Performance Chemicals Guide
Performance Chemicals Guide
Performance Chemicals Guide
Industrial Chemicals
Reference Guide
Solvents, Intermediates
& Surfactants
Vinyl Monomers
Performance Polymers
Specialty Chemicals
INTERNATIONAL SPECIALTY PRODUCTS
Introduction
Map Key
Regional Headquarters
Major Sales Office
Major Technical Service Labs
Manufacturing Facilities
Contents
Introduction ................................................................................................2
Performance Polymers
PVP (Polyvinylpyrrolidone).......................................................................19
ViviPrint 540 ..........................................................................................21
PVPP (Polyvinylpolypyrrolidone)..............................................................21
Disintex Disintegrants ............................................................................22
ViviPrint PS-10.......................................................................................22
Vinylpyrrolidone Copolymers....................................................................23
Ganex/Antaron Copolymers..................................................................23
PVP/VA Copolymers..................................................................................24
Polectron/Antara 430 ...........................................................................25
Copolymers of Vinylpyrrolidone/Alkylaminomethacrylate and
Alkylaminomethacrylamide .....................................................................25
Copolymer and Gafquat..........................................................................26
Gafquat HS-100 ......................................................................................26
Styleze CC-10 .........................................................................................27
ViviPrint 121 & 131 ................................................................................27
Setleze 3000 ..........................................................................................27
Styleze W Series.....................................................................................27
Acrylidone 1005......................................................................................28
Styleze 2000 and Acrylidone LM..........................................................28
Vinylcaprolactam Polymers ......................................................................29
Copolymer VC-713 ....................................................................................29
Aquaflex SF-40 .......................................................................................30
ViviPrint 200 ..........................................................................................30
ViviPrint 300 ..........................................................................................31
Chromabond Dye Complexing Polymers ................................................31
Sorez 100 ...............................................................................................32
Aquazol Polymers ...................................................................................32
Gantrez Copolymers................................................................................33
Stabileze Rheology Modifiers .................................................................35
EasySperse Polymeric Dispersant ...........................................................35
I-Rez 160................................................................................................36
Aquaflex FX-64 .......................................................................................36
Aquaflex XL-30 .......................................................................................37
Contents.......................................................................................................4
Product Overview........................................................................................5
Solvents, Intermediates & Surfactants .....................................................6
Vinyl Monomers .......................................................................................6
Performance Polymers..............................................................................7
Specialty Chemicals ..................................................................................7
Solvents, Intermediates & Surfactants
Propargyl Alcohol .....................................................................................8
Butynediol................................................................................................8
Butenediol................................................................................................9
Butanediol................................................................................................9
THF (Tetrahydrofuran) ..............................................................................10
BLO Solvent.............................................................................................10
Pyrrolidones
2-Pyrol Solvent .......................................................................................11
M-Pyrol Solvent......................................................................................12
Other Alkylpyrrolidones
NEP Solvent........................................................................................12
HEP Solvent........................................................................................13
CHP Solvent........................................................................................13
Surfadone LP-100...................................................................................14
Surfadone LP-300...................................................................................14
Easy-Wet 20...........................................................................................15
Microflex Microemulsifier.......................................................................15
Engineered Solvents .................................................................................16
Vinyl Monomers
V-Pyrol Reactive Monomer .....................................................................17
V-Cap Reactive Monomer.......................................................................17
Rapi-Cure Vinylethers .............................................................................18
Specialty Chemicals
Silcron Silica Gels ....................................................................................37
Escalol UV Absorbers ..............................................................................38
Emulsifier, Dispersants and Lubricants .....................................................38
Carbonyl Iron Powders (Micropowder Iron) ............................................40
Iron Pentacarbonyl ...................................................................................40
Applications Chart.......................................................................................41a-c
Product Overview
Solvents, Intermediates
& Surfactants
Vinyl Monomers
Performance Polymers
Specialty Chemicals
Vinyl Monomers
Solvents, Intermediates
& Surfactants
Vinyllactams and vinylethers are offered for applications based on the utility of
their olefin linkage.
Propargyl Alcohol and Butynediol due to their high electron density of the
acetylenic bond function as metal complexing and corrosion inhibiting agents.
Butenediol, having a cis double bond enters into Diels-Alder Reactions and
Butanediol finds application as a plasticizer and humectant.
All four alcohols function as precursors to numerous derivatives such as
esters, carbamates, polyesters and urethanes.
Tetrahydrofuran is an inert solvent for numerous polymer and
organometallic reactions and is the precursor of polytetramethyleneglycol.
BLO (-Butyrolactone) is a polar solvent for ionic substrates and functions as
an acid donor in aqueous media at elevated temperatures.
Specialty Chemicals
Performance Polymers
PVP, high polarity, dispersancy, hydrophilicity, adhesion, cohesivity and high Tg.
PVP/VA, thermoplasticity, oxygen permeability, varying hydrophilicity and
adhesion.
Ganex/Antaron, hydrophobicity, an emulsifier and dispersant for
nonaqueous systems.
Gafquat, basicity, substantivity, and high charge density.
ViviPrint, ink-binding, water resistance, high gloss and transparency, light
stability (fastness).
Polectron/Antara, thickening and opacifying emulsion.
Chromabond, dye complexation and soil anti-redeposition.
Aquazol, thermoplastic, hydrophilicity, adhesion, cohesivity, thermal and
shear stable and high decomposition temperature.
ISP also offers a wide variety of industrial biocides sold under the Nuocide,
Nuosept, Integra and Fungitrol tradenames and industrial alginates
(sodium, potassium, ammonium, and propylene glycol alginate) sold under the
Kelgin, Keltex, Manutex, Manucol and Collatex tradenames.
(1)
(2)
Solvents, Intermediates
& Surfactants
Butynediol (2-butyne-1,4-diol)
Applications
Iron dissolution inhibitor in mineral acids.
Corrosion inhibitor during oil well stimulation and acid pickling.
Electroplating bath additive giving bright, uniform metal deposition without
film formation.
Precursor to Iodopropynylbutyl Carbamate (IPBC), a coating fungicide.
Applications
Iron dissolution inhibitor in mineral acids.
Corrosion inhibitor during acid pickling.
Nickel electroplating bath additive giving bright, uniform metal deposition
without film formation.
Oven cleaners.
Photoresist Strippers.
Physical Properties
Boiling point...................................................115C
Vapor pressure ................................................11.6mm Hg @ 20C
Flash point .....................................................35C
Freezing point.................................................-50C
Viscosity..........................................................1.6 cP @ 25C
Specific gravity ...............................................0.9485 @ 25C
Physical Properties
Boiling point...................................................238C
Vapor pressure ................................................2.5mm Hg @ 100C
Flash point .....................................................157C
Melting point..................................................54C
Specific gravity ...............................................1.17 @ 25C
Chemistry
There are three reactive sites in propargyl alcohol; the triple bond, methyne
hydrogen and hydroxyl group. The triple bond has a high electron density and
thereby an affinity for a number of industrially important metals. Both the methyne
and hydroxyl hydrogens can be substituted with appropriate chemical reagents.
Chemistry
Butynediol is commercially available as a solid or in 35% aqueous solution. The
triple bond in butynediol has a high electron density and an affinity for metals
similar to propargyl alcohol. The two hydroxyl groups undergo typical reactions
such as ethoxylation to produce Butoxyne 497, a 100% active liquid with a
melting point of approximately -15C.
Solvents, Intermediates
& Surfactants
Butenediol (2-butene-1,4-diol)
Butanediol (1,4-butanediol)
Applications
Butanediol is used mainly as a co-monomer in classical diol-condensation
reactions with:
Applications
Diels-Alder reactions to produce Vitamin B-6, Endosulfan, etc.
Diacylation with bromoacetic acid to produce a paper slimicide.
