Weigel + Schmidt Lackchemie GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

WS-Zink Spray 80/81

Print date: 30.04.2012 Product code: 3999 Page 1 of 11

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

WS-Zink Spray 80/81

Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture

Paint, Varnish. industrial paint

Uses advised against

Do not use for products which come into contact with the food stuffs.
Details of the supplier of the safety data sheet

Company name: Street: Place: Telephone: e-mail: Responsible Department:

Emergency telephone:

Weigel + Schmidt Lackchemie GmbH Am Sportplatz 5 D-63791 Karlstein-Dettingen +49 6188 9575-0 h-p.schmidt@ws-lackchemie.de Abt. Produkt / Sicherheit +49 6188 9575-0

Telefax: +49 6188 9575-30

SECTION 2: Hazards identification

Classification of the substance or mixture

Indications of danger : Extremely flammable, Dangerous for the environment R-phrases: Extremely flammable. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Label elements

Danger symbols:

F+ - Extremely flammable; N - Dangerous for the environment

F+ - Extremely flammable
R phrases 12 50/53 S phrases 02 03 09 15 16 21 35 41 42 43
Revision No: 1,06

N - Dangerous for the environment Extremely flammable. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Keep out of the reach of children. Keep in a cool place. Keep container in a well-ventilated place. Keep away from heat. Keep away from sources of ignition - No smoking. When using do not smoke. This material and its container must be disposed of in a safe way. In case of fire and/or explosion do not breathe fumes. During spraying wear suitable respiratory equipment. In case of fire, use sand, dry chemical or alcohol-resistant foam. Do not use water.
GB - EN Revision date: 14.10.2011

Weigel + Schmidt Lackchemie GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

WS-Zink Spray 80/81

Print date: 30.04.2012 51 61 29/56 Product code: 3999 Use only in well-ventilated areas. Avoid release to the environment. Refer to special instructions / Safety data sheets. Do not empty into drains, dispose of this material and its container to hazardous or special waste collection point. Page 2 of 11

Special labelling of certain mixtures Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children.

SECTION 3: Composition/information on ingredients

Mixtures Chemical characterization Aerosole

Revision No: 1,06

GB - EN

Revision date: 14.10.2011

Weigel + Schmidt Lackchemie GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

WS-Zink Spray 80/81

Print date: 30.04.2012
Hazardous components
EC No CAS No Index No REACH No 231-175-3 7440-66-6 030-001-01-9 200-827-9 74-98-6 601-003-00-5 203-448-7 106-97-8 601-004-00-0 202-436-9 95-63-6 601-043-00-3 215-535-7 1330-20-7 601-022-00-9 203-604-4 108-67-8 601-025-00-5 202-849-4 100-41-4 601-023-00-4 215-222-5 1314-13-2 030-013-00-7 202-704-5 98-82-8 601-024-00-X Chemical name Classification GHS classification Quantity

Product code: 3999

Page 3 of 11

zinc powder - zinc dust (stabilized) N R50-53 Aquatic Acute 1, Aquatic Chronic 1; H400 H410 propane F+ R12 Flam. Gas 1; H220 butane F+ R12 Flam. Gas 1; H220 1,2,4-trimethylbenzene Xn, Xi, N R10-20-36/37/38-51-53 Flam. Liq. 3, Acute Tox. 4, Eye Irrit. 2, STOT SE 3, Skin Irrit. 2, Aquatic Chronic 2; H226 H332 H319 H335 H315 H411 xylene Xn, Xi R10-20/21-38 Flam. Liq. 3, Acute Tox. 4, Acute Tox. 4, Skin Irrit. 2; H226 H332 H312 H315 1,3,5-trimethylbenzene, mesitylene Xi, N R10-37-51-53 Flam. Liq. 3, STOT SE 3, Aquatic Chronic 2; H226 H335 H411 ethylbenzene F, Xn R11-20 Flam. Liq. 2, Acute Tox. 4; H225 H332 zinc oxide N R50-53 Aquatic Acute 1, Aquatic Chronic 1; H400 H410 cumene Xn, Xi, N R10-65-37-51-53 Flam. Liq. 3, Asp. Tox. 1, STOT SE 3, Aquatic Chronic 2; H226 H304 H335 H411

35 - 40 %

15 - 20 %

15 - 20 %

5 - 10 %

1-5%

1-5%

1-5%

1-5%

<1 %

Full text of R- and H-phrases: see section 16.

