Safety Data Sheet according to (EC) No 1907/2006 - ISO 11014-1

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SDS no. : 153499 V001.2

Loctite 510

Revision: 07.11.2008 printing date: 31.12.2008

1. Identification of the substance/preparation and of the company/undertaking

Trade name: Loctite 510 Intended use: Anaerobic Company name: Henkel AG & Co. KGaA Henkelstr. 67 40191 Dsseldorf Germany Phone: +49 (211) 797-0

E-mail address of person responsible for Safety Data Sheet: ua-productsafety.uk@uk.henkel.com

Emergency information: 24 Hours Emergency Tel: +44 (0)20 8312 0291

2. Hazards identification
Prolonged contact with skin, particularly damaged skin, may cause sensitization or dermatitis in sensitive individuals. R36/37 Irritating to eyes and respiratory system. R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

3. Composition / information on ingredients

General chemical description: Anaerobic Sealant Declaration of ingredients according to EC/1907/2006:
Hazardous components CAS-No. 1,1'-(methylenedi-pphenylene)bismaleimide 13676-54-5 Cumene hydroperoxide 80-15-9 EINECS ELINCS 237-163-4 content > 5 - <= 10 % Classification T - Toxic; R23 Xi - Irritant; R36/38, R43 N - Dangerous for the environment; R50/53 O - Oxidizing; R7 T - Toxic; R23 N - Dangerous for the environment; R51, R53 Xn - Harmful; R21/22, R48/20/22 C - Corrosive; R34 Xn - Harmful; R65 Xi - Irritant; R37 R10 N - Dangerous for the environment; R51, R53

201-254-7

> 1 - <= 3 %

Cumene 98-82-8

202-704-5

> 0,1 - <= 1 %

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For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available.

4. First aid measures

Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Seek medical advice. Eye contact: Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. Seek medical advice.

5. Fire fighting measures

Suitable extinguishing media: Carbon dioxide, foam, powder Special protection equipment for firefighters: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Hazardous combustion products: Oxides of carbon, oxides of nitrogen, irritating organic vapors.

6. Accidental release measures

Personal precautions: Avoid skin and eye contact. Ensure adequate ventilation. Environmental precautions: Do not let product enter drains. Clean-up methods: For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal.

7. Handling and storage

Handling: Use only in well-ventilated areas. Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation. Storage: Store in original containers at 8-21C (46.4-69.8F) and do not return residual materials to containers as contamination may reduce the shelf life of the bulk product.

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8. Exposure controls / personal protection

Components with specific control parameters for workplace: Valid for Great Britain Basis UK EH40 WELs
Ingredient CUMENE 98-82-8 CUMENE 98-82-8 CUMENE 98-82-8 CUMENE 98-82-8 CUMENE 98-82-8 CUMENE 98-82-8 ppm 20 50 mg/m3 100 250 Type Time Weighted Average (TWA). Short Term Exposure Limit (STEL): Skin designation: Time Weighted Average (TWA). Short Term Exposure Limit (STEL): Skin designation: Category Remarks EU-2000/39/EC EU-2000/39/EC Can be absorbed through the skin. EU-2000/39/EC EH40 WEL EH40 WEL Can be absorbed through the skin. EH40 WEL

25 50

125 250

Respiratory protection: Use only in well-ventilated areas. Hand protection: The use of chemical resistant gloves such as Nitrile are recommended. Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many influencing factors (e.g. temperature). Suitable risk assessment should be carried out by the end user. If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Wear protective glasses. Skin protection: Wear suitable protective clothing. General protection and hygiene measures: Good industrial hygiene practices should be observed.

9. Physical and chemical properties

General characteristics: Appearance Gel Pink Mild

Odor:

Phys./chem. properties:
pH-value Boiling point Flash point Vapor pressure (27 C (80.6 F)) Density () Solubility (qualitative) (Solvent: Water) Vapor density: VOC content (2004/42/EC) not applicable > 150 C (> 302 F) > 100 C (> 212 F) < 5 mm Hg 1,178 g/cm3 Slight Not available < 3 % (As defined in the Council Directive 2004/42/EC)

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10. Stability and reactivity

Conditions to avoid: Stable Materials to avoid: Reaction with strong acids. Reacts with strong oxidants. Hazardous decomposition products: Irritating organic vapours. carbon oxides. Sulphur oxides nitrogen oxides

11. Toxicological information

Oral toxicity: This material is considered to have low toxicity if swallowed. Inhalative toxicity: Irritating to respiratory system Skin irritation: May cause sensitization by skin contact. Eye irritation: Irritating to eyes.

12. Ecological information

Ecotoxicity: Toxic to aquatic organisms May cause long-term adverse effects in the aquatic environment. Do not empty into drains / surface water / ground water. Mobility: Cured adhesives are immobile. Persistence and Biodegradability: The product is not biodegradable. Bioaccumulative potential: No data available. General ecological information: Cured Loctite products are typical polymers and do not pose any immediate environmental hazards. Precautions required with respect to Environmental Hazards of articles in which this product is used should be considered.

13. Disposal considerations

Product disposal: Dispose of in accordance with local and national regulations. Contribution of this product to waste is very insignificant in comparison to article in which it is used Waste code( ): 08 04 09 waste adhesives and sealants containing organic solvents and other dangerous substances Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated.

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14. Transport information

Road transport ADR: Class: Packaging group: Classification code: Hazard ident. number: UN no.: Label: Technical name: 9 III M6 90 3082 9 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Diphenylmethane Bismaleimide)

Railroad transport RID: Class: Packaging group: Classification code: Hazard ident. number: UN no.: Label: Technical name: 9 III M6 90 3082 9 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Diphenylmethane Bismaleimide)

Inland water transport ADN: Class: Packaging group: Classification code: Hazard ident. number: UN no.: Label: Technical name: 9 III M6 3082 9 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Diphenylmethane Bismaleimide)

Marine transport IMDG: Class: Packaging group: UN no.: Label: EmS: Seawater pollutant: Proper shipping name: 9 III 3082 9 F-A ,S-F ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Diphenylmethane Bismaleimide)

Air transport IATA: Class: Packaging group: Packaging instructions (passenger) Packaging instructions (cargo) UN no.: Label: Proper shipping name: 9 III 914 914 3082 9 Environmentally hazardous substance, liquid, n.o.s. (Diphenylmethane Bismaleimide)

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15. Regulations - classification and identification

Indication of danger: N - Dangerous for the environment Xi - Irritant

Contains 1,1'-(methylenedi-p-phenylene)bismaleimide Risk phrases: R36/37 Irritating to eyes and respiratory system. R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S23 Do not breathe vapour. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S51 Use only in well-ventilated areas. S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.

16. Other information

The labelling of the product is indicated in Section 15. The full text of the R-phrases indicted by codes in this safety data sheet are as follows: R10 Flammable. R21/22 Harmful in contact with skin and if swallowed. R23 Toxic by inhalation. R34 Causes burns. R36/38 Irritating to eyes and skin. R37 Irritating to respiratory system. R43 May cause sensitization by skin contact. R48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51 Toxic to aquatic organisms. R53 May cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R7 May cause fire. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.

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