Cleaning
Cleaning
Cleaning
Introduction
In the present context, cleaning means the removal of contaminating or unwanted liquid,
solid, or semisolid matter from the surfaces of a work-piece. During manufacturing process,
cleaning of work-piece is recommended to keep the component in proper condition for
subsequent events like machining, painting, plating, or assembly. In fact, cleaning is
performed prior to storage to remove corrosives.
Work-pieces are generally cleaned one or more times either by chemical or mechanical
cleaning process.
The type of cleaning need to be carried out depends on the following factors:
In addition to these, part design is also another factor might play a role (might not be
significant) in selecting the proper cleaning agent.
Soils to be removed
In industries, the following basic types of soil are generally removed
Rust and scale (formed due to surface oxidation of hot worked mill products like
Chips and metal-cutting fluids (these are residues from machining operations)
Pigmented drawing compounds (mostly used in cold-finishing steel bars, white lead,
molybdenum disulfide, graphite, and soaps are the most sticky pigments)
wide variety of abrasive action is required and this is achieved by using different brush
materials, bristle thicknesses and lengths. Abrasive action can be mild, moderate and strong
depending on the type of bristles.
Abrasive blasting: This is a process to remove rust, scale, and other corrosion products, dry
surface dirt, and paint. Working principle of this process involves bombardment of various
abrasive particles namely, aluminum oxide, sand, silicon carbide, steel shot (hard material)
rice hulls, corncobs, nut shell, plastic beads (soft materials) etc., to the work-piece surface at
a high velocity. However, removal of grease in this process is difficult.
Steam-jet cleaning: It is a method of removal of oil, grease, and dirt from the
object/equipment which is too large or bulky (difficult to immerse in a cleaning tank). Flame
jets are preferred for the removal of scale or old paint from large iron or steel components.
Tumbling: This method is used for removing rust and scale and is generally considered to be
a low-cost method. This method can be applied for in-process cleaning and as part of a prepainting, pre-plating sequence.
Chemical processes
Solvent cleaning: In this process of cleaning, liquid hydrocarbons are used. Cleaning is
carried out with one or a combination of three application methods namely, immersion or
soak-tank cleaning, spray degreasing and vapor degreasing. Commonly used solvents are
petroleum solvents (Stoddard solvent, mineral spirits, or kerosene) and chlorinated
hydrocarbons (trichloroethylene or perchlorethylene).
Immersion cleaning: It is considered to be the most effective in-process cleaning method.
This method removes oil, grease and oil-borne dirt. However, the level of cleanliness is not
high due to rapid solvent contamination.
Vapor degreasing: This is another effective method for removal of oil and grease. Sufficient
flushing (immersion and spraying) are to be done prior to this vapor-degreasing cycle. The
following steps are followed for this type of cleaning operation. A small amount of solvent is
allowed to vaporize and the vapor is contained in the tank by the tank walls and a cooling
coil. When a work-piece is lowered into the vapor, the vapor condenses on its surface and
drips back to the reservoir below. When the work-piece is heated by the warm vapor,
condensation stops and the work-piece dries.The work-piece is then taken out from the vapor
warm and is completely free of oil and grease. Various problems associated with solvent
cleaning process are solvent disposal, toxicity and fire prevention.
Ultrasonic cleaning: It is the most convenient method for thorough cleaning of small,
intricate parts which may not be even possible with other cleaning methods. In this method,
cleaning solution agitated by ultrasonic vibrations. Commonly used cleaning solutions are
chlorinated and alkaline solvents.
Emulsion cleaning: When the work-piece contains heavy buffing compounds (cakes
materials) or grease loaded with solid particles, this method is preferred. The liquid cleaner
used for this purpose is a mixture of water, a hydrocarbon (petroleum) solvent, and
emulsifying agents (soaps, glycerol, and polyether). Usually, the cleaner is applied by spray
or immersion at a temperature of 54 to 60C and often upto 82C. If work-piece is to be
immersed then agitation of the cleaning liquid is recommended. After cleaning of the workpiece, rinsing in hot water is required.
Alkaline cleaning: It is used for the removal of oil, grease, shop dirt, and compounds from
polishing, buffing, and drawing operations. In this type of cleaning, the cleaner used is the
combination of a solution of certain alkaline salts (caustic soda, tri-sodium phosphate,
silicates, borates, or carbonates) and detergents in water. Cleaning process involves pressure
spray in soak tanks, often with agitation at a temperature of 60 to 93C and water rinsing of
the work-piece after the alkaline. This method is considered to be the least expensive and
most popular for mass production.
Acid cleaning: It is similar to alkaline cleaning process except that, the cleaner is a solution
of acids or acid salts instead of alkaline salts. Acid cleaning is used for removal of light rust,
tarnish, scale, drawing compounds, oil, and grease. Acid cleaning does not work efficiently
when heavy coatings of oil and grease are there on the work-piece.
