An American National Standard

Designation: D 2501 91 (Reapproved 2000)

Standard Test Method for

Calculation of Viscosity-Gravity Constant (VGC) of
Petroleum Oils1
This standard is issued under the fixed designation D 2501; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.

1. Scope 3. Summary of Test Method

1.1 This test method covers the calculation of the viscosity- 3.1 The kinematic viscosity at 40C (104F) and the density
gravity constant (VGC) of petroleum oils2 having viscosities in at 15C of the oil are determined. If the oil is extremely
excess of 4 cSt. 5 4 3 10 6 m2/s at 40C (104F). viscous, or if it is otherwise inconvenient to determine the
1.2 Annex A1 describes a method for calculating the VGC viscosity at 40C, the kinematic viscosity at 100C (212F) can
from Saybolt (SUS) viscosity and relative density. be used. The viscosity-gravity constant is calculated from the
1.3 The values stated in either acceptable SI units or in other measured physical properties using the appropriate equation.
units shall be regarded separately as standard. The values stated
in each system may not be exact equivalents; therefore, each 4. Significance and Use
system must be used independently of the other, without 4.1 The viscosity-gravity constant (VGC) is a useful func-
combining values in any way. tion for the approximate characterization of the viscous frac-
1.4 This standard does not purport to address all of the tions of petroleum.2 It is relatively insensitive to molecular
safety concerns, if any, associated with its use. It is the weight and is related to a fluids composition as expressed in
responsibility of the user of this standard to establish appro- terms of certain structural elements. Values of VGC near 0.800
priate safety and health practices and determine the applica- indicate samples of paraffinic character, while values close to
bility of regulatory limitations prior to use. 1.00 indicate a preponderance of aromatic structures. Like
other indicators of hydrocarbon composition, the VGC should
2. Referenced Documents not be indiscriminately applied to residual oils, asphaltic
2.1 ASTM Standards: materials, or samples containing appreciable quantities of
D 287 Test Method for API Gravity of Crude Petroleum and nonhydrocarbons.
Petroleum Products (Hydrometer Method)3
D 445 Test Method for Kinematic Viscosity of Transparent 5. Measurement of Physical Properties
and Opaque Liquids (and the Calculation of Dynamic 5.1 Preferably, determine the kinematic viscosity at 40C as
Viscosity)3 described in Test Method D 445. However, if the sample is
D 1298 Test Method for Density, Relative Density (Specific extremely viscous or if it is otherwise inconvenient to measure
Gravity), or API Gravity of Crude Petroleum and Liquid the viscosity at 40C, the viscosity at 100C may be deter-
Petroleum Products by Hydrometer Method3 mined.
D 2140 Test Method for Carbon-Type Composition of In- 5.2 Determine the density at 15C in accordance with Test
sulating Oils of Petroleum Origin4 Method D 1298 or Test Method D 4052. Equivalent results can
D 4052 Test Method for Density and Relative Density of be obtained by determining API Gravity at 60F (15.56C) in
Liquids by Digital Density Meter5 accordance with Test Method D 287, and converting the result
to density at 15C by means of Table 3 of the Petroleum
Measurement Tables (American Edition).6
1
This test method is under the jurisdiction of ASTM Committee D02 on
Petroleum Products and Lubricants and is the direct responsibility of Subcommittee NOTE 1If it is necessary to convert a result obtained using the digital
D 02.04 on Hydrocarbon Analysis.
Current edition approved Oct. 15, 1991. Published December 1991. Originally
published as D 2501 66. Last previous edition D 2501 87.
2 6
Coats, H. B., and Hill, J. B., Industrial and Engineering Chemistry, Vol 20, Published jointly by, and available from ASTM Headquarters and the Institute
1928, p. 641. of Petroleum, 61 New Cavendish St., London W1M 8AP, Companion volumesthe
3
Annual Book of ASTM Standards, Vol 05.01. British Edition and the Metric Editionare also available. These tables supersede
4
Annual Book of ASTM Standards, Vol 10.03. all other similar tables previously published by either of these societies and the
5
Annual Book of ASTM Standards, Vol 05.02. National Bureau of Standards Circular C-410 and the supplement to Circular C-410.

Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.

1
 D 2501
density meter to a density at another temperature, the Petroleum Measure- 8.2.1 For viscosity measured at 40C,
ment Tables can be used only if the glass expansion factor has been
1
excluded. rY 5 (3)
0.94 2 0.109 log10 ~V 2 5.5!

