Opium Poppy Cultivation in SEA PDF
Opium Poppy Cultivation in SEA PDF
Opium Poppy Cultivation in SEA PDF
September 1992
. eC
7
7 s DEA- 92004
141189
U.S. Department of Justice
National Institute of Justice
September 1992
ADMINISTRATOR·S MESSAGE
Opium Poppy Cultivation and Heroin Processing in Southeast Asia reviews in detail several
complex natural and chemical procedures linked with heroin production. It further explains
how the opium poppy plant of Southeast Asia is grown and harvested, how the poppy's opium
is chemically converted into morphine, and fmally. how that morphine is then refmed into
"China White" heroin by Southeast Asian "cooks" and "chemists." The report will interest
a wide audience: those studying "source country" issues, those determining opium poppy
crop estimates in mainland Southeast Asia, and those monitoring and controlling the
intemational import and export of chemicals.
Opium Poppy Cultivation and Heroin Processing in Southeast Asia also presents the
technical relationship between opium poppy cultivation in the Golden Triangle (the moun-
tainous region where Burma, Laos, and Thailand share common borders) and heroin
production in the laboratories of Southeast Asia.
Robert C. Bonner
Administrator of
Drug Enforcement
iii
TABLE OF CONTENTS
Conclusion ................................................................................................................................................... 22
Distribution .................................................................................................................................................. 31
v
•
LIST OF ,ILL.USTRAT.IONS .
'" . ~ ,
Figure 14. Double U-O Globe Trademark of Southeast Asian Heroin ..................................................... 22
. LIST OF MAPS'
vi
, · .
ECUTIVE SUMMARY
The opium poppy has been cultivated in China and mainland Southeast Asia for more than
two centuries. The mature plant produces a highly addictive latex which may be refined tc·
produce opium for smoking, or treated with certain chemicals to produce morphine or heroin.
This report focuses on the necessary steps in this process-taking a mature but raw opium
poppy plant and synthesizing it's contents into finished heroin.
This report gives a brief history of the opium poppy plant and analyzes the plant in botanical
detail. Cultivation methods are described, to include field selection, land clearing and soil
preparation. It further explains the method of extracting morphine from opium, as the
operation typically occurs in clandestine jungle laboratories in Southeast Asia. Finally, the
intricate procedures used by heroin chemists to convert morphine to heroin are depicted step-
by-step.
A glossary of terms related to opium poppy cultivation and heroin processing in Southeast
Asia is included for reference.
Vll
-
. -
. . ORIGIN AND HistORY OF "
THE OPIUM pappy ,
~ , .
1
soldiers during the Civil War. The inevitable result Although heroin has been used in the United King-
was opium addiction, contemporarily called "the dom in the treatment of the terminally ill, its "medical
army disease" or "soldier's disease." These opium value" is a subject of intense controversy.
and morphine abuse problems prompted a scientific
search for potent but nonaddictive painkillers. In the
1870s, chemists developed an opium-based and sup-
posedly non-addictive substitute for morphine. The
Bayer pharmaceutical company of Germany was the
first to produce the new drug in large quanti ties under
the brand name Heroin. This product was obtained
by the acetylation of morphine. Soon thereafter
studies showed heroin to have narcotic and addictive
properties far exceeding those of morphine.
MATURE
QI'IUM Poppy POD.
OR "SEED POD"
"CAPSULE"
"BULB"
"POPPY HEAD"
SECONDARY STEM
(''TILLER")
LEAF
2
..
, . .
.
. ..
..
THt;: QPIUM POppy
.. PLANT
' . . '
The opium poppy, Papaver somniferum, is an annual Opium poppies generally flower after about 90 days
plant. From a small seed, it grows, flowers, and bears of growth and continue to flower for two to three
fruit (a "pod") only once. The entire growth cycle for weeks. The petals last for two to four days and then
most varieties of this plant takes about 120 days. The drop to reveal a small, round, green fruit which
tiny seeds, like the seeds on a poppy seed roll, continues to develop. These fruits or pods (also
germinate quickly in warmth and sufficient mois u called "seedpods," "capsules," "bulbs," or "poppy
ture. In less than six weeks, the young plant emerges heads") are either oblate, elongated, or globular and
from the soil, grows a set of four leaves, and re- mature to about the size of a chicken egg. The oblate-
sembles a small cabbage in appearance. The lobed, shaped pods are more common in Southeast Asia.
dentate lc;aves are glaucous green with a dull gray or
blue tint. Only the pod portion of the plant can produce opium
alkaloids. The skin of the poppy pod encloses the
Within two months, the plant will grow from one to wall of the pod ovary. The ovary wall consists of
two feet in height, with one primary, long, smooth three layers: the outer, middle and inner layers. The
stem. The upper portion of this stem is without plant's latex (opium) is produced within the ovary
leaves and is called the "peduncle" (see Figure 1). wall and drains into the middle layer through a
One or more secondary stems, called "tillers," may system of vessels and tubes within the pod. The cells
grow from the main stem of the plant. Single poppy of the middle layer secrete more than 95 percent of
plants in Southeast Asia often have one or more the opium when the pod is scored and harvested.
tillers.
