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    Instrumental Methods of Analysis Sessio

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    Mir Sahib
    Conductometric titration of mixture of acetic acid and hvdrochloric acid by sodium hvdroxide solution

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    © All Rights Reserved
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    Instrumental Methods of Analysis Sessio

    Uploaded by

    Mir Sahib
    87 views5 pages
    Conductometric titration of mixture of acetic acid and hvdrochloric acid by sodium hvdroxide solution

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    © © All Rights Reserved

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    Conductometric titration of mixture of acetic acid and hvdrochloric acid by sodium hvdroxide solution

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    87 views5 pages

    Instrumental Methods of Analysis Sessio

    Uploaded by

    Mir Sahib
    Conductometric titration of mixture of acetic acid and hvdrochloric acid by sodium hvdroxide solution

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 5

    Course No: Chem 352 Course Title: Instrumental Methods of Analysis

    Sessional

    Date of perforrnance: 19/01/14 Group No: 06 (A-2) Group members ID: 1002045
    1002053

    t002057 1002058 0402043

    Experiment No: 03 Name of the experiment: Conductometric titration of mixture of acetic acid and hvdrochloric acid by sodium hvdroxide solution

    1.

    OBSERYED DATA

    Table 01: Observed data for standardization of sodium hvdroxide bv oxalic acid No. of
    observation

    Volume of NaOH solution taken/ml

    0l
    02 03 04

    l0
    10 10 10

    Burette readine/ml Initial Final 7.0 27.7 1.9 22.7 22.8 43.3 6.5 27.3

    Volume of oxalic acid used/ml


    20.7 20.5

    Mean volume acid used / ml

    of

    20J

    / 20.8 /

    20.8-

    ",/

    Table 02: Observed values solution added

    of specific conductance

    and volume of sodium hvdroxide

    No. of observation

    0l
    02
    03

    o4
    05

    Volume of sodium hydroxide added/ml 0.0 0.2 0.4 0.6 0.9


    1.2

    Specific conductance, Lr/mS


    3.49 3.43
    3.34

    06
    07

    08 09
    10

    t.4 r.6
    1.9 2.1

    3.23 3.05 2.89 2.78 2.66 2.53


    2.41

    1t
    12

    2.3 2.6

    2.5)

    2.rl

    l3 t4 l5
    16

    2.8 3.2
    3.5 3.8

    2.04
    1.81 1.68 1.57 1.43

    t7
    18

    4.t
    4.4 4.7 5.0
    5.3

    1.36
    1.35

    t9
    20

    1.35

    2l
    22
    23

    t.37
    1.34 1.38
    1,.39

    5.6
    5.9 6.3

    24
    25

    6.7
    7.0

    26 27
    28

    29 30

    7.4 7.6 8.0


    8.3

    1.43 1.45 1.48

    l.5l
    1.53

    t.s6
    1.59

    3l
    32
    JJ

    8.6 8.9 9.2


    9.5

    t.62
    1.65

    34
    35

    9.8

    t.77 r.82

    36
    37 38 39

    l0.l
    10.4 10.8 11.2 I 1.5 11.9

    l.9t
    .2.04 2.17
    2.31

    40

    4t
    42
    43

    t2.3
    12.7 13.0
    13.3

    2.47 2.63 2.72 2.88


    3.05

    44 45 46 47

    3.22
    3.35

    13.6 14.0

    3.50

    //

    2.

    GRAPHS

    Specific Conductance vs Volume of NaOII


    4
    3.5
    a J

    2.5

    Specific conductance/
    mS

    2
    1.5

    , i l"hI i I i i ilt i i I i ,

    I
    0.5

    0 | 2 3 4 5 6 7 I 9 10 11 12 13 L4 15
    Volume of NaOIVml

    3.

    CALCULATION

    (a) Concentration of sodium hydroxide solution: Volume of oxalic acid, Vz:20.8 ml (from table 0l) Strength of oxalic acid, Sz:0.1 N Volume of sodium hydroxide taken, Vr = 10 ml Strength of sodium hydroxide, Sr : ? Now, V1 xS1 :VzXSz , 20.8 mlx0.1N :0.208 Sr: 10 ml N

    (b) Concentration of hydrochloric acid: Volume of sodium hydroxide solution required to neutralize hydrochloric acid Yz:4.5 ml (from graph) Strength of sodium hydroxide , Sz:0.208 N Volume of hydrochloric acid taken , Vr : 10 ml Strength of hydrochloric acid, Sr : ? Now, V1 x51 :V2X52

    Sr:

    4.5 mlx0.2oBN 10 ml

    :0.0936 N

    (c) Mass of hydrochloric acid:


    Mass of hydrochloric acid,

    msq:

    (SeV)g61:

    0.0936Nx36.5 g x10 ml
    1O0O

    ml

    :0.0342

    (d) Concentration of acetic acid: Volume of sodium hydroxide solution required to neutralize acetic acid, Vz = ( 9.4 - 4.5)ml- 4.9 ml (from graph) of sodium hydroxide , Sz :0.208 N
    $-Sength

    ic acid, Sr

    ix Sr:VzXSz
    Sr:
    4.9 mlx0.208N 10

    ml

    = 0.102 N

    (e) Mass of acetic acid:


    Mass of acetic acid, TttcH3coon: (SeV)sHrcooH: 0.102Nx609x10m1 1000ml

    :0.0612g

    (f)

    Percentage composition of hydrochloric acid and acetic acid in the mixture:

    Total mass of mixture, Mr

    rrncr

    IIICHTCO6g

    (0.0342 + 0.0612)

    g:

    0.09549

    o/o

    composition of hydrochloric

    acid:

    Yx 0.09549

    100% :35.8yo
    ,./

    o/o

    composition of acetic acid

    :W:x L00o/o = 0.09549

    64.20/o

    --

    4.

    RESULT
    o/o

    composition of hydrochloric acid composition of acetic acid

    35.8 %

    oZ

    64.20/o

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