Pickling: It is used for the removal of surface oxides, scale, and dirt from metals.This process
is stronger than acid cleaning. The cleaning solution is prepared by mixing an aqueous
solution of acid with a wetting agent. The type of acid to be considered depends on the metal
to be cleaned. For example, in ferrous metals sulfuric, hydrochloric, and phosphoric acids are
used. It is essential to neutralize the effect of pickling acid and hence an alkaline rinse is
required to be performed after the process
Salt-bath cleaning: It is a suitable method for the removal of scale, oxides, sand, carbon, and
graphite from a various metals. Cleaning is done by immersing the work-piece in a bath of
the molten salt at a temperature about 440 to 524C. The salt in the bath reduces the scale and
loosen it to some extent from the work-piece surface. Further, the work-piece is placed in a
water rinsing bath and due to heat of the work-piece the water turns to steam and blasts the
scale from its surface.Often this is called sodium hydride de-scaling.
Electrochemical processes
Among various cleaning methods, alkaline cleaning, acid cleaning, pickling, and salt-bath
cleaning can be performed by using an electrolyte (electrochemical). For example, in
electrolytic-alkaline cleaning, the work-piece is taken as one electrode and the tank or a steel
plate is as other. The alkaline solution works as the electrolyte. With the supply of current,
hydrogen gas is released at the cathode and oxygen at the anode. The produced gas bubbles
provide a scrubbing action at the work-piece surface, causing the soil to break up rapidly.
Various cleaning processes and their suitable materials are summarized in Table M5.1.1.
Suitable materials
Table M5.1.1:Suitable Materials for Common Cleaning Processes. (Source: Design for
Manufacturability Handbook by James G Bralla, 2nd Ed)
Process
Suitable
materials
Brushing
Abrasive
blasting
Design recommendations
1. The cleaning surface must be easily accessible for cleaning and full flow of cleaning
fluid as shown in Figure M5.1.1.
Not this
This
Figure M5.1.1: Wide path in the right side image for full flow of cleaning fluids.
2. Parts subjected to liquid cleaning operations should have some provision of hole for
hanging or a rack for supporting the part easily. (See Figure M5.1.2.)
Not recommended
Recommended
3. When parts are subjected to liquid cleaners, drain holes must be provided. Generally,
the part configuration or method of hanging traps the cleaning solution as shown in
Figure M5.1.3 and Figure M5.1.4.
Figure M5.1.3: Drain hole and wide space for unimpeded flow of coating material
4. Cleaning and finishing smaller parts and then assembling is more economical than
cleaning and finishing a large single component.
5. Nest table parts may cause difficulties in some cleaning operations which involve
immersion in a bath. Advantages and disadvantages of handling nest-able parts need
to be understood.
Cleanliness specifications
The following methods can be used to specify cleanliness requirements:
1. Specifications of the maximum allowable weight of soils on a part
2. Specifications of the maximum particle size of allowable soils on a part
3. Various specifications based on some kind of performance test, e.g.,
Water-break test
Atomizer test
Wiping test
Polishing processes
Conventional polishing
In conventional polishing, surface irregularities are removed from the workpiece by using
abrasive particles which is glued to a flexible wheel or a belt. Often this process is referred as
flexible grinding. Roughing, fining, and oiling are common terms for three steps of polishing.
Metal removal process might be slow or rapid and causes some plastic deformation of the
metal surface. Wheels can be made up of fabric, hemp, leather, wood, or felt. Polishing belts
have contact wheels of various materials and the most common is rubber. For faster cutting,
harder wheels and for contoured shapes soft wheels are preferred. To extend the service life
of abrasive surface, different lubricants like tallow, wax, and fatty acids are used in both
wheel and belt polishing.
Buffing:
Buffing operation is carried out after polishing with a finer abrasive to further smoothen the
surface and to provide the surface a lustrous, grain less finish. Through this process a very
little material is removed from the work piece. In buffing the abrasive is generally loosely
held by the wheel.
Barrel polishing or Tumbling:
This is a deburring operation used for surface polishing. This process requires, a rotating
barrel or vibrating hopper, water, a compound (cleaners or detergents plus fine abrasives) a
medium (chunks of ceramic, stone, or metal) and the parts to be polished. When a rotation in
the barrel or vibration in the hopper is given, it causes the medium to rub against the part with
the abrasive action.
Electropolishing:
Electro polishing is a reverse process of electroplating. In this, the work piece acts as anode.
After connecting the anode and cathode to DC power source, the setup is immersed in a
conductive solution. A typical nature of the electrolytic action is that the higher points
including micro-projections are subjected to more intense electrolytic action and metal
removal is more rapid. The process is gradual, finally resulting a smooth and glossy metal
surface.
Suitable materials
All metallic and rigid nonmetallic materials with uniform and fine grained structure are
preferred for the polishing process, the most suitable being then on-ductile machinable
metals. However, ductile materials are also can be used for polishing in this method.
Design recommendations
It is recommended to have the workpiece in such a shape that the polishing wheel or belt can
contact all points of the surface uniformly without any interference. Few design
recommendations for the parts for wheel or belt polishing and buffing are listed below.
1. It is recommended to avoid compound curves, inside or outside sharp corners, deep
recesses and other irregular shapes. If it is unavoidable, mild contours need to be
provided as shown in Figure M5.2.1.
Figure M5.2.1: Avoid deep recesses, irregular shapes and sharp corners
2. Designs of parts involving hooked edges or sharp projections that are likely to cut the
polishing wheel or belt as illustrated in Figure M5.2.2.
