Seruni 100EC

Jl. Mangga Dua Abdad Raya Material Safety Data Sheet

Blok J no 12A Jakarta, 10730 , Indonesia Date of revisi: Aug, 2010
Phone. 021- 601 5568 (information & emergency case)
Fax. 021- 601 5575

1. DESCRIPTION
Trade name : SERUNI 100EC
Active ingredient : Cypermethrin technical 92%
Chemical name : (RS)-α-cyano-3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-
2,2-dimethylcyclopropanecarboxylate
Chemical family : Synthetic Pyrethroid
Formula : C22H19Cl2NO3
Molecular mass : 416.3
Kind of use : Insecticide
Contact address in case : PT. Aman Asri
of Emergency Jl. Mangga Dua Dalam Blok J No. 12A Jakarta 10730
Telephone No : 021-6015562, 6015568, 6015586
Fax No : 021-6015575

2. COMPOSITION OR INFORMATION ON ACTIVE INGRIDIENTS

Name of the active ingredient (IUPAC) Concentration Stability
(RS)-α-cyano-3-phenoxybenzyl 92% Min Stable under acid or neutral conditions
(1RS,3RS;1RS,3SR)-3-(2,2- but not alkaline conditions; Photolytic
dichlorovinyl)-2,2- stable; Stable up to 220oC; stable in air
dimethylcyclopropanecarboxylate at ambient temperatures

Hazard Identification of : Toxic to aquatic life. Avoid contamination of surface water

Active Ingredients

3. Stability and Reactivity

Hazardous reactions : unknown
Sensitivity to jolting : none
Condition to avoid : Avoid spark generation and flames
Material to avoid : Strong alkali and acids
Hazardous decompotition : Combustion may lead to hazardous oxides of carbon and other toxic
product fumes.

4. Simptom of Poisoning
Skin and eye : irritation
Ear and skin : Irritability for sound and touch; abnormal facial sensation
Head and nervous tissues : Headache, dizziness, nausea, diarrhea, excessive salivation
Severe cases : Fluid in the lungs and muscle twitching may develop.

5. FIRST AID MEASURES

Special Instruction
Inhalation : Move to fresh air immediately. Maintain airway and blood pressure and
administer oxygen if available. Keep affected person warm and at rest.
Treat symptomatically and supportively. Administration of oxygen should
be performed by qualified personnel. Get medical attention immediately.
Skin contact : Remove contaminated clothing and shoes immediately. Wash affected
area with soap or mild detergent and large amounts of water until no

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 evidence of chemical remains (approximately 15-20 minutes). If swelling,
redness, blistering or irritation occurs seek medical attention immediately.
Eye contact : Wash eyes immediately with large amounts of water or normal saline,
with eyelids held open, until no evidence of chemical
remains(approximately 15-20 minutes). Get medical attention immediate

Information to doctor or : The signs and symptoms of poisoning with Seruni are not very
other Trains persons pronounced and are likely to consist of hypersensitivity type reactions.
giving first aid There is no specific antidote to Cypermethrin. Symptomatic and
supportive treatment is indicated.
Ingestion : remove by giving syrup of Ipecac (if vomiting occurs, keep the head
below the hips to prevent aspiration). Give activated charcoal followed by
gastric lavage. Follow with a saline cathartic. Do not give fats or oils. Give
artificial respiration with oxygen if respiration is depressed. Treat
symptomatically and supportively. Lavage and administration of oxygen
should be performed by qualified medical personnel. Get medical
attention immediately.

6. FIRE FIGHTING MEASURES

Suitable extinguishing : Extinguish fire with water fog, foam, carbon dioxide, dry chemical powder
media and prevent runoff from entering drains.
Unsuitable extinguishing : Do not scatter spilled material with high pressure water jets
media
Special exposure hazard : As for all organic materials, combustion may lead to hazardous oxides
in a fire of carbon an other toxic fumes
Special protective equip: : Full protective clothing including breathing apparatus and protective
for fire-fighting gloves should be worn.
Other instruction : The product is a flammable liquid. Decomposes on heating emitting toxic
vapour/fumes. Fire fighters to wear self-contained breathing apparatus if
risk of exposure to vapour or products of combustion.

5. ACCIDENTAL RELEASE MEASURES

Personal precautions : Slippery when spilt. Avoid accidents, clean up immediately. Wear
protective equipment to prevent skin and eye contamination and
inhalation of vapours.
Environmental : For larger spills wet down with water and dike for later disposal.
precautions Disposal must be in accordance with applicable to generators of
hazardous waste. Increase ventilation. Contain using sand and earth and
prevent run off into drains or waterways.
Methods for cleaning up : Wash area down with detergent and excess water. Ensure that washings
are prevented from entering any surface water drains. If contamination of
sewers or waterways has occurred advise the local emergency services.