Physical Properties
Boiling point...................................................234C
Flash point .....................................................135C
Freezing point.................................................7C
Viscosity..........................................................22 cP @ 25C
Specific gravity ...............................................1.07 @ 25C
Chemistry
Butenediol, as produced by ISP, is 93-97% cis isomer, facilitating its use in 1,4addition reactions. The two hydroxyl groups undergo the typical reactions of
alcohols. Butenediol readily dehydrates to 2,3-dihydrofuran in the presence of
acids and polymerizes above 165C.
Solvents, Intermediates
& Surfactants
THF (Tetrahydrofuran)
BLO (-Butyrolactone)
Applications
Solvent for vinyl polymers used in PVC pipe adhesives, industrial cleaning,
magnetic tape coatings, vinyl fabric topcoats among others.
Reaction medium for organometallic reagents, including linear low density
polyethylene catalyst manufacture.
Monomer for polytetramethylene glycol, a Spandex intermediate.
Applications
Electrolyte dissociating solvent for nonaqueous capacitors.
Photoresist stripper.
Solvent for a wide spectrum of polymers and an effective substitute for
chlorinated hydrocarbons.
Paint strippers, industrial cleaners and lithographic developers.
Hydrolyzed in water at elevated temperatures to yield 4-hydroxybutyric acid,
leading to its use as an acid donor in nylon fiber dyeing.
Stabilizes urea in fertilizers.
Physical Properties
Boiling point...................................................66C
Vapor pressure ................................................161mm Hg @ 20C
Flash point .....................................................-14C
Freezing point.................................................-108.5C
Viscosity..........................................................0.5 cP @20C
Dipole moment...............................................1.75D
Specific gravity ...............................................0.886 @ 25C
Dielectric constant ..........................................7.52
Physical Properties
Boiling point...................................................204C
Vapor pressure ................................................0.16mm Hg @ 20C
Flash point .....................................................93C
Freezing point.................................................-44C
Viscosity..........................................................1.2 cP @25C
Dipole moment...............................................4.27D
Specific gravity ...............................................1.124 @ 25C
Dielectric constant ..........................................39.0
Chemistry
THF (stabilized with 250-400 ppm BHT) is an excellent polymer solvent,
combining rapid dissolution and evaporation with significant solubilizing
capacity for many high molecular weight polymers at moderate viscosity. It has
unique characteristics in Grignard and other organometallic reactions. As noted
above, THF undergoes an acid-catalyzed ring opening polymerization reaction to
produce polytetramethylene glycol.
Chemistry
Although BLO is stable under a wide range of conditions, at elevated
temperatures and in the presence of appropriate reagents, it serves as an
intermediate in a variety of useful syntheses, such as:
Precursor to 2-pyrrolidone and the extensive family of alkyl pyrrolidones
produced from ammonia and primary amines.
Reacting with phenols to yield phenoxybutyric acid derivatives with
applications in pharmaceuticals and as photographic coupling agents.
10
Solvents, Intermediates
& Surfactants
2-Pyrol (2-Pyrrolidone)
Pyrrolidones
The family of 2-pyrrolidones offered by ISP has a variety of properties primarily
derived from the unique features of the lactam ring and modified by
substitution on the nitrogen atom. The general characteristics of these
compounds result from the polar N-C=O linkage in the five-membered ring. The
reactivity, physical properties and stability of these molecules results from the
well documented amide resonance. In anionic media, the partially positive
nitrogen readily coordinates with negatively charged species while in acidic
systems the electron-rich carbonyl oxygen is rapidly protonated.
Applications
Solubilization of complex organic molecules in water.
Humectant and cosolvent in digital printing inks.
Coalescent or plasticizer for acrylic resins, especially in floor polishes, inks
and adhesives.
Physical Properties
Boiling point...................................................245C
Vapor pressure ................................................<0.1mm Hg @ 20C
Flash point .....................................................129C
Freezing point.................................................25C
Viscosity..........................................................13.3 cP @ 25C
Dipole moment...............................................3.5D
Specific gravity ...............................................1.116 @ 25C
Chemistry
The reactive site of 2-Pyrol is its labile hydrogen on the nitrogen. It can undergo
vinylation with acetylene, alkylation with alkylhalides and acylation with acylhalides.
Hydrolysis in basic media produces -aminobutyric acid. It is also available as
95% active solution that freezes/solidifies at 12C to ensure ease of handling.
11
Solvents, Intermediates
& Surfactants
M-Pyrol (N-Methyl-2-Pyrrolidone)
NEP (N-Ethyl-2-Pyrrolidone)
Applications
Polymerization medium for polyethersulfones, polyaramids, polyesters,
polyamide-imides.
Polyamide-imide diluent for wire enamel coatings.
Paint and photoresist strippers.
Coalescent in latex paints allowing excellent formulation latitude.
Polydifluoroethylene solvent in rechargeable battery manufacture.
Industrial cleaners; neat or in combination with numerous other solvents.
Solvent for extraction of aromatics from lube oil.
Solvent for separation of acetylene and butadiene from light hydrocarbon streams.
High precision electronic cleaning agent.
Applications
Low temperature reaction solvent for temperature sensitive pharmaceutical
active ingredients.
Circuit board/defluxing/stencil cleaners - used as a co-solvent, usually in
combination with other water-soluble solvents such as glycol ethers or
tetrahydrofurfuryl alcohol and surfactants for removal of flux residues, oils
and greases. Used as an alternative for N-methyl-2-pyrrolidone.
Physical Properties
Boiling point...................................................200C
Vapor pressure ................................................0.2 mm Hg @ 20C
Flash point......................................................92.8C
Freezing point.................................................< -70C
Viscosity..........................................................3.5 cP
Specific gravity ...............................................0.993 @ 25C
Physical Properties
Boiling point...................................................202C
Vapor pressure ................................................0.27 mm Hg @ 20C
Flash point .....................................................90C
Freezing point.................................................-24C
Viscosity..........................................................1.7 cP @ 25C
Dipole moment...............................................4.06 Debye @ 25C
Specific gravity ...............................................1.027 @ 25C
Dielectric constant ..........................................32.2
Soluble in water and most organic solvents; sparingly soluble in aliphatic hydrocarbons.
Chemistry
M-Pyrol is extremely resistant to hydrolysis from pH 2-10, even at elevated
temperatures. Beyond these limits, hydrolysis to 4-(methylamino) butanoic acid
occurs at a rate dependent on pH and temperature. A large body of chemistry
has been developed on the reactions of strong nucleophiles with M-Pyrol. High
purity, low trace metal grades are sold under the Micropure and Pharmasolve
tradenames for the electronic and pharmaceutical industries.
12
Solvents, Intermediates
& Surfactants
HEP (N-Hydroxyethyl-2-Pyrrolidone)
CHP (N-Cyclohexyl-2-Pyrrolidone)
Applications
Photoresist Strippers - used as a co-solvent, usually in combination with
M-Pyrol (N-methyl-2-pyrrolidone) solvent, to enhance performance by
broadening solubility range.
Paint Strippers - as a solvent in high temperature stripping applications for
chemically resistance coatings.
Silk Screen Cleaners - as a co-solvent in cleaning formulations to enhance
removal of inks from silk screen fibers.
Hard Surface Cleaners - used as a co-solvent with glycol ethers in oven
cleaning formulations.
Intermediate for alkoxylated derivatives used in gasoline additives.
Applications
Photoresist Strippers - used as a co-solvent, usually in combination with
M-Pyrol (N-methyl-2-pyrrolidone) and BLO (-Butyrolactone) solvents, to
enhance performance by broadening solubility range.
Circuit Board Fabrication - used in chemical polishing of copper and copper
alloys to increase the stability of hydrogen peroxide in acid brightening baths.
Dye Carrier or Dyeing Bath Additive - used in dyeing of aromatic polyamide
fibers (i.e., Duponts Kevlar and Nomex, Teijins Conex) as a swelling/
diffusion agent to enhance dye and flame retardant penetration.
Paint Strippers - as a solvent in high temperature stripping applications for
chemically resistant coatings.
Silk Screen Cleaners - as a co-solvent in cleaning formulations to enhance
removal of inks from silk screen fibers.
