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SAFETY DATA SHEET according to Regulation (EC) No.

1907/2006

AGENDA EC25 12X1L BOT MDE 1/11


Version 4 / IND Revision Date: 11.07.2018
102000001794 Print Date: 18.12.2018

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING

1.1 Product identifier


Trade name AGENDA EC25 12X1L BOT MDE
Product code (UVP) 05924596

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use Insecticide
1.3 Details of the supplier of the safety data sheet
Supplier Bayer CropScience Limited
Bayer House, Central Avenue
Hiranandani Estate
400607 Thane (W)
Maharashtra
India
Telephone +91-22-25311826 / 25311234

Telefax +91-22-25455116

1.4 Emergency telephone no.


Indian Emergency Number 022-25311885 (24 hours/day)
Global Incident Response +1 (760) 476-3964 (Company 3E for Bayer AG, Crop Science Division)
Hotline (24h)

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture


Classification in accordance with Regulation (EC) No 1272/2008 on classification, labelling and
packaging of substances and mixtures, as amended.
Aspiration hazard: Category 1
H304 May be fatal if swallowed and enters airways.
Skin irritation: Category 2
H315 Causes skin irritation.
Carcinogenicity: Category 2
H351 Suspected of causing cancer.
Specific target organ toxicity - repeated exposure: Category 2
H373 May cause damage to organs (Liver, Central nervous system) through prolonged or
repeated exposure if swallowed.
Acute aquatic toxicity: Category 1
H400 Very toxic to aquatic life.
Chronic aquatic toxicity: Category 1
H410 Very toxic to aquatic life with long lasting effects.
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

AGENDA EC25 12X1L BOT MDE 2/11


Version 4 / IND Revision Date: 11.07.2018
102000001794 Print Date: 18.12.2018

2.2 Label elements


Labelling in accordance with Regulation (EC) No 1272/2008 on classification, labelling and
packaging of substances and mixtures, as amended.
Hazard label for supply/use required.
Hazardous components which must be listed on the label:
 Fipronil
 Tributyl phosphate

Signal word: Danger


Hazard statements
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs (Liver, Central nervous system) through prolonged or
repeated exposure if swallowed.
H410 Very toxic to aquatic life with long lasting effects.
EUH401 To avoid risks to human health and the environment, comply with the instructions for
use.
Precautionary statements
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/ physician.
P331 Do NOT induce vomiting.
P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor/ physician.
P501 Dispose of contents/container in accordance with local regulation.
2.3 Other hazards
No other hazards known.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS


3.2 Mixtures
Chemical nature
Emulsifiable concentrate (EC)
Fipronil 25 g/l
Hazardous components
Hazard statements according to Regulation (EC) No. 1272/2008
Name CAS-No. / Classification Conc. [%]
EC-No. / REGULATION (EC) No
REACH Reg. No. 1272/2008
Fipronil 120068-37-3 Acute Tox. 3, H311 2.91
Acute Tox. 3, H331
Aquatic Chronic 1, H410
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

AGENDA EC25 12X1L BOT MDE 3/11


Version 4 / IND Revision Date: 11.07.2018
102000001794 Print Date: 18.12.2018

Acute Tox. 3, H301


STOT RE 1, H372
Aquatic Acute 1, H400
Hydrocarbons, C11-C14, Asp. Tox. 1, H304 > 25.0
n-alkanes, isoalkanes, 01-2119456620-43-xxxx
cyclics, <2% aromatics
Tributyl phosphate 126-73-8 Skin Irrit. 2, H315 > 1 – < 25
01-2119492859-14-xxxx Carc. 2, H351
Acute Tox. 4, H302
Nonylphenol ethoxylate 68412-54-4 Skin Irrit. 2, H315 > 0.1 – < 2.5
Eye Irrit. 2, H319
Aquatic Chronic 2, H411
Polyoxyethylene- 68412-53-3 Eye Dam. 1, H318 > 2.5 – < 25
nonylphenyl-ether- Skin Irrit. 2, H315
phosphate Aquatic Chronic 2, H411
Benzenesulfonic acid, 68953-96-8 Acute Tox. 4, H312 > 0.25 – <
mono-C11-13-branched 01-2119964467-24-xxxx Skin Irrit. 2, H315 2.5
alkyl derivs., calcium salts Eye Dam. 1, H318
Aquatic Chronic 2, H411
Further information
Fipronil 120068-37-3 M-Factor: 1,000 (acute), 10,000 (chronic)
Nonylphenol 68412-54-4 M-Factor: 1 (acute)
ethoxylate
M-Factor: 0 (chronic)
For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures


