Sodium Hypochlorite Tech Msds

REVISION DATE: 14/08/2009
SODIUM HYPOCHLORITE TECH MSDS

According to Regulation (EC) No 1907/2006
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
PRODUCT NAME
SODIUM HYPOCHLORITE TECH
SUPPLIER
Reagent Chemical Services

18 Aston Fields Road
Whitehouse Industrial Estate
Runcorn
Cheshire WA7 3DL
T: 01928 716903
F: 01928 716425
E: info@reagent.co.uk
PRODUCT NO.
2604
APPLICATION
General chemical reagent
EMERGENCY TELEPHONE
Emergency Telephone : +44 (0) 1928 716903 Between 08.30 - 17.00
2 HAZARDS IDENTIFICATION
Contact with acids liberates toxic gas. Causes burns.
CLASSIFICATION (1999/45)
C;R34. R31.
3 COMPOSITION/INFORMATION ON INGREDIENTS
Name
EC No.
CAS-No.
Content
Classification (67/548)
SODIUM HYPOCHLORITE SOLUTION, ... % Cl

ACTIVE
231-668-3
7681-52-9
10-30%
C;R34 R31 N;R50
The Full Text for all R-Phrases are Displayed in Section 16
4 FIRST-AID MEASURES
GENERAL INFORMATION
CAUTION! First aid personnel must be aware of own risk during rescue! First aid personnel must protect themselves with all necessary
personal protective equipment during the assistance of casualties. When breathing is difficult, properly trained personnel may assist the
casualty by administering oxygen. If casualty needs to be resuscitated avoid mouth to mouth contact, use a mechanical device such as a
bag and mask to provide artificial respiration. Place unconscious person on the side in the recovery position and ensure breathing can take
place. Do not give victim anything to drink if they are unconscious. If medical attention is required take this information sheet with the
casualty.
INHALATION
Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. In case of severe exposure or if any discomfort
continues get medical attention.
INGESTION
Do not induce vomiting. Immediately rinse mouth and drink plenty of water. Get medical attention immediately!
SKIN CONTACT
Immediately remove contaminated clothing and wash before re-use. Rinse the skin immediately with lots of water. Unless contact has
been slight and no discomfort is felt, obtain medical attention.
EYE CONTACT
May cause permanent damage if eye is not immediately irrigated. Promptly wash eyes with plenty of water or eye wash solution while lifting
the eyelids.If possible remove any contact lenses and continue to wash. Get medical attention immediately.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
The product is non-combustible. Water spray.
SPECIFIC HAZARDS
In case of fire, toxic and corrosive gases may be formed. Chlorine compounds.
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
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6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
SPILL CLEAN UP METHODS
If local regulations allow run to drain with copious amounts of water. Otherwise Small Spillages: Absorb with sand or other inert absorbent.
Large Spillages: Dam and absorb spillages with sand, earth or other inert material. Collect spillage in containers, seal securely and deliver
for disposal according to local regulations. Containers with collected spillage must be properly labelled with correct contents and hazard
symbol. Wash spillage site well with water and detergent, be aware of the potential for surfaces to become slippery. Ventilate well.
7 HANDLING AND STORAGE

USAGE PRECAUTIONS
Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists.
STORAGE PRECAUTIONS
Store away from: Acids. Store in vented , original containers in a cool, dry place. Store away from direct sunlight and moisture
STORAGE CLASS
Corrosive storage.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Name
Std
SODIUM HYPOCHLORITE SOLUTION, ... % Cl

ACTIVE
OES
TWA - 8 hrs
1.5 (Chlorine)
mg/m3
STEL - 15 min
Notes
2.9 (Chlorine)
mg/m3
ENGINEERING MEASURES
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined workplace exposure limit (WEL) is not
exceeded. If vapours or mists are generated, work in a fume cupboard.
RESPIRATORY EQUIPMENT
Wear suitable respiratory protection if vapours or mists are generated. Consult with the supplier as to the compatibility of the equipment
with the chemical of concern.
HAND PROTECTION
Use full length gloves. Rubber or plastic Be aware that the liquid may penetrate the gloves. Frequent change is advisable. The most
suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material.
EYE PROTECTION
Wear approved safety goggles.
OTHER PROTECTION
Wear suitable protective clothing as protection against splashing or contamination. Provide eyewash station and safety shower. Wear
plastic apron and full length gloves if handling large amounts. If there is a risk of splashing then wear a face shield.
HYGIENE MEASURES
Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated.
Promptly remove any clothing that becomes wet or contaminated. When using do not eat, drink or smoke.
9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE
Liquid
COLOUR
Colourless to pale yellow
ODOUR
Chlorine.
SOLUBILITY
Miscible with water
BOILING POINT (C)

