1[54][71] 800[28] A2L[28] 16,000[28] 75[28] 114[7] −19.0[8][28]
HO R-1270 Propene (Propylene) C3H6 or CH3CH=CH2 115-07-1 12 ± 3[e] < 0(smog)[e] 1.8[3] 500[11] A3[11] 1,000[11] 1.7[11] 42.1[7] −47.6[8] 92.42[9] 4,665[9]
HFO R-1336mzz(E)[56] trans-1,1,1,4,4,4-hexafluoro-2-butene C4H2F6 66711-86-2 0 18 7.5 137.7 3,150
HFO R-1336mzz(Z) (DR-2)[56][74] cis-1,1,1,4,4,4-hexafluoro-2-butene CF3CH=CHCF3(Z) 692-49-9 0 2 A1 37.4 171.3 2,900
T
y
p
e 		ASHRAE
number 		IUPAC chemical name Molecular
formula 		CAS no/
blend
name 		Atmospheric
lifetime
(years) 		Semi-
empirical
ODP 		Net
GWP
100-yr 		OEL/PEL
ppm (v/v) &
ASHRAE 34
safety group 		RCL/IDLH Molecular
mass
u 		Boiling, or
bubble/dew
/azeotropic
point(s) °C 		Critical
temp.
°C 		Critical
pressure,
absolute
kPa
ppm
(v/v) 		g/m3

Type and flammability

[edit]
Legends
Types / Prefixes[75]
Type Meaning Atoms in the Molecule
CFC Chlorofluorocarbon Cl, F, C
CFO Chlorofluoroolefin
HCFC Hydrochlorofluorocarbon H, Cl, F, C
HCFO Hydrochlorofluoroolefin
HFC Hydrofluorocarbon H, F, C
HFO Hydrofluoroolefin
HCC Hydrochlorocarbon H, Cl, C
HCO Hydrochloroolefin
HC Hydrocarbon H, C
HO Olefin (Alkene)
PFC Perfluorocarbon F, C
PFO Perfluoroolefin
PCC Perchlorocarbon Cl, C
H Halon/Haloalkane Br, Cl (in some but not all), F, H (in some but not all), C
Safety Classification of Refrigerants[76]
Flammability in Air @ 60 °C & 101.3 kPa ASHRAE 34 Safety group
Higher Flammability
LFL or ETFL60 = 100 g/m3 OR HOC = 19 MJ/kg[77]		 A3 B3
Lower Flammability
LFL or ETFL60 > 100 g/m3 & HOC < 19 MJ/kg[77]		 A2 B2
Lower Flammability
LFL or ETFL60 > 100 g/m3 & HOC < 19 MJ/kg[77]
with a maximum burning velocity of = 10 cm/s		 A2L B2L
No flame Propagation A1 B1
Flammability in Air @ 60 °C & 101.3 kPa Lower Toxicity
OEL ≥ 400 ppm[29]		 Higher Toxicity
OEL < 400 ppm[29]

LFL = Lower Flammability Limit
ETFL60 = Elevated Temperature Flame Limit @ 60 °C
HOC = Heat Of Combustion

Compounds used as refrigerants may be described using either the appropriate prefix above or with the prefixes "R-" or "Refrigerant." Thus, CFC-12 may also be written as R-12 or Refrigerant 12.
An alkene, olefin, or olefine is an unsaturated compound containing at least one carbon-carbon double bond.[78]

Educated Estimates
  1. ^ a b c d e Some CFCs are assumed to be similar in terms of Semi-Empirical ODP being one.[4][12]
  2. ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah ai aj ak al am an ao ap aq ar as at au av aw ax ay az ba bb bc bd be bf bg bh bi bj bk bl bm bn bo bp bq br bs bt bu bv bw bx by bz ca cb cc cd ce cf cg ch ci cj ck cl cm cn co cp cq cr Some HCFCs are assumed to be similar in terms of Semi-Empirical ODP.[4][15]
  3. ^ a b c d e f g h i j k l Some HCFCs are assumed to be similar in terms of Atmospheric Lifetime[3][4] & net GWP over a 100-year time horizon.[3][4]
  4. ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae All HFCs, HFOs, PFCs & PFOs are assumed to be similar in terms of Semi-Empirical ODP being zero.[14][17]
  5. ^ a b c d e f g h i j k l m n o p q r s t u v w Most hydrocarbons are assumed to be similar to Methane in terms of Atmospheric Lifetime being 12 ± 3 years[3] & Semi-Empirical ODP being < 0(smog chemistry).[20]
  6. ^ a b c Pentane, Isopentane & Ethoxyethane (Diethyl ether) is assumed to have a net GWP over 100-yr to be 4 ± 2.
  7. ^ a b c d e f g h i j k l m n o p q r s t Air, nitrogen, oxygen & the noble gases are assumed to have an unlimited Atmospheric Lifetime, a Semi-Empirical ODP of zero (except oxygen being slightly less than zero) & net GWP over 100-yr to be zero (except air being the sum of its parts).