Figure M5.2.2: Avoid designs which incorporate hooked edges or sharp projections
3. The obstructions like bosses, handles etc. which puts restriction on the free access of
the wheel or belt to the surface to be polished are to be avoided as shown in Figure
M5.2.3.
Figure M5.2.3:.Bosses, handles, and other obstructions to the free access of the
polishing wheel or belt.
4. It is recommended to avoid polishing on large surfaces.
5. It is advisable to design parts which can be easily hold by hand or fixture so as to
avoid difficulty in polishing.
In addition to these, the recommended design guidelines for barrel polishing are listed below.
1. Parts with small holes, slots and recesses are to be avoided in case of barrel-polish as
illustrated in Figure M5.2.4.
Figure M5.2.4: Small holes, slots, or recesses are undesirable in parts to be barrel-polished.
Certain parts like springs and other wire or strip parts might get interlock and tangle
during the barrel finishing operation and hence care must be taken.
Recommended tolerances
Table M5.2.1 summarizes the recommended surface finish to be provided for Mechanically
Polished, Barrel-Polished, and Electro polished Surfaces.
Surface finish( m)
Most economical 0.4
Normal
0.2
Finest
0.05
Plating is the application of a thin metallic layers coating on the surface of a substrate
material. The substrate is usually metallic. However, methods are available also to plate
plastics and ceramics.
Electroplating process
Electroplating is an electrolytic process in which metal ions in an electrolyte solution are
deposited onto cathode work part. The metal to be plated is used as anode. When the setup is
connected to the external DC supply, electrolyte (an aqueous solution of acids, bases, or salts)
conducts electric current by the movement of plate metal ions in solution. To achieve
optimum plating, thorough cleaning operation of the work material must be done before
electroplating process. Figure M5.3.1 shows the setup for electroplating process
Typical characteristics
The main purpose of carrying out plating operation is to impart certain required properties on
parts or their surfaces. The properties are improving corrosion resistance, permitting use of
base materials which would not be satisfactory without such protection, improved
appearance, greater wear resistance, higher electrical conductivity and better electrical
contact with other parts, greater surface smoothness, better light reflectance, and a more
suitable base for bonding to other materials, to change a parts dimensions or a combination
of these reasons.
In electroplating process, parts of the simplest as well as complex shapes of any size can be
used. Typical thicknesses of metal coating achieved in electroplate process ranges from a few
molecules to a maximum of 0.05 mm. Generally, 0.05 mm thickness and even thinner
coatings are preferred. Electroplating can be done on any material; however, many parts
require special processing procedures thereby increasing the overall cost.
Suitable materials
Even though any material can be electroplated, the applications are normally limited to
metals and some specific plastics. Electroplating in plastics (except very few), requires to
create a conductive surface through pre-plating operation prier to actual plating. Commonly
used electroplated plastics are acrylonitrile butadiene styrene (ABS), chlorinated
polyethylene (PEC), ABS/polycarbonate, Polyphenylene oxide, polysulfone, polypropylene,
nylon, polyester, polyacetal, polystyrene and polycarbonate. Commonly used combinations
of basis materials and plating metals are provided in Table M5.3.1. In Table M5.3.1, the
1,2
1,2
Zinc
1,2
1,2
Brass
Nickel
1,2
Copper
Tin
1,2,5,6
Chromium
2
2
1,2
2
1,2
6
6
4
2
Gold
1,2
1,2,5,6
4
Silver
Bronze
1,2
1,2
Design recommendations
Surface finish prior to plating: Plating must be preceded by polishing to achieve good final
product. If the surface is rough or discontinuous, it would be reflected on the final product.
Plated area: Designer need to specify the areas which are critical and which need not be
covered.
Flat surfaces: Electroplating of completely flat surface appears hollow after electroplating,
which can be eliminated by using crowning technique. It is basically providing a positive
radius in the shortest direction across the face of flat surfaces. The rise provided is about 0.1
mm/cm of width.
Inside corners: It is recommended to avoid sharp inside corners as these receive insufficient
deposit. Plating becomes better by using larger inside radius.
Outside corners: External corners receive excess plating deposit as shown in Figure M5.3.2.
It is recommended to use generous radii on such corners to minimize this effect
Figure M5.3.2: Avoid external and internal sharp corners and use rounded corner
Grooves: If the plating is to be done on the sides and bottom of the grooves, then the required
groove depth must be less than 1.5 times the width. A through slot is recommended than a
groove as illustrated in Figure M5.3.3.
Figure M5.3.3: Groove depth must be less than 1.5 times width
Bosses and ridges: Bosses and ridges should be well rounded to avoid excessive plating build
up as shown in Figure M5.3.4.
Figure M5.3.4: Rounded Bosses, ribs, and ridges to avoid excessive plating build up
Pockets: Pockets can be thought of as stopped grooves. It is recommended to use a depth-towidth ratio of 1:1.5 with a maximum radii permitted by the design.
Holes and tubes: Screw holding bosses in die castings should have a slot in the side wall to
allow gases formed from the chemical action of the plating solution to escape easily.
Otherwise lines may appear on adjacent surfaces as shown in Figure M5.3.5.