VAPOUR DENSITY (air=1)
Approx. 96 - 99 760 mm Hg
2.49
RELATIVE DENSITY
Approx. 1.2 20
10 STABILITY AND REACTIVITY

STABILITY
Limited storage life.
CONDITIONS TO AVOID
Avoid heat. Avoid contact with acids.
MATERIALS TO AVOID
Acids (liberation of chlorine). Amines. Alcohols, glycols. Organic nitrites. Inorganic nitrites. Strong oxidising substances.
HAZARDOUS DECOMPOSITION PRODUCTS
Chlorine.
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11 TOXICOLOGICAL INFORMATION
TOXIC DOSE 1 - LD 50
8200 mg/kg (oral rat)
INHALATION
Irritating to respiratory system. May cause oedemas in the respiratory tract.
INGESTION
Corrosive. Even small amounts may cause serious damage. May cause burns to the oesophagus and stomach. Toxic if swallowed.
SKIN CONTACT
Causes burns.
EYE CONTACT
Strongly corrosive. Causes severe burns and serious eye damage. Immediate first aid is imperative.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Ecological effects cannot be excluded in the event of improper handling or disposal. May cause long-term adverse effects in the aquatic
environment.
DEGRADABILITY
Readily degradable in water
13 DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements.
14 TRANSPORT INFORMATION
UK ROAD CLASS
PROPER SHIPPING NAME
SODIUM HYPOCHLORITE SOLUTION
UN NO. ROAD
1791
UK ROAD PACK GR.
II
ADR CLASS NO.
ADR CLASS
Class 8: Corrosive substances.
ADR PACK GROUP
II
ADR LABEL NO.
RID CLASS NO.
RID PACK GROUP
II
UN NO. SEA
1791
IMDG CLASS
MARINE POLLUTANT
No.
UN NO. AIR
1791
AIR CLASS
AIR PACK GR.
II
15 REGULATORY INFORMATION
LABELLING
Corrosive
CONTAINS
SODIUM HYPOCHLORITE SOLUTION, ... % Cl ACTIVE
RISK PHRASES
R31
Contact with acids liberates toxic gas.
R34
Causes burns.
S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S45
In case of accident or if you feel unwell, seek medical advice immediately (show label
where possible).
SAFETY PHRASES
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S24/25
Avoid contact with skin and eyes.
S36/37/39
Wear suitable protective clothing, gloves and eye/face protection.
S60
This material and its container must be disposed of as hazardous waste.
STATUTORY INSTRUMENTS
Chemicals (Hazard Information and Packaging) Regulations. Control of Substances Hazardous to Health.
APPROVED CODE OF PRACTICE
Classification and Labelling of Substances and Preparations Dangerous for Supply. COSHH essentials: Easy steps to control chemicals.
Control of Substances Hazardous to Health Regulations.
GUIDANCE NOTES
Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37.
NATIONAL REGULATIONS
Control of Substances Hazardous to Health Regulations 2002 (as amended)
16 OTHER INFORMATION
GENERAL INFORMATION
Under REACH Material Safety Datasheets (MSDS) are referred to as Safety Datasheets (SDS).
REVISION COMMENTS
This is first issue.
REVISION DATE
14/08/2009
REV. NO./REPL. SDS GENERATED 1

SDS NO.
11499
SAFETY DATA SHEET STATUS

Approved.
RISK PHRASES IN FULL
R34
Causes burns.
R31
Contact with acids liberates toxic gas.
R50
Very toxic to aquatic organisms.
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REVISION DATE: 14/08/2009