Cultivators tap the opium from each pod while it
The main stem of a fully-matured Papaver remains on the plant. After the opium is scraped, the
somniferum ranges between two and five feet in pods are cut from the stem and allowed to dry. Once
height. The green leaves are oblong, toothed and dry, the pods are cut open and the seeds are
lobed and vary between four to fifteen inches in removed and dried in the sun before storing for the
diameter at maturity. The matured leaves have no following year's planting. An altematitive method
commercial value except for use as animal fodder. of collecting planting seeds is to collect them from
intentionally unscored pods, because scoring may
As the plant grows tall, the main stem and every tiller diminish the quality of the seeds. Aside from being
terminates in a flower bud. During the development used as planting seed, the poppy seeds may also be
ofthe bud, the peduncle portion of the stem elongates used in cooking and in the manufacture of paints and
and forms a distinctive "hook" which causes the bud perfumes. Poppy seed oil is straw-yellow in color,
to be turned upside down. As the flower develops, odorless, and has a pleasant, almond-like taste.
the peduncle straightens and the buds point upward.
A day ortwo after the buds first point upward, the two
outer segments of the bud, called "sepals," fall away,
exposing the flower petals. The exposed flower
blossom is at first crushed an:.' crinkled, but the petals
soon expand and become smooth in the sun. Poppy
flowers have four petals. The petals may be single or
double and are either white, pink, reddish purple,
crimson red, or variegated.
3
I
-
Yunnan Province
Shan State
Kachin State .~ Laos
Kokang Area d
': .
.: Vll'l1lalll
Louangnamtha Province
J Tllllll~\I111 Bokco Province
L~uangphabang Province Son La Province
Oudomxai Province
Chiang Mlli Province Phong Sali Province
Chiang Rai Province Xaignabouli Province
Mae Hong Son Province Xiangkhoang Province
im-1it Nan Province
Tak Province
tBiilIiGiIll Houaphan Province
4
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22_
.. , .'
OPIUM POppy
GROWING AREAS
The opium poppy does best in temperate, warm Opium poppies were widely grown as anomamental
climates with low humidity and requires only a plant and for seeds in the United States until the
moderate amount of water before and during the possession of this plant was declared illegal in the
early stages of growth. In addition, the opium poppy Opium Poppy Control Act of 1942.
is a "long day" photo-responsive plant. As such,
poppies require long days ai1d short nights before The highlands of mainland Southeast Asia, at eleva-
they will develop flowers. tions of 800 meters or more above sea level, are
prime poppy growing areas. Generally speaking,
The opium poppy plant can be grown in a variety of these poppy-farming areas do not require irrigation,
soils-clay, sandy loam, sandy, and sandy clay-but fertilizer, or insecticides for successful opium yields.
it grows best in a sandy loam soil. This type of soil Most of the opium poppies of Southeast Asia are
has good moisture-retentive and nutrient-retentive grown in Burma (Myanmar), specifically in the Wa
properties, is easily cultivated and has a favorable and Kokang areas which are in the northeastern
structure for root development. Clay soil types are quadrant of the Shan State of Burma. Laos is the
hard and difficult to pulverize into a good soil tex- second-largest illicit opium-producing country in
ture. The roots of a young poppy plant cannot readily Southeast Asia and third-largest in the world. In this
penetrate clay soils, and growth is inhibited. Sandy country, poppy is cultivated extensively in Houaphan
soil, by contrast, does not retain sufficient water or and Xiangkhoang Provinces, in addition to the six
nutrients for proper growth of the plant. northern provinces of Bokeo, Louangnamtha,
Louangpnabang, Oudomxai, Phongsali and
Excessive moisture or extremely arid conditions will Xaignabouli. Poppy is also grown in many of the
adversely affect the poppy plant's growth, thus re- remote, mountainous areas of northern Thailand,
ducingthe alkaloid content Poppy plants can become particularly in Chiang Mai, Chiang Rai, Mae Hong
waterlogged and die after a heavy rainfall in poorly Son, Nan and Tak Provinces.
drained soil. Heavy rainfall in tlle second and third
months of growth can leach alkaloids from the plant In China, opium poppies are cultivated by ethnic
and spoil the harvest. Dull, rainy, or cloudy weather minority groups in the mountainous frontier regions
during this growth stage may reduce both the quan- of Yunnan Province, particularly along the border
tity and the quality of the alkaloid content. area with Burma's Kachin and Shan States. Son La
Province, situated between China and Laos, is a
The major legal opium poppy growing areas in the major opium poppy cultivation area in Vietnam.
world today are ingovemment-regulated opium farms
in India, Turkey and Tasmania, Australia. The major It is noteworthy that the dominant ethnic groups of
illegal growing areas are in the highlands of main- mainland Southeast Asia are Tlot poppy cultivators.
land Southeast Asia, specifically Burma, Laos and The Burmans and Shan of Burma, the Lao of Laos,
Thailand (the Golden Triangle), as well as adjacent the Thai of Thailand, the Han Chinese of Yunnan,
areas of southern China and northwestern Vietnam China, and the Vietnamese of Vietnam arelowlanders
(see Figure 2 and Map 1); in Southwest Asia, specifi- and do not traditionally cultivate opium poppies.
cally Pakistan, Iran, Afghanistan and in Mexico. Rather, it is the ethnic minority highlander groups,
Opium poppy is also grown in Lebanon, Guatemala, such as the Wa, Pa-O, Palaung, Lahu, Lisu, Hmong,
and Colombia. and Akha who grow poppies in the highlands of the
countries of Southeast Asia. (See Figure 3.)