Figure M5.3.5: Screw-holding bosses in die castings with a slot in the sidewall
Cupping: A drain hole is provided to drain the electroplating solution (or air if the part is in
the solution with its open top down) from the part. Such holes also improve overall plating in
other ways.
Other considerations: Parts must not lock together. Often parts get locked or plated together
making the disassembly difficult or impossible. It is required to have provisions for the parts
to be hung on the plating rack as shown in the Figure M5.3.6. Holes, attachment studs, spring
contacts or tabs that are required for assembly of parts are often can be used for these
connections.
Figure M5.3.6: Provision for the parts to be hung on the plating rack.
Dimensional considerations
During electroplating process, generally change in the size does not occur which will create
assembly related problems. However, in exceptional cases where the parts are to be produced
to extremely close tolerance or for which, because of sharp edges or corners, thicker-thannormal coatings are produced. It becomes more difficult with threaded fasteners. Plating
thickness can vary significantly over the area of a work piece if sharp corners and recesses
are involved. Recommended minimum electroplating thickness for nickel or chromium
finishes on steel, iron, and zinc products are summarized in Table M5.3.2
Table M5.3.2: Recommended minimum electroplating thickness for nickel and chromium
Minimum thickness
Service conditions
Nickel
0.130.8
m
0.258 m
1520
m
Hot dipping is a process in which a metal substrate is immersed in a molten bath of a second
metal. After removal, the second metal is coated into the first. It is essential to have higher
melting temperature of first metal than the second. The most common substrate metals are
steel and iron and the common coating materials are zinc, aluminum, tin and lead.
Prior to coating, cleaning of rust, scale, oil, paint and other surface contaminants is required.
For coating process, immersion in the molten metal is done for periods ranging from a
fraction of a minute for small objects like fasteners to several minutes for large scale
structures. Temperature of approximately 450C and 700C need to be maintained (bath
temperature) for galvanizing (zinc coating) and aluminum coating respectively. It is followed
by a post coating treatment depending on the requirement of the coated component. For
example, slow cooling, quenching, conversion coating and painting (preceded by pre-painting
treatments) might be done.
Characteristics
Hot-dip metallic coatings can be considered to have excellent long term corrosion resistance
property when properly sealed. Corrosion resistance comes through two distinct ways.
1. The coating functions as a barrier providing shielding to the base material.
2. The coating may provide sacrificial galvanic protection.
Coatings of metals higher in the electromotive series than the basis metal will corrode in
preference to the basis metal. Protection will be provided even if there is a break in the
continuity of the coating. Table M5.4.1 provides list of common metals in accordance with
their places in the electromotive series.
Table M5.4.1: List of common metals in accordance with their places in the electromotive
series. (Source: Design for Manufacturability Handbook by James G Bralla, 2nd Ed)
Metals
Magnesium
Zinc
More Noble
Cadmium
Steel
Lead
More active
Aluminum
Tin
Copper
Gold
Thickness of coating usually dependent on both process and coating type. Consider a typical
example, in case of hot-dip-galvanized material coating, thickness is customarily specified in
grams per square meter as either a minimum or an average coating weight. Normal values
range from about 150 to 920 g/m2. This is equivalent to a thickness of 0.01 to 0.13 mm. Few
examples of hot dip metallic coating are: fence components, playground equipment, and
tubular condensers.
Suitable materials
Substrates: The most common substrate materials for hot-dip metallic coating are cast iron
and steel. Materials like high-strength low-alloy steel also used under certain situations.
Coatings: Commonly used coating materials for hot-dip coating are zinc, aluminum, tin,
lead, and terne (a lead alloy with 10 to 20 % tin). Zinc, aluminum and terne provide good
corrosion resistance under most atmospheric conditions.
Design recommendations
Access and drainage of molten metal:
Molten coating metal must be able toflow freely to all surfaces of the part to achieve
corrosion protection over full surface. Use of hollow sections for coating is a better choice
andsignificantly reduces the possibility of hidden space.Recommended guidelines to achieve
full,uniform coverage are given below.
Holes for venting and draining should be placed diagonally opposite at the high and
lowpoints of the fabrication which are generally not used for the coating process.
To have free flow of molten metal, corners of internal and external stiffeners, baffles,
diaphragms, and gussets must be cropped.These guidelines have been illustrated in
Figure M5.4.1to Figure M5.4.3.
Figure M5.4.2: Venting and draining of enclosed and semi enclosed products.
Not Recommended
Recommended
Assemblies and subassemblies should be built in units suitable for single dipping
whenever possible.
Figure M5.4.4: Avoid a combination of extremes in the weight and cross section of structural
members.
Screw threads: When a threaded member has to be hot-dip-coated, the pitch diameter must
be adjusted in order to allow for the thickness of the coating. Table M5.4.2 summarizes the
recommended oversize tappings for female threads to be used with galvanized bolts.
