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Material Safety Data Sheet

(+/-)-10-Camphorsulfonic Acid MSDS
Section 1: Chemical Product and Company Identification
Product Name: (+/-)-10-Camphorsulfonic Acid

Contact Information:
Sciencelab.com, Inc.
14025 Smith Rd.
Houston, Texas 77396

Catalog Codes: SLC2272

CAS#: 5872-08-2
RTECS: Not available.
TSCA: TSCA 8(b) inventory: (+/-)-10-Camphorsulfonic Acid
CI#: Not available.
Synonym: DL-6-oxobornane-10-sulphonic acid;
Bicyclo[2.2.1]heptane-1-methanesulfonic acid,7,7dimethyl-2-oxoChemical Name: DL-10-Camphorsulfonic Acid

US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
Order Online: ScienceLab.com
CHEMTREC (24HR Emergency Telephone), call:
1-800-424-9300
International CHEMTREC, call: 1-703-527-3887
For non-emergency assistance, call: 1-281-441-4400

Chemical Formula: C10-H16-O4-S

Section 2: Composition and Information on Ingredients

Composition:
Name

CAS #

% by
Weight

{(+/-)-10-}Camphorsulfonic Acid

5872-08-2

100

Toxicological Data on Ingredients: (+/-)-10-Camphorsulfonic Acid LD50: Not available. LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects:
Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skin
contact (corrosive), of eye contact (corrosive). The amount of tissue damage depends on length of contact. Eye contact can
result in corneal damage or blindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce
irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can
produce lung damage, choking, unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and
itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. Repeated exposure of the eyes to a low level of dust can produce eye irritation.
Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying
degree of respiratory irritation or lung damage.

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Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.
Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances:
Slightly flammable to flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Slightly explosive in presence of open
flames and sparks.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards:
As with most organic solids in powder form, fire is possible at elevated temperatures or by contact with an ignition source
Special Remarks on Explosion Hazards:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition sources is a potential dust explosion
hazard.

Section 6: Accidental Release Measures

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Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for
assistance on disposal.

Section 7: Handling and Storage

Precautions:
Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate
the residue under a fume hood. Ground all equipment containing material. Do not breathe dust. Never add water to this
product. In case of insufficient ventilation, wear suitable respiratory equipment. If you feel unwell, seek medical attention and
show the label when possible. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents,
alkalis.
Storage: Hygroscopic. Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (crystalline powder.)
Odor: Not available.
Taste: Not available.
Molecular Weight: 232.3 g/mole
Color: Tan.
pH (1% soln/water): Not available.
Boiling Point: Not available.
Melting Point: 199C (390.2F)
Critical Temperature: Not available.
Specific Gravity: Not available.
Vapor Pressure: Not applicable.
Vapor Density: Not available.
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Volatility: Not available.

Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not available.
Solubility: Not available.

Section 10: Stability and Reactivity Data

Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Excess heat, moisture, exposure to moist air or water, dust generation
Incompatibility with various substances: Reactive with oxidizing agents, alkalis.
Corrosivity: Not available.
Special Remarks on Reactivity: Hygroscopic; keep container tightly closed.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.
Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:
Very hazardous in case of skin contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive), of eye contact
(corrosive), of inhalation (lung corrosive).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Corrosive! Skin: Causes severe skin irritation and skin burns. Eyes: Causes severe eye
irritation and eye burns. Inhalation: May cause severe irritation and chemical burns of the respiratory tract with sore throat,
coughing, shortness of breath and delayed lung edema. Ingestion: Causes gastrointestinal tract burns. May cause nausea and
vomiting. May cause severe and permanent damage to the digestive tract.

Section 12: Ecological Information

Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
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Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material
Identification: : Corrosive Solid, Acidic, Organic, n.o.s. ((+/-)-10-Champhorsulfonic Acid) UNNA: 3261 PG: III
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: (+/-)-10-Camphorsulfonic Acid
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): CLASS E: Corrosive solid.
DSCL (EEC):
R34- Causes burns. S24/25- Avoid contact with skin and eyes. S36/37/39- Wear suitable protective clothing, gloves and
eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 1
Reactivity: 0
Personal Protection: j
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.
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Other Special Considerations: Not available.

Created: 10/09/2005 04:33 PM
Last Updated: 05/21/2013 12:00 PM
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