PT.

INDOPORLEN
R E F R A C T O R I E S

MATERIAL SAFETY DATA SHEET

CALDE CAST LW 121 C/G
Section 1- Product Name
Product Name : Insulating Castable
Category : A Refractory Unshape
Intended Use : Insulating Castable for casting & gunning application
Product Name : CALDE CAST LW 121 C/G
Section 2- Composition And Information On Hazardous Ingredients
This product is an unsheped refractory material. It is composed of the following mineral phases some of which
may be present in dust generated by mixing or gunning during installation or tear-out.
Ingredient name CAS Number: Percent: ARC/NTP/OSHA Exposure Limits
Aluminum Oxide 1344-28-1 41 No Nuisance Particulate Not Otherwise
Regulated.
OSHA PEL:TWA total dust: 15 mg/m3;
respirable dust: 5mg/m3.
ACGIH TLV:TWA total dust: 10mg / m3;
respirable dust: 5mg/m3.
Quartz (SiO2) 14808-60-7 33 Yes ACGIH TLV:TWA respirable quartz
0.05mg/m3.
OSHA PEL:TWA total 30mg/m3
respirable 10mg/m3
3
Calcium Oxide (CaO) 1305-78-8 14 No NIOSH PEL: TWA 5 mg/m
3
NIOSH REL: TWA 2 mg/m

Section 3- Hazards Identification

HMIS
HEALTH HAZARD 1 -SLIGHT
FLAMMABILITY HAZARD 0 - MINIMAL
REACTIVITY HAZARD 0 - MINIMAL
PERSONAL PROTECTION E Glasses, Gloves & Dust Respirator

EMERGENCY OVERVIEW:
The product is a grey, refractory unshaped for installation. Slight health risk from inhalation of dust generated
during installation. Not a fire, spill or environmental hazard.

Target organs: Upper Respiratory System

Primary route(s) of entry: Inhalation

Head Office & Factory:

Jl. Raya Bekasi Km.38-39
Tambun Selatan, Bekasi 17510 - INDONESIA
Phone : +62 (0) 21 880 7121 (Hunting)
Fax : +62 (0) 21 880 2557
www.calderys-indoporlen.com
PT. INDOPORLEN
R E F R A C T O R I E S

ACUTE EFFECTS
Eye contact: Dust particulate is a physical irritant.
Skin contact: Physical abrasion.
Inhalation: Inhalation of airborne particulate from mixing or gunning may irritate upper respiratory
system.
Ingestion: An unlikely route of exposure. If ingested in sufficient quantity, may cause gastrointestinal
disturbances. Symptoms will include irritation and may include nausea, vomiting and abdominal pain.

CHRONIC EFFECTS
Dust which may be generated from sawing, or crushing product during installation and from after service tear-
out may contain free/crystalline silica. The prolonged inhalation (usually years) of mineral dusts containing
free/crystalline silica may result in the development of a disabling pulmonary fibrosis known as silicosis; a
progressive, incapacitating and sometimes fatal lung disease. IARC has classified crystalline silica as a "Known
Human Carcinogen - Group 1". NTP lists respirable crystalline silica amongst substances which may
"reasonably be anticipated to be carcinogens". See Section 16 for safe "Removal After Service Precautions".

Section 4- First Aid Measures

Eye contact: Flush eyes, including under the eyelids, with large amounts of water. If irritation persists, seek
medical attention.
Skin contact: Wash affected areas with mild soap and water.
Inhalation: Remove victim to fresh air. If not breathing, give artificial respiration. Get immediate medical
attention.
Ingestion: Ingestion is an unlikely route of exposure. If ingested in sufficient quantity and victim is conscious,
give 1-2 glasses of water or milk. Never give anything by mouth to an unconscious person. Leave decision to
induce vomiting to qualified medical personnel, since particles may be aspirated into the lungs. Seek immediate
medical attention.

Section 5- Fire Fighting Measures

NFPA code: Flammability: 0 , Health: 0 , Reactivity: 0 , Special: 0 .
Flash point: Not Combustible
Hazardous Decomposition Products: None
Extinguishing media: No special instructions or conditions.
Firefighting instructions: Firefighters should wear NIOSH-approved, positive pressure, self-contained
breathing apparatus and full protective clothing where appropriate.

