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    C-X C-CL C-BR C - H: IR Spectroscopy Tutorial: Alkyl Halides

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    jinzo88
    Alkyl halides contain a carbon-halogen (C-X) bond where X is a halogen such as bromine or chlorine. The infrared spectroscopy spectrum of alkyl halides shows absorption bands in three regions: C-H wag of -CH2X from 1300-1150 cm-1, general C-X stretches from 850-515 cm-1, and specific C-Cl stretches from 850-550 cm-1 or C-Br stretches from 690-515 cm-1. The spectra can be complicated by other absorptions from 1250-770 cm-1, especially in smaller alkyl halides.

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    C-X C-CL C-BR C - H: IR Spectroscopy Tutorial: Alkyl Halides

    Uploaded by

    jinzo88
    91 views2 pages
    Alkyl halides contain a carbon-halogen (C-X) bond where X is a halogen such as bromine or chlorine. The infrared spectroscopy spectrum of alkyl halides shows absorption bands in three regions: C-H wag of -CH2X from 1300-1150 cm-1, general C-X stretches from 850-515 cm-1, and specific C-Cl stretches from 850-550 cm-1 or C-Br stretches from 690-515 cm-1. The spectra can be complicated by other absorptions from 1250-770 cm-1, especially in smaller alkyl halides.

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    Infrarred IR

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    Infrarred

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    Alkyl halides contain a carbon-halogen (C-X) bond where X is a halogen such as bromine or chlorine. The infrared spectroscopy spectrum of alkyl halides shows absorption bands in three regions: C-H wag of -CH2X from 1300-1150 cm-1, general C-X stretches from 850-515 cm-1, and specific C-Cl stretches from 850-550 cm-1 or C-Br stretches from 690-515 cm-1. The spectra can be complicated by other absorptions from 1250-770 cm-1, especially in smaller alkyl halides.

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    © All Rights Reserved
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    91 views2 pages

    C-X C-CL C-BR C - H: IR Spectroscopy Tutorial: Alkyl Halides

    Uploaded by

    jinzo88
    Alkyl halides contain a carbon-halogen (C-X) bond where X is a halogen such as bromine or chlorine. The infrared spectroscopy spectrum of alkyl halides shows absorption bands in three regions: C-H wag of -CH2X from 1300-1150 cm-1, general C-X stretches from 850-515 cm-1, and specific C-Cl stretches from 850-550 cm-1 or C-Br stretches from 690-515 cm-1. The spectra can be complicated by other absorptions from 1250-770 cm-1, especially in smaller alkyl halides.

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    IR Spectroscopy Tutorial: Alkyl Halides

    Alkyl halides are compounds that have a CX bond, where X is a halogen: bromine, chlorine, fluorene, or iodine
    (usually Br or Cl in the organic chemistry teaching labs). In general, CX vibration frequencies appear in the region
    850-515 cm-1, sometimes out of the range of typical IR instrumentation. CCl stretches appear from 850550 cm-1,
    while CBr stretches appear at slightly lower wavenumbers from 690-515 cm-1. In terminal alkyl halides, the C
    H wag of the CH2X group is seen from 1300-1150 cm-1. Complicating the spectra is a profusion of absorptions
    throughout the region 1250-770 cm-1, especially in the smaller alkyl halides. Note that all of these bands are in the
    fingerprint region.
    In summary, the following bands are specific to alkyl halides:

    CH wag (-CH2X) from 1300-1150 cm-1


    CX stretches (general) from 850-515 cm-1
    o CCl stretch 850-550 cm-1
    o CBr stretch 690-515 cm-1

    The spectra of 1-bromopropane and 1-chloro-2-methylpropane are shown below. Note the CBr or CCl stretches in
    the region 850-515 cm-1. They also show CBr or CCl wag in the region 1300-1150 cm-1.

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