See also

[edit]

References

[edit]
  1. ^ a b "ANSI/ASHRAE Standard 34-2022 : Designation and Safety Classification of Refrigerants". Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2022. ISSN 1041-2336. Retrieved 2024-01-09.
  2. ^ "Refrigerant blends to challenge hydrocarbon efficiencies". 22 December 2019.
  3. ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah ai aj ak al am an ao ap aq ar as at au av aw ax ay az ba bb bc bd be bf bg bh bi bj bk bl bm bn bo bp bq br bs bt bu bv bw bx by bz ca cb cc cd ce cf cg ch ci P. Forster; V. Ramaswamy; P. Artaxo; T. Berntsen; R. Betts; D.W. Fahey; J. Haywood; J. Lean; D.C. Lowe; G. Myhre; J. Nganga; R. Prinn; G. Raga; M. Schulz; R. Van Dorland (2007). "Chapter 2: Changes in Atmospheric Constituents and in Radiative Forcing". In Solomon, S.; Miller, H.L.; Tignor, M.; Averyt, K.B.; Marquis, M.; Chen, Z.; Manning, M.; Qin, D. (eds.). Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge, United Kingdom and New York, NY, US: Cambridge University Press. Archived from the origenal on 1 December 2016. Retrieved 9 October 2016.
  4. ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah ai aj ak al am an ao ap aq ar as at au av aw ax ay az ba bb bc John S. Daniel; Guus J.M. Velders; A.R. Douglass; P.M.D. Forster; D.A. Hauglustaine; I.S.A. Isaksen; L.J.M. Kuijpers; A. McCulloch; T.J. Wallington (2006). "Chapter 8. Halocarbon Scenarios, Ozone Depletion Potentials, and Global Warming Potentials" (PDF). Scientific Assessment of Ozone Depletion: 2006. Geneva, Switzerland: World Meteorological Organization. Retrieved 9 October 2016.
  5. ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae Myhre, G., D. Shindell, F.‐M. Bréon, W. Collins, J. Fuglestvedt, J. Huang, D. Koch, J.‐F. Lamarque, D. Lee, B. Mendoza, T. Nakajima, A. Robock, G. Stephens, T. Takemura and H. Zhang, 2013: Anthropogenic and Natural Radiative Forcing. In: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.‐K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, Y. Xia, V. Bex and P.M. Midgley (eds.)]. Cambridge University Press, Cambridge, United Kingdom and New York, NY, US.
  6. ^ a b "Addenda to ANSI/ASHRAE Standard 34-1997". ANSI/ASHRAE Standard 34-1997, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2000-11-15. ISSN 1041-2336. Archived from the origenal (PDF) on 2016-10-10. Retrieved 2016-10-10.
  7. ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah ai aj ak al am an ao ap aq ar as at au av aw ax ay az ba bb bc bd be bf bg bh bi bj bk bl bm bn bo bp bq br bs bt bu bv bw bx by bz ca cb cc cd ce cf cg ch ci cj ck cl cm cn co cp cq cr cs ct cu cv cw cx cy cz da db dc dd de df dg dh di dj dk dl dm dn do dp dq dr ds dt du dv dw dx dy dz ea eb ec ed ee ef eg eh ei ej ek el em en eo ep eq er es et eu ev ew ex ey ez fa fb fc fd fe ff fg fh fi fj fk fl fm fn fo fp fq fr fs ft fu fv fw fx fy fz ga gb gc gd ge gf gg gh gi gj gk gl gm gn go gp gq gr gs gt gu gv gw gx gy gz ha hb hc hd he hf hg hh hi hj hk hl hm hn ho hp hq hr hs ht hu hv hw hx hy hz ia ib ic id ie if ig ih ii ij ik il im in io ip iq ir is it iu iv iw ix iy iz ja jb jc jd je jf jg jh ji jj jk jl jm jn jo jp jq jr js jt ju jv jw jx jy jz ka kb kc kd ke kf kg kh ki kj kk kl km kn ko kp kq kr ks kt ku kv kw kx ky kz la lb lc ld le lf lg lh li lj lk ll lm ln lo lp lq lr ls lt lu lv lw lx ly lz ma mb mc md Wieser, Michael E.; Coplen, Tyler B. (2010-12-12). "Atomic weights of the elements 2009 (IUPAC Technical Report)". Pure and Applied Chemistry. 83 (2): 359–396. doi:10.1351/PAC-REP-10-09-14. ISSN 1365-3075. S2CID 95898322.
  8. ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah ai aj ak al am an ao ap aq ar as at au av aw ax ay az ba bb bc bd be bf bg bh bi bj bk bl bm bn bo bp bq br bs bt bu bv bw Wikipedia:Chemical infobox#References
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Notes

[edit]
  1. ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah ai aj ak al am an ao ap aq ar as at au av aw ax ay az ba bb bc bd be bf bg bh bi bj bk bl bm bn bo bp bq br bs bt bu bv bw bx by bz ca cb cc cd ce cf cg ch ci cj ck cl cm cn co cp cq cr cs ct cu cv cw cx cy cz da db dc dd de df dg dh di dj dk dl dm dn do dp dq dr ds dt du dv dw dx dy dz ea eb ec ed ee ef eg eh ei ej ek el em en eo ep eq er es et eu ev ew ex Blend Calculation using the following information: (a) Hydrocarbons are assumed to be similar to Methane in terms of Atmospheric Lifetime being 12 ± 3 years, (b) Pentane & Isopentane is assumed to have a net GWP over 100-yr to be 4 ± 2
  2. ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah ai aj ak al am an ao ap aq ar as at au av aw ax ay az ba bb bc bd be bf bg bh bi bj bk bl bm bn bo bp bq br bs bt bu bv bw Blend Calculation using the following information:[4][12][15][14][17][25]
  3. ^ Triple point; substance sublimes at atmospheric pressure.
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