Name: Dimalibot, Audrey Frederica Manuella W.

Course: Chemical Engineering Kinetics

Experiment Title: Neutralization of Acetic Acid with Sodium Bicarbonate
Objective:
· To determine the order of reaction of the neutralization of acetic acid with sodium bicarbonate.
· To determine the rate of reaction with different particle size of sodium bicarbonate.

Materials: Reagents:
· Graduated Cyinder (100mL) · Vinegar (4.5% Acetid acid)
· Glass bottle with cover · Sodium Bicarbonate (tablets/powder)
· Siphoning tube · Water
· Improvised beehive shelf
· Water Basin

Procedure:
· Make a hole in the center of the bottle cap.
· Insert the siphoning tube into the hole. Secure the hole by surrounding it with a tape.
· Place the improvised beehive shelf into the water basin.
· Fill the water basin until the water level is just above the improvised beehive shelf.
· Fully fill the graduated cylinder with water.
· Cover the opening of the graduated cylinder with a thick paper.
· Immediately turn it upside down into the water basin, above the improvised beehive shelf.
· Now, place the other end of the siphoning tube under the opening of the graduated cylinder.
· Record the volume of the water in the graduated cylinder. (This will be your reference point)

For Set-up 1(Tablets)

Ø Measure 40 mL of vinegar with 4.5% Acetic acid and pour it into the glass bottle.
Ø Drop 20 pcs of 650 mg Sodium Bicarbonate into the glass bottle and cover it immediately.
Ø Observe. Record time every 10 mL of water displaced.

For Set-up 2 (Powder)

Ø Measure 40 mL of vinegar with 4.5% Acetic acid and pour it into the glass bottle.
Ø Powderized 20 pcs of 650 mg Sodium Bicarbonate. Then, drop it into the glass bottle and cover it i
Ø Observe. Record time every 20 mL of water displaced.
ith sodium bicarbonate.
bicarbonate.

% Acetid acid)
arbonate (tablets/powder)

t with a tape.

ised beehive shelf.

graduated cylinder.
your reference point)

o the glass bottle.

and cover it immediately.

o the glass bottle.

t into the glass bottle and cover it immediately.
 Set-Up 1 (Tablets)
Physical Properties
Chemical Reaction Equation: Molecular Weight of CO2:
2 𝐻_4 𝑂_(2 )+ 〖��𝐻�𝑂〗 _3→ 〖���〗 _2 𝐻_3 𝑂_(2 )+𝐻_2 𝑂_ + 〖�𝑂〗 _(2 ) Density of CO2
(at room temperature, 25C)

Carbon Dioxide
Zero order First Order
Volume (L) Time (s) Concentration (mol/L)
Rate of Reaction (mol/L-s)Time (s)
0.01 1.92 0.0004110818 0.0002141051 1.92
0.02 3.77 0.0008221636 0.0002180805 3.77
0.03 5.71 0.0012332455 0.0002159799 5.71
0.04 7.05 0.0016443273 0.0002332379 7.05
0.05 9.97 0.0020554091 0.0002061594 9.97
0.06 11.76 0.0024664909 0.0002097356 11.76
0.07 13.72 0.0028775727 0.0002097356 13.72
0.08 15.61 0.0032886545 0.0002106761 15.61
0.09 17.51 0.0036997364 0.0002112928 17.51

Zero Order Graph

0.004

0.0035 f(x) = 0.0002074576x + 4.95242079098781E-05

R² = 0.9976339562
Concentration

0.003
(mol/L)

0.0025

0.002

0.0015

0.001

0.0005

0
0 2 4 6 8 10 12 14 16 18 20

Time (s)

Second Order Graph

3000

2500

2000
 Second Order Graph
3000

2500
Concentration

2000
(mol/L)