Table M5.4.2: Recommended Oversize Tapping for threaded Holes to be used with
Galvanized Bolts (Source: Design for Manufacturability Handbook by James G Bralla, 2nd
Ed)
Bolt or stud diameter (mm) Minimum oversize tapping required (mm)
11 and smaller
Over 11 to 25
Over 25
+0.4
+0.5
+0.8
Class Of Material
Products fabricated from rolled, pressed,and forged steel shapes, plates, bars,and strips
3-5 mm thick
550
6 mm and heavier
610
Hardware
Castings - gray iron,malleable iron, steel
550
Process
In thermal spraying, molten and semi molten coating materials are sprayed on to a substrate,
where they solidify and adhere to the surface. To do this operation, a gun is used either in a
combustion flame, a plasma arc, or an electric arc, melts and propels coating material in
finely divided form towards the part to be coated. Heating of the coating material is done
through different methods namely: oxyfuel flame, electric arc, and plasma arc. Initial form of
the coating material are either wire or rod, or powder. Examples of different
coating
materials used in this process are, pure metal and metal alloys, ceramics (oxides, carbides and
certain glasses), other metallic compounds (sulfides, silicates), cermet composites and certain
plastics (epoxy, nylon, teflon and others). Various substrate materials are metal ceramic,
glass, some plastics, wood and paper.
Suitable materials
Coatings:
Any material that can be melted without decomposing can be used for thermal sprayed
coating. Different categories of such materials are
1. Pure metals- Aluminum, zinc, nickel, refractory metals, etc.
2. Alloys- Steel, cobalt and nickel-based superalloys, hard-surfacing and self-fluxing
alloys, etc.
3. Compounds- Aluminum oxides and other metal oxides, carbides, cermets, and
nitrides, etc.
4. Composites and blends - Admixtures and combinations of two or more of the above in
a single powder. Cobalt-bonded tungsten carbide and nickel-clad graphite comes
under this category.
Substrates:
Commonly used substrate is metal but other materials like ceramic, glass, concrete, plaster,
carbon wood, plastic, rubber, or cloth also can be used.
Bonding coatings:
Sprayed coatingis applied over the bonding coating. In bonding coating, materials adhere to
a clean, smooth surface which will not be subjected to mechanical roughening or gritblasting. This approach has advantages of reduction in pre-coating surface preparation, which
is costly and adversely affect the workpiece. In addition, it provides resistance to bond
failure. It is important in many applications. For example, when it is necessary to machine or
grind the coating to a featheredge. Molybdenum is the major bond-coating material.
Design recommendations
The following recommendations need to be followed for providing proper coatings.
1. If the primary coat is not self-bonding, the coating is applied through the plasma gun
and a thickness less than 0.25 mm is recommended, with the use of a blasted surface.
Figure M5.5.1: Avoid exposed edges of flame-sprayed coatings and also feather edges.
4. Few coatings can serve both the purpose of adhesion of bonding coatings and the
functional properties of top coatings. Separate adhesion coating is not required in such
cases. It is preferred to avoid exposing of edges of flame sprayed coatings and also
feather edges. Surfaces held by undercuts at the edges are the best. (Refer Figure
M5.5.1.)
Depth of internal surfaces that can be used for flame sprayed is to be decided based on
recommended values. In case, the opening is large enough for a spray-gun extension, no
length restriction is put, otherwise the maximum coating depth is twothirds of the
diameter of the opening, as shown in Figure M5.5.2.
Figure M5.5.2: Limitations on the depth of internal surfaces for flame spraying
5. It is advisable to design the workpiece to facilitate handling. For example, if a
cylindrical part is designed, a means must be provided by which it can be rotated:
centers, flanges, etc. A sheet-metal stamping could be partially sheared through to
allow handling a continuous strip rather than individual parts at the spraying
operation. Irregular parts should include a locating hole or other means for easy
orientation.
Figure M5.5.3: Nested parts during flame spraying to reduce over spray losses.
6. Parts are designed in such a manner that they can be nested together during flame
spraying to reduce overspray losses as illustrated in FigureM5.5.3.
To ensure adequate strength, the coated parts to be press-fitted and the coating should be
at least 0.13 mm thick. For rotating shafts, recommended minimum coating thicknesses
for average conditions of wear and finish machining are provided in Table M5.5.1.
Table M5.5.1: Recommended Minimum Thickness of Thermal- Sprayed Coatings on
Shafts (Source: Design for Manufacturability Handbook by James G Bralla, 2nd Ed)
Minimum coating thickness
Shaft diameter, mm
per side, mm
25 or less
0.25
2550
0.38
5075
0.50
75100
0.63
100125
0.76
125150
0.89
150 or more
1.0
DIMENSIONAL FACTORS
The surface finish of flame-sprayed coatings ranges from 1.0 to 10.0 m rms. The surface
finish and the accuracy of coating thickness depend on a number offactors.
The normal variation of coating thickness under controlled production conditions ranges
between 0.05 mm to 0.13 mm.
The process
In vacuum metalizing, mostly pure metals are first heated to transform from solid to vapor
state in a vacuum and then allowed to condense on the substrate surface. This process is
shown in Figure M5.6.1. The material to be deposited is called as source and is heated in
either electrical resistance or induction or electron beam. The common one is resistance
method. This process is carried out in a closed chamber maintaining a vacuum of 10-3 to 10-5
mbar.