Physical Properties
Boiling point...................................................295C
Vapor pressure ................................................<0.005 mm Hg @ 20C
Flash point......................................................160C
Freezing point.................................................20C
Viscosity..........................................................53 cP
Specific gravity ...............................................1.139 @ 25C
Physical Properties
Boiling point...................................................284C
Vapor pressure ................................................<0.005 mm Hg @ 20C
Flash point......................................................145C
Freezing point.................................................12C
Viscosity @ 25C..............................................11.5 cP
Specific gravity ...............................................1.026 @ 25C
13
Solvents, Intermediates
& Surfactants
Applications
Soil penetrant and softener in hard surface cleaners, laundry prespotters and
metal cleaning.
Wetting agent for dishwashing, industrial and institutional cleaners.
Isopropyl alcohol replacement in fountain solutions.
Solvent for polymers and hydrophobic substances.
Pigment dispersion aid and pigment conditioning solvent.
Component of photoresist strippers.
Wetting agent for aqueous systems.
Component in microemulsifying systems.
Applications
High boiling solvent for polymers and hydrophobic substances.
Substitute for fluorocarbon surfactants used for oil well stimulation.
Additive in hand or automatic dish wash detergents.
Ingredient in pressure sensitive adhesives.
Physical Properties
Boiling point...................................................145C @ 0.2 mm Hg
Flash point......................................................116C
Freezing point.................................................10C
Viscosity..........................................................17 cP @ 25C
Minimum equilibrium surface tension............26 mN/m @ 20 ppm
Physical Properties
Boiling point...................................................100C @ 0.3mm Hg
Vapor pressure ................................................<0.001mm Hg @ 25C
Flash point......................................................113C
Freezing point.................................................-25C
Viscosity..........................................................8 cP @ 20C
Minimum equilibrium surface tension............28 mN/m @ 0.12%
Minimum dynamic surface tension.................35 mN/m @ 10 bubbles/sec
Chemistry
Surfadone LP-300 is sparingly soluble in water (0.002 weight percent) and
soluble in most organic solvents. It is a low foaming, nonionic surfactant with an
HLB of 3 and has no critical micelle concentration (CMC). Like its lower homolog,
Surfadone LP-300 interacts with anionic surfactants forming mixed micelles
which greatly enhances its solubility resulting in a synergistic surface tension
reduction and wetting enhancement. Appropriate combinations of Surfadone
LP-300 and anionic surfactants produce viscous solutions and gels.
Chemistry
Surfadone LP-100 is a low foaming, nonionic rapid wetting agent with an HLB
of 6 having no critical micelle concentration (CMC). Due to the electron
delocalized lactam ring, Surfadone LP-100 interacts with anionic surfactant
micelles. This greatly enhances its water solubility, resulting in a synergistic
surface tension reduction and wetting enhancement at low concentrations.
14
Solvents, Intermediates
& Surfactants
Easy-Wet 20
Microflex Microemulsifier
Applications
Hard surface cleaners.
Glass and tile cleaners.
Industrial and institutional cleaners.
Textile processing.
Pigment wetting.
Agricultural and industrial products.
Applications
Microemulsifier for hydrophobic active solubilization.
Delivers permethrin active in shampoos.
Preparation of stabilized silicones delivered from aqueous solutions.
Formulation of aqueous wood preservatives.
Dispersions of waxes and polishes.
Benefits
Optimized microemulsifier with particle sizes < 0.06.
High solvency for many hydrophobic water-insoluble organic chemicals
(active ingredients).
Concentrates prepared are compatible with high levels of emulsifiers
(anionic and non-ionic).
Benefits
Faster wetting.
Lower use levels.
Low contact angles.
Improved spreading on most surfaces.
Better equilibrium surface tension.
Enhanced cleaning performance.
Physical Properties
Physical form ..................................................Yellow liquid
pH...................................................................3.5
Viscosity..........................................................100-140 cP
Specific gravity @ 25C ...................................1.0-1.1
Physical Properties
Physical form ..................................................Clear liquid
pH (10 wt% aq.) .............................................4.0-6.0
Viscosity @ 25C..............................................15-30 cP
Specific gravity @ 25C ...................................0.92-0.95
Chemistry
Easy-Wet 20 is a proprietary super-wetting agent in a convenient to use liquid
form. Easy-Wet 20 is a cost-effective, premium wetter/surfactant suitable for
HI&I cleaning, textiles, pigments, agricultural and other industrial applications
where superior wetting and spreading performance is required.
15
Solvents, Intermediates
& Surfactants
Engineered Solvents
ISP produces a family of Engineered Solvents based on M-Pyrol, which are
designed to meet the needs of specific cleaning operations. These include:
ShipShape, FoamFlush and PartsPrep, which are each recommended for
unique applications when M-Pyrol alone cannot meet certain cleaning
requirements. In addition to their excellent solvency, our Engineered Solvents
are formulated for low VOC and low toxicity. They are effective replacements for
methylene chloride, acetone, MEK and halogenated solvents.
Product
Uses
ShipShape
Resin Cleaner
FoamFlush
Urethane Remover
PartsPrep
Degreaser
Light yellow
clear
Clear liquid
Clear liquid
1.07
1.05
1.03
22.0 (-20.0)
22.0 (-20.0)
14.0 (-24.4)
396-399
(202-204)
396-399
(202-204)
396
(202)
Flashpoint F (C)
197 (91.7)
197 (88.3)
193 (89.4)
2.02
2.09
2.49
Density (g/ml)
16
Vinyl Monomers
V-Pyrol (N-Vinyl-2-Pyrrolidone)
V-Cap (N-Vinyl-2-Caprolactam)
Applications
Reactive diluent for radical initiated UV radiation curing used in vinyl
flooring, wood coatings, release coatings, inks, etc.
Numerous conventional polymerizations to generate an array of materials
with a variety of properties as noted in the following Polymer Section.
Gafgard 233, a formulated UV radiation curable coating containing V-Pyrol
RC and a multifunctional acrylate, is used to impart high levels of abrasion
resistance to coatings for plastic lenses, protective window films, credit cards, etc.
Applications
Reactive diluent for radical initiated UV radiation curing used in inks
(especially silk screening), vinyl flooring, wood coatings, release coatings, etc.
Conventional polymerizations to generate materials which have more
hydrophobic character than analogous V-Pyrol based products.
Gafgard 300, a formulated UV radiation curable coating containing V-Cap
RC and a multifunctional acrylate. It is used in applications similar to that of
Gafgard 233, but the resultant coatings are more hydrophobic.
Physical Properties
Boiling point...................................................193C @ 400 mm Hg
Melting point..................................................13C
Vapor pressure ................................................<0.10mm Hg @ 20C
Flash point......................................................96C
Viscosity..........................................................2 cP @ 25C
Physical Properties
Boiling point...................................................116C @ 10mm Hg
Melting point..................................................35C
Vapor pressure ................................................<0.1mm Hg @ 20C
Flash point......................................................114C
Viscosity..........................................................3.5 cP @ 40C
Chemistry
V-Pyrol is a clear liquid stabilized with insoluble sodium hydroxide or soluble
N,N-di-sec-butyl-p-phenylenediamine. The latter inhibitor is supplied in
V-Pyrol RC and V-Pyrol/Amine at concentrations of 25 ppm and at 100 ppm,
respectively for radiation curing and nonradiation curing applications. This
monomer is known to be a supercooled liquid well below its freezing point of
13C. It can remain as a liquid at room temperature for extended periods. Rapid,
exothermic crystallization under these conditions should not be confused with
bulk polymerization.
Chemistry
V-Cap is a pale yellow crystalline solid stabilized with 10 ppm N,N-di-sec-butyl
p-phenylenediamine having chemical reactivity characteristics similar to those
cited above for V-Pyrol. Polymers synthesized from V-Cap are significantly
more hydrophobic than their V-Pyrol analogs, but still exhibit the adhesiveness,
strength and complexing capability characteristic of the lactam functionality.
As with V-Pyrol, V-Cap is a super cooled liquid and can remain as a liquid at
room temperature for extended periods.
