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    Tutorial 1 Question

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    Soon Lee
    This tutorial document contains 5 problems related to chemical processes and thermodynamics. Problem 1 involves calculating heat capacity and enthalpy changes for hydrogen cyanide. Problem 2 estimates enthalpy of steam at different temperatures and pressures using steam tables and ideal gas behavior. Problem 3 calculates heat input required to heat chlorine gas at constant pressure and in a closed vessel. Problem 4 calculates heat required to increase sodium carbonate temperature using true and estimated heat capacities. Problem 5 involves using steam to heat methanol vapor in a countercurrent heat exchanger.

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    Tutorial 1 Question

    Uploaded by

    Soon Lee
    126 views2 pages
    This tutorial document contains 5 problems related to chemical processes and thermodynamics. Problem 1 involves calculating heat capacity and enthalpy changes for hydrogen cyanide. Problem 2 estimates enthalpy of steam at different temperatures and pressures using steam tables and ideal gas behavior. Problem 3 calculates heat input required to heat chlorine gas at constant pressure and in a closed vessel. Problem 4 calculates heat required to increase sodium carbonate temperature using true and estimated heat capacities. Problem 5 involves using steam to heat methanol vapor in a countercurrent heat exchanger.

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    This tutorial document contains 5 problems related to chemical processes and thermodynamics. Problem 1 involves calculating heat capacity and enthalpy changes for hydrogen cyanide. Problem 2 estimates enthalpy of steam at different temperatures and pressures using steam tables and ideal gas behavior. Problem 3 calculates heat input required to heat chlorine gas at constant pressure and in a closed vessel. Problem 4 calculates heat required to increase sodium carbonate temperature using true and estimated heat capacities. Problem 5 involves using steam to heat methanol vapor in a countercurrent heat exchanger.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    126 views2 pages

    Tutorial 1 Question

    Uploaded by

    Soon Lee
    This tutorial document contains 5 problems related to chemical processes and thermodynamics. Problem 1 involves calculating heat capacity and enthalpy changes for hydrogen cyanide. Problem 2 estimates enthalpy of steam at different temperatures and pressures using steam tables and ideal gas behavior. Problem 3 calculates heat input required to heat chlorine gas at constant pressure and in a closed vessel. Problem 4 calculates heat required to increase sodium carbonate temperature using true and estimated heat capacities. Problem 5 involves using steam to heat methanol vapor in a countercurrent heat exchanger.

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    TUTORIAL 1

    SKKK2123 (Principle Chemical Processes II)


    1. The heat capacity at constant pressure of hydrogen cyanide is given by
    the expression:
    Cp [J/mol.C] = 35.3 + 0.0291 T (C)
    (a) Write an expression for the heat capacity at constant volume for HCN,
    assuming ideal gas behaviour
    (b) Calculate H [J/mol] for the constant pressure:
    HCN (25 C, 1 atm) HCN (100 C, 1 atm)
    (c) Calculate U [J/mol] for the constant volume process:
    HCN (25 C, 1 m3/kmol) HCN (100 C, 1 m3/kmol)
    (d) If the process of part (b) were carried out in such a way that the initial
    and final pressures were each 1 atm but the pressure varied during the
    heating, the value of H would still be what you calculated assuming a
    constant pressure. Why is this so?

    2. Estimate the specific enthalpy of steam (kJ/kg) at 350 C and 100 bar
    relative to steam at 100 C and 1 atm using:
    (a)

    The steam table

    (b)

    Table B2 and assuming ideal gas behaviour

    (c)

    What is the physical significance of the difference between the values of


    H calculated by the two methods?

    3. Chlorine gas is to be heated from 100 C and 1 atm to 200 C.

    (a)

    Calculate the heat input (kW) required to heat a stream of the gas
    flowing at 5 kmol/s at constant pressure

    (b)

    Calculate the heat input (kJ) required to raise the temperature of 5 kmol
    of chlorine in a closed rigid vessel from 100 C and atm to 200 C.

    4. Calculate the heat required to raise 50 kg of solid sodium carbonate


    (Na2CO3) from 10 C to 50 C at 1 atm using:
    (a)
    (b)

    The true heat capacity of Na2CO3, which is 1.14 kJ/kg.C


    A heat capacity estimated by Koops rule. Calculate the percentage error
    in the latter calculation.

    5. Saturated steam at 300 C is used to heat a countercurrently flowing


    stream of methanol vapour from 65 C to 260 C in an adiabatic heat
    exchanger. The flow rate of the methanol is 5500 standard liters per
    minute (STP), and the steam condenses and leaves the heat exchanger as
    liquid water at 90 C.

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