General advice Move out of dangerous area. When symptoms develop and persist,
seek medical advice.
Inhalation When inhaled remove to fresh air and seek medical aid.
Skin contact Wash off thoroughly with plenty of soap and water, if available with
polyethyleneglycol 400, subsequently rinse with water.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at
least 15 minutes.
Ingestion Do not induce vomiting: contains petroleum distillates and/or aromatic
solvents. Risk of product entering the lungs on vomiting after ingestion.
Call a physician or poison control center immediately. Keep at rest.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms The following symptoms may occur:, Anxiety, Tremors, Restlessness,
Convulsions
4.3 Indication of any immediate medical attention and special treatment needed
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

AGENDA EC25 12X1L BOT MDE 4/11


Version 4 / IND Revision Date: 11.07.2018
102000001794 Print Date: 18.12.2018

Treatment There is no specific antidote. Carefully monitor the respiratory


functions. In case of convulsions, a benzodiazepine (e.g. diazepam)
should be given according to standard regimens. Oxygen or artificial
respiration if needed. Keep respiratory tract clear. In case of ingestion
gastric lavage should be considered in cases of significant ingestions
only within the first 2 hours. However, the application of activated
charcoal and sodium sulphate is always advisable. Symptoms of
poisoning may appear several hours later. Keep under medical
supervision for at least 48 hours.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media


Suitable Water spray, Foam, Carbon dioxide (CO2), Dry powder
Hazchem Code 3Z

5.2 Special hazards arising In the event of fire the following may be released:, Carbon monoxide
from the substance or (CO), Hydrogen chloride (HCl), Nitrogen oxides (NOx), Hydrogen
mixture fluoride, Sulphur oxides
5.3 Advice for firefighters
Special protective Wear self-contained breathing apparatus and protective suit.
equipment for firefighters
Further information Contain the spread of the fire-fighting media. Cool closed containers
exposed to fire with water spray. Do not allow run-off from fire fighting
to enter drains or water courses.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures


Precautions Avoid contact with spilled product or contaminated surfaces. Use
personal protective equipment.

6.2 Environmental Do not allow to get into surface water, drains and ground water.
precautions
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up Recover the product by pumping, suction or absorption using a dry
and inert absorbent clay. Collect and transfer the product into a
properly labelled and tightly closed container. Clean contaminated
floors and objects thoroughly, observing environmental regulations.
Additional advice Check also for any local site procedures.

6.4 Reference to other Information regarding safe handling, see section 7.


sections Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

AGENDA EC25 12X1L BOT MDE 5/11


Version 4 / IND Revision Date: 11.07.2018
102000001794 Print Date: 18.12.2018

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling


Advice on safe handling No specific precautions required when handling unopened
packs/containers; follow relevant manual handling advice. Avoid contact
with skin, eyes and clothing. Use only in area provided with appropriate
exhaust ventilation.
Hygiene measures Remove soiled clothing immediately and clean thoroughly before using
again. Wash hands immediately after work, if necessary take a shower.
Smoking, eating and drinking should be prohibited in the application
area.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage Store in a place accessible by authorized persons only. Keep containers
areas and containers tightly closed in a dry, cool and well-ventilated place. Protect from frost.
Keep away from direct sunlight.
Advice on common storage Keep away from food, drink and animal feedingstuffs.
Suitable materials Coex HDPE/EVOH/HDPE
7.3 Specific end use(s) Refer to the label and/or leaflet.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters


Components CAS-No. Control parameters Update Basis
Fipronil 120068-37-3 0.035 mg/m3 OES BCS*
(TWA)
Tributyl phosphate 126-73-8 2.5 mg/m3/0.2 ppm 2001 IN OEL
(TWA)
*OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure Standard"
8.2 Exposure controls
Personal protective equipment
In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the
following recommendations would apply.
Respiratory protection Wear respirator with an organic vapours and gas filter mask
(protection factor 10) conforming to EN140 type A or equivalent.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.

