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    This safety data sheet provides information on a product called AGENDA EC25 12X1L BOT HK. It contains the active ingredient Fipronil at a concentration of 25 g/L. The document lists hazards such as skin and eye irritation. It also provides first aid measures in case of exposure and instructions for safe handling and storage.

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    Agenda

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    287 views7 pages
    This safety data sheet provides information on a product called AGENDA EC25 12X1L BOT HK. It contains the active ingredient Fipronil at a concentration of 25 g/L. The document lists hazards such as skin and eye irritation. It also provides first aid measures in case of exposure and instructions for safe handling and storage.

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    This safety data sheet provides information on a product called AGENDA EC25 12X1L BOT HK. It contains the active ingredient Fipronil at a concentration of 25 g/L. The document lists hazards such as skin and eye irritation. It also provides first aid measures in case of exposure and instructions for safe handling and storage.

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    © All Rights Reserved
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    287 views7 pages

    Agenda

    Uploaded by

    MYUTILITY
    This safety data sheet provides information on a product called AGENDA EC25 12X1L BOT HK. It contains the active ingredient Fipronil at a concentration of 25 g/L. The document lists hazards such as skin and eye irritation. It also provides first aid measures in case of exposure and instructions for safe handling and storage.

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    Bayer CropScience

    SAFETY DATA SHEET according to EC Directive 2001/58/EC

    AGENDA EC25 12X1L BOT HK

    1/7
    Revision Date: 02.03.2007
    Print Date: 10.03.2008

    Version 1 / EU
    102000001794

    1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE


    COMPANY/UNDERTAKING
    Product information
    Trade name
    Product code (UVP)
    Usage

    AGENDA EC25 12X1L BOT HK


    05924596
    Insecticide

    Company

    Bayer CropScience AG
    Alfred-Nobel-Strae 50
    40789 Monheim
    Germany

    Telephone
    Telefax
    Responsible Department

    +49(0)2173-38-3373
    +49(0)2173-38-7394
    Material and Transport Safety Management
    +49(0)2173-38-3409/4566

    Emergency telephone number +49(0)2133-51-4233 (Sicherheitszentrale Dormagen, Bayer AG)

    2. COMPOSITION/INFORMATION ON INGREDIENTS
    Chemical nature
    Emulsifiable concentrate (EC)
    Fipronil 25 g/l
    Hazardous components
    Chemical Name
    Fipronil

    Odourless kerosine
    Tributyl phosphate
    Nonylphenol ethoxylate

    CAS-No. /
    EINECS-No.
    120068-37-3

    Symbol(s)

    R-phrase(s)

    Concentration [%]

    T, N

    2,93

    64742-47-8
    265-149-8
    126-73-8
    204-800-2
    68412-54-4

    Xn

    R23/24/25,
    R48/25,
    R50/53
    R65, R66

    Polyoxyethylene-nonylphenyl- 68412-53-3
    ether-phosphate
    Branched calcium dodecyl
    68953-96-8
    benzene sulfonate
    273-234-6

    Xn
    Xi, N
    Xi, N
    Xi, N

    R22, R38,
    R40
    R36/38,
    R51/53
    R38, R41,
    R51/53
    R38, R41,
    R51/53

    > 25,00
    > 1,00 - < 25,00
    > 0,10 - < 2,50
    > 2,50 - < 25,00
    > 0,10 - < 2,50

    3. HAZARDS IDENTIFICATION
    Risk advice to man and the environment
    Irritating to skin.
    Limited evidence of a carcinogenic effect.
    Harmful: danger of serious damage to health by prolonged exposure if swallowed.
    Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
    Harmful: may cause lung damage if swallowed.

    Bayer CropScience
    SAFETY DATA SHEET according to EC Directive 2001/58/EC

    AGENDA EC25 12X1L BOT HK


    Version 1 / EU
    102000001794

    2/7
    Revision Date: 02.03.2007
    Print Date: 10.03.2008

    Repeated exposure may cause skin dryness or cracking.