SECTION 4: First aid measures

Description of first aid measures General information In case of accident or if you feel unwell, seek medical advice immediately (show safety data sheet if possible). No administration in cases of unconsiousness or cramps. After inhalation Provide fresh air. Put victim at rest, cover with a blanket and keep warm. If victim is at risk of losing consciousness, position and transport on their side. After contact with skin After contact with skin, wash immediately with: Water. Change contaminated clothing. Take off
Revision No: 1,06 GB - EN Revision date: 14.10.2011

Weigel + Schmidt Lackchemie GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

WS-Zink Spray 80/81

Print date: 30.04.2012 Product code: 3999 Page 4 of 11 immediately all contaminated clothing, including underwear and shoes . Wash thoroughly (shower or bath). After contact with skin, wash immediately with plenty of water and soap.
After contact with eyes Rinse immediately carefully and thoroughly with eye-bath or water. If product gets into the eye, keep eyelid open and rinse immediately with large quantities of water, for at least 5 minutes. Subsequently consult an ophthalmologist. After ingestion If swallowed, immediately drink: Water. Immediately get medical attention. Do not induce vomiting. Give nothing to eat or drink. Caution if victim vomits: Risk of aspiration! Most important symptoms and effects, both acute and delayed Vapours may cause drowsiness and dizziness. Frequently or prolonged contact with skin may cause dermal irritation. Indication of any immediate medical attention and special treatment needed In case of accident or if you feel unwell, seek medical advice immediately (show safety data sheet if possible).

SECTION 5: Firefighting measures

Extinguishing media Suitable extinguishing media Carbon dioxide (CO2). Foam. Extinguishing powder. Foam. Dry extinguishing powder. Carbon dioxide (CO2). Water fog. Extinguishing media which must not be used for safety reasons High power water jet. Special hazards arising from the substance or mixture Combustible. Vapours may form explosive mixtures with air. Special exposure hazards arising from the substance itself, combustion products, resulting gases: Nitrogen oxides (NOx). Carbon monoxide. Advice for firefighters In case of fire: Wear self-contained breathing apparatus. In case of fire: Wear self-contained breathing apparatus. Additional information Use water spray/stream to protect personnel and to cool endangered containers. Use a water spray jet to knock down vapours/gases/mists. Contaminated fire-fighting water must be collected separately. Do not empty into drains or the aquatic environment. Use water spray/stream to protect personnel and to cool endangered containers. Contaminated fire-fighting water must be collected separately.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures Remove all sources of ignition. Provide adequate ventilation. Remove all sources of ignition. Provide adequate ventilation. See protective measures under point 7 and 8. Environmental precautions Do not empty into drains or the aquatic environment. Explosion hazard. Do not empty into drains or the aquatic environment. Retain contaminated washing water and dispose. Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the assimilated material according to the section on waste disposal. Treat the assimilated material according to the section on waste disposal. Suitable absorbing material: diatomaceous earth. Reference to other sections See protective measures under point 7 and 8.

Revision No: 1,06

GB - EN

Revision date: 14.10.2011

Weigel + Schmidt Lackchemie GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

WS-Zink Spray 80/81

Print date: 30.04.2012 Product code: 3999 Page 5 of 11

SECTION 7: Handling and storage

Precautions for safe handling Advice on safe handling Information for safe handling: In case of open handling equipment with built-in suction must be used. The following must be prevented: inhalation. skin contact. Eye contact. Advice on protection against fire and explosion Keep away from sources of ignition - No smoking. Vapours may form explosive mixtures with air. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed. Keep in a cool, well-ventilated place. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. Only use material in places where open light, fire and other sources of ignition can be kept away. Keep only in the original container in a cool, well-ventilated place. Advice on storage compatibility Do not store together with: Material, rich in oxygen, oxidizing. Materials to avoid: Acid. Base. Oxidizing agents. Paper. Further information on storage conditions Store only in original container. Protect against: heat. Heating causes rise in pressure with risk of bursting.

SECTION 8: Exposure controls/personal protection

Control parameters Exposure limits (EH40)
CAS No Chemical name ml/m 600 750 98-82-8 Cumene 25 50 100-41-4 Ethylbenzene 100 125 108-67-8 Trimethylbenzenes 25 95-63-6 Trimethylbenzenes 25 1330-20-7 Xylene, o-, m-, p- or mixed isomers 50 100 mg/m 1450 1810 125 250 441 552 125 125 220 441 F/ml Category TWA (8 h) STEL (15 min) TWA (8 h) STEL (15 min) TWA (8 h) STEL (15 min) TWA (8 h) STEL (15 min) TWA (8 h) STEL (15 min) TWA (8 h) STEL (15 min) Origin WEL WEL WEL WEL WEL WEL WEL WEL WEL WEL WEL WEL

106-97-8 Butane

Biological Monitoring Guidance Values (EH40)

CAS No Chemical name Parameter methyl hippuric acid Value Test material Sampling time Post shift