Section 6- Accidental Release Measures

Spill procedures: Product is not a spill nor environmental hazard.

Section 7- Handling And Storage

Handling: Avoid direct contact with product or dust from product by wearing protective clothing, using approved
respiratory protection, and wearing gloves of the impermeable type.
Storage: The product should be stored in a dry location. Pallet protection such as shrink-wrap or stretch-wrap
should be
kept in place until the product is required for installation.

Head Office & Factory:

Jl. Raya Bekasi Km.38-39
Tambun Selatan, Bekasi 17510 - INDONESIA
Phone : +62 (0) 21 880 7121 (Hunting)
Fax : +62 (0) 21 880 2557
www.calderys-indoporlen.com
PT. INDOPORLEN
R E F R A C T O R I E S
Section 8- Exposure Control/Personal Protection
Engineering controls: Provide sufficient ventilation, in both volume and air flow patterns, to control dust
concentrations below allowable exposure limits.
Personal protective equipment: The use of eye protection, gloves and long sleeve
clothing is recommended.
Respiration protection: Provide workers with NIOSH approved respirators in accordance
with requirements of 29 CFR 1910.134 for level of exposure incurred.
Hygienic Practices: Avoid contact with skin, eyes and clothing. After handling this
product, wash hands before eating or drinking.

Section 9- Physical and Chemical Properties

Appearance: These refractory unshapes are grey in color and available in mix of granular and powder;
Odor : NonE
Boiling Point: Not Applicable
Maximal Service Temperature: 1200C
Water Solubility: 0
Vapor Pressure: Not Applicable
Vapor Density: Not Applicable
pH: Not Determined
Bulk Density : 1.02

Section 10- Stability And Reactivity

Chemical Stability: This product is stable under normal conditions of shipping, storage, and installation.
Conditions to avoid: None
Incompatible Materials: None
Hazardous Decomposition: None
Hazardous Polymerization: Not Applicable

Section 11- Toxicological Information

Aluminum Oxide CAS#1344-28-1 Toxic and Hazard Review (Sax): an experimental tumorigen
and neoplastigen by implant. Inhalation of finely divided particles may cause lung
damage (Shaver's disease). TOXICITY DATA: ipl-rat TDLo:90mg/kg:ETA;
imp-rat TDLo:200 mg/kg:NEO; imp-rat TD :200 mg/kg:ETA.

Aluminosilicates Toxic and Hazard Review (Sax): an experimental tumorigen by implant.

Toxicity Data: ipl-rat TDLo:90 mg/kg:ETA.

Quartz CAS# 14808-60-7. Toxic and Hazard Review (Sax): Experimental poison by
intratracheal and intravenous routes. An experimental carcinogen, tumorigen, and
neoplastigen. CLASS OF COMPOUND(RTECS): Tumorigen; Mutagen; Human data. Human
systemic effects by inhalation: cough, dyspnea, liver effects. Listed by IARC as a
"known human carcinogen" Group 1. Listed by NTP. No LD50 in RTECS.
Toxicity Data:Inhalation human: TCLo 16 million particles per cubic centimeter per
8 hours per 17.9 Years-Intermittent:Pulmonary system effects;
Inhalation-human LCLo: 300 micrograms/m3 per 10 years-intermittent: liver.
Other species toxicity data (NIOSH RTECS): intravenous-rat LDLo: 90 mg/kg;
intraperitoneal-rat LDLo: 200 mg/kg;intravenous-mouse LDLo: 40 mg/kg;
intravenous-dog LDLo: 20 mg/kg.

Head Office & Factory:

Jl. Raya Bekasi Km.38-39
Tambun Selatan, Bekasi 17510 - INDONESIA
Phone : +62 (0) 21 880 7121 (Hunting)
Fax : +62 (0) 21 880 2557
www.calderys-indoporlen.com
PT. INDOPORLEN
R E F R A C T O R I E S
Section 12- Ecological Information
Accidental Release: No information has been developed regarding the ecotoxicity or environmental fate of this
product.