5
A typical nuclear family of Southeast Asian high-
landers ranges between five and ten persons, including
two to five adults. An average household of poppy
fanners can cultivate and harvest about one acre of
opium poppy per year. Most of the better fields can
support opium poppy cultivation for ten years or
more without fertilization, inigation, orinsecticides,
before the soil is depleted and new fields must be
cleared.
Opium Poppy
Growers & Smokers
Figure 3. Ethnic groups involved in opium and heroin trafficking in Southeast Asia.
6
· .
In choosing a field to grow opium poppy, soil quality The slash-and-bum method is also used to clear
and acidity are critical factors and experienced fields for poppy cultivation. Before the rainy season
poppy fanners choose their fields carefully. In in April, fields by the hundreds of thousands all over
Southeast Asia, westerly orientations are typically the region are set ablaze. A fog-like yellow haze
preferred to optimize sun exposure. Most fields are hangs over the area for weeks, reducing visibility for
on mountain slopes at elevations of 1,000 meters hundreds of miles. In the mountains, the density of
(3,000 feet) ormore above sealevel. Slope gradients haze blocks out the sun and stings the eyes.
of 20 degrees to 40 degrees are considered best for
drainage .;f rain water. A typical highlander family will plant an area of two
or three rai in opium poppy (2.53 rai is equivalent to
In Mainland Southeast Asia, virgin land is prepared one acre). (See Figure 4.)
by cutting and piling all brush, vines and small trees
in the field during March. at the end of the dry season.
After allowing the brush to dry in the hot sun for
several days, the field is set afire. This method,
called "slash-and bum" or "swidden" agriculture, is
commonly practiced by dry field fanners - both
highland and lowland - throughout Mainland South-
east Asia in order to ready the land for a variety of
field crops.
2.46 6.23
acres rai
0.403 1.00 2.53
acre hectare 6Cf1l rai
1,600 0.160 0.397 1.00
rai (Ial) sqmeters hectare acre rai
7
I
8
HARVESTING
LAND
PREPARATION
·RAINYSEASON COLD SEASON
[SEP QCT NOV DEC JAN FEB
Figure 5. Opium poppy cultivation in Southeast Asia.
The opium poppy plants fonn leaves in the first Three to four months after planting, from late De-
growth stage, called the "cabbage" or "lettuce" stage. cember to efl.:ly February, the opium poppies are in
After a month of growth. when the opium poppy is full bloom. Mature plants range between three to
about a foot high, some of the plants are removed five feet in height. Most opium poppy varieties in
(called "thinning") to allow the others more room to Southeast Asia produce three to five mature pods per
grow. The ideal spacing between plants is believed plant.
to be 20 to 40 centimeters, or about eight to twelve
plants per square meter, although some researchers A typical opium poppy field has 60,000 to 120,000
in northern Thailand have reported as many as 18 poppy plants per hectare, with a range of 120,000 to
plants per square meter. 275,000 opium-producing pods. The actual opium
yield will depend largely on weather conditions and
During the first two months, the opium poppies may the precautions taken by individual farmers to
be damaged or stunted by nature through the lack of safeguard the crop. The fanner and his family
adequate sunshine, excessive rainfall, insects, wonns, generally move into the field for the fmal two weeks,
hail stonns, early frost, or trampling by animals. The setting up a small field hut on the edge of the opium
third month of growth does not require as much care poppy field.
as the first two months.
9
" '
, ,
The scoring of the pods (also called "lancing," "in- The opium yield from a single pod varies greatly,
cising," or "tapping") begins aout two weeks after ranging from 10to 100 milligrams of opium per pod.
the flower petals fall fromthe pods. The farmer The average yield is about 80 milligrams. The dlied
examines the pod and the tiny crown (see Figure 1) opium weight yield per hectare of opium poppies
portion on the top of the pod very carefully before ranges between eight and fifteen kilograms of opium.
scoring. The grayish-green pod will become a dark
green color as it matures and it will swell in size. If As the faffilers gather the opium, tlle larger or more
the points ofthe pod's crown are standing straight out productive pods are tagged with colored string or
or are cuved upward, HIe pod is ready to be scored. If yarn. These pods will later be cut from their stems,
the crown's points turn downward, the pod is not yet cut open, dried in the sun and their seeds will be used
fully matured. Not all the plants in a field will be for the following year's planting.
ready for scoring at the same time and each pod can
be tapped more than once. The wet opium gum collected from the pods contains
a relatively high amount of water and needs to be
A set of three or four small blades of iron, glass, or dried for several days. High-quality raw opium will
glass splinters bound tightly together on a wooden be brown (rather than black) in color and will retain
handle is used to score two or three sides of the pod its sticky texture. Experienced opium traders can
in a vertical direction. If the blades cut too deep into quickly deteffiline if the opium has been mixed with
the wall of the pod, the opium will flow too quickly tree sap, sand or other such materials.
and will drip to tiie ground. If the incisions are too
shallow, the flow will be too slow and the opium will Raw opium in Burma, Laos and Thailand is usually
harden in the pods. A depth of about one millimeter sun-dried, weighed in a standard 1.6 kilogram quan-
is desired for the incision. Using a blade-tool de- tity (called a "viss" in Burma; a "choi" in Laos and
signed to cut to that depth, scoring ideally starts in Thailand), wrapped in banana leaf orplastic and then
late afternoon so the white latex-like raw opium can stored until ready to sell, trade, or smoke. Opium
ooze out and slowly coagulate on the surface of the smoking is common among most adult opium poppy
pod overnight If the scoring begins too early in the farmers, whereas heavy addiction is generally lim-
afternoon, the sun will cause tlle opium to coagulate ited to older, male farmers. The average yearly
over the incision and block the flow. The opium consumption of cooked opium per smoker is esti-
oxiqizes, darkens and thickens in the cool night air. mated to be 1.6 kilograms.