    4. FIRST AID MEASURES


    General advice
    Move out of dangerous area. When symptoms develop and persist, seek medical advice.
    Inhalation
    When inhaled remove to fresh air and seek medical aid.
    Skin contact
    Wash off thoroughly with plenty of water and soap, if available with polyethyleneglycol 400,
    subsequently rinse with water.
    Eye contact
    Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
    Ingestion
    If swallowed, seek medical advice immediately and show this container or label.
    Notes to Physician
    Symptoms
    The following symptoms may occur:, anxiety, Tremors, restlessness, Convulsions
    Treatment
    Carefully monitor the respiratory functions.
    Endotracheal intubation and gastric lavage, followed by administration of charcoal.
    Artificial respiration and/or oxygen may be necessary.
    There is no specific antidote.
    Symptoms of poisoning may not appear for several hours. Keep under medical supervision for
    at least 48 hours.
    Against convulsions: give diazepam. For adults 5-10 mg intravenously as necessary until fully
    sedated; for children 2.5 mg i.v.
    Keep under medical supervision for at least 48 hours.

    5. FIRE-FIGHTING MEASURES
    Suitable Extinguishing Media
    Water spray
    Foam
    Carbon dioxide (CO2)
    Dry powder
    Specific hazards during fire fighting
    In the event of fire the following can be released:
    carbon monoxide (CO)
    hydrogen chloride (HCl)
    nitrogen oxides (NOx)
    Hydrogen fluoride
    Sulphur oxides
    Special protective equipment for fire-fighters
    Wear self-contained breathing apparatus and protective suit.
    Further information
    Contain the spread of the fire-fighting media.
    Cool closed containers/ tanks exposed to fire with water spray.
    Do not allow run-off from fire fighting to enter drains or water courses.

    Bayer CropScience
    SAFETY DATA SHEET according to EC Directive 2001/58/EC

    AGENDA EC25 12X1L BOT HK


    Version 1 / EU
    102000001794

    3/7
    Revision Date: 02.03.2007
    Print Date: 10.03.2008

    6. ACCIDENTAL RELEASE MEASURES


    Personal Precautions
    Avoid contact with spilled product or contaminated surfaces.
    Use personal protective equipment.
    Environmental Precautions
    Do not allow to get into surface water, drains and ground water.
    Methods for Cleaning Up
    Recover the product by pumping, suction or absorption using a dry and inert absorbent clay.
    Collect and transfer the product into a properly labelled and tightly closed container.
    When picked up, treat material as prescribed in Ch. 13. "Disposal considerations".
    Additional Advice
    Information regarding safe handling, see section 7.
    Information regarding personal protective equipment, see section 8.
    Information regarding waste disposal, see section 13.

    7. HANDLING AND STORAGE


    Handling
    Advice on safe handling
    No specific precautions required when handling unopened packs/containers; follow relevant
    manual handling advice.
    Use only in area provided with appropriate exhaust ventilation.
    Storage
    Requirements for storage areas and containers
    Keep out of the reach of children.
    Keep container tightly closed in a dry and well-ventilated place.
    Advice on common storage
    Keep away from food, drink and animal feedingstuffs.
    Suitable materials
    Coextruded containers with an internal barrier layer made of ethylene vinyl alcohol copolymer
    (EVOH)
    Coextruded containers with an internal barrier layer made of polyamide (PA).