1500 f(x) = - 104.2410760766x + 1772.5358798129

R² = 0.6634089375
1000

500

0
0 2 4 6 8 10 12 14 16 18 20

Time (s)
 44 g/mol
1.80876 g/L
rature, 25C)

oxide
First Order Second Order
Concentration (mol/L) Time (s) Concentration (mol/L)
-7.7967182923 1.92 2432.6057630642
-7.1035711117 3.77 1216.3028815321
-6.6981060036 5.71 810.8685876881
-6.4104239312 7.05 608.1514407661
-6.1872803798 9.97 486.5211526128
-6.0049588231 11.76 405.434293844
-5.8508081432 13.72 347.5151090092
-5.7172767506 15.61 304.075720383
-5.5994937149 17.51 270.2895292294

First Order Graph

0
0 2 4 6 8 10 12 14 16 18 20
-1
Concentration

-2
(mol/L)

-3

-4

-5
f(x) = 0.1260645191x - 7.5931968446
-6 R² = 0.9024884437
-7

-8

18 20 -9
Time (s)
18 20

Figure 1: Neutralization of Acetic Acid with Sodium Bicarbonate

14 16 18 20
m Bicarbonate
 Set-Up 2 (Powder)
Physical Properties
Chemical Reaction Equation: Molecular Weight of CO2:
2 𝐻_4 𝑂_(2 )+ 〖��𝐻�𝑂〗 _3→ 〖���〗 _2 𝐻_3 𝑂_(2 )+𝐻_2 𝑂_ + 〖�𝑂〗 _(2 ) Density of CO2
(at room temperature)

Carbon Dioxide
Zero order First Order
Volume (L) Time (s) Concentration (mol/L)
Rate of Reaction (mol/L-s) Time (s)
0.02 1.51 0.0008221636 0.0005444792 1.51
0.04 2.74 0.0016443273 0.0006001194 2.74
0.06 4.19 0.0024664909 0.0005886613 4.19
0.08 5.79 0.0032886545 0.0005679887 5.79
0.1 7.29 0.0041108182 0.0005638982 7.29

Zero Order Graph

0.0045

0.004 f(x) = 0.0005615641x + 4.95191125539509E-05

R² = 0.9979097631
Concentration

0.0035
(mol/L)

0.003

0.0025

0.002

0.0015

0.001

0.0005

0
1 2 3 4 5 6 7 8

Time (s)

Second Order Graph

1400

1200
Concentration

1000
(mol/L)

f(x) = - 150.4206660201x + 1202.8555291169

R² = 0.7772723928
800

600
 1200

Concentration
1000

(mol/L)
f(x) = - 150.4206660201x + 1202.8555291169
R² = 0.7772723928
800

600

400

200

0
1 2 3 4 5 6 7 8

Time (s)
 44 g/mol
1.80876 g/L

de
First Order Second Order
Concentration (mol/L) Time (s) Concentration (mol/L)
-7.1035711117 1.51 1216.3028815321
-6.4104239312 2.74 608.1514407661
-6.0049588231 4.19 405.434293844
-5.7172767506 5.79 304.075720383
-5.4941331993 7.29 243.2605763064

First Order Graph

0
1 2 3 4 5 6 7 8
-1
Concentration

-2
(mol/L)

-3

-4

-5
f(x) = 0.2644465728x - 7.2842508124
-6 R² = 0.9259361595

-7

7 8 -8

Time (s)
8

Figure 2: Neutralization of Acetic Acid with Sodium Bicarbonate

6 7 8
m Bicarbonate
Results:

Set-Up 1 (tablets):
Order of reaction with respect to CO2 Zero
Average Rate of formation of Carbon Dioxide 0.0002143 mol/L-s

Set-Up 2 (powder):
Order of reaction with respect to CO2 Zero
Average Rate of formation of Carbon Dioxide 0.00057303 mol/L-s

Conclusion:

I, therefore, conclude that the smaller particle size of sodium bicarbonate, the faster
the rate of reaction. By decreasing the particle size of a reactant, we are increasing its sur
A smaller particle size of reactants provides a greater surface area that collisions can take p
The greater the surface area, the faster the rate of reaction.
rbonate, the faster
we are increasing its surface area.
a that collisions can take place on.