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    Parcial 3

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    ソーダ エドゥアルド
    1) The document contains experimental data from multiple kinetics experiments including concentration vs time data and plots of log(time) vs inverse temperature used to determine activation energies. 2) Linear regression analysis was performed on plots of log(time) vs concentration and 1/concentration vs time to determine the orders of reactions. 3) The activation energy of one reaction was calculated to be 103.5 kJ/mol based on the slope and intercept of an Arrhenius plot of log(time) vs inverse temperature.

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    Parcial 3

    Uploaded by

    ソーダ エドゥアルド
    21 views9 pages
    1) The document contains experimental data from multiple kinetics experiments including concentration vs time data and plots of log(time) vs inverse temperature used to determine activation energies. 2) Linear regression analysis was performed on plots of log(time) vs concentration and 1/concentration vs time to determine the orders of reactions. 3) The activation energy of one reaction was calculated to be 103.5 kJ/mol based on the slope and intercept of an Arrhenius plot of log(time) vs inverse temperature.

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    PARCIAL 3.xlsx

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    1) The document contains experimental data from multiple kinetics experiments including concentration vs time data and plots of log(time) vs inverse temperature used to determine activation energies. 2) Linear regression analysis was performed on plots of log(time) vs concentration and 1/concentration vs time to determine the orders of reactions. 3) The activation energy of one reaction was calculated to be 103.5 kJ/mol based on the slope and intercept of an Arrhenius plot of log(time) vs inverse temperature.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    21 views9 pages

    Parcial 3

    Uploaded by

    ソーダ エドゥアルド
    1) The document contains experimental data from multiple kinetics experiments including concentration vs time data and plots of log(time) vs inverse temperature used to determine activation energies. 2) Linear regression analysis was performed on plots of log(time) vs concentration and 1/concentration vs time to determine the orders of reactions. 3) The activation energy of one reaction was calculated to be 103.5 kJ/mol based on the slope and intercept of an Arrhenius plot of log(time) vs inverse temperature.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
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    R(mmHg*L/mol*K)

    tiempo (1/2)
    62.364
    860
    T (k)
    470
    1030
    255
    n
    212
    1.3
    k
    1.5

    precion parcial inicial(mmHg)


    Ca0
    82.5 0.0012843481
    139 0.002163932
    296 0.0046080854
    360 0.0056044282

    es orden m

    f(x) = - 0.927944862x + 0.231


    R = 0.9933769172

    Log(t1/2)

    -3

    -2.9

    -2.8

    -2.7

    LOG t 1/2
    LOGCa0
    t(1/2)
    t(1/2)
    t(1/2)
    TEXP-TCAL
    2.93449845 -2.89131724 0.23114441 1.70325069 3.78500153 858.296749
    2.67209786 -2.66475639 0.23114441 1.45649942 3.23666539 468.543501
    2.40654018 -2.33647948 0.23114441 1.1609867 2.57997044 253.839013
    2.32633586 -2.25146869 0.23114441 1.09477282 2.43282849 210.905227

    es orden mayor que 1


    3.5
    3

    0.927944862x + 0.2315948626
    9933769172

    2.5
    2
    1.5
    1
    0.5

    -2.8

    -2.7

    -2.6

    Log(Ca0)

    -2.5

    -2.4

    -2.3

    0
    -2.2

    (ANTERIOR)^2
    736673.31
    219533.012
    64434.2447
    44481.0149
    1065121.58

    n
    k

    Caexp-2<mol/dm^3> tiempo(h)
    13.8
    11.05
    1.5
    8.43
    5.69
    1.6
    3

    0
    10
    20
    30
    40

    (1/Ca)=(k1/2) t(1/2)
    190.44 1.82842712
    122.1025 1.82842712
    71.0649 1.82842712
    32.3761 1.82842712
    9 1.82842712

    Orden 2
    200
    f(x) = - 4.526064x + 175.51798
    R = 0.9647542674

    150

    1/Ca

    100
    50
    0
    0

    10

    15

    20

    tiempo (h)

    25

    30

    35

    40

    t(1/2)
    log(t1/2)
    435.257077
    Err:502
    279.069404
    0.69897
    162.421238
    1
    73.9966743 1.17609126
    20.5698052
    1.30103

    30

    35

    40

    45

    Caexp-3<mol/dm^3> tiempo (seg) menos logca/ca0


    7.36E-03
    0
    0
    3.68E-03
    60
    0.6931471806
    2.45E-03
    120
    1.0999719082
    1.47E-03
    240
    1.610797532
    1.23E-03
    300
    1.7890457634

    Ttulo del grf


    2
    f(x) = 0.0056379847x + 0.2267226787
    R = 0.9406750644

    1.5

    Axis Title

    1
    0.5
    0
    0

    50

    100

    150

    Axis Title

    200

    250

    300

    350

    300

    350

    T(C)

    t (1/2)
    50
    100
    150
    200
    300

    780
    4.6
    0.088
    0.0039
    0.000039

    log(t1/2)
    1/t
    6.65929392 0.00309598
    1.5260563 0.00268097
    -2.43041846 0.00236407
    -5.54677873 0.00211416
    -10.1519489 0.0017452

    Energia de activacin

    Log(t1/2)

    8
    6
    f(x) = 12449.7943454225x - 31.8691923089
    4
    R = 0.9999957144
    2
    0
    0.0016
    0.0018 0.002 0.0022 0.0024 0.0026 0.0028
    -2
    -4
    -6
    -8
    -10
    -12

    1/T

    0.00

    R(J/MOLK)
    pendiente
    interseccion
    Ea

    8.314
    12450
    -31.869
    103509.3

    activacin

    225x - 31.8691923089

    0.0024 0.0026 0.0028

    1/T

    0.003

    0.0032

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