Early the next morning, the opium gum is scraped
from the surface ofthe pods with a short-handled flat, A typical opium poppy farmer household in South-
iron blade three to four inches wide. east 'Asia will collect 2 to 5 choi or viss (3 to 9
kilograms) of opium from a year's harvest of a one-
Opium harvesters work their way backwards across acre field. That opium will be dried, wrapped and
the field scoring lower, mature pods before the taller stacked on a shelf by February or March. If the
pods, soasnotto inadvertently spill thesticky ooze. opium has been properly dried, it can be stored
The pods will continue to secrete opium for several indefinitely. Excessive moisture and heat can cause
days. Fanners will return to these plants-- some- the opium to deteriorate but, once dried, opium is
times up to five or six times-to gather additional relatively stable. In fact, as opium dries and becomes
opium until the pod is totally depleted. The opium is less pliable, its value increases due to the decrease in
collected in a container which hangs from the farmer's water weight per kilogram.
neck or waist
10
Standard Units oj Weight used in
.375 kg. .454 kg. 0.50 kg. 1.0 kg. 1.6 kgs. 1.657 kgs .
pong pound jin/chin kilogram choiljoi viss
Figure 6. Units of opium weight in Southeast Asia.
Harvested pod with opium poppy seeds revealed prior to drying and storage for next year's planting.
11
COOKING OPIUM '
Before opium is smoked, it is usually cooked.
Uncooked opium contains moisture, vegetable mat-
ter and other impurities which detract from a
smooth-smoking product. The raw opium which is
collected from the opium poppy pod is placed in an
open cooking pot of boiling water where the sticky
glob of opium alkaloids quickly dissolve. The soil,
twigs, plant scrapings, etc. remain undissolved. The
solution is strained through cheesecloth to remove
these impurities. The clear brown liquid, sometimes
called "liquid opium," is actually opium in solution.
This liquid is then re-heated over a low flame until
the water turns to steam and is driven off into the air.
When the water has evaporated. a thick paste re-
mains. This paste is called "prepared opium," "cooked
opium," or "smoking opium" and itis dried in the sun
until it has a putty-like consistency. The net weight
of the cooked opium is generally about twenty per-
cent lighter than the original raw opium. Likewise,
cooked opium is also more pure than in its original,
raw form.
Cooked opium is suitable for smoking or eating by Opium being cooked during the morphine extraction stage.
opium users. Traditionally there is only one group
of opium poppy farmers, the Hmong, who prefer to
not cook their opium before smoking. Most other
ethnic groups, including Chinese opium addicts,
prefer smoking cooked opium.
12
. .
EXTRACTI"ON OF MORPHINE
. FROM OPIUM
The process of extracting morphine from opium do not react with the lime to form calcium salts.
involves dissolving opium in hot water, adding lime Codeine is an opium alkaloid which is slighty
to precipitate non-morphine alkaloids and then add- water soluble and which will be carried over
ing ammonium chloride to precipitate morphine from with the calcium morphenate in the liquid. For
the solution. An empty oil drum and some cooking the most part, the other alkaloids will become
pots are needed. a part of the "sluge."
Following is a step-by-step description of morphine 4. As the solution cools, the morphine solution
extraction in a typical Southeast Asian laboratory: is scooped from the drum and poured through
a filter of some kind. Burlap rice sacks are
1. An empty 55-gallon oil drum is placed on often used as filters and can then be squeezed
bricks about a foot above the ground and a fire in a press to remove most of the solution from
is built under the drum. Thirty gallons of water the wet sacks. The solution is then poured into
are added to the drum and broughtto a boil. Ten largecookingpotsandre-heated,butnotboiled.
to fifteen kilograms of raw opium are added to
the boiling water. 5. Ammonium chloride is added to the heated
calcium morphenate solution to adjust the al-
2. With stirring, the raw opium eventually kalinity to a pH of8 to 9, and the solution is then
dissolves in the boiling water, while soil, leaves, allowed to cool. Within one or two hours, the
twigs, and other non-soluble materia1s float in morphine base and the unreacted codeine base
the solution. Most ofthese materials are scooped precipitate out of the solution and settle to the
out of the clear brown "liquid opium" solution. bottom of the cooking pot.
3. Slaked lime (calcium hydroxide) or more 6. The solution is then poured off through
often a readily available chemical fertilizer cloth fllters. Any solid morphine base chunks
with a high content of lime is added to the in the solution will remain on the cloth. The
solution. The lime will r..onvert the water morphine base is reploved from both the cook-
insoluble morphine into the water soluble cal- ing pot and from the filter cloths, wrapped and
cium .llorphenate. The other opium alkaloids
13
squeezed in cloth, and then dried in the sun.