17
Vinyl Monomers
Rapi-Cure Vinylethers
Applications
Reactive diluents for cationic, charge transfer and free radical radiation
curable coatings.
Co-monomers in specialty coating manufacture.
Effective in generating low surface energy release coatings.
Monomers for tackifying adhesives with varying properties.
Chemistry
Vinylethers can undergo three distinct types of polymerizations; cationic, charge
transfer or free radical.
Cationic Polymerization: The vinylether double bond is unusually electron rich
and forms rapidly polymerizing carbocations in the presence of initiators such as
Lewis and Bronsted Acids. These reactive intermediates are generated in
conventional and UV-curing vinylether homo- or copolymerizations.
Physical Properties
Properties of available commercial vinylethers
18
Performance Polymers
PVP (Polyvinylpyrrolidone)
Applications
Dye transfer inhibition in detergents using K-15 and K-30 to complex fugitive
dyes in wash water.
Textile dye stripping and strike rate control through complexation and
dispersion with K-30.
Photoprocessing where sulfide salts are complexed by K-30 in developing
baths to inhibit redeposition on film.
Laundry detergents where K-30 inhibits soil redeposition.
Emulsion polymerization where K-30 latex stabilizer, functioning as a
protective colloid, facilitates redispersion of a brokenlatex end-use application.
Dispersions using K-30 and K-90 for nonaqueous dye and pigment-based
writing ink delivery systems.
Production of expandable polystyrene, with K-90 used as the protective colloid.
Polyvinylpyrrolidone and a number of its copolymers find use as media
components in digital ink jet printing.
Hollow fiber membrane manufacture in which K-90 and K-30 create voids
and hydrophilic domains in polysulfone membranes.
In oil field cementing, where K-30 and K-90 serve as fluid loss control agents.
On lithographic plates using hydrophobic inks, where K-15 provides
enhancement of the nonimage area.
K-85 and 90 in stearate-based adhesive sticks for arts and crafts applications.
Both ends of toilet paper rolls, utilizing K-60 as an adhesive.
In fiber glass sizing, using K-30 and K-90 film forming action to promote
polyvinylacetate adhesion.
As combustible ceramic binders, using K-30 and K-90 to enhance green strength.
In tablet binder formulations, where K-30 and K-90 are used for industrial
and pharmaceutical applications.
In CRT fabrication using negative photoresist technology, where K-90 is used
with a chemical crosslinker in water-based coating systems.
Production of electrolead hydrogels, where K-90 is crosslinked by E-beam
irradiation to produce a conducting medium.
As metal quenchant bath where K-60, K-90 and K-120 are effective thickeners.
The use of K-30 and K-90 for enzyme stabilization.
Production of nano-sized metal pigments.
Dispersant for carbon nano-fibers.
19
Performance Polymers
PVP (Polyvinylpyrrolidone)
Physical Properties
Grade
K-15
K-30
K-60
K-85
K-90
K-120
K-Value Range
13-19
26-35
50-62
83-88
88-100
114-130
Chemistry
Polyvinylpyrrolidone can be plasticized with water and most common organic
plasticizers. It is considered to be physiologically inert. Applications take
advantage of one or more properties inherent in the polymer, typically due to
the lactam ring:
High Polarity and the resultant propensity to form complexes with hydrogen
donors, such as phenols and carboxylic acids, as well as anionic dyes and
inorganic salts;
Solubility Characteristics
Soluble in water and most polar solvents.
Insoluble in esters, ethers, ketones and hydrocarbons.
K-60, K-85 and K-120 are currently available only as aqueous solutions. All other
PVPs are available as dried powder or in solution.
20
Performance Polymers
PVPP (Polyvinylpolypyrrolidone)
PVPP is a highly cross-linked, amorphous, white free flowing polymer produced
through a unique proliferous (popcorn) polymerization. Although insoluble in
water, acids, bases and organic solvents, the polymers offered have swell
volumes of between 4 and 8 ml/g in water. PVPP strongly complexes with
phenols, such as tannins, flavonoids and dyes, adsorbing these compounds
within its interior cavities.
Applications
Digital printing media.
Oilfield shale stabilization.
Rheology modifier.
Physical Properties
Physical form ..................................................10-12% aqueous solution
Brookfield viscosity.........................................5,000-20,000 cps as supplied
650 cP @ 5% solids
Molecular weight............................................600,000-800,000 (GPC)
1,500,000-2,000,000 (MALLS)
Tg....................................................................174C
Chemistry
ViviPrint 540 is produced by a proprietary in-situ process resulting in a 2-phase
matrix consisting of soluble PVP and nanoscale PVP particles approximately 320
nm in size. This unique matrix allows for high viscosity, greater flexibility, better
adhesion, curl resistance and improved water-fastness in inkjet media as
compared to PVP K-90.
21
Performance Polymers
Disintex Disintegrants
Applications
Tablet and granule disintegrants, high capillary activity and hydration capacity.
Physical Properties
Physical Properties
Disintex 75
Disintex 200
Disintex 600
Chemistry
PVPP
PVPP
inert salt
PVPP
inert salt/cellulose
Particle size
75
150
750
Use level
2%
2%
4-5%
Applications
Hard tablet
> 10 tons
Dishwashing
tabs
Applications
Digital print media.
Synergistic absorption effects with silica for both dye and pigment based inks.
Improve silica aqueous dispersions by reducing hard pack.
Dye binding pigment useful in non-aqueous coatings.
Hard tablet
Soft tablets
> 10 tons
< 3 tons
Dishwashing Laundry tabs
tabs
Water-softening
tabs
Chemistry
ViviPrint PS-10 is 100% PVPP with an average particle size of 15-30. The
hydroscopic nature of pyrrolidone enhances the ability of PS-10 particles to absorb
liquid rapidly, and its highly hydrophilic nature leads to rapid dispersion in water.
Chemistry
The Disintex series are propertiary blends of PVPP, cellulose and/or inert salts.
They are used extensively as disintegrants in laundry and dishwashing detergent
tablets, taking advantage of their high swell volumes. The cross-linked PVPP
homopolymers are highly hydrophilic and will rapidly absorb water on contact to
swell and create internal stress points that will break-up tablets.
22
Performance Polymers
Vinylpyrrolidone Copolymers
Applications
The Ganex family of Alkylated Polyvinylpyrrolidones are relatively low molecular weight
polymers varying in degree of hydrophobicity from water soluble powder (P-904LC) to
water insoluble flaked solid (WP-660) and are useful in the following applications:
Emulsifiers and dispersants in nonaqueous systems.
Desensitizer/wax dispersant in melt-cast explosives.
Dye dispersant for candles and shoe polish.
Water resistant film former in wood coatings.
Kinetic inhibitor against hydrate formation in oil field operations.
Oil pipeline dewaxer.
Pigment dispersant in solvent based coatings and inks.
Physical Properties
1
2
Product
Co-Polymer
Composition1
Tg/
Melting Pt.
Viscosity2
Supplied As:
Ganex
P-904LC
90% VP,
10% C4 -olefin
155C
14 @ 25Ca
White powder
Ganex
V-516
50% VP,
50% C16 -olefin
150C
300 @ 25Cb
55% actives in
IPA3
Ganex
V-216
20% VP,
80% C16 -olefin
Melting Pt.
8.5C
2500 @ 50Cc
Viscous liquid
Ganex
V-220
20% VP,
80% C20 -olefin
Melting Pt.
~35C
20M @ 80Cd
Wax
Ganex
WP-660
20% VP,
80% C30 -olefin
Melting Pt.
~63C
Flaked solid
VP= Vinylpyrrolidone, C4 -olefin= 1-butene, C16 -olefin= 1-hexadecene, C20 -olefin= 1-eicosene, C30 -olefin= 1-tricosene.
Brookfield, cP. a) RVT#2, 20rpm/10%solids; b) RVT#3, 20rpm/as is; c) RVT#2, 20rpm/neat; RVT# 5, 20rpm/neat.