Hand protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness of 0,4 mm). Wash when contaminated and dispose of
when contaminated inside, when perforated or when contamination
on the outside cannot be removed. Wash hands frequently and
always before eating, drinking, smoking or using the toilet.
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

AGENDA EC25 12X1L BOT MDE 6/11


Version 4 / IND Revision Date: 11.07.2018
102000001794 Print Date: 18.12.2018

Eye protection Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).


Skin and body protection Wear standard coveralls and Category 3 Type 6 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly
contaminated, decontaminate as far as possible, then carefully
remove and dispose of as advised by manufacturer.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties


Form Liquid
Colour colourless to light yellow
pH 3.0 - 4.0 at 1 % (23 °C) (deionized water)
Flash point >= 80 °C
Density ca. 0.86 g/cm³ at 20 °C
Water solubility dispersible
9.2 Other information Further safety related physical-chemical data are not known.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity
Thermal decomposition Stable under normal conditions.
10.2 Chemical stability Stable under recommended storage conditions.

10.3 Possibility of No hazardous reactions when stored and handled according to


hazardous reactions prescribed instructions.

10.4 Conditions to avoid Extremes of temperature and direct sunlight.

10.5 Incompatible materials Store only in the original container.

10.6 Hazardous No decomposition products expected under normal conditions of use.


decomposition products

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects


Acute oral toxicity LD50 (Rat) > 2,000 mg/kg
Acute inhalation toxicity LC50 (Rat) > 5.03 mg/l
Exposure time: 4 h
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

AGENDA EC25 12X1L BOT MDE 7/11


Version 4 / IND Revision Date: 11.07.2018
102000001794 Print Date: 18.12.2018

Acute dermal toxicity LD50 (Rat) > 2,000 mg/kg


Skin corrosion/irritation Irritating to skin. (Rabbit)
Serious eye damage/eye No eye irritation (Rabbit)
irritation
Respiratory or skin Non-sensitizing.
sensitisation OECD Test Guideline 406, Buehler test
Assessment STOT Specific target organ toxicity – single exposure
Fipronil: Based on available data, the classification criteria are not met.
Tributyl phosphate: Based on available data, the classification criteria are not met.
Assessment STOT Specific target organ toxicity – repeated exposure
Fipronil caused specific target organ toxicity in experimental animal studies in the following organ(s):
Liver. Fipronil caused neurobehavioral effects and/or neuropathological changes in animal studies.
Tributyl phosphate did not cause any significant specific adverse effects or target organ toxicity in
subchronic toxicity studies.
Assessment mutagenicity
Fipronil was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.
Tributyl phosphate was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.
Assessment carcinogenicity
Fipronil caused an increased incidence of tumours in rats in the following organ(s): Thyroid. The
mechanism that triggers tumours in rodents and the type of tumours observed are not relevant to
humans.
Tributyl phosphate caused tumours secondary to the chronic irritation in rats (urinary bladder) and mice
(liver) at the highest dose tested in oncogenicity studies. Based on these studies, Tributyl phosphate did
not demonstrate any oncogenic potential relevant for human risk assessment.
Assessment toxicity to reproduction
Fipronil caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the
parent animals. The reproduction toxicity seen with Fipronil is related to parental toxicity.
Tributyl phosphate did not cause reproductive toxicity in a two-generation study in rats.
Assessment developmental toxicity
Fipronil did not cause developmental toxicity in rats and rabbits.
Tributyl phosphate did not cause developmental toxicity in rats and rabbits.
Aspiration hazard
May be fatal if swallowed and enters airways.

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity
Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 4.5 mg/l
Exposure time: 96 h
Toxicity to aquatic EC50 (Daphnia magna (Water flea)) 0.09 mg/l
invertebrates Exposure time: 48 h

Toxicity to aquatic plants EC50 (Desmodesmus subspicatus (green algae)) 0.074 mg/l
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

AGENDA EC25 12X1L BOT MDE 8/11


Version 4 / IND Revision Date: 11.07.2018
102000001794 Print Date: 18.12.2018

Exposure time: 96 h
The value mentioned relates to the active ingredient fipronil.
12.2 Persistence and degradability
Biodegradability Fipronil:
Not rapidly biodegradable
Koc Fipronil: Koc: 427 - 1278
12.3 Bioaccumulative potential
Bioaccumulation Fipronil: Bioconcentration factor (BCF) 321
Does not bioaccumulate.
12.4 Mobility in soil
Mobility in soil Fipronil: Slightly mobile in soils
12.5 Results of PBT and vPvB assessment
PBT and vPvB assessment Fipronil: This substance is not considered to be persistent,
bioaccumulative and toxic (PBT). This substance is not considered to be
very persistent and very bioaccumulative (vPvB).
12.6 Other adverse effects
Additional ecological No other effects to be mentioned.
information