6. TRANSPORT INFORMATION
Land transport : UN No. 3349
Enviromentally hazardous substances.
Sea transport : UN Hazard class : 6.1, UN No. 3349 Marine pollutant
Air transport : Non clasified
Eye protection : Moderate irritant. Employee must wear splash-proof or dust-resistant
safety goggles and a face shield to prevent contact with this substance.
Skin protection : Employee must wear appropriate protective (impervious) clothing and
equipment to prevent any possibility of skin contact with this substance.

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7. HANDLING AND STORAGE
Handling : When using chemical do not eat, drink or smoke. Wash hands and
Special protection exposed skin before meals and after work
measures
Storage : Stable under normal atmospheric conditions when stored in closed
Sensibility to humidity, container. Store in original container, tightly closed in a safe, cool, dry,
light & oxidation well-ventilated, secure area out of reach of children and animals.
Special storage : Keep away from food, drink and animal feeding stuffs. Keep out of the
requirements reach children. Keep container in well ventilated place. Maintain a well
ventilated storage area which is relatively free from temperature
fluctuations. Low temperature does not determine a product
deterioration but, rather complete solidification. Thus a possible
separation or segregation of various isomers.
Shelf life : Will keep their physical & biological properties for minimum 2 years
when stored in their original packing in a dry place at an annual
average temperature not exceeding 250C.
Recommended packaging : Carton, packed with polyethylene bag
material
Supplier packaging : Carton, packed with polyethylene bag
Packaging material to be : No special material
avoid
Incompatible substances : Sensitive to alkalis. Unstable in methyl and ethyl alcohol solution.

Note: Classified as a Class 6, 1b [Poisonous (Harmful) and Subclass 3 [Flammable Liquid] Dangerous Substance
for the purpose of transport. Refer to State Regulations for storage and transport requirements. Not to be loaded
with gases (class 2), spontaneously combustible substances (class 4.2), oxidising agents (class 5) or foodstuffs.
The product is a Scheduled Poison (S5) and must therefore be stored,

8. EXPOSURE CONTROL/PERSONAL PROTECTION

Limits values for air in : The recommended hygiene standard is the time weighted average
working place none concentration of the work atmosphere for a normal 8-hour work day and a
established 40-hour work week, to which nearly all workers can be repeatedly
exposed day after day without adverse effect.
Respiratory protection : Wear mask filter for organic vapors. Provide adequate local exhaust or
process enclosure ventilation.
Hand protection : Wear suitable protective gloves
Eye protection : Moderate irritant. Employee must wear splash-proof or dust-resistant
safety goggles and a face shield to prevent contact with this substance.
Skin protection : Employee must wear appropriate protective (impervious) clothing and
equipment to prevent any possibility of skin contact with this substance.

9. TOXICOLOGICAL INFORMATION
Note: None carcinogenic, none reproductive effects

Acute toxicity
ƒ LD50 oral (rat) : 1017 mg/kg
ƒ LD50 dermal (rat) : 2000 mg/kg
Irritancy
ƒ Eye irritancy : Mild irritant to rabbit eye
ƒ Skin irritancy : Mild irritant to rabbit skin
ƒ Skin sensitization : Mild skin sensitization potential to guinea pig

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10. PHYSICAL AND CHEMICAL PROPERTIES

1. Physical state : liquid

2. Colour : Clear yellow to brownish
3. Specific gravity : 1.23 g/ml at 200 C
4. Viscosity : Easily flowable liquid
5. Water content : Less then 0.5%
6. PH : 4
7. Flash point : >110 C
8. Tap bulk density : 0.905 ± 0.005
9. Excludability : Non explosive
10. Corosivity : Corrosive to copper and brass
11. boiling point : NA
12. Melting point : NA
13. Flammability : NA
(solid/gas)
14. Autoflmmability : Not auto flammable
15. vapour pressure : NA
16. Oxidazing properties : NA
17. Relative density : 1.15
18. Solubility in water : soluble
19. Solubility in inorganic : NA
solvent

11. ECOLOGICAL INFORMATION

Biodegradation : The half-life of this chemical in the soil is 30 days. Easily degraded by
soil microbes.
Chemical degradation : Product breakdown is included by soil PH. It is unlikely to contamined
groundwater cause it binds tightly to soil particles.
Aquatic toxicity of
cypermethrin technical
LC50 fish : 2-28 mg/l brown trout
LC50 Daphnia Magna : 0.15 mg/l 48 h
LD50 : 0.035 ug a.i /bee

12. DISPOSAL CONSIDERATION

Product : Disposal must be accordance with standards applicable to generators of
hazardous waste
Empty packaging : Disposal method as per state or local codes of practice and laws.

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