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    1,2-Benzodihydropyrone MSDS: Section 1: Chemical Product and Company Identification

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    Pulbere Neagra
    1. This document provides a material safety data sheet for 1,2-benzodihydropyrone, including information on its composition, hazards, safe handling and storage, exposure controls, physical properties, stability, toxicity, disposal considerations, transport, and regulatory information. 2. 1,2-benzodihydropyrone is a white to yellowish liquid with a sweet then bitter taste, slightly soluble in organic solvents and insoluble in water. It is a skin and eye irritant and possible carcinogen. 3. Proper precautions include avoiding skin and eye contact, wearing protective equipment, keeping it away from heat and ignition sources, and properly disposing of any waste.

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    1,2-Benzodihydropyrone MSDS: Section 1: Chemical Product and Company Identification

    Uploaded by

    Pulbere Neagra
    85 views5 pages
    1. This document provides a material safety data sheet for 1,2-benzodihydropyrone, including information on its composition, hazards, safe handling and storage, exposure controls, physical properties, stability, toxicity, disposal considerations, transport, and regulatory information. 2. 1,2-benzodihydropyrone is a white to yellowish liquid with a sweet then bitter taste, slightly soluble in organic solvents and insoluble in water. It is a skin and eye irritant and possible carcinogen. 3. Proper precautions include avoiding skin and eye contact, wearing protective equipment, keeping it away from heat and ignition sources, and properly disposing of any waste.

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    1. This document provides a material safety data sheet for 1,2-benzodihydropyrone, including information on its composition, hazards, safe handling and storage, exposure controls, physical properties, stability, toxicity, disposal considerations, transport, and regulatory information. 2. 1,2-benzodihydropyrone is a white to yellowish liquid with a sweet then bitter taste, slightly soluble in organic solvents and insoluble in water. It is a skin and eye irritant and possible carcinogen. 3. Proper precautions include avoiding skin and eye contact, wearing protective equipment, keeping it away from heat and ignition sources, and properly disposing of any waste.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    85 views5 pages

    1,2-Benzodihydropyrone MSDS: Section 1: Chemical Product and Company Identification

    Uploaded by

    Pulbere Neagra
    1. This document provides a material safety data sheet for 1,2-benzodihydropyrone, including information on its composition, hazards, safe handling and storage, exposure controls, physical properties, stability, toxicity, disposal considerations, transport, and regulatory information. 2. 1,2-benzodihydropyrone is a white to yellowish liquid with a sweet then bitter taste, slightly soluble in organic solvents and insoluble in water. It is a skin and eye irritant and possible carcinogen. 3. Proper precautions include avoiding skin and eye contact, wearing protective equipment, keeping it away from heat and ignition sources, and properly disposing of any waste.

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    © All Rights Reserved
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    1

    He a lt h

    Fire

    Re a c t iv it y

    P e rs o n a l
    P ro t e c t io n

    Material Safety Data Sheet


    1,2-Benzodihydropyrone MSDS
    Section 1: Chemical Product and Company Identification
    Product Name: 1,2-Benzodihydropyrone

    Contact Information:
    Sciencelab.com, Inc.
    14025 Smith Rd.
    Houston, Texas 77396

    Catalog Codes: SLB3844


    CAS#: 119-84-6
    RTECS: MW5775000
    TSCA: TSCA 8(b) inventory: 1,2-Benzodihydropyrone
    CI#: Not available.
    Synonym: Melilotin, Melilotine, Melilotol, Oxochroman;
    2-Chromanone; 3,4-Dihydro-2H-1-benzopyran-2-one; 3,4Dihydrocoumarin; Croman, 2-oxo; Coumarin, 3,4-dihydro;
    Dihydrocoumarin; Hydrocinnamic acid, o-hydorxy-, deltalactone

    US Sales: 1-800-901-7247
    International Sales: 1-281-441-4400
    Order Online: ScienceLab.com
    CHEMTREC (24HR Emergency Telephone), call:
    1-800-424-9300
    International CHEMTREC, call: 1-703-527-3887
    For non-emergency assistance, call: 1-281-441-4400

    Chemical Name: Hydrocoumarin


    Chemical Formula: C9-H8-O2

    Section 2: Composition and Information on Ingredients


    Composition:
    Name

    CAS #

    % by Weight

    {1,2-}Benzodihydropyrone

    119-84-6

    100

    Toxicological Data on Ingredients: 1,2-Benzodihydropyrone: ORAL (LD50): Acute: 1460 mg/kg [Rat]. 1760 mg/kg [Guinea
    pig]. DERMAL (LD50): Acute: >5000 mg/kg [Rabbit].

    Section 3: Hazards Identification


    Potential Acute Health Effects:
    Hazardous in case of skin contact (irritant). Slightly hazardous in case of skin contact (permeator), of eye contact (irritant), of
    ingestion, of inhalation.
    Potential Chronic Health Effects:
    CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
    DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.

    Section 4: First Aid Measures


    p. 1

    Eye Contact:
    Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
    minutes. Get medical attention.
    Skin Contact:
    In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
    clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
    Serious Skin Contact:
    Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
    attention.
    Inhalation:
    If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
    attention.
    Serious Inhalation: Not available.
    Ingestion:
    Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
    person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
    tie, belt or waistband.
    Serious Ingestion: Not available.