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods


Product In accordance with current regulations and, if necessary, after
consultation with the site operator and/or with the responsible authority,
the product may be taken to a waste disposal site or incineration plant.
Contaminated packaging Empty remaining contents.
Rinsed packaging may be acceptable for landfill, otherwise incineration
will be required in accordance with local regulations.
Not completely emptied packagings should be disposed of as
hazardous waste.
Legal basis
Waste key in accordance with Schedule I of the Hazardous Waste Rules, 2008 as amended (India
- EP Act):
29.1Process wastes/residues
29.3Date-expired and off-specification pesticides

SECTION 14: TRANSPORT INFORMATION

ADR/RID/ADN
14.1 UN number 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FIPRONIL SOLUTION)
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

AGENDA EC25 12X1L BOT MDE 9/11


Version 4 / IND Revision Date: 11.07.2018
102000001794 Print Date: 18.12.2018

14.3 Transport hazard class(es) 9


14.4 Packaging Group III
14.5 Environm. Hazardous Mark YES
Hazard no. 90
Hazchem Code 3Z

This classification is in principle not valid for carriage by tank vessel on inland waterways. Please
refer to the manufacturer for further information.

IMDG
14.1 UN number 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FIPRONIL SOLUTION)
14.3 Transport hazard class(es) 9
14.4 Packaging Group III
14.5 Marine pollutant YES

IATA
14.1 UN number 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FIPRONIL SOLUTION )
14.3 Transport hazard class(es) 9
14.4 Packaging Group III
14.5 Environm. Hazardous Mark YES

14.6 Special precautions for user


See sections 6 to 8 of this Safety Data Sheet.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
No transport in bulk according to the IBC Code.

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Further information
WHO-classification: III (Slightly hazardous)
Labeling according to Insecticide Rules 1971 as amended. (INDIA)
Class II: Highly toxic
Colour: bright yellow
Poison!
Keep out of the reach of children.

SECTION 16: OTHER INFORMATION


SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

AGENDA EC25 12X1L BOT MDE 10/11


Version 4 / IND Revision Date: 11.07.2018
102000001794 Print Date: 18.12.2018

Text of the hazard statements mentioned in Section 3


H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H351 Suspected of causing cancer.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
Abbreviations and acronyms
ADN European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by
Road
ATE Acute toxicity estimate
CAS-Nr. Chemical Abstracts Service number
Conc. Concentration
EC-No. European community number
ECx Effective concentration to x %
EINECS European inventory of existing commercial substances
ELINCS European list of notified chemical substances
EN European Standard
EU European Union
IATA International Air Transport Association
IBC International Code for the Construction and Equipment of Ships Carrying Dangerous
Chemicals in Bulk (IBC Code)
ICx Inhibition concentration to x %
IMDG International Maritime Dangerous Goods
LCx Lethal concentration to x %
LDx Lethal dose to x %
LOEC/LOEL Lowest observed effect concentration/level
MARPOL MARPOL: International Convention for the prevention of marine pollution from ships
N.O.S. Not otherwise specified
NOEC/NOEL No observed effect concentration/level
OECD Organization for Economic Co-operation and Development
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
TWA Time weighted average
UN United Nations
WHO World health organisation

The information contained within this Safety Data Sheet is in accordance with the guidelines
established by Regulation (EU) 1907/2006 and Regulation (EU) 2015/830 amending Regulation (EU)
No 1907/2006 and any subsequent amendments. This data sheet complements the user's
instructions, but does not replace them. The information it contains is based on the knowledge
available about the product concerned at the time it was compiled. Users are further reminded of the
possible risks of using a product for purposes other than those for which it was intended. The required
information complies with current EEC legislation. Addressees are requested to observe any additional
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

AGENDA EC25 12X1L BOT MDE 11/11


Version 4 / IND Revision Date: 11.07.2018
102000001794 Print Date: 18.12.2018

national requirements.

Reason for Revision: Section 2: Hazards Identification.


The following sections have been revised: Section 2: Hazards
Identification. Section 3: Composition / Information on Ingredients.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.

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