When dry, the crude morphine base is a coffee-
colored powder.
blocks are then bundled and packed for transport to Morphine solution is scooped into
other containers.
heroin laboratories by human couriers or by pack
animals. Pack mules are able to carry lOO-kilogram
payloads over 200 miles of rugged mountain trails in
Figure 8. Morphine extraction process.
less than three weeks.
ACETIC ANHYDDRIDE,
AC nON CALCIUM HYDROXIDE,
AMMONIUM CHLORIDE,
PROCESS ALCOHOL, ETHER,
t
PURIFj~AnoN
~-.:
ACETONE
PRECIFfrAnON
~~~
\f'
14
·
~ CONVERSION OF MORPH"INE ~
TO HEROIN BASE
The conversion of morphine to heroin base is a anhydride is then added. The acetic anhydride reacts
relatively simple and inexpensive procedure. The with the morphine to form diacetylmorphine (heroin).
necessary chemicals for conversion to heroin are
commonly available industrial chemicals. (See Fig- This acetylation process will work either with mor-
ure lO.) The equipment is very basic and quite phine hydrochloride or morphine base. The pot lid is
portable. Heroin conversion laboratories are gener- tied or clamped on, with a damp towel for a gasket.
ally located in isolated, rural areas due to the telltale The pot is carefully heated for about two hours,
odors of the lab's chemicals. Acetic anhydride, in below boiling, at a constant temperature of 185·
particular, is a key chemical with a very pungent odor Fahrenheit. It is never allowed to boil or to become
resembling pickles. so hot as to vent fumes into the room. It is agitated
by tilting and rotation until all of th.e morphine has
Chemicals used to isolate the morphine from the dissolved. When cooking is completed, the pot is
opium include ammonium chloride, calcium carbon- cooled and opened. During this step, morphine and
ate (limestone) and calcium hydroxide (slaked lime). the anhydride become chemically bonded, creating
The precursor chemical nOImally used in the conver- an impure form of diacetylmorphine (heroin). (See
sion of morphine to heroin is acetic anhydride. Figure 9.)
Chemical reagents used in the conversion process
include sodium carbonate and activated charcoal. Water is added at three times the volume of acetic
Chemical solvents needed are chloroform, ethyl al- anhydride and the mixture is stirred. Activated
cohol (ethanol), ethyl, ether and acetone. Other charcoal is added and mixed by stirring and the
chemicals may be substituted for these preferred mixture is then filtered to remove colored impurities.
chemicals, but most or all of these preferred chemi- Solids remaining on the filter are discarded. Sodium
cals are readily available through smugglers and carbonate at 2.5 pounds per pound of morphine is
suppliers. dissolved in hot water and added slowly to the liquid
until effervescence stops. This precipitates the
Laboratory equipment includes measuring cups, fun- heroin base which is then filtered and dried by
nels, filter paper, litmus paper and a stainless steel heating in a steam bath for an hour. For each pound
pot. Only the most sophisticated heroin labs use of morphine, about 11 ounces of crude heroin base is
glass flasks, propane gas ovens, Bunsen burners, formed.
vacuum pumps, autoclaves, electric blenders, vent-
ing hoods, centrifuges, reflux condensers, electric The heroin base may be dried, packed and trans-
drying ovens and elaborate exhaust systems. It is ported to a heroin refining laboratory or it may be
also possible to find portable, gasoline-powered purified further and/or converted to heroin hydro-
generators at clandestine heroin conversion labora- chloride, a water-soluble salt form of heroin, at the
tories used to power various electrical devices. same site.
Heroin synthesis from morphine is a two-step pro- Southeast Asian heroin base is an intermediate prod-
cess which requires twelve to fourteen hours to uct which can be further converted to either smoking
complete. Heroin base is the intermediate product. heroin ("heroin no. 3") or injectable heroin ("heroin
Typically, morphine hydrochloride bricks are pul- no. 4").
verized and the dried powder is then placed in an
enamel or stainless steel rice cook pot. Acetic
15
Key Chemicals
raw opium
water supply
slaked lime
empty oil drum
fIrewood heroin base
anullonium chloride (litmus) paper
LI.u.o,.a'Vl
hydrochloric acid chloroform or cresol ethyl alcohol
cheesecloth flIter sodium carbonate activated charcoal
morphine press enamel pots hydrochloric acid
drying boxes, lime rock
funnels, beakers
cooking oven
fllter cloths or paper
Bunsen burner
16
••
CONVERSION OF HEROIN
BASE TO HEROIN
, HYDROCHLORIC ACID
Heroin No.3
(Smoking Heroin)
(Heroin hydrochloride)
To make heroin no. 3, the crude base is mixed with ADUL TION
hydrochloric acid resulting in heroin hydrochloride. (CAFFEINE, STRYCHNINE)
Aldulterants including caffeine are added after this
conversion. For each kilogram of crude heroin base
about one kilogram of caffeine is used. Various
"flavorings" such as quinine hydrochloride or strych~
nine hydrochloride may be added in 7 gram or 14
gram increments. Next, the wet paste mix is stirred
to dryness over the steam bath.
17
CONVERSION OF HEROIN filtration removes the traces of so-
dium carbonate that remained in the
.