If the substrate surface is smooth, the resulting vacuum coating finish will be brilliant and
does not require buffing. Commonly used products in which decorative vacuum coatings are
employed, are costume jewelry, toys, home appliances, hardware, automotive trim (normally
interior), decorative nameplates, and various sheet materials. Among various optical
applications, mirrors, automobile head lights, flash lights and other reflectors, telescopes,
microscope filters, sun-glasses, optical filters and other instruments, beam splitters, and other
objects requiring some degree of light reflection are common. Most usable application of
vacuum coating is in food containers, for which tin can be applied by vacuum methods more
economically than by electroplating.
Table M5.6.1: Typical Applications of Vacuum-Deposited Coatings. (Source: Design for
Manufacturability Handbook by James G Bralla, 2nd Ed)
Coating material
Function
Coating thickness(mm)
Substrate material
Aluminum
Decorative
0.0010.005
Metal
Aluminum
Reflective
0.0010.005
Glass
Aluminum
Protective
0.5
Steel
Aluminum
Decorative
0.001
Plastic sheet
Aluminum
Decorative
0.5
Aluminum
Aluminum
Electrodes
0.00050.001
Plastic shot
Cadmium
Protective
0.5
Steel
Cadmium
Electrical
resistance
0.00010.001
Glass orplastic
Chromium
Electrical
resistance
0.00010.001
Glass or
plastic
Gold
Electrodes for
piezoelectric
crystals
0.0010.005
Organic or
inorganic
crystals
Magnesium
fluoride
Nonreflective
0.004
Glass
Silicon
monoxide
Abrasion
resistance
0.004
Glass
Titanium
dioxide
Decorative;
optical
0.004
Glass
Zinc
Electrical
conductivity
0.0010.005
Paper
Vacuum-deposited coatings are generally of high purity and density. The maximum size of
component that can be vacuum-coated depends on the size of vacuum chamber available.
Tables M5.6.1 summarize different applications of vacuum coatings.
Suitable materials
Aluminum is considered to be the most common vacuum-coated material. It is found in over
90% of decorative coatings and also used for optical, electronic, or corrosion-protection
purposes also. In accordance with the decreasing vapor pressure (the most important factor in
vacuum coatability), after aluminum, selenium, cadmium, silver, copper and silicon
monoxide fall in the series. Further, another group, in order of decreasing vapor pressure, is
gold, chromium, palladium, nickel-chromium alloy, magnesium fluoride and titanium.
In fact, certain compounds of metals and other elements are also useful for coatings and can
be deposited by this method. Silicon monoxide is one of such compounds. It provides an
abrasive-resistant finish over aluminum and is often applied immediately after the deposit of
aluminum without interrupting the vacuum. Magnesium fluoride and aluminum oxide are
used in the manufacture of electronic capacitors.
Design recommendations
Recommendations are provided for vacuum-coated components based on two different
aspects.
The need for an enclosed vacuum chamber with its inherent size limitations
The line-of-sight travel path of coating vapor from source to work piece
Based on these factors, the design recommendations are given below.
1. Compact parts are preferred to enable a large number to be placed in the vacuum
chamber. Arms and other extensions that may interfere with the placement of other
work pieces or with the holding fixtures should be avoided. If possible, it is
recommended to separate large component (to be vacuum coated) into different parts
and perform assembly operation after coating.
2. Deep recesses on the surface to be coated should be avoided. (Refer Figure M5.6.1.)
Figure M5.6.4: Minimum angle of part surface and the line of the sight of the path of vapor
Finishes
Even though the coating thickness can be controlled to close tolerance, there are normally
variations in part-to-part coating thickness and in the thickness on one workpiece. The factors
affecting this coating thickness are:
Shadow effect which results when the supporting frame comes between the workpiece
and the vapor source
Degree of vacuum
Vaporization time
For normal applications, the following nominal dimensional ranges are recommended:
Corrosion-protection coatings, 5 to 10 m
Heat treatment is a property enhancing operation. It is secondary in sequence to other partsmaking operations. Property enhancing operations are performed to improve mechanical or
physical property of the work material. They dont alter material part geometry. Heat treatment
involves various heating and cooling procedures performed to affect the micro-structural changes
in a material, which in turn affect the mechanical property of the work part. This heating (and
eventual cooling to room temperature) either softens the material or hardens it. The results of this
process depends, on
1. Specific material
2. Temperature to which the material is heated
3. Method and rate of cooling
As the number of heat treatment processes is large and the details of each process are infinite, it
is impossible for a designer to know every property enhancing process. The designer should be
aware of the general types of heat treatment processes available and know enough of their details
so that they can make reasonable decisions as to how their parts should be heat-treated.
cementite & then cool slowly at the rate of about 20C/hr. Annealing is performed to improve the
ductility of material so that it can be mechanically processed more easily by other processes.
Normalizing: This process is slight different from annealing. The process of annealing consists
of heating the metal to a temperature above the austenizing temperature, holding at that
temperature for certain time, but it is allowed to cool in air at a faster rate. The resulting structure
is uniform but not as soft as fully annealed.
Hardening processes
Hardening is the process of heating the material to a temperature above the austenizing
temperature until all pearlite is transformed into austenite, and then quenching it rapidly in water
or oil. The temperature at which austenizing rapidly takes place depends upon the carbon content
in the steel used. Depending upon the required hardened structure, different heating & cooling
operations are performed subsequently.