1330-20-7 Xylene, o-, m-, p- or mixed isomers

650 urine mmol/mol

Additional advice on limit values

source:
Revision No: 1,06 GB - EN Revision date: 14.10.2011

Weigel + Schmidt Lackchemie GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

WS-Zink Spray 80/81

Print date: 30.04.2012
Exposure controls Occupational exposure controls Refer to chapter 7. No further action is necessary. Protective and hygiene measures Change contaminated clothing. Wash hands before breaks and at the end of work. When using do not eat or drink. If technical suction or ventilation measures are not possible or are insufficient, protective breathing apparatus must be worn. Respiratory protection

Product code: 3999

Page 6 of 11

Filter respirator (full mask or mouth-piece) with filter:

Hand protection Tested protective gloves are to be worn: Pull-over gloves of rubber. NBR (Nitrile rubber). German Industry Norms (DIN) / European Norms (EN): DIN EN 374 Breakthrough times and swelling characteristics of the material must be taken into consideration. Eye protection Suitable eye protection: Goggles. Skin protection Additional body protection measures: Do not eat, drink, smoke or sneeze at the workplace. Avoid contact with skin, eye and clothing. Wash hands before breaks and at the end of work. Set out skin protection guidelines. Environmental exposure controls Refer to chapter 7 No further action is necessary.

SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties

Physical state: Colour: Odour:

Changes in the physical state Boiling point:

Aerosol characteristic characteristic

Test method

-42 C -25 C DIN EN ISO 1523 1 vol. % 13,1 vol. % 273 C DIN 51794 3,2 hPa DIN EN 12 1 g/cm 32 (3 mm) 58,17 % VOC-value (in g/l): 611,4 ~40 %

Flash point: Lower explosion limits: Upper explosion limits: Ignition temperature: Vapour pressure: (at 20 C) Density: Flow time: Solvent content:
Other information

Solid content:

SECTION 10: Stability and reactivity

Reactivity

No risks worthy of mention. Please observe the information on the safety data sheet at all times.
Revision No: 1,06 GB - EN Revision date: 14.10.2011

Weigel + Schmidt Lackchemie GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

WS-Zink Spray 80/81

Print date: 30.04.2012 Product code: 3999 Page 7 of 11
Chemical stability No risks worthy of mention. Please observe the information on the safety data sheet at all times. Possibility of hazardous reactions No risks worthy of mention. Please observe the information on the safety data sheet at all times. Conditions to avoid Keep away from heat. Ignition hazard. Danger of bursting container. Incompatible materials Reacts with : Alkalis (alkalis). Oxidizing agents. Hazardous decomposition products Thermal decomposition can lead to the escape of irritating gases and vapors.

SECTION 11: Toxicological information

Information on toxicological effects Acute toxicity Propan LC50: 56 - 80 Vol.-% (Rat. , 15 min.) Dimethylether LC50: 308 mg/L ( Rat.)
CAS No Chemical name Exposure routes 95-63-6 1,2,4-trimethylbenzene Acute oral toxicity 1330-20-7 100-41-4 xylene Acute dermal toxicity ethylbenzene Acute oral toxicity Acute dermal toxicity 1314-13-2 zinc oxide Acute oral toxicity 98-82-8 cumene Acute dermal toxicity LD50 12300 mg/kg Rabbit LD50 > 5000 mg/kg Rat LD50 LD50 3500 mg/kg 15400 mg/kg Rat Rabbit ATE 1100 mg/kg LD50 5000 mg/kg Rat Method Dose Species h

Specific effects in experiment on an animal Toxicological data are not available. Severe effects after repeated or prolonged exposure Can cause frostbite. Has de-greasing effect on the skin. Additional information on tests The classification was undertaken in accordance with the calculation method governed by the Preparations Directive (1999/45/EC).

SECTION 12: Ecological information

Toxicity

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Aquatoxicity Harmful for Water fleas.

Revision No: 1,06

GB - EN

Revision date: 14.10.2011

Weigel + Schmidt Lackchemie GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

WS-Zink Spray 80/81

Print date: 30.04.2012
CAS No 95-63-6 Chemical name Aquatic toxicity 1,2,4-trimethylbenzene Acute fish toxicity Acute crustacea toxicity 108-67-8 1,3,5-trimethylbenzene, mesitylene Acute fish toxicity Acute crustacea toxicity 100-41-4 98-82-8 ethylbenzene Acute algae toxicity cumene Acute fish toxicity Acute algae toxicity LC50 ErC50 2,7 mg/l 2,6 mg/l Leuciscus idus Selenastrum capricornutum 96 72 ErC50 3,6 mg/l Algen 96 LC50 EC50 12,5 mg/l 13 mg/l 96 48 LC50 EC50 7,72 mg/l 3,6 mg/l Pimephales promelas Daphnia 96 48 Method Dose Species h