    8. EXPOSURE CONTROLS / PERSONAL PROTECTION


    Additional Advice
    OES for fipronil: 0.035 mg/m (internal limit)
    Personal protective equipment
    In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the
    following recommendations would apply.
    Respiratory Protection

    Wear respirator with an organic vapours and gas filter mask


    (protection factor 10) conforming to EN140 type A or equivalent.
    Respiratory protection should only be used to control residual risk of
    short duration activities, when all reasonably practicable steps have

    Bayer CropScience
    SAFETY DATA SHEET according to EC Directive 2001/58/EC

    AGENDA EC25 12X1L BOT HK


    Version 1 / EU
    102000001794

    4/7
    Revision Date: 02.03.2007
    Print Date: 10.03.2008

    been taken to reduce exposure at source e.g. containment and/or


    local extract ventilation. Always follow respirator manufacturer's
    instructions regarding wearing and maintenance.
    Hand Protection

    Wear CE Marked (or equivalent) nitrile rubber gloves (minimum


    thickness 0,40 mm). Wash when contaminated. Dispose of when
    contaminated inside, when perforated or when contamination
    outside cannot be removed. Wash hands always before eating,
    drinking, smoking or using the toilet.

    Eye protection

    Wear goggles conforming to EN166 (Field of Use 5 or equivalent).

    Skin and body protection

    Wear standard coverall and type 6 suit.


    Wear two layers of clothing wherever possible. Polyester/cotton or
    cotton overalls should be worn under chemical protection suit and
    should be professionally laundered frequently.
    If chemical protection suit is splashed, sprayed or significantly
    contaminated, decontaminate as far as possible, then carefully
    remove and dispose of as advised by manufacturer.

    Hygiene measures
    Wash hands immediately after work, if necessary take a shower.
    Remove soiled clothing immediately and clean thoroughly before using again.
    Smoking, eating and drinking should be prohibited in the application area.

    9. PHYSICAL AND CHEMICAL PROPERTIES


    Appearance
    Form
    Colour

    liquid
    colourless to yellowish

    Safety data
    pH

    3,1 - 3,3 at 1 %
    emulsion in water

    Flash point

    >= 80 C

    Density

    approx. 0,86 g/cm at 20 C

    Water solubility

    dispersible

    10. STABILITY AND REACTIVITY


    Hazardous Reactions

    No hazardous reactions when stored and handled according to


    prescribed instructions.
    Stable under normal conditions.

    11. TOXICOLOGICAL INFORMATION


    Acute Oral Toxicity

    LD50 (rat) > 2.000 mg/kg

    Bayer CropScience
    SAFETY DATA SHEET according to EC Directive 2001/58/EC

    AGENDA EC25 12X1L BOT HK


    Version 1 / EU
    102000001794

    Acute Inhalation Toxicity

    LC50 (rat) > 5,03 mg/l


    Exposure time: 4 h

    Acute Dermal Toxicity

    LD50 (rat) > 2.000 mg/kg

    Skin Irritation

    Irritating to skin. (rabbit)

    Eye Irritation

    No eye irritation. (rabbit)

    Sensitization

    Non-sensitizing.
    OECD Test Guideline 406, Buehler test

    5/7
    Revision Date: 02.03.2007
    Print Date: 10.03.2008

    12. ECOLOGICAL INFORMATION


    Ecotoxicity effects
    Toxicity to Fish

    LC50 (Rainbow trout (Oncorhynchus mykiss)) 4,5 mg/l


    Exposure time: 96 h

    Toxicity to daphnia

    EC50 (Water flea (Daphnia magna)) 0,09 mg/l


    Exposure time: 48 h

    Toxicity to algae

    EC50 (Scenedesmus subspicatus) 0,074 mg/l


    Exposure time: 96 h
    The value mentioned relates to the active ingredient fipronil.

    13. DISPOSAL CONSIDERATIONS


    Product
    In accordance with current regulations and, if necessary, after consultation with the site operator
    and/or with the responsible authority, the product may be taken to a waste disposal site or
    incineration plant.
    Contaminated packaging
    Empty remaining contents.
    Rinsed packaging may be acceptable for landfill, otherwise incineration will be required in
    accordance with local regulations.
    Not completely emptied packagings should be disposed of as hazardous waste.
    Waste key for the unused product
    020108 agrochemical waste containing dangerous substances

    14. TRANSPORT INFORMATION


    ADR/RID/ADNR
    UN-No.
    Labels
    Packaging group
    Hazard no.
    Description of the goods

