1251 MSDS

REVISION DATE: 19/07/2010
SAFETY DATA SHEET

Domestos Thick Bleach Original Blue
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
PRODUCT NAME
SUPPLIER
Unilever UK Limited
Springfield Drive
Leatherhead
Surrey
KT22 7GR
0800 77 66 45 / Eire 1850 388 399
unileversds@unileverconsumerlink.c
o.uk
PRODUCT NO.
8463303 / 4
APPLICATION
Hygienic Cleaner for Hard surfaces and Toilets
EMERGENCY TELEPHONE
0137294 8999
CONTAINER SIZE
Bottle
2 HAZARDS IDENTIFICATION
Irritating to skin. Risk of serious damage to eyes.
CLASSIFICATION (1999/45)
Xi;R38, R41.
PHYSICAL AND CHEMICAL HAZARDS
Warning! Do not use together with other products. May release dangerous gases (chlorine).
3 COMPOSITION/INFORMATION ON INGREDIENTS
Name
EC No.
CAS-No.
Content
Classification (67/548)
SODIUM HYPOCHLORITE SOLUTION, ... % Cl

ACTIVE
c12-18 alkyl dimethylamine oxide
231-668-3
7681-52-9
1-5%
C;R34 R31 N;R50
68955-55-5
1-5%
Xi;R38,R41. N;R50.
SODIUM HYDROXIDE
215-185-5
1310-73-2
< 1%
C;R35
The Full Text for all R-Phrases are Displayed in Section 16

COMPOSITION COMMENTS
For confidentiality reasons, the levels of components listed in Section 3 are given in percentage bands. The bandings do not reflect
potential variation in composition of this formulation, but are used simply to mask the exact component levels, which we consider to be
proprietary information. The classification given in Section 2 and 15 reflects the exact composition of this mixture.
4 FIRST-AID MEASURES
INHALATION
Move the exposed person to fresh air at once. If Chlorine released: Get medical attention immediately! When breathing is difficult,
properly trained personnel may assist affected person by administering oxygen. If no Chlorine is released Get medical attention if any
discomfort continues.
INGESTION
If swallowed, rinse mouth with water (only if the person is conscious). In case of accident or if you feel unwell, seek medical advice
immediately (show label where possible). Contact physician if larger quantity has been consumed.
SKIN CONTACT
Rinse the skin immediately with lots of water. Remove contaminated clothing. Rinse with water. Get medical attention if any discomfort
continues.
EYE CONTACT
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
5 FIRE-FIGHTING MEASURES
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EXTINGUISHING MEDIA
This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.
SPECIAL FIRE FIGHTING PROCEDURES
No specific fire fighting procedure given.
UNUSUAL FIRE & EXPLOSION HAZARDS
No unusual fire or explosion hazards noted.
SPECIFIC HAZARDS
When heated and in case of fire, toxic vapours/gases may be formed.
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS
In case of spills, beware of slippery floors and surfaces. Avoid inhalation of vapours/spray and contact with skin and eyes. Wash
thoroughly after dealing with a spillage. For industrial settings: Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Small quantities can be dissolved/diluted in water and flushed to drain. Large Spillages: Avoid discharge into drains, water courses or onto
the ground. If risk of water pollution occurs, notify appropriate authorities.
SPILL CLEAN UP METHODS
Small or household quantities may be cleaned up and disposed of with normal household waste. For industrial settings: Collect with
absorbent, non-combustible material into suitable containers. Unsuitable containers: metals. Avoid contact with acids. Wash
contaminated area with water. For waste disposal, see section 13.
7 HANDLING AND STORAGE

USAGE PRECAUTIONS
Do not mix with other products. Contact with acids liberates toxic gas. Avoid inhalation of vapours/spray and contact with skin and eyes.
For prolonged or repeated skin contact use suitable protective gloves. For industrial settings: Use appropriate engineering controls and
personal precautions as defined in Section 8.
STORAGE PRECAUTIONS
Keep in original container. Store at moderate temperatures in dry, well ventilated area. Avoid exposure to high temperatures or direct
sunlight. Oxidising material - Keep away from flammable and combustible materials. Store away from: Acids. Organic solvents.
STORAGE CLASS
Unspecified storage.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Name
Std
SODIUM HYDROXIDE
WEL
TWA - 8 hrs
STEL - 15 min
Notes
2 mg/m3
WEL = Workplace Exposure Limit.