Chemistry
Ganex resins are copolymers produced from -olefins and vinylpyrrolidone. The
alkyl component varies from a C-4 to C-30 moiety, in concentrations from 10 to
80%. The combination of vinylpyrrolidone and alkyl functionalities produce a
balance of dispersing and waterproofing capacity in the Ganex line of polymers.
23
Performance Polymers
Applications
PVP/VA copolymers produce transparent, flexible, oxygen permeable films
which adhere to glass, plastics and metals. These properties, coupled with the
ability to control their hydrophilicity through monomer composition, lead to
extensive industrial use:
Chemistry
Polyvinylpyrrolidone/vinyl acetate (PVP/VA) resins are linear, random
copolymers produced by the free-radical polymerization of the monomers in
ratios varying from 70/30 to 30/70 vinyl acetate to vinylpyrrolidone.
The PVP/VA copolymers are thermoplastic resins with molecular weights from
approximately 15M-60M. Their glass transition temperatures vary from 70 to
115C and hydrophilicity increases with vinylpyrrolidone content.
PVP/VA copolymers are available as white powders or clear solutions in ethanol,
isopropanol and water. Polymers in the four ranges of vinylpyrrolidone content;
30, 50, 60 and 70%, are produced in ethanol or isopropanol. The PVP/VA
copolymers with 60 and 70% vinylpyrrolidone content are available as solids or
as 50% aqueous solutions.
Physical Properties
PVP/VA Grades
Supplied As
~Mw
Glass Transition
Temp. of Copolymer
in C; low to high
Mw Range
E-335, -535, -635, -735 50% Ethanol 29,000-57,000 69, 96, 106, 117
solution
I-335, -535, -735
50% IPA
solution
W-635, -735
S-630
Dry powder
51,000
110
24
Performance Polymers
Copolymers of
Vinylpyrrolidone/Alkylaminomethacrylate or
Alkylaminomethacrylamide
Applications
These polymers have a number of unique properties, such as substantivity to
anionic materials, that make them useful as:
Chemistry
Polectron 430 is a white, thermoplastic, 38-41% solids, latex produced as a
graft, emulsion copolymer of 30% Polyvinylpyrrolidone and 70% styrene in the
presence of an anionic surfactant. The size distribution of the emulsion is such
that 90% of the particles are <0.5 micron with a maximum 25C viscosity of
750cps @ pH 2.0-5.0. Polectron 430 is thermally and mechanically stable in the
presence of a variety of ionic compounds. The viscosity is unaffected after three
freeze-thaw cycles between ambient and -20C, the emulsion is unbroken at
25C after 1/2 hr @ 10,000 rpm and does not coagulate on addition of 1%
hydrochloric acid, calcium chloride, alum or sodium borate.
25
Performance Polymers
Physical Properties
Mw1
Product
Solution
Copolymer 845
20% H20
1,000,000 172C
20,000-70,000
Physical Properties
Copolymer 937
20% H20
1,000,000 104C
20,000-70,000
Product
Solution
Mw1
Copolymer 958
50% Ethanol
60,000- 100C
1,100,000
1,000,000 155C/
149C
60,000- 140C
110,000
60,000-90,000
Gafquat HS-100
20% H20
900,0001,200,000
50% Ethanol
Tg
Brookfield
Viscosity2
20,000-70,000
30,000-70,000
26
Tg
Brookfield
Viscosity2
184C 50,000-125,000
Performance Polymers
(Vinylpyrrolidone/Dimethylaminopropylmethacrylamide Copolymer)
Applications
Digital printing media (ViviPrint 121 and 131).
Settling agent for hard surface cleaner (Setleze 3000).
Physical Properties
Properties
Styleze CC-10
ViviPrint 121
pH (as is)
6.0-8.0
6.5-7.8
ViviPrint 131
& Setleze 3000
6.5-7.8
10,000-35,000
6,000-24,000
6,000-24,000
Viscosity (cP)
Mw
Nanoparticles
Neutralized
Tg
Applications
Thickener for strong acid formulations such as toilet bowl cleaners.
Inkjet receptive media.
Physical Properties
Physical form ..................................................Slightly hazy aqueous solution
% Solids..........................................................10% (W-10), 20% (W-20)
pH (as is).........................................................3.5-5.0
Viscosity..........................................................<5000 cP (W-10)
40,000-100,000 (W-20)
Molecular weight............................................2,700,000
Tg....................................................................135C
Yes
Yes
H2SO4
161C
H2SO4
167C
HCI
167C
Chemistry
These high molecular weight copolymers have a strong affinity for anionically
charged substrates, which can be further enhanced through quaternization. It
produces transparent, flexible high gloss coatings with improved water
resistant. Cross-linking significantly improves water resistance. Presence of the
amide linkage imparts greater hydrolysis resistance. Compatible with nonionic,
cationic and amphoteric surfactant, soluble in ethanol and water, insoluble
(Styleze CC-10) and partially soluble (ViviPrint 121/131 and Setleze 3000)
in acetone. ViviPrint and Setleze are produced by a proprietary in-situ process
resulting in a 2-phase matrix consisting of soluble copolymer and nanoscale
particles approximately 320 nm in size that impart improved water-resistance,
light fastness and curl resistance in digital media applications.
Chemistry
Styleze W polymers are random terpolymers of vinyl pyrrolidone,
dimethylaminopropyl methacrylamide and methacryloylaminopropyl lauryl
dimethyl ammonium chloride. They promote and stabilize foam through their
ability to reduce surface tension, excellent adhesion to high energy substrates
and are flexible, elastic, low tack and heat resistant films. Additional solution
viscosity improvements can be achieved by the addition of salts. (Material is not
listed on the US EPA TSCA inventory.)
27
Performance Polymers
Applications
Inkjet coatings.
Membranes.
Rinse aids.
Applications
High efficacy styling gels.
Rinse aid in automatic dish detergent.
Metal quenching.
Ink jet receptive media.
Physical Properties
Physical form ..................................................White, free flowing powder
Molecular weight............................................120,000-150,000
Tg....................................................................143C
Physical Properties
Physical form ..................................................White, free flowing powder
Molecular weight............................................1,010,000
Tg....................................................................176C
Chemistry
Acrylidone 1005 is a random copolymer of vinyl pyrrolidone (25%) and acrylic
acid (75%). It forms transparent films that adhere to glass, plastics and metal. It
is soluble in alcohol/water blends, basic solutions, M-Pyrol (N-methyl-2pyrrolidone), propylene glycol and insoluble in ethers, esters, ketones, and
aliphatic and chlorinated hydrocarbons. It is water dispersible and cross-linkable.
Chemistry
Styleze 2000 is a high molecular weight, film forming anionic terpolymer
composed of Vinyl Pyrrolidone and Acrylate backbone with a hydrophobic
pendant C-12 chain. Styleze 2000 is insoluble in ethanol and water until
neutralized for easy dispersion. Exhibits synergistic thickening when combined
with associative rheology modifiers.
28
Performance Polymers
Vinylcaprolactam Polymers
Applications
Vinylcaprolactam derived polymers give hard, glossy transparent films with
excellent adhesive and cohesive properties. These products are also available
in 2-butoxyethanol for application as kinetic gas hydrate inhibitors. The
polymers also find use in many of the markets noted for polyvinylpyrrolidone.
In general, vinylcaprolactam imparts reduced water solubility and cloud point
relative to vinylpyrrolidone-based polymers, while enhancing the
hydrophobicity of the resin.
Applications
Gas hydrate inhibition.
Flocculating agent.
Film former in hair styling products.
Inkjet receptive media.
Physical Properties
Product
Monomer
Composition
Solution
Inhibex
101
Inhibex
301
Inhibex
501
100% VCL
50%
butoxyethanol
50%
butoxyethanol
50%
butoxyethanol
VCL/DEAEMA
50% VCL/
50% VP
Mw1
Viscosity2
2-5x103
~2000
6-9x103
5-8x10
Physical Properties
Physical form ..................................................Viscous ethanol solution
Molecular weight............................................82,700
Tg....................................................................152C
Chemistry
Vinyl caprolactam imparts increased hydrophocity and reduces tack. Watersoluble film former, pseudo-cationic functionality, substantive to negatively
charged surfaces; Quaternization yields cationic polymer; Compatible with
anionic, nonionic and cationic surfactants, silicones and thickeners.