    3082
    9
    III
    90
    ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
    N.O.S.
    (FIPRONIL SOLUTION)

    Bayer CropScience
    SAFETY DATA SHEET according to EC Directive 2001/58/EC

    AGENDA EC25 12X1L BOT HK


    Version 1 / EU
    102000001794

    IMDG
    UN-No.
    Labels
    Packaging group
    EmS
    Marine pollutant
    Description of the goods

    IATA
    UN-No.
    Labels
    Packaging group
    Description of the goods

    6/7
    Revision Date: 02.03.2007
    Print Date: 10.03.2008

    3082
    9
    III
    F-A , S-F
    Marine pollutant
    ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
    N.O.S.
    (FIPRONIL SOLUTION)

    3082
    9
    III
    ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
    N.O.S.
    (FIPRONIL SOLUTION )

    15. REGULATORY INFORMATION


    Classification and labelling in accordance with the EC Directive on dangerous preparations
    1999/45/EC as amended.
    Classification:
    Hazard warning labelling compulsory
    Hazardous components which must be listed on the label:
    Fipronil
    Tributyl phosphate
    Symbol(s)
    Xn
    N
    R-phrase(s)
    R38
    R40
    R48/22
    R50/53
    R65
    R66
    S-phrase(s)
    S26
    S35
    S36/37
    S39
    S57
    S62

    Harmful
    Dangerous for the environment
    Irritating to skin.
    Limited evidence of a carcinogenic effect.
    Harmful: danger of serious damage to health by prolonged exposure if
    swallowed.
    Very toxic to aquatic organisms, may cause long-term adverse effects in the
    aquatic environment.
    Harmful: may cause lung damage if swallowed.
    Repeated exposure may cause skin dryness or cracking.
    In case of contact with eyes, rinse immediately with plenty of water and
    seek medical advice.
    This material and its container must be disposed of in a safe way.
    Wear suitable protective clothing and gloves.
    Wear eye/face protection.
    Use appropriate container to avoid environmental contamination.
    If swallowed, do not induce vomiting: seek medical advice immediately and
    show this container or label.

    Exceptional labelling
    To avoid risks to man and the environment, comply with the instructions for use.

    Bayer CropScience
    SAFETY DATA SHEET according to EC Directive 2001/58/EC

    AGENDA EC25 12X1L BOT HK


    Version 1 / EU
    102000001794

    7/7
    Revision Date: 02.03.2007
    Print Date: 10.03.2008

    Further information
    WHO-classification: III (Slightly hazardous)

    16. OTHER INFORMATION


    Further information
    Text of R phrases mentioned in Section 2:
    R22
    Harmful if swallowed.
    R23/24/25
    Toxic by inhalation, in contact with skin and if swallowed.
    R36/38
    Irritating to eyes and skin.
    R38
    Irritating to skin.
    R40
    Limited evidence of a carcinogenic effect.
    R41
    Risk of serious damage to eyes.
    R48/25
    Toxic: danger of serious damage to health by prolonged exposure if
    swallowed.
    R50/53
    Very toxic to aquatic organisms, may cause long-term adverse effects in the
    aquatic environment.
    R51/53
    Toxic to aquatic organisms, may cause long-term adverse effects in the
    aquatic environment.
    R65
    Harmful: may cause lung damage if swallowed.
    R66
    Repeated exposure may cause skin dryness or cracking.
    The information given in this Data Sheet has been included in accordance with the guidelines
    established by EC Directive 1991/155/EC as amended. This data sheet complements the user's
    instructions, but does not replace them. The information it contains is based on the knowledge
    available about the product concerned at the time it was compiled. Users are further reminded of the
    possible risks of using a product for purposes other than those for which it was intended. The
    required information complies with current EEC legislation. Addressees are requested to observe
    any additional national requirements.
    Changes since the last version are highlighted in the margin. This version replaces all previous
    versions.

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