Section 13- Disposal Considerations

Waste Management/Disposal: This block, or fragments of such, does not exhibit any characteristics of a
hazardous waste and is suitable for landfill disposal.
However, debris generated during installation or tear-out procedures may be contaminated with other
hazardous materials. Therefore, appropriate waste analysis in these instances may be necessary to determine
proper method of disposal. Waste characterization and disposal/treatment methods should be determined by a
qualified environmental professional in accordance with applicable federal, state and local regulations.

Section 14-Transport Information

US Department of Transportation: Not regulated by DOT as a hazardous material. No hazard class, no label
or placard required, no UN or NA number assigned.
Canadian TDG Hazard Class & PIN: Not regulated

Section 15- Regulatory Information

Product or components of mixture regulated under following lists:
SARA TITLE III:
Section 302: No (Extremely Hazardous Substances)
Section 304: No (Emergency Release)
Section 311: Yes, Cutting/Crushing Product may produce hazardous products - MSDS
Section 312: No, Tier I/II
Section 313: No (Toxic Chemicals, Toxic Chemical Release Reporting, Form R)
CERCLA Hazardous Substance List, RQ: No
TSCA: All substances in this product are listed in the Chemical Substance Inventory of the Toxic Substances
Control Act.
California Proposition 65: This product contains chemicals known to the State of California to cause cancer,
birth defects or other reproductive toxins.

Section 16- Other Information

REMOVAL AFTER SERVICE/TEAR-OUT PRECAUTIONS:
Because of the possible presence of crystalline silica in used refractory debris, particular care should be
exercised during tear-out to minimize the generation of dust. Adherence to proper methods of dust suppression
and control is imperative. The following precautions should be taken during tear-out.
1. Employees should be apprised of the hazards and proper conditions and precautions for safe use or
exposure.
2. Approved respirators, in accordance with requirements of 29 CFR 1910.134, should be used for dust levels
above 0.05mg/m3 respirable crystalline silica.
3. Dust generation should be minimized by the use of dust control equipment or water spray.
4. Wear protective clothing and vacuum clean prior to removing clothing.
5. Where there is a possibility of exposure to dust containing respirable crystalline silica, the following warning
should be posted.

FREE SILICA WORK AREA AVOID BREATHING DUST

DUST MAY CAUSE DELAYED LUNG INJURY( SILICOSIS)

Head Office & Factory:

Jl. Raya Bekasi Km.38-39
Tambun Selatan, Bekasi 17510 - INDONESIA
Phone : +62 (0) 21 880 7121 (Hunting)
Fax : +62 (0) 21 880 2557
www.calderys-indoporlen.com
PT. INDOPORLEN
R E F R A C T O R I E S

ACRONYMS AND REFERENCES USED IN PREPARATION OF MSDS':

ACGIH : American Conference of Governmental Industrial Hygienists
CAS# : CAS Registration Number is an assigned number to identify a specific substance. CAS stands
for Chemical Abstracts Service.
CERCLA : Comprehensive Environmental Response, Compensation & Liability Act
EPCRA : Emergency Planning and Community Right-to-Know Act of 1986
HMIS : Hazardous Materials Identification System (National Paint & Coatings Association)
IARC : International Agency for Research on Cancer
MSHA : Mine Safety and Health Administration
mg/m3 : Milligrams per cubic meter
NIOSH : National Institute for Occupational Safety and Health
NFPA : National Fire Protection Association
OSHA : Occupational Safety and Health Administration
PEL : Permissible Exposure Limit (OSHA)
REL : Recommended Exposure Limit (NIOSH)

SARA : Superfund Amendments and Reauthorization Act

TITLE III : Emergency Planning and Community Right To Know Act
Section 302 : Extremely Hazardous Substances
Section 304 : Emergency Release
Section 311 : Community Right-to-Know, MSDSs or List of Chemicals
Section 312 : Community Right-to-Know, Inventories & Locations, (Tier I/II)
Section 313 : Toxic Chemicals, Toxic Chemical Release Reporting, Form R
TLV : Threshold Limit Values (ACGIH)
TWA : Time Weighted Average
29CFR1910.134: OSHA Respiratory Protection Standard

Head Office & Factory:

Jl. Raya Bekasi Km.38-39
Tambun Selatan, Bekasi 17510 - INDONESIA
Phone : +62 (0) 21 880 7121 (Hunting)
Fax : +62 (0) 21 880 2557
www.calderys-indoporlen.com