Surface hardening: Surface hardening refers to any of the several thermo-chemical treatments
applied to steels in which carbon or nitrogen must be diffused into the surface at an elevated
temperature and then the work piece is cooled at a rate sufficient to harden the surface. The term
case hardening is used for surface hardening. Four methods used are carburizing, cyaniding,
nitriding, and carbonitriding. The name suggests the type of material to be diffused.
Through hardening: This is achieved by heating the part uniformly for a long time to a point
above the critical temperature and finally quenching it in an appropriate medium. To provide
necessary cooling rate required to harden the part, generally water, oil, or air, with varying
degrees of agitation are recommended to be used. The grade of steel & the size and shape of the
part also affects the selection of quenching medium.
Martempering: It is a common heat treatment process that quenches the material to an
intermediate temperature just above the point at which martensite starts and then allowed to cool
slowly thereby, providing through-hardened structure with less distortion.
Austempering: In this process, the part is quenched directly into a liquid salt bath at a
temperature between 590 to 710 Fahrenheit to transform the Austenite into Bainite. The part is
then removed from the salt quench and air cooled to room temperature to produce higher
ductility.
Note: Interested reader can refer heat treatment process for other ferrous metals such as cast iron,
stainless steel etc. and nonferrous metals and their alloys such as copper and copper alloys,
magnesium alloys, nickel and nickel alloys, aluminum and aluminum alloys, titanium and
titanium alloys etc.
Selection of material
It is recommended to use common materials that will produce improved physical properties and
would be easily available at reasonable cost. Further, it is essential to have the knowledge of
what is required for heat treatment and the expected results on the specific part under
consideration. This would again provide a limited number of grades from which a final
determination has to be made.
Low-carbon steel
Due to the case hardening heat treatment process, the low-carbon steel (up to 0.25 percent
carbon) produces a hard, wear-resistant surface.
Medium-carbon steel
The medium-carbon steels (0.25 to 0.55 % of carbon) are generally produced by throughhardening & tempering process which provides higher tensile strength ranging from 690 to 1380
MPa. Due to the lower strength of low carbon steels, designers opt for high strength mediumcarbon steels. It is widely used in parts requiring medium strength and high toughness.
High-carbon steel
Due to the higher percentage of carbon, the high-carbon steel (0.55 to 1.00 percent carbons) has
higher strength, hardness, higher fatigue & abrasion resistance. Due to difficulty in fabrication
and higher cost, it is rarely used.
Alloy Steels
Generally, alloying elements are added to plain carbon steels to provide various improved
properties like (1) better strength in larger sections (2) less distortion during hardening (3) higher
resistance to abrasion keeping the hardness same (4) higher toughness at the same hardness in
small sections or (5) greater hardness and strength at elevated temperatures. To achieve these
properties (one or more), it is required to carry out the following: (1) changing the hardening
characteristic, (2) changing the nature and amount of the carbide phase of the steel (3) changing
the tempering characteristics.
When alloying elements (expect cobalt) are added to steel, a higher hardenability is achieved.
Hardenability provides the measure of the depth of hardening produced by quenching.
Cast Iron
The combined carbon content in gray cast iron is one of the major determining factors in flame
hardenability. Generally alloy gray iron ranging between 0.50 and 0.70 % is more prone to flame
hardening process than unalloyed gray iron because of wider temperature range & greater
martensitic depth.
Stainless Steels
Heat treatment of stainless steels is mostly carried out under controlled conditions to avoid
carburization, decarburization and scaling on the metal surface. The carbon content affects the
maximum strength and hardness of material. Austenitic stainless steels can be surface hardened
by nitriding.
Copper and Copper Alloys
Stress relieving, annealing, solution treating and precipitation hardening are the various heat
treatment process i.e. applied to copper & copper alloys. Aluminum bronze, Beryllium copper,
Copper-nickel-silicon, and Copper-nickel phosphorous are produced by precipitation hardening
process.
Distortion
Due to the heat treatment process, a considerable improvement in physical properties occurs
along with some undesirable changes in size & shape. These changes in dimensions occur
mainly due to the various stresses (i.e. thermal stresses, stresses developed by the transformation
of hardened structure etc.) that are developed by the manufacturing operations. Further, some
distortions are also developed during the handling of heat treatment processes at the austenizing
temperature which is more intensified due to rapid heating and cooling. (See Figure M5.7.1)
Arrows show direction of stress. (a) Part heated uniformly throughout. Center area and surface
both are expanded. (b) Start of quench; surface contracted more than center. (c) Midway during
quench; surface transformed, center contracting. (d) Near end of quench: surface cold and rigid,
center transforming and expanding. Dimensional changes and distortion in the case of case-
hardened parts are dependent on (1) configuration of the part (2) the process used (3) previous
stresses in the part (4) grade of steel used.
Figure M5.7.1: The distribution of stresses in a typical part during heating and quenching.
However, the amount of distortion is also dependent on the design, no matter which method is
used. These distortion can be controlled by simple change in the way in which the part is handled
or using a completely different method. For example, suppose a case-hardening method causes
high distortion for a given part, then the heat treater must select a less severe method like
cyaniding to produce the specified results.
