Scribd Logo
Upload

Welcome to Scribd!

  • 23 views

    PC1 Formulaesheet Final

    Uploaded by

    Izzat Fuad Parkjat
    This document provides definitions and formulas for important physical chemistry concepts and constants. It includes formulas for thermodynamics, kinetics, electrochemistry, and enzyme mechanisms. Key constants defined include the gas constant R, Faraday's constant F, and Avogadro's number NA. Thermodynamic relationships covered are Gibbs free energy G, entropy S, and the reaction quotient Q. Kinetics relationships include rate laws and half-lives for zero, first, and second-order reactions.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd

    PC1 Formulaesheet Final

    Uploaded by

    Izzat Fuad Parkjat
    23 views3 pages
    This document provides definitions and formulas for important physical chemistry concepts and constants. It includes formulas for thermodynamics, kinetics, electrochemistry, and enzyme mechanisms. Key constants defined include the gas constant R, Faraday's constant F, and Avogadro's number NA. Thermodynamic relationships covered are Gibbs free energy G, entropy S, and the reaction quotient Q. Kinetics relationships include rate laws and half-lives for zero, first, and second-order reactions.

    Original Title

    PC1formulaesheetFinal

    Copyright

    © Attribution Non-Commercial (BY-NC)

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document provides definitions and formulas for important physical chemistry concepts and constants. It includes formulas for thermodynamics, kinetics, electrochemistry, and enzyme mechanisms. Key constants defined include the gas constant R, Faraday's constant F, and Avogadro's number NA. Thermodynamic relationships covered are Gibbs free energy G, entropy S, and the reaction quotient Q. Kinetics relationships include rate laws and half-lives for zero, first, and second-order reactions.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    23 views3 pages

    PC1 Formulaesheet Final

    Uploaded by

    Izzat Fuad Parkjat
    This document provides definitions and formulas for important physical chemistry concepts and constants. It includes formulas for thermodynamics, kinetics, electrochemistry, and enzyme mechanisms. Key constants defined include the gas constant R, Faraday's constant F, and Avogadro's number NA. Thermodynamic relationships covered are Gibbs free energy G, entropy S, and the reaction quotient Q. Kinetics relationships include rate laws and half-lives for zero, first, and second-order reactions.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    You are on page 1of 3

    Final Fall 2010 Physical Chemistry I

    Constants
    g =9.81ms
    2
    gravitational acceleration
    N
    A
    =6.02210
    23
    mol
    1
    Avogadro constant
    R =8.314J mol
    1
    K
    1
    =0.08206Latmmol
    1
    K
    1
    gas constant
    1atm760Torr =760mmHg 1.0132510
    5
    Pa
    1bar 10
    5
    Pa
    F =9.648510
    4
    Cmol
    1
    Faraday constant
    Formulas
    hydrostatic pressure P =gh
    G H TS =U +PV TS; dG =V dP SdT
    T =const : G =V (P
    2
    P
    1
    ) (solids or liquids), G =nRT ln
    _
    P
    2
    P
    1
    _
    (ideal gas)

    r
    S

    (product)

    (reactant)

    r
    G

    f
    G

    (product)

    f
    G

    (reactant)
    Daltons law: P =

    J
    P
    J
    ; P
    J
    =
    n
    J
    RT
    V
    ; P
    J
    =x
    J
    P
    x
    J
    =b
    J
    M
    solv
    ; c
    J
    =b
    J

    solv
    ; M
    solv
    in kg/mol;
    solv
    in kg/L

    J
    (T, P) =

    J
    +RT lna
    J
    ; ideal gas: a
    J
    =
    P
    J
    P

    ; pure solid or liquid: a


    J
    =1;
    ideal solution: a
    J
    =x
    J
    ; ideal-dilute: solvent a
    A
    =x
    A
    and solute a
    B
    =
    [B]
    c

    electrolytes: a
    B
    =
    B
    b
    B
    b

    , log

    =A

    z
    +
    z

    I , A =0.509, I =
    1
    2

    i
    z
    2
    i
    (b
    i
    /b

    )
    Gibbs phase rule F =2+C
    vapor pressure of volatile ideal solutions: P =P