, "BASE TO HEROIN "
base. The solution is quickly cooled
Heroin No.4
in an ice bath, where it becomes
very thick like ice cream. The sub-
(Injectable Heroin)
stance is put into a pan and set in a
large refrigerator. A fan is set to
To the heroin base mixture in the pot, water is added
blow across the pan to cause slow
at three times the volume of acetic anydride and evaporation of the alcohol while the
mixed by stirring. A small amount of chloroform is
paste crystallizes. After several
added. The mixture is stirred and then allowed to
hours, it is vacuum-filtered. The
stand for twenty minutes. Doing so precipitates
filtrate, pure ethyl alcohol, is re-
highly-colored impurities and a red, greasy liqui?
used. The solid material, "alcohol
The water layer is carefully poured off and saved m
morphine base," is actually re-crys-
a clean pot, leaving the red grease in the pot.
tallized heroin base.
In a clean pot, activated charcoal is stirred into the
The heroin. product, either heroin base or re-crystal-
aqueous solution and is filtered to remove solid
lized heroin base, is weighed. For each pound of
impurities. The decolorizing effects of the charcoal,
solid product, 3,000 milliliters of ethyl alcohol, 3,000
combined with the chloroform treatment, will leave
milliliters of ether, and 102 milliliters of concen-
a light yellow solution. The use of charcoal is
trated hydrochloric acid are measured out. The solid
repeated one or more times, until the solution is
is dissolved by heating with one-third of the alcohol
colorless.
and one-half of the acid. Another one-third of the
acid is added and mixed by stirring. Next, acid is
Approximately 1.1 kilograms of sodium carbonate
added slowly, drop by drop, until the product is
per 0.5 kilograms of morphine is dissolved in hot
completely converted to the hydrochloride. Two
water and added slowly to the mixture until the
methods of testing this end product may be used.
effervescence stops. This precipitates the heroin
Either a drop of solution evaporates on a clean glass
basewhich is then filtered and dried by heating on a
plate, leaving no trace of cloudiness in the residue, or
steam bath. The heroin base is heated until dryness
a drop of the solution placed on Congo red paper
is complete, an imperative for the preparation of
causes the paper to tum blue.
heroin no.4. The powder should be very white atthis
stage. Ifnot white, the base is redissolved in diluted
Once the acid is added, the remaining alcohol is
acid, treated repeatedly with activated charcoal,
stirred in. Then, half of the ether is added with
reprecipitated and dried. The ultimate purity and
stirring and the mixture is allowed to stand for
color of the resulting heroin hydrochloride depends
fifteenminutes. Itmustbeexamined with greatcare
largely on the quality of the heroin base.
since it is extremely volatile and flammable. Once
the first small crystals are detected, the remaining
An optional step taken by skilled heroin chemists to
ether is added at once. The vessel is stirred, covered
increase the quality of the heroin follows:
and allowed to stand for twenty minutes to one hour.
Foreach pound ofheroin base, 1,100
The mixture becomes nearly solid after an hour. At
milliliters of ethyl alcohol is heated
this point, it is filtered and the solids are collected on
to boiling. The heroin base is added
clean filter paper. The paper is wrapped around the
and stirred until completely dis-
crystals and placed on wooden trays, usually ov~r
solved. The heated solution is then
lime rock, to dry. When the crystals of pure herom
quickly filtered through a Buchner
hydrochloride are dry, they are packaged. Batches of
funnel that has been preheated and
5 to 10 kilograms arc commonly made at one time,
poured into a heated flask. This hot
the largest batch being an estimated 20 kilograms.
18
-
SODIUM CARBONATE
CHLOROFORM
ACTNATED CHARCOAL
ALCOHOL
ETHER
HYDROCHLORIC ACID
19
tv
o
II
2S'OO'N i \ J-~'O_---H-~--ry_b-ultivati()~Feas-~ooN
of S'outheas1t Asia
Kunming
;,. •
~~
] ~
~
24'OO'N C, '"'.
~.~) China
i
22'OO'N ,-
JI Yunnan Province
(China)
-,
,"' .
•
Hanoi
22'OO'N
"- ~ 1
j : 1 ~ 1
.~
(Vietnam)
t ~.
... .1 • " 4:~ ,
0"
\, I
I!-
---~
•
Viangchan (Vientiane)
1a·OO'N \ I " 7' JOJ'"
secondary cultivation
O no significant cultivation
(unshaded areas)
MILES
o
o
- -
20 40 GO 80 100
so 100 160
KILOMETERS
",rOO'E 100·00'E
I
102·00'E 104·00'E
•
Bangkok
-
tv
, . ,
,'. CONCLUSION .
' . ' .
Southeast Asia, especially the Golden Triangle area, is ideally suited for the propagation and synthesis of the
opium poppy- geograpically, topologically and culturally.
Although the opium poppy plant will grow remarkably well with little tending, farmers in recent years have
introduced the use of fertilizers that have produced bumper crop yields. In addition, the chemicals used in the
synthesis of heroin are inexpensive and readily available. At the same, the time laboratory equipment needed
to synthesize heroin is very basic and easily obtainable.