3000-6000
29
Performance Polymers
Applications
Digital printing media.
Applications
Film forming polymer in hair styling products.
Physical Properties
Physical form ..................................................Slightly hazy, viscous
aqueous solution
% Solids..........................................................29-31
Viscosity..........................................................3,000-15,000 cP
Molecular weight............................................1,000,000-1,500,000
Tg....................................................................139C (freeze-dried)
pH...................................................................6.5-7.8
Physical Properties
Physical form ..................................................Clear viscous ethanol solution
Molecular weight............................................37,500
Tg....................................................................119C
Chemistry
Transparent, flexible glossy films; Pseudo-cationic, substantive to negatively
charged surfaces; Quaternization yields cationic polymer; Decreased tackiness
and improved hydrocarbon compatibility due to V-Cap; Water and ethanol
soluble. (Material is not listed on the US EPA TSCA Inventory)
Chemistry
ViviPrint 200 polymer is a terpolymer of V-Cap/DMAPMA/HEMA, neutralized
with HCl, specifically engineered to provide light fastness in formulated coatings
for inkjet media. Pseudo-cationic, substantive to negatively charged surfaces,
crosslinkable with azridine and glycidyl ether. When dried, forms flexible high
gloss films. Compatible with many nonionic, cationic and amphoteric chemicals.
Soluble in ethanol, isopropanol and water and compatible with PVOH, Aquazol
and gelatins.
30
Performance Polymers
Chromabond S-100
Chromabond S-400
Applications
Dye transfer inhibitors
Hard surface cleaners.
Applications
Digital printing media.
Excellent adhesion to metal substrates.
Physical Properties
Physical Properties
Physical Properties
Physical form ..................................................30% aqueous solution
(with <3% IPA)
% Solids..........................................................29-31
Viscosity..........................................................3,000-15,000 cP
Molecular weight............................................250,000-400,000
Tg....................................................................102C (freeze-dried)
pH...................................................................9.5-10.5
Physical form
% Solids
38-42
38-42
33-37
850
350
90
Molecular weight
35,000
28,000-32,000
9,000-17,000
pH (5% solution)
4-7
4-5
4-5
Viscosity (cP)
Chemistry
Chromabond vinylpyridine based polymers contain either nitrogen oxide (S400 and S-403) or betaine (S-100) functionalities. Chromabond is a new family
of premium dye transfer inhibitors (DTI), developed and used in color-safe
laundry detergents. Chromabond polymers demonstrate superior complexing
of fugitive dyes at cost effective levels, under different temperature and
surfactant environments. Its chemical structure promotes dye complexation up
to 60C, while resisting interaction with anionic surfactants. Chromabond
polymers are soluble in water and water-alcohol mixtures, but insoluble in most
other solvents.
Chemistry
ViviPrint 300 polymer is a copolymer of DMAPMA and HEMA specifically
engineered to provide improved dry times of formulated inkjet media where
high levels of organic solvents in inks impact unfavorably on dry times. Excellent
absorption of water and high solvent based inks, excellent dry times, excellent
adhesion to metallized substrates, excellent chelator and cross-linkable with
azridine or epoxides. Soluble in ethanol, isopropanol and water. Partially soluble
in acetone.
31
Performance Polymers
Aquazol (Poly-2-ethyl-2-oxazoline)
Applications
Soil release agent in laundry detergents, fabric softeners and pre and post
wash stain removers.
Ironing aid.
Physical Properties
Physical form ..................................................Slightly turbid amber liquid
% Solids..........................................................75-77%
Applications
Metal quenchants.
Adhesives.
Ceramic binders.
Fiberglass sizing.
Paper coatings.
Inkjet coatings.
Chemistry
Sorez 100 is a modified polyester copolymer concentrate in water-soluble
form. The product imparts wicking properties to hydrophobic textiles. It provides
soil release and anti-redeposition properties while reducing the electrostatic
charge of treated polyester. The polymer forms a thin film on the substrate,
enabling effective soil removal during subsequent wash cycles.
Physical Properties
Physical form ..................................................Off-white solids
% Active .........................................................100%
Specific gravity ...............................................1.14
Tg....................................................................69-71C
Chemistry
Aquazol is poly (2-ethyl-2-oxazoline) and is available in four molecular weight
grades ranging from 5,000 to 500,000. They are non-ionic and soluble in polar
organic solvents and water. They have good adhesive properties and excellent
temperature stability. The long polymer chains provide high molecular weights
with low viscosity solutions that do not degrade over time. Its excellent
thermoplasticity allows it to be used in plastic extrusions.
32
Performance Polymers
Gantrez Copolymers
Physical Properties
Specific Viscosity1
Molecular Weight2
Gantrez AN-119
0.1-0.5
130,000
Gantrez AN-139
1.0-1.5
690,000
Gantrez AN-149
1.5-2.5
1,250,000
Gantrez AN-169
2.6-3.5
2,500,000
Grade
SEC/LALLS detector
Gantrez AN
(Polymethylvinylether/Maleic Anhydride) Copolymer
Chemistry
As produced, Gantrez AN copolymers contain alternating units of
methylvinylether and maleic anhydride. The fundamental character of this
polymerization requires a maleic anhydride unit must be adjacent to a
methylvinylether unit and vice versa, resulting in a true alternating copolymer.
As shown in the table above, Gantrez AN (anhydride form) is available in the
molecular weight range of 130M-2500M. The polymers are white, hygroscopic
powders soluble in tetrahydrofuran and M-Pyrol; insoluble in aliphatic and
halogenated hydrocarbons. All five grades cited have a glass transition
temperature of 151-154C, independent of molecular weight and form
transparent, tack-free films.
Applications
Because of their unique chemical structure and reactivities, Gantrez
Copolymers function well as:
Dispersants for fluorescent light phosphors.
Microcapsule clusterants in carbonless paper and latex systems.
Complex coacervates with gelatin to form the microcapsule wall in
carbonless paper.
Calcium encrustation inhibitors in laundry detergents.
Acid layers in diffusion transfer film to neutralize alkaline developers and dyes.
Intermediates in adhesive applications and liquid laundry detergent stabilizers.
Imide derivatives for anti-reflective layers on silicon wafers prior to
photoresist coating and light exposure.
Gas fade inhibitors for Spandex fibers.
Water retention aid in concrete.
Metal sequestrant.
Anionic polyacids.
33
Performance Polymers
Gantrez S
(Poly(Methylvinylether/Maleic Acid) Copolymer)
Gantrez ES
(Poly(Methylvinylether/Maleic Acid) Half Esters Copolymer)
Applications
Calcium encrustation inhibitors in laundry detergents.
Dispersant aid.
Aluminum surface conditioning.
Diagnostic test strips.
Base-activated adhesive for peel apart instant film.
Applications
Pigment dispersants in cosmetic formulations.
pH dependent soluble films (enteric coatings).
Chemistry
Ethyl, isopropyl and n-butyl half esters are produced by opening up the
anhydride in alcohol. These polymers, based on AN-119, are sold as 50%
solutions in ethanol or isopropanol. They are water soluble when neutralized
greater than 40% using either an organic or inorganic base. Adhesive strength
can be adjusted through controlling the degree of neutralization. Films are
flexible, clear and glossy and have improved water resistance compared to
Gantrez S.
Chemistry
Gantrez S95S and S97 have repeating co-maleic acid units produced by
hydrolysis of Gantrez AN. The polycarboxylic acid derivatives with a pH of ~2 at
5% concentration are available either as viscous solutions or white powders. The
vicinal dicarboxylic acid functionality of these materials is useful in a number of
applications. The free acid forms are water-soluble, giving clear and tacky films.
Solution rheology can be modified by the addition of salts and bases.
Gantrez MS
(Poly(Methylvinylether/Maleic Acid) Mixed Salts Copolymer)
Applications
Bioadhesives.
