Formula Rio

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Formul ario

P1V1/ T1 = P2V2/ T2 , PV = nRT , P + an


2
/V
2
(V- nb) = nRT
1 atm = 760 mm de Hg
K = C + 273 R = 0.082 atm L / K mol Pt = P1 + P2 +Pn
!"me#o de $%ogad#o& 6.02 ' 10
23
a#t()*la+
, en e+o de $ = -g#amo+ de $/ g#amo+ totale+. ' 100
, en %ol*men de $ = -%ol*men de $ / %ol*men total. ' 100
/ = mole+ de +ol*to / L de +ol*)01n, 2 de mole+ = g#amo+ / e+o
mole)*la#
m = mole+ de +ol*to / Kg de d0+ol%ente
! = 2 de e+o+ e3*0%alente+ / L de +ol*)01n
2 de e+o+ e3*0%alente+ = g de +ol*to / Pe+o e3*0%alente de +ol*to
Pe+o e3*0%alente de +ol*to = P/ / H
+
+*4+t0 t*4le+ o +*4+t0t*0 do+
5$ = mole+ de $ / mole+ de +ol*to + mole+ de d0+ol%ente
P1 = P0 5 d0+ol%ente
P = P0 6 P1 = P0 5 +ol*to +ol*to+ 01n0)o+
T) = K) m = T0 6 T ,
Te4 = Ke4 m = T 6 T0
= /RT
H #ea))01n = H #od*)to+ 6 H #ea)t0%o+
7 #ea))01n= 7 #od*)to+ 6 7 #ea)t0%o+ 8 = H 6 T 7
9#den
de
#ea))01
n
Le: de
%elo)0dad
;)*a)0 1n 0nteg#ada
)on)ent#a)01n6
t0emo
L(nea #e)ta V0da med0a
0
V = k <$= t = <$= 0 6 kt <$= +. t0emo t 1/2 = <$= o /2K
1
V = k <$= ln<$= t = ln<$= 0 6 kt ln <$= +.
t0emo
t 1/2 = ln2 / K
2
V = k <$=
2
1/<$= t = 1/ <$= o +
>t
1/ <$= +.
t0emo
t 1/2 = 1 / K<$= o
K) = <C=
)
<?=
d
... #od*)to+ / <$=
a
<@=
4
....#ea)t0%o+
K = K) -0.0821 T.
n -ga+e+.
, n-ga+e+. =n -#od*)to+ ga+e+. 6 n -#ea)t0%o+ ga+e+.
KA = <H
+
=<9H
6
= = 1 ' 10
61B
, H + 9H = 1B
H = 6 log <H
+
=
;)elda = ;Cnodo + ;)Ctodo o ;)elda = ;)Ctodo 6 ;Cnodo
; = ;D6 RT/nE -ln F. o ;= ;D 6 0.0GH2V/n -log F. o ;= ;D6 0.02G7/n -lnF.
8D = 6 nE;D)elda = 6 RT lnKe3*0l04#0o , ;D = RT/nE -lnKe3*0l04#0o .
;D)elda = 0.02G7/n -ln >e3*0l04#0o .
1 $me#e = 1Co*lom4/+eg*ndo, 1$ = 1 C/+
Co##0ente ' t0emo en +eg*ndo+ = )a#ga, $ ' + =- C/+. = C
T0emo en +eg*ndo+ = C/$
1E = H6G00C/mol e6
Te = i Ke m
Tc = i Kc m
= i MRT
i = # de iones de
soluto en solucin

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