These factors, coupled with powerful financial incentives and an absence of cultural prohibitions, clearly
suggest that opium poppy cultivation and heroin synthesis in Southeast Asia show no signs of abatement. •
22
acetic acid, glacial
Also known as ethanoic acid orvinegar acid. Glacial as a solvent include manufacture of rayon, photo-
acetic acid is the pure compound, as distinguished graphic films, paint and varnish removers. Shippedin
from the usual water solutions known as acetic acid. cans, steel drums, barrels, and tank cars. Can be used
A clear, colorless liquid with a pungent odor. Mis- as a solvent in processing opium and in the purifica-
cible with water, alcohol, glycerin, and ether. tion of morphine base, but is not commonly used in
Highly-concentrated, produces bums on the skin. Southeast Asia.
Chronic exposure may cause erosion ofdental enamel,
bronchitis, eye irritation. Excellentsolventformany
organic compounds. Widely used in commercial acetyl chloride
organic synthesis. Normally contained in5-lb bottles
(corrosive liquid). Can be used in place of ammo- Also known as ethanoyl chloride. A flammable,
nium chloride or ammonia solutions as a reagent to fuming, colorless liquid with a pungent odor. Soluble
adjust alkalinity in the precipitation of morphine (as in ether,. acetone, acetic acid. Highly toxic and
crude morphine base) from an opium solution. corrosive. Extremely irritating to the eyes. Danger-
ous fire risk. Reacts violently with water and alcohol.
Used as an acetylating agent; in testing for choles-
acetic anhydride terol, determination of water in organic liquids.
Shipped in polyurethane-lined iron drums and 110-
Also known as acetic oxide; acetyl oxide. A color- Ib glass carboys in cool, dry area with adequate
less liquid with a strong, pickle-like odor. Fumes in ventilation. Protect from moisture. Controlled or
moist air, and its vapor is extremely irritating to eyes, regulated in Hong Kong and Thailand. Can be used
nose, and throat. Not readily miscible with water, in place of acetic anhydride as an acetylating agent in
forming a separate layer on the bottom, but will the acetylation of morphine, although it is more
eventually form acetic acid. Soluble in chloroform hazardous to use.
or ether. Readily combustible (fire hazard). Nor-
mally contained in various sizes of glass or plastic
bottles, 5-gallon glass carboys, and 55-gallon metal acetylation
drums lined with stainless steel or polyethylene.
Used in the textile, leather tanning, pharmaceutical The key chemical process in converting morphine
(particularly aspirin), and photography industries. base to heroin. Can be accomplished using either
Under strict government regulation in some coun- acetyl chloride or acetic anhydride. Acetyl chloride
tries. Manufactured in United States, WestemEurope, is flammable, irritating to the eyes, reacts violently
and Japan. Acetic anhydride is also the most com- with water or alcohol, and requires careful handling
monly used acetylating agent in the acetylation of in laboratory processes. For these reasons, acetyla-
morphine. A key precursor chemical and reagent in tion using acetyl chloride is not favored by processors
heroin synthesis. of heroin. Although acetic anhydride is corrosive
and requires care in handling, it is less hazardous to
the user than acetyl chloride and hence is the key
acetone chemical used in processing of heroin.
23
alcohol (ethyl alcohol) acute toxic properties make it a poor choice for this
process.
An anhydrous alcohol, also known as ethanol, grain
alcohol, fermentation alcohol, "drinking alcohol,"
anhydrous alcohol, ethyl hydroxide, and methyl carbi- brown sugar heroin
nol. A clear, colorless, volatile, flammable liquid
with a pleasant, sweet odor. Absorbs water rapidly A common name for heroin (any source) which has
from air. Miscible with water. Must be stored in the appearance of light brown, granulated sugar.
tightly closed container, cool, and away from flame. Used in contrast with the white, fluffy powder or
Most ethyl alcohol is used in alcoholic beverages in crystals form of heroin, such as Southeast Asian
suitable dilutions. Shipped in metal or plastic con- "China White" heroin. Injected, snorted, or smoked.
tainers, such as 55-gallon drums, gerry cans, etc.
Some drums may be lined with phenolic resin. Used
as a solvent during purification of heroin base and in caffeine
conversion of heroin base to heroin hydrochloride.
White, fleecy masses oflong, flexible, silky crystals.
A bitter, white alkalc'id found in coffee, tea, and cola
alkaloid nuts. Caffeine is generally used in combined forms,
as a monohydrate, a.cetate, or other compounds. In
Any of various physiologically active, nitrogen- addition to its use as a stimulant and diuretic, crystal-
containing organic bases derived from plants. line caffeine is commonly used as an adulterant in
Common alkaloids include atropine, caffeine, co- heroin hydrochlOIide, or as a necessary ingredient in
caine, codeine, mescaline, morphine, narcotine, "smoking heroin" (e.g., Southeast Asian heroin no. 3).
nicotine, noscapine, papaverine, quinine, strychnine,
and thebaine.
calcium hydroxide
24
China White "diluents" refer to extenders. Typical diluents for
heroin are mannitol, sucrose, lactose, and starch.
Southeast Asian heroin no. 4, in white powderfonn.