Inkjet coatings.
Chemistry
Gantrez MS-955 is a mixed salt of sodium/calcium and is supplied as a
free-flowing powder. The copolymer is soluble in water and produces solutions
with high viscosity.
34
Performance Polymers
EasySperse Polymeric Dispersant (Poly(Methylvinylether/Maleic Acid) -Butyl Ethyl Ester, Sodium Salt)
Applications
Stabileze rheology modifiers yield clear, aqueous gels that are shear thinning
and slightly thixotropic, having good shear, temperature and UV-A radiation
stability. Stabileze is effective as a rheology modifier for:
Applications
Dispersant for hydrophobic insectides, fungicides, herbicides.
Dispersant for hydrophobic organic compounds (fragrances, emollients,
essential oils, etc.).
Thickener.
Coatings and inks.
Sealants.
Electroconductive gels.
Deicing fluids.
Pigment dispersant.
Chemistry
EasySperse dispersant is a copolymer of the monobutyl/ethyl ester of poly
(methyl vinyl ether/maleic acid) partially neutralized with sodium hydroxide. The
material is supplied as a 25% aqueous solution and is an excellent film former.
Chemistry
Stabileze is produced in a manner similar to that of Gantrez AN but with the
added monomer decadiene present to yield a crosslinked, water swellable resin.
The polymer is a white, free-flowing powder with a glass transition temperature
of approximately 150C. The powder is available in two particle sizes; < 850
microns (Stabileze 06) and < 75 microns (Stabileze QM). The solid can be
dispersed in water without coagulating and the anhydride function will
hydrolyze directly or through the action of base. A neutralized 0.5% solution in
water at pH 7 and 25C has a viscosity range of 45,000-70,000 cP.
35
Performance Polymers
Physical Properties
Physical form ..................................................Free flowing white powder
Molecular weight............................................78,000-94,000
Tg....................................................................164C
Applications
Film former.
Adhesive/cohesive properties.
Chemistry
I-Rez 160 is a linear, alternating copolymer of isobutylene and maleic
anhydride that forms transparent, tack free films and reacts with alcohols/
amines to yield half esters/amides. Soluble in aprotic solvents, forms gels with
ketones and esters. Water solubility control by degree of neutralization.
Insoluble in alcohol and aliphatic hydrocarbons.
Physical Properties
Physical form ..................................................Yellow viscous liquid.
Molecular weight............................................39,000
Tg....................................................................135C
Chemistry
Aquaflex FX-64 is an imidized isobutylene/maleic anhydride copolymer that
produces low tack, glossy films supplied as 40% hydroalcoholic solution.
(Material is not listed on the US EPA TSCA inventory)
36
Specialty Chemicals
Performance Polymers
Applications
Film former, flexible coating with low coefficient of friction.
Physical Properties
Physical form ..................................................Straw-like hazy, viscous
aqueous solution.
Molecular weight............................................86,000
Physical Properties
Properties
Chemistry
Aquaflex XL-30 is an isobutylene dimethylaminopropylmaleimide/ethoxylated
maleimide/maleic anhydride copolymer that produces highly flexible, glossy
and humidity resistant films and forms clear gels with anionic rheology
modifiers. (Material is not listed on the US EPA TSCA inventory)
Silcron
G-100 G-601 G-602 G-650 G-860 G-900 IJ-25 IJ-50
Supplied as
37
30% solution
Pore volume
(ml/g)
1.5
1.2
1.2
1.2
1.6
0.6
Surface area
(m2/g)
260
290
280
290
340
715
125
50
5.5
7.0
9.5
4.3
6.0
8.0
0.025 0.050
pH
(5% aq slurry)
7.5
7.0
7.0
7.0
4.0
2.5
3.5
3.5
Oil absorption
(g/100g)
280
210
210
220
300
70
Loss on drying
(at 105C, % max)
4.5
3.5
3.5
3.5
4.5
3.2
Specialty Chemicals
Escalol UV Absorbers
ISP has a broad family of water insoluble esters and hydroxyesters sold under the
Ceraphyl and Cerasynt trademarks as lubricants, dispersants and emulsifiers.
These chemicals typically are surface active and find use in HI&I, plastics, textile,
photography, inks and coatings markets. A variety of esters are available with a
range of properties, including liquids and waxy solids. In addition, amide and
quaternary-ammonium salts are available.
Physical Properties
Product
Escalol 507
2-Ethylhexy-pdimethylaminobenzoate
Bp 362C
Escalol 517
1-(4-Methoxyphenyl)-3-(4-terbutylphenyl) propan-1,3-dione
Escalol 557
2-Ethylhexyl-pmethoxycinnamate
Escalol 567
2-Hydroxy-4methoxybenzophenone
Mp 62C min.
Escalol 577
Mp >120C
Escalol 587
2-Ethylhexyl salicylate
Bp 150C @ 3mm Hg
Escalol 598
2-Ethylhexyl 2-cyano-3,3diphenylacrylate
Bp 218C @ 1.5mm Hg
Bp 198-200C @ 3 mm Hg
38
Specialty Chemicals
Product
Chemical Name
Applications
Ceraphyl 28
Hexadecyl lactate
Ceraphyl ODS
Octyldodecyl stearate
Ceraphyl RMT
Ceraphyl 31
Lauryl lactate
Ceraphyl SLK
Isodecyl neopentanoate
Ceraphyl 41
Plasticizing effects
Cerasynt 303
Ceraphyl 45
Ceraphyl 50
Tetradecyl lactate
Diethylaminoethyl
stearate
Polyoxyethylene (20)
stearate
Ceraphyl 55
Tridecyl neopentanoate
Ceraphyl 140
Decyl oleate
Ceraphyl 140A
Isodecyl oleate
Ceraphyl 230
Diisopropyl adipate
Ceraphyl 368
2-Ethylhexyl palmitate
PVC plasticizer
Textile finishing surfactant
O/W emulsions
Plasticizing effects
Lubricant
Hard surface cleaners
Erasable markers
Mold release agent
Inkjet inks
Circuit board cleaning
Hard surface cleaners
Tissue paper lotion
Lubricant
Ceraphyl 375
Isostearyl neopentanoate
Pigment dispersion
Ceraphyl 424
Tetradecyl
tetradecanoate
Ceraphyl 494
Isocetyl stearate
Ceraphyl 791
Ceraphyl 847
Octyldodecyl stearoyl
stearate
Ceraphyl CE
Cetyl esters
Ceraphyl GA-D
Ceraphyl ICA
Isohexadecanol
Cerasynt 840
Cerasynt GMS
Glyceryl monostearate
Cerasynt 945
Cerasynt D
Stearic monoethanolamide
stearate
2-Hydroxyethyl stearate
Opacifier and pearlizing agent
and ethylene glycol
2-Hydroxyethyl stearate, Opacifier and pearlizing agent
sodium laureth sulfate and
hexylene glycol
Cerasynt IP
Cerasynt LP
Cerasynt M
2-Hydroxyethyl stearate
Pearlizing agent
Liquid detergent compositions
Pigment dispersions
Cerasynt MN
Anti-fogging agent
Pigment dispersions
Polycarbonate mold release agent
2-Hydroxyethyl stearate
and potassium stearate
Cerasynt PA
Propylene glycol
monostearate
Cerasynt SD
Glyceryl stearate
Pigment dispersions
Mold release
Graffiti removal
Polyester finishing agent
39
Specialty Chemicals
Micropowder Iron
Carbonyl Iron Powder (Fe)
Applications
Carbonyl iron powder is manufactured by the chemical decomposition of iron
pentacarbonyl. The resulting iron particles are uniform gray microscopic spheres
with only traces of carbon, oxygen, and nitrogen. Over 25 different grades of iron
powder are manufactured through this process and marketed under the
tradename Micropowder. Specific applications include:
Applications
Iron pentacarbonyl is an intermediate that has found utility in a variety of
applications. In the past, it has been used as a fuel antiknock agent, a
photochemical additive and an intermediate for many iron products. The most
important current applications are:
Catalyst: for coal liquefaction, Fischer-Tropsch hydroformylation, olefin
isomerization, and water gas shift reactions.