Design recommendations
The recommended principles to achieve a good design for heat treatment are:
Required properties in the heat-treated part need to be achieved without allowing the part
to be distorted beyond the acceptable limits
Heat-treated part resist external stresses during service without failure.
Keeping the above principles in mind, the following design recommendations need to
follow for heat treatment.
1. General rule is to make the part as simple as possible, keep it symmetrical, have uniform
cross-sections, and balance the weight.
2. Abrupt changes in sections of parts to be heat treated need to be avoided (See Figure
M5.7.2)
Figure M5.7.5: Minimum spacing from edge to center of hole should be 1.5 times
diameters.
6. Sharp internal corners, generally concentrate heat treating stresses and hence need to be
avoided. It is recommended to have all internal corners as round, and non-cutting holes
should have radii at the top and bottom surfaces.(See Figure M5.7.6)
Figure M5.7.6: Avoid sharp internal corners, which concentrate heat-treating stresses.
7. Sharp edges at the entry and exit edge of the hole need to be avoided and it is preferred to
provide radii at the top and bottom surfaces.(See Figure M5.7.7)
Figure M5.7.7: Smooth (radius) surface at entry and exit edges of holes.
8. Press-metal dies are usually heavy, flat sections designed to resist high stresses during
operation and these need extreme precision after hardening. Die section should have
balanced mass to avoid heat treating problem.(See Figure M5.7.8)
9. Section width of the die around large openings should be twice the thickness of the die
block (See Figure M5.7.9).
Figure M5.7.9: Minimum section width is around two times stock thickness.
Figure M5.7.11: Rounded corners at the base of gear and ratchet teeth
10. The two-piece construction is advisable to eliminate the stress concentration in internal
corners for a die section which is having unbalanced sections or irregular in shape. (See
Figure M5.7.10).
11. Individual teeth should have ample radii at the root and edges to avoid to thermal stresses
(See Figure M5.7.11).
12. Teeth should be located properly to avoid thin sections.
13. Keyways, whether external or internal, should have generous radii and be located
symmetrically. Keyways used with gear or cutter teeth should be positioned in line with
the base of the tooth so as to maintain uniform cross-section.
14. The hub of a gear is subjected to distortion in case of unbalanced mass. Generally a
sectional design is considered for a function which requires unequal mass distribution.
(See Figure M5.7.12).
Figure M5.7.13: Right side through holes provide more uniform section thickness.
16. It is recommended to specify the desired end condition in the drawing rather than the
process to maintain same standard.
17. The total case depth or effective case depth is required to specify case hardening. If the
part is to be ground, it is to be stated whether the depth applies before or after grinding. In
case depth and hardness, it is required to provide tolerance as liberal as possible.
B) Steam-jet cleaning
C) Both A and B
D) Tumbling
3. Sufficient flushing (immersion and spraying) are to be done ________ to this vapordegreasing cycle.
A) Prior
B) At the end
D) Not required
4. Which method is preferred, when the work-piece contains heavy buffing compounds
(cakes materials) or grease loaded with solid particles?
A) Immersion cleaning
B) Solvent cleaning
C) Ultrasonic cleaning
D) Emulsion cleaning
5. Cleaning is done by immersing the work-piece in a bath of the molten salt at which
temperature approximately?
A) 440 to 524 C
B) 720 to 950 C
C) 110 to 130 C
D) 1500 to 1700 C
(1) An electrolytic process in which metal ions from electrolyte solution are deposited onto
work part. The metal to be plated is used as part.
(2) The main purpose of carrying out plating operation is to improve such required
properties on parts or their surfaces are like (a)..(b).(c)..
(3) Typical thicknesses of metal coating achieved in electroplate process ranges from a
few molecules to a maximum of...
(4) Electroplating in plastics requires to create a. through pre-plating
operation prior to actual plating.
(5) Electroplating of completely flat surface appears hollow after electroplating, which can
be eliminated by using.. .
a) combustion-flame coatings - 6 to 13 %
b) plasma-arc coatings - 1 to 12%
5) The surface finish and the accuracy of coating thickness does not depend on
d) aluminum
M.5.6.3. under the design recommendations for vacuum-coated components, the angle
of the parts surface and the line of sight path of the vapour should not be less
than_________.
a) 75
b) 450
c) 900
d) 300
M.5.6.5. Among the following, the factor that does not affect coating thickness is
Answers:
DESIGN FOR CLEANING
1.
(D)
2. (D)
3. (A)
4. (D)
5. (A)
10. Ductile metals require special abrasives. Plastics and other soft materials may entrap
abrasive. Stainless steel, copper, brass, zinc, aluminum, lead, and tin require
nonmetallic abrasive. Magnesium can be hazardous.
1.
2.
3.
4.
(c)
(c)
(a)
(b)
(1).cathode, anode
(2). a) corrosion resistance b) wear resistance c) electrical conductivity
(3).0.05mm
(4). conductive surface
(5). crowning technique.
450C
Tin
Sodium dichromate
Symmetrical
High Temperature
Gold, Magnesium
Corrosion
True
1) - Martempering.
2) - Austempering.
3) - The carbon content.
4) - Flame hardening.
5) - 1.5 times.