    Section 5: Fire and Explosion Data


    Flammability of the Product: May be combustible at high temperature.
    Auto-Ignition Temperature: Not available.
    Flash Points: CLOSED CUP: 130C (266F).
    Flammable Limits: Not available.
    Products of Combustion: These products are carbon oxides (CO, CO2).
    Fire Hazards in Presence of Various Substances:
    Slightly flammable to flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.
    Explosion Hazards in Presence of Various Substances:
    Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
    presence of static discharge: Not available.
    Fire Fighting Media and Instructions:
    SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
    Special Remarks on Fire Hazards: Not available.
    Special Remarks on Explosion Hazards: Not available.

    Section 6: Accidental Release Measures


    Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.
    Large Spill:
    If the product is in its solid form: Use a shovel to put the material into a convenient waste disposal container. If the product is
    in its liquid form: Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by
    spreading water on the contaminated surface and allow to evacuate through the sanitary system.

    Section 7: Handling and Storage


    p. 2

    Precautions:
    Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a
    fume hood. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Avoid contact
    with skin. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label.
    Keep away from incompatibles such as oxidizing agents.
    Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

    Section 8: Exposure Controls/Personal Protection


    Engineering Controls:
    Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
    threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
    Personal Protection: Safety glasses. Lab coat. Gloves.
    Personal Protection in Case of a Large Spill:
    Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE
    handling this product.
    Exposure Limits: Not available.

    Section 9: Physical and Chemical Properties


    Physical state and appearance: Liquid. (Oily liquid.)
    Odor: Sweetish. Fruity or herbal
    Taste: Burning. Sweet then Bitter.
    Molecular Weight: 148.16 g/mole
    Color: White to yellowish. Colorless to light yellow.
    pH (1% soln/water): Not applicable.
    Boiling Point: 272C (521.6F)
    Melting Point: 25C (77F)
    Critical Temperature: Not available.
    Specific Gravity: 1.169 @ 18 deg C(Water = 1)
    Vapor Pressure: Not available.
    Vapor Density: Not available.
    Volatility: Not available.
    Odor Threshold: Not available.
    Water/Oil Dist. Coeff.: Not available.
    Ionicity (in Water): Not available.
    Dispersion Properties: Not available.
    Solubility:
    Slightly soluble in diethyl ether. Insoluble in hot water. Slightly soluble in carbon tetrachloride. Soluble in chloroform

    Section 10: Stability and Reactivity Data


    p. 3

    Stability: The product is stable.


    Instability Temperature: Not available.
    Conditions of Instability: Excessive heat, incompatible materials
    Incompatibility with various substances: Reactive with oxidizing agents.
    Corrosivity: Not available.
    Special Remarks on Reactivity: Not available.
    Special Remarks on Corrosivity: Not available.
    Polymerization: Will not occur.

    Section 11: Toxicological Information


    Routes of Entry: Absorbed through skin. Eye contact.
    Toxicity to Animals:
    Acute oral toxicity (LD50): 1460 mg/kg [Rat]. Acute dermal toxicity (LD50): >5000 mg/kg [Rabbit].
    Chronic Effects on Humans: Not available.
    Other Toxic Effects on Humans:
    Hazardous in case of skin contact (irritant). Slightly hazardous in case of skin contact (permeator), of ingestion, of inhalation.
    Special Remarks on Toxicity to Animals: Not available.
    Special Remarks on Chronic Effects on Humans: May cause cancer based on animal test data
    Special Remarks on other Toxic Effects on Humans:
    Acute Potential Health Effects: Skin: Causes skin irritation. Irritation may be moderate. It may be absorbed by the skin. Eyes:
    May cause eye irritation. Inhalation: May cause respiratory tract irritation. Ingestion: Maybe harmful if swallowed. May cause
    gastrointestinal tract irritation with nausea, vomiting and diarrhea. It may affect liver, blood(changes in red blood cell count),
    and behavior/central nervous system (somnolence).

    Section 12: Ecological Information


    Ecotoxicity: Not available.
    BOD5 and COD: Not available.
    Products of Biodegradation:
    Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
    Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
    Special Remarks on the Products of Biodegradation: Not available.

    Section 13: Disposal Considerations


    Waste Disposal:
    Waste must be disposed of in accordance with federal, state and local environmental control regulations.

    Section 14: Transport Information


    DOT Classification: Not a DOT controlled material (United States).
    p. 4

    Identification: Not applicable.


    Special Provisions for Transport: Not applicable.

    Section 15: Other Regulatory Information


    Federal and State Regulations: TSCA 8(b) inventory: 1,2-Benzodihydropyrone
    Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
    Other Classifications:
    WHMIS (Canada): Not controlled under WHMIS (Canada).
    DSCL (EEC):
    R22- Harmful if swallowed. R38- Irritating to skin. S24- Avoid contact with skin. S28- After contact with skin, wash immediately
    with plenty of water. S36/37- Wear suitable protective clothing and gloves.
    HMIS (U.S.A.):
    Health Hazard: 2
    Fire Hazard: 1
    Reactivity: 0
    Personal Protection: b
    National Fire Protection Association (U.S.A.):
    Health: 2
    Flammability: 1
    Reactivity: 0
    Specific hazard:
    Protective Equipment:
    Gloves. Lab coat. Not applicable. Safety glasses.

    Section 16: Other Information


    References: Not available.
    Other Special Considerations: Not available.
    Created: 10/09/2005 04:20 PM
    Last Updated: 05/21/2013 12:00 PM
    The information above is believed to be accurate and represents the best information currently available to us. However, we
    make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
    no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
    their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
    lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
    has been advised of the possibility of such damages.

    p. 5

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