Precursor: for chemically pure iron, iron oxides, iron catalysts and thin iron films.
Desulfurization: removal of sulfur from coal and petroleum products.
Physical Properties
Boiling point...................................................103C
Melting point..................................................-20C
Specific gravity ...............................................1.453
Physical Properties
The fine size and high purity of the carbonyl iron powders are the principal
reasons for their superior properties compared to other forms of elemental iron
powders. Distinct characteristics of the Micropowder Iron products include:
Chemistry
Iron pentacarbonyl is a specialty chemical that is produced as an intermediate
during the manufacture of carbonyl iron powders. It is produced from a high
pressure reaction between high grade iron and carbon monoxide. This
organometallic compound exists as a liquid at room temperature. It may ignite
spontaneously in air and is decomposed by heat to metallic iron and carbon
monoxide. In air it decomposes to iron oxides, and in sunlight to iron
nonacarbonyl. While Fe(CO)5 is highly reactive, it is stable in dark storage under
nitrogen. It is soluble in common organic solvents such as acetone or toluene
and insoluble in water or liquid ammonia. It is unreactive with most acids.
40
Application Chart
Coatings
&
Adhesives
HI&I/Textiles
Metallurgy
Oil/Chemical
Plastics
Electronics
Printing/Inks
Miscellaneous
Adhesives
Coatings, Industrial
Coatings, Specialty & Imaging
Paints/Latex Systems
Radiation Curing (RC)
Detergents
Fiber Dyeing
Industrial & Institutional Cleaners
Surface Cleaners
Textile Processing
Tabletting
Acid Pickling
Electroplating
Metal Cleaners
Metal Quenchants
MIM/PM Products
Precision Electronic Cores
Catalysts
Gasoline & Oil Additives/Processing
Oil/Gas Well Maintenance
Petrochemical Processing
Reaction Solvent
Polymer Intermediate
Polystyrene Manufacture
Battery Manufacture
Radar Absorbing Material
EMI/RF Shielding
Photo-Resist Processing
Printed Circuit Boards
Lithographic Developers
Paper Manufacture
Printing Inks
Dispersants
Gel Former
Paint Stripper
UV Absorbers
Lubrication
Emulsification
Membranes
41a
Microflex Microemulsifier
Easy-Wet 20
Surfadone LP-300
Surfadone LP-100
CHP (N-Cyclohexyl-2-Pyrrolidone)
HEP (N-(2-Hydroxyethyl)-2-Pyrrolidone)
NEP (N-Ethyl-2-Pyrrolidone)
M-Pyrol (N-Methyl-2-Pyrrolidone)
2-Pyrol (2-Pyrrolidone)
BLO
THF (Tetrahydrofuran)
Butanediol
Butenediol
Butoxyne 497
Butynediol
Propargyl Alcohol
41b
Copolymer VC-713
V-Cap Polymers
Styleze 2000
Acrylidone 1005
Setleze 3000
Styleze CC-10
Gafquat HS-100
Vinyl Monomers
VP Alkylamino Copolymers
PVP/VA Copolymers
ViviPrint PS-10
PVPP (Polyvinylpolypyrrolidone)
ViviPrint 540
PVP (Polyvinylpyrrolidone)
V-Cap/RC
PartsPrep Degreaser
Performance Polymers
Application Chart
Iron Pentacarbonyl
Escalol UV Absorbers
Aquaflex XL-30
Aquaflex FX-64
I-Rez 160
EasySperse Dispersant
Gantrez Copolymers
Aquazol Polymers
Sorez 100
ViviPrint 300
ViviPrint 200
Aquaflex SF-40
Specialty Chemicals
41c
The information contained in this brochure and the various products described are
intended for use only by persons having technical skill and at their own discretion and
risk after they have performed necessary technical investigations, tests and
evaluations of the products and their uses. While the information herein is believed to
be reliable, we do not guarantee its accuracy and a purchaser must make its own
determination of a products suitability for purchasers use, for the protection of the
environment, and for the health and safety of its employees and the purchasers of its
products. Neither ISP nor its affiliates shall be responsible for the use of this
information, or of any product, method, formulation, or apparatus described in this
brochure. Nothing herein waives any of ISPs or its affiliatesconditions of sale, and WE
MAKE NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS OF ANY
PRODUCT FOR A PARTICULAR USE OR PURPOSE. We also make no warranty against
infringement of any patents by reason of purchasers use of any information, product,
method or apparatus described in this brochure.
Trademark registration applied for
Registered trademark of the ISP group
International Specialty Products. 2005
Aquazol is a registered trademark of Polymer Chemistry Innovations Inc. The
products are marketed and sold exclusively by ISP globally for industrial applications.
Silcron is a registered trademark of Millennium Specialty Chemicals Inc.,
a Lyondell Company.
For more information visit us at www.ispcorp.com
43
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(Denmark, Estonia, Iceland,
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Tel: +46 (0) 8 519 920-10
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info.switzerland@ispcorp.com
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Tel: +32 (0) 2 626-49 30
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Fax: +32 (0) 2 626-49 32
info.belgium@ispcorp.com
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Fax: +359 (0) 2 850-5480
info.bulgaria@ispcorp.com
GERMANY
Tel: +49 (0) 2236 9649-260
+49 (0) 2236 9649-264
+49 (0) 2236 9649-266
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Tel: +44 (0) 207 519-5054
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myamashita@ispcorp.com
SINGAPORE
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Fax: +656 226-0853
ffoo@ispcorp.com
VICTORIA, AUSTRALIA
Tel: +613 9899-5082
Fax: +613 9899-5102
roppy@ispcorp.com
SHANGHAI, CHINA
Tel: +8621 6249-3900
Fax: +8621 6249-3908
hwong@ispcorp.com
KOREA
Tel: +82 2 554-6622
Fax: +82 2 554-6944
ksoh@ispcorp.com
TAIWAN
Tel: +886 2 2508-0212
Fax: +886 2 2504-3543
cchiang@ispcorp.com
BEIJING, CHINA
Tel: +8610 6515-6265
Fax: +8610 6515-6267
hwong@ispcorp.com
HONG KONG
Tel: +852 2881-6108
Fax: +852 2895-1250
hwong@ispcorp.com
INDONESIA
Tel: +6221 530-7181
+6221 530-7182
Fax: +6221 530-7183
mchondrodihardjo@ispcorp.com
MALAYSIA
Tel: +60 5513-1498
Fax: +60 5512-8311
ffoo@ispcorp.com
THAILAND
Tel: +662 267-8103
Fax: +662 236-0041
pwilliams@ispcorp.com
CHENGDU, CHINA
Tel: +8628 8557-1040
Fax: +8628 8557-2313
hwong@ispcorp.com
HYDERABAD, INDIA
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Fax: +9140 2331-1090
ekalyanpur@ispcorp.com
OSAKA, JAPAN
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Fax: +816 6838-5566
myamashita@ispcorp.com
PHILIPPINES
Tel: +632 848-7188
Fax: +632 848-7191
rcomagon@ispcorp.com
Trademark registration applied for Registered trademark of the ISP group International Specialty Products. 2005 Designed & Printed in USA.
The information contained in this brochure and the various products described are intended for use only by persons having technical skill and at their own discretion and risk after they have performed necessary technical investigations,
tests and evaluations of the products and their uses. While the information herein is believed to be reliable, we do not guarantee its accuracy and a purchaser must make its own determination of a products suitability for purchasers
use, for the protection of the environment, and for the health and safety of its employees and the purchasers of its products. Neither ISP nor its affiliates shall be responsible for the use of this information, or of any product, method,
formulation, or apparatus described in this brochure. Nothing herein waives any of ISPs or its affiliates conditions of sale, and WE MAKE NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS OF ANY PRODUCT
FOR A PARTICULAR USE OR PURPOSE. We also make no warranty against infringement of any patents by reason of purchasers use of any information, product, method or apparatus described in this brochure.