6. Calculation of Viscosity-Gravity Constant
0.00224 ~Y 2 1.059! 2
6.1 From Kinematic Viscosity at 40C and Density at rG 2 1 rV 2
~V 2 5.5! 2
15CUse the following equation to calculate the VGC from
the measured properties: where:
G 2 0.0664 2 0.1154 Log~V 2 5.5!
rY 5 precision of the VGC,
VGC 5 rG 5 precision of the gravity from D287,
0.94 2 0.109 Log~V 2 5.5!
rV 5 precision of the viscosity from D445,
(1) V 5 measured viscosity, and
Y 5 VGC.
where: 8.2.2 For viscosity measured at 100C,
G 5 density at 15C, g/mL, and
1
V 5 kinematic viscosity at 40C, cSt. rY 5 (4)
0.90 2 0.097 log10 ~V 2 0.8!
6.2 From Kinematic Viscosity at 100C and Density at
15CUse the following equation to calculate the VGC:

VGC 5
G 2 0.108 2 0.1255 Log~V8 2 0.8!

rG 2 1 r V 2
0.00177~Y 2 1.294! 2
~V 2 0.8! 2
0.90 2 0.097 Log~V8 2 0.8!
8.3 The VGC calculated from the viscosity at 100C can
(2) differ slightly from that calculated from the viscosity at 40C.
A statistical evaluation of VGC data derived from equivalent
where: viscosities at both 100F and 210F suggests that in the range
G 5 density at 15C, g/mL, and from about 0.80 to 0.95 VGC, the expected average difference
V8 5 kinematic viscosity at 100C, cSt. will be approximately 0.003 units. Whenever possible, it is
preferable to determine the VGC using Eq 1.
7. Report
8.4 BiasThe procedure in Test Method D 2501 for calcu-
7.1 Report the calculated VGC to the nearest .002 unit. lation of viscosity-gravity constant has no bias because the
7.2 If the viscosity at 100C was used for the calculation, value of viscosity-gravity constant can be defined only in terms
state this in the report. of a test method.
8. Precision and Bias 8.5 The term viscosity-gravity constant is also used in Test
Method D 2140, for determining carbon-type composition of
8.1 The calculation of viscosity-gravity constant from kine-
insulating oils of petroleum origin. The equations used are
matic viscosity at 40C and density at 15C is exact. Precision
different from those in this test method; the bias between the
limits are not assigned to this calculation.
two test methods is unknown.
8.2 The precision of the calculated VGC is dependent only
on the precision of the original determinations of viscosity and
9. Keywords
density. Those precision statements are found in their respec-
tive test methods. The precision can be calculated as follows: 9.1 aromatic; density; kinematic viscosity; paraffinic

ANNEX

(Mandatory Information)

A1. CALCULATION OF VISCOSITY-GRAVITY CONSTANT FROM SAYBOLT VISCOSITY AND RELATIVE DENSITY
(SPECIFIC GRAVITY)

A1.1 The calculation of viscosity-gravity constant (VGC) 10G 2 1.0752 log ~V 2 38!
VGC 5
can also be calculated from viscosity in units of Saybolt 10 2 log ~V 2 38!
seconds universal (SUS) and relative density (specific gravity). (A1.1)

A1.2 From Saybolt Viscosity at 100F and Relative Density where:

(Specific Gravity) 60/60FUse the following equation to G 5 relative density (specific gravity) at 60/60F, and
calculate the VGC from the measured properties: V 5 Saybolt Universal viscosity at 100F.

2
 D 2501
A1.3 From Saybolt Viscosity at 210F and Relative Density A1.4 The viscosity-gravity constant calculated from the
(Specific Gravity) 60/60FUse the following equation to Saybolt viscosity at 210F can differ slightly from that calcu-
calculate the VGC: lated from the 100F viscosity. A statistical evaluation of VGC
G 2 0.1244 log~V1 2 31! data derived from both the 100F and 210F viscosities
VGC 5 2 0.0839 (A1.2)
0.9255 2 0.0979 log ~V 1 2 31! suggests that in the range from about 0.80 to 0.5 VGC, the
expected average difference will be approximately 0.003 units.
where: Whenever possible, it is preferable to determine the VGC using
G 5 relative density (specific gravity) at 60/60F, and
Eq A1.1.
V1 5 Saybolt Universal viscosity at 210F.

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