    B
    +
    _
    P

    A
    P

    B
    _
    x
    A
    ; P =
    P

    A
    P

    B
    P

    A
    +
    _
    P

    B
    P

    A
    _
    y
    A
    y
    A
    =
    x
    A
    P

    A
    P

    B
    +
    _
    P

    A
    P

    B
    _
    x
    A
    , x
    A
    =
    y
    A
    P

    B
    P

    _
    P

    A
    P

    B
    _
    y
    A
    lever rule: n

    =n

    Final Fall 2010 Physical Chemistry I


    regular solutions: G
    E
    =wx
    A
    x
    B
    Margules equations:
    A
    =exp
    _
    wx
    2
    B
    RT
    _
    ,
    B
    =exp
    _
    wx
    2
    A
    RT
    _

    r
    G =
    r
    G

    +RT lnQ
    Q =

    i
    a

    i
    i
    K =Q
    eq
    =

    i
    a

    i
    i ,eq
    equilibrium constant

    r
    G

    =RT lnK; K =exp


    _

    r
    G

    RT
    _
    ; ln
    _
    K
    2
    K
    1
    _
    =

    r
    H

    R
    _
    1
    T
    2

    1
    T
    1
    _
    E
    cell
    =E =E
    R
    E
    L
    (intensive quantity)

    r
    G =FE;
    r
    S =F
    _
    E
    T
    _
    P
    ;
    r
    H =F
    _
    E +T
    _
    E
    T
    _
    P
    _
    E =E

    RT
    F
    lnQ Nernst equation
    E

    =
    RT
    F
    lnK; E
    +
    =E

    +16.1
    RT
    F

    H
    ; E
    +
    =
    RT
    F
    lnK

    d[J]
    dt
    =
    J
    v
    zero order: A
    k
    P,
    d[A]
    dt
    =k, [A](t ) =[A]
    0
    kt
    rst order: A
    k
    P,
    d[A]
    dt
    =k[A], ln
    _
    [A](t )
    [A]
    0
    _
    =kt , [A](t ) =[A]
    0
    exp(kt )
    second order: A
    k
    P,
    d[A]
    dt
    =k[A]
    2
    , [A](t ) =
    [A]
    0
    1+kt [A]
    0
    second order: A+B
    k
    P,
    d[A]
    dt
    =k[A][B],
    1
    [B]
    0
    [A]
    0
    ln
    _
    [A]
    0
    [B](t)
    [A](t ) [B]
    0
    _
    =kt ;
    if [B]
    0
    =[A]
    0
    , then
    d[A]
    dt
    =k[A]
    2
    other orders:(x =1) A
    k
    P,
    d[A]
    dt
    =k[A]
    x
    ,
    1
    x 1
    _
    1
    [A](t )
    x1

    1
    [A]
    x1
    0
    _
    =kt
    half-life: t
    1/2
    =
    ln2
    k
    =0.693k
    1
    rst order; t
    1/2
    =
    2
    x1
    1
    (x 1)k[A]
    x1
    0
    (x =1) other orders
    k = Aexp
    _

    E
    a
    RT
    _
    relaxation methods: A

    B, x(t ) =[A](t ) [A]


    eq
    =x(0) exp(t /), =
    1
    k
    1
    +k
    1
    , K
    c
    =k
    1
    /k
    1
    Michaelis-Menten mechanism: E+S
    k
    1

    k
    1
    (ES)
    k
    2
    P+E,
    Final Fall 2010 Physical Chemistry I
    d[P]
    dt
    =v =
    k
    2
    [E]
    0
    [S]
    K
    M
    +[S]
    , K
    M
    =
    k
    1
    +k
    2
    k
    1
    ,
    k
    cat
    =k
    2
    =
    v
    max
    [E]
    0
    , =
    k
    cat
    K
    M

    You might also like

    pFad - Phonifier reborn

    Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

    Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


    Alternative Proxies:

    Alternative Proxy

    pFad Proxy

    pFad v3 Proxy

    pFad v4 Proxy