Volumetric Analysis - Class XI

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Prepare M/10 NaOH solution (250 ml) and using this solution estimate the

molarity and strength of the given HCL solution.




Step I : Preparation of 250 ml of M/10 NaOH :



Molecular Formula of
NaOH
= NaOH

Molecular Mass

=

40 g/mol


NaOH required to prepare
250 ml of M/20 NaOH
= Required molarity X Molecular
mass of
NaOH
X Required volume of NaOH in mL
1000
= 1/10 X 40X 250
1000

= 1 g

Weight of the weighing bottle + NaOH = 1.7 g

Weight of the weighing bottle = 0.7 g


Weight of NaOH = 1.0 g

Molarity of NaOH solution = Strength (g/L)
Molecular mass of NaOH

= 1 X 1000
40 250

= 1 X 4
40

= 0.1 M

Step II : Molecular equation and Ionic equations:

Molecular equation:

NaOH + HCl NaCl + H
2
O




Ionic Equation:

OH
-
+ H
+
H
2
O


Step III : Simple Procedure

a) Burette solution : HCl
b)Pipette Solution : M/10 NaOH
c)Medium : Aqueous
d)Temperature : Room temperature
e)Indicator : Phenolphthalein
f)End Point : Appearance of pink colour
g)Molecular Mass of HCl : 36.5 g/mol

Step IV: Observation Table:
NaOH X HCl
Sl.No. Volume of
NaOH in mL
Burette readings in mL Volume of
HCl in mL Initial Final
1 20 0 19.2 19.2
2 20 0 19.1 19.1
3 20 0 19.1 19.1

Concordant Value: 19.1 mL

StepV: Calculation of Molarity of HCl

In the balanced equation,
1moles of NaOH reacts with 1 moles of HCl

V
HCl
X M
HCl
1
----------------------------------- = ----------
V
NaOH
X M
NaOH
1

V
HCl
X M
HCl
1
= ---------- X V
NaOH
X M
NaOH



1

1
1
V
HCl
X M
HCl
= ---------- X 20

X ------
1 10



1 1
19.1 X M
HCl
= ---------- X 20

X ------
1 10



1 1 1
M
HCl
= ---------- X 20

X ------ X -----
1 10 19.1


1 X 20 X 1 X 1
M
HCl
= -----------------------------------


1 X 10 X 19.1


M
HCl
= 0.104712 M

Therefore, Molarity of given HCl

Solution = 0.104712 M

StepVI: Calculation of Strength of HCl Solution:

Strength of HCl

Solution = Molarity of HCl X Molecular mass of HCl

= 0.104712 X 36.5 g/L

= 3.821988 g/L

Step VII: Result:

Molarity of given HCl = 0.1047 M

Strength of given HCl

Solution = 3.821988 g/Litre.


**************************








2.0000
0 .500
0.050
0.001

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