MSDS
MSDS
1907/2006
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use Insecticide
1.3 Details of the supplier of the safety data sheet
Supplier Bayer CropScience Limited
Bayer House, Central Avenue
Hiranandani Estate
400607 Thane (W)
Maharashtra
India
Telephone +91-22-25311826 / 25311234
Telefax +91-22-25455116
5.2 Special hazards arising In the event of fire the following may be released:, Carbon monoxide
from the substance or (CO), Hydrogen chloride (HCl), Nitrogen oxides (NOx), Hydrogen
mixture fluoride, Sulphur oxides
5.3 Advice for firefighters
Special protective Wear self-contained breathing apparatus and protective suit.
equipment for firefighters
Further information Contain the spread of the fire-fighting media. Cool closed containers
exposed to fire with water spray. Do not allow run-off from fire fighting
to enter drains or water courses.
6.2 Environmental Do not allow to get into surface water, drains and ground water.
precautions
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up Recover the product by pumping, suction or absorption using a dry
and inert absorbent clay. Collect and transfer the product into a
properly labelled and tightly closed container. Clean contaminated
floors and objects thoroughly, observing environmental regulations.
Additional advice Check also for any local site procedures.
Hand protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness of 0,4 mm). Wash when contaminated and dispose of
when contaminated inside, when perforated or when contamination
on the outside cannot be removed. Wash hands frequently and
always before eating, drinking, smoking or using the toilet.
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
10.1 Reactivity
Thermal decomposition Stable under normal conditions.
10.2 Chemical stability Stable under recommended storage conditions.
12.1 Toxicity
Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 4.5 mg/l
Exposure time: 96 h
Toxicity to aquatic EC50 (Daphnia magna (Water flea)) 0.09 mg/l
invertebrates Exposure time: 48 h
Toxicity to aquatic plants EC50 (Desmodesmus subspicatus (green algae)) 0.074 mg/l
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
Exposure time: 96 h
The value mentioned relates to the active ingredient fipronil.
12.2 Persistence and degradability
Biodegradability Fipronil:
Not rapidly biodegradable
Koc Fipronil: Koc: 427 - 1278
12.3 Bioaccumulative potential
Bioaccumulation Fipronil: Bioconcentration factor (BCF) 321
Does not bioaccumulate.
12.4 Mobility in soil
Mobility in soil Fipronil: Slightly mobile in soils
12.5 Results of PBT and vPvB assessment
PBT and vPvB assessment Fipronil: This substance is not considered to be persistent,
bioaccumulative and toxic (PBT). This substance is not considered to be
very persistent and very bioaccumulative (vPvB).
12.6 Other adverse effects
Additional ecological No other effects to be mentioned.
information
ADR/RID/ADN
14.1 UN number 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FIPRONIL SOLUTION)
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
This classification is in principle not valid for carriage by tank vessel on inland waterways. Please
refer to the manufacturer for further information.
IMDG
14.1 UN number 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FIPRONIL SOLUTION)
14.3 Transport hazard class(es) 9
14.4 Packaging Group III
14.5 Marine pollutant YES
IATA
14.1 UN number 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(FIPRONIL SOLUTION )
14.3 Transport hazard class(es) 9
14.4 Packaging Group III
14.5 Environm. Hazardous Mark YES
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
No transport in bulk according to the IBC Code.
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Further information
WHO-classification: III (Slightly hazardous)
Labeling according to Insecticide Rules 1971 as amended. (INDIA)
Class II: Highly toxic
Colour: bright yellow
Poison!
Keep out of the reach of children.
The information contained within this Safety Data Sheet is in accordance with the guidelines
established by Regulation (EU) 1907/2006 and Regulation (EU) 2015/830 amending Regulation (EU)
No 1907/2006 and any subsequent amendments. This data sheet complements the user's
instructions, but does not replace them. The information it contains is based on the knowledge
available about the product concerned at the time it was compiled. Users are further reminded of the
possible risks of using a product for purposes other than those for which it was intended. The required
information complies with current EEC legislation. Addressees are requested to observe any additional
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
national requirements.