Product code: 3999

Page 8 of 11

Persistence and degradability No data available Bioaccumulative potential No data available Partition coefficient n-octanol/water
CAS No 106-97-8 95-63-6 108-67-8 100-41-4 98-82-8 Chemical name butane 1,2,4-trimethylbenzene 1,3,5-trimethylbenzene, mesitylene ethylbenzene cumene Log Pow 2,89 3,63 3,42 3,15 3,66

Mobility in soil

No data available
Results of PBT and vPvB assessment No data available Other adverse effects No data available Further information Do not empty into drains or the aquatic environment. The classification was undertaken in accordance with the calculation method governed by the Preparations Directive (1999/45/EC). Do not allow uncontrolled leakage of product into the environment.

SECTION 13: Disposal considerations

Waste treatment methods Advice on disposal Do not empty into drains or the aquatic environment. Waste disposal according to official state regulations. Waste disposal number of waste from residues/unused products WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded 160504 chemicals; gases in pressure containers (including halons) containing dangerous substances Classified as hazardous waste. Waste disposal number of used product

Revision No: 1,06

GB - EN

Revision date: 14.10.2011

Weigel + Schmidt Lackchemie GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

WS-Zink Spray 80/81

Print date: 30.04.2012 160504 Product code: 3999 Page 9 of 11 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded chemicals; gases in pressure containers (including halons) containing dangerous substances Classified as hazardous waste.

Contaminated packaging Cleaned containers may be recycled. Handle contaminated packaging in the same way as the substance itself.

SECTION 14: Transport information

Land transport (ADR/RID) UN number: UN proper shipping name: Transport hazard class(es):

1950 AEROSOLS 2 2.1

Hazard label:

Classification code: Limited quantity:

5F LQ2

Other applicable information (land transport) : 190 - 327 - 625 :2 : B1D Inland waterways transport UN number: UN proper shipping name: Transport hazard class(es):

1950 AEROSOLS 2 2.1

Hazard label:

Classification code: Limited quantity:

5F LQ2

Other applicable information (inland waterways transport) : 190 327 625 Marine transport UN number: UN proper shipping name: Transport hazard class(es): Packing group:

1950 AEROSOLS 2 2.1

Hazard label:

Marine pollutant: Limited quantity: EmS:

Revision No: 1,06

See SP277 F-D, S-U

GB - EN Revision date: 14.10.2011

Weigel + Schmidt Lackchemie GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

WS-Zink Spray 80/81

Print date: 30.04.2012
Other applicable information (marine transport) : 63, 190, 277, 327, 959 Air transport UN/ID number: UN proper shipping name: Transport hazard class(es):

Product code: 3999

Page 10 of 11

1950 AEROSOLS 2.1 2.1

Hazard label:

Limited quantity Passenger: IATA-packing instructions - Passenger: IATA-max. quantity - Passenger: IATA-packing instructions - Cargo: IATA-max. quantity - Cargo:

Forbidden Forbidden 203 150 kg

Other applicable information (air transport) :: A1

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information

1999/13/EC (VOC):
National regulatory information

58,17 % VOC-value (in g/l): 611,4 Observe employment restrictions for young people. Observe employment restrictions for child bearing mothers and nursing. 2 - water contaminating

Employment restrictions: Water contaminating class (D):

Chemical Safety Assessment

For this substance a chemical safety assessment has not been carried out.

SECTION 16: Other information

Full text of R-phrases referred to under sections 2 and 3 10 Flammable. 11 Highly flammable. 12 Extremely flammable. 20 Harmful by inhalation. 20/21 Harmful by inhalation and in contact with skin. 36/37/38 Irritating to eyes, respiratory system and skin. 37 Irritating to respiratory system. 38 Irritating to skin. 50 Very toxic to aquatic organisms. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 51 Toxic to aquatic organisms. 53 May cause long-term adverse effects in the aquatic environment. 65 Harmful: may cause lung damage if swallowed. Full text of H-Statements referred to under sections 2 and 3 H220 Extremely flammable gas.
Revision No: 1,06 GB - EN Revision date: 14.10.2011

Weigel + Schmidt Lackchemie GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

WS-Zink Spray 80/81

Print date: 30.04.2012 H225 H226 H304 H312 H315 H319 H332 H335 H400 H410 H411 Product code: 3999 Highly flammable liquid and vapour. Flammable liquid and vapour. May be fatal if swallowed and enters airways. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. Page 11 of 11

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)

Revision No: 1,06

GB - EN

Revision date: 14.10.2011