PROCESS CONDITIONS
For industrial settings: Eye wash facilities and emergency shower must be available when handling this product.
ENGINEERING MEASURES
Exposure to hazardous materials should be controlled at source by provision of engineering containment and/or ventilation. Refer to local
risk assessment for further details. Observe relevant occupational exposure limits and minimise exposure to hazardous materials at all
times.
RESPIRATORY EQUIPMENT
None under normal conditions. For industrial settings: Respiratory protection must be used if air contamination exceeds acceptable level.
Refer to local risk assessment for further details
HAND PROTECTION
For prolonged or repeated skin contact use suitable protective gloves. For industrial settings: Use protective gloves made of: Rubber,
neoprene or PVC.
EYE PROTECTION
For industrial settings: Wear eye/face protection.
HYGIENE MEASURES
When using do not eat, drink or smoke. Wash hands after handling.
SKIN PROTECTION
For industrial settings: Wear appropriate clothing to prevent repeated or prolonged skin contact.
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ENVIRONMENTAL EXPOSURE CONTROLS
For industrial settings: Do not discharge into drains, water courses or onto the ground. If risk of water pollution occurs, notify appropriate
authorities.
9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE
Liquid
SOLUBILITY
Soluble in water.
RELATIVE DENSITY
VISCOSITY
1.082 (1.065 to 1.097)
pH-VALUE, CONC. SOLUTION
13
650 (500-850) mPas @ 25C,

21
s-1
10 STABILITY AND REACTIVITY

STABILITY
Stable under normal temperature conditions and recommended use.
CONDITIONS TO AVOID
Avoid contact with acids. Warning! Do not use together with other products. May release dangerous gases (chlorine). Avoid exposure to
high temperatures or direct sunlight.
MATERIALS TO AVOID
Acids. Flammable/combustible material.
HAZARDOUS DECOMPOSITION PRODUCTS
When heated, toxic and corrosive vapours/gases may be formed.
11 TOXICOLOGICAL INFORMATION
INHALATION
May cause irritation to the respiratory system.
INGESTION
May cause discomfort if swallowed.
SKIN CONTACT
Irritating to skin.
EYE CONTACT
Irritating to eyes.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
The product is not expected to be hazardous to the environment.
DEGRADABILITY
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and
will be made available to them, at their direct request or at the request of a detergent manufacturer.
13 DISPOSAL CONSIDERATIONS
GENERAL INFORMATION
The product is not classified as dangerous to the environment in accordance with the criteria of the Dangerous Preparations Directive
1999/45/EC as amended. However, large volumes should not be discharged into drains, watercourses or onto the ground.
DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements.
14 TRANSPORT INFORMATION
GENERAL
Not classified for transportation.
15 REGULATORY INFORMATION
SYMBOLS
Irritant
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RISK PHRASES
R38
Irritating to skin.
R41
Risk of serious damage to eyes.
S2
Keep out of the reach of children.
S24/25
Avoid contact with skin and eyes.
S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S37/39
Wear suitable gloves and eye/face protection.
S46
If swallowed, seek medical advice immediately and show this container or label.
S64
If swallowed, rinse mouth with water (only if the person is conscious).
P6
Warning! Do not use together with other products. May release dangerous gases
(chlorine).
SAFETY PHRASES
EU DIRECTIVES
Dangerous Preparations Directive 1999/45/EC. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European
Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)
No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC,
including amendments.
16 OTHER INFORMATION
REVISION DATE
19/07/2010
REV. NO./REPL. SDS GENERATED 18

RISK PHRASES IN FULL
R34
Causes burns.
R35
Causes severe burns.
R31
Contact with acids liberates toxic gas.
R38
Irritating to skin.
R41
Risk of serious damage to eyes.
R50
Very toxic to aquatic organisms.
DISCLAIMER
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no
warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the
suitability of such information for his own particular use.
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REVISION DATE: 19/07/2010

SAFETY DATA SHEET

Domestos Thick Bleach Original Blue

Hygienic Cleaner for Hard surfaces and Toilets

SODIUM HYPOCHLORITE SOLUTION, ... % Cl

C;R34 R31 N;R50

The Full Text for all R-Phrases are Displayed in Section 16

REVISION DATE: 19/07/2010

Domestos Thick Bleach Original Blue

6 ACCIDENTAL RELEASE MEASURES

7 HANDLING AND STORAGE

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

WEL = Workplace Exposure Limit.

REVISION DATE: 19/07/2010

Domestos Thick Bleach Original Blue

9 PHYSICAL AND CHEMICAL PROPERTIES

1.082 (1.065 to 1.097)

pH-VALUE, CONC. SOLUTION

650 (500-850) mPas @ 25C,

10 STABILITY AND REACTIVITY

Not classified for transportation.

REVISION DATE: 19/07/2010

Domestos Thick Bleach Original Blue

Risk of serious damage to eyes.

Keep out of the reach of children.

Avoid contact with skin and eyes.

Wear suitable gloves and eye/face protection.

If swallowed, rinse mouth with water (only if the person is conscious).

REV. NO./REPL. SDS GENERATED 18

Causes severe burns.

Contact with acids liberates toxic gas.

Risk of serious damage to eyes.

Very toxic to aquatic organisms.

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