Tenn is used by English-speaking westerners to
contrast the white powder fonn with the light brown, ether (ethyl ether)
granular fonn of heroin (see "brown sugar heroin,"
above). May be injected, snorted, or smoked. The Also known as diethyl ether; ethyl oxide; diethyl
tenn "China White" has also been used in recent oxide; sulfuric ether, anesthetic ether; or simply
years as an alternate name for fentanyl, a syntheti- "ether." A colorless, mobile, very volatile and
cally-produced compound with heroin-like highly flammable liquid. Characteristic, sweetish,
properties. pungent odor, more agreeable than chlorofonn. Ether
vapors are heavier than air; tends to fonn explosi ve
peroxides under the influence of air and light. When
chloroform shaken under absolutely dry conditions, ether can
generate enough static electricity to start a fire.
Also known as trichloromethane. A clear, colorless, Shipped in cans, drums, barrels, and tank. cars. Not
miscible with water, forming a separate layer on the
heavy, and very volatile liquid with a characteristic surface. In addition to its well-known use as an
sweet odor. It is an irritant to the skin and eyes and anesthetic, ether is used as a solvent in fats, waxes,
may also be carcinogenic. Not miscible with water, dyes, perfumes, oils, resins, etc. Ether is also used as
fonning a separate layer on the bottom. Miscible a solvent in conversion of heroin base to heroin
with alcohol. Shipped in bottles, tins, or drums; hydrochloride.
stainless steel forvery high-purity products. Used in
industry as a solvent for fats, oils, rubber, alkaloids,
waxes, and resins. Used extensively as a solvent in ethyl alcohol
the rubber industry; used to make the refrigerant
Fluorocarbon-22. Can be used as a solvent in the See ualcohol."
synthesis of heroin.
ethyl ether
choi See "ether."
diluent gram
A chemical diluent is an ingredient used to reduce
the concentration of an active material. Another A standard unit of weight in the metric system equal
common definition of diluent is a substance added to to one-thousandth of a kilogram. 28.350 grams
finished product (e.g., heroin) to increase bulk. In equal one ounce.
this sense, there is no clear distinction between a
diluent and an extender. In heroin manufacture,
25
hai Southeast Asian heroin no. 4
Northern Thai-Shan term used with land areas. See An injectable form of Southeast Asian heroin.
"rai" and "lai" (Lao). Also known as heroin hydrochloride or "China
White." Highly refined heroin produced from
Southeast Asian opium. Usually a fine white
hectare powder, flakes, or crystals. May be smoked or
snorted, although, from the standpoint of the
A metric unit of area equal to 2.471 acres (10,000 abuser, these are expensive and wasteful uses of
square meters). See Figure 4. this form of heroin. Diluents, such as lactose, are
not normally added until the heroin is diluted, or
"cut."
heroin
26
jin liter
A metric unit of weight in Chinese system. Equiva- A metric unit of volume. Equivalent to 1.056liquid
lent to one-halfkilogram (500 grams). Chinese term, quarts. See Figure 11.
romanized: jin (Pinyin) or chin (Wade-Giles Man-
lowlander (Southeast Asia)
darin). See Figure 7.
A lowland dweller, in either a rural or urban commu-
joi nity. The ethnic Lao are a typical example of
lowlanders in Southeast Asia. However, some Lao
Standard unit of weight for opium. See "choi." have migrated into the highlands and are now
permanent dwellers in highland communities. Con-
versely, some members of ethnic groups which are
kilogram generally highland dwellers (e.g., the Hmong hill
tribe) have permanently moved into lowland areas in
A metric unit of weight equal to 1,000 grams, or Laos and Thailand.
2.2046 pounds.
mannitol
lactose
Also known as mannite, manna sugar. A white,
Also known as milk sugar, saccharum lactis. Present crystalline, sweetish, water-soluble carbohydrate
in milk in mammals. White, hard crystalline mass or alcohol. Used as a nutrient, a dietary supplement,
white powder; sweet taste, odorless. Stable in air. and as the basis of dietetic sweets. Mannitol is
Soluble in water; insoluble in ether and chloroform; commonly used as a mild laxative for infant'). Shipped
very slightly soluble in alcohol. Used commercially in multi wall paper sacks or bulk. Commonly used as
in infant foods, baking and confectionery, margarine a diluent (or "extender") by heroin dealers to in-
and butter manufacture, etc. Shipped in multiwall crease bulk of "injectable heroin" (e.g., Southeast
paper sacks or bulk. Commonly used as a diluent (or Asian heroin no. 4).
"extender") by heroin dealers to increase bulk of
"injectable heroin" (e.g., Southeast Asian heroin no. 4).
morphine
morphine base
h,lle, slaked
Morphine base is an intermediate product be-
Also kpown ac; calcium hydroxide, calcium hydrate, tween morphine alkaloid in opium and a
caustic lime, hydrated lime. Crystals or soft, odor- morphine brick (morphine hydrochloride). The
less, granules or powder, with a slightly bitter taste. base is formed as a precipitate (solid) when
Slightly soluble in water. Readily absorbs C02 from ammonium chloride is added to a solution of
air, forming CaC03. Used in industry to manufac- calcium morphenate. This base is usually quite
ture cement, pesticides, fertilizers, and in water crude (50% to 70% pure) because of the mar-
treatment. Normally packaged in tightly closed and ginal conditions under which it is prepared.
dry containers, such as wooden barrels or multiwall Morphine base is not easily soluble in water, and
paper sacks. Used as a reagent in the extraction of thus is not readily absorbed by the human body.
morphine from opium by forming an intermediate Morphine base must therefore be converted to a
calcium salt (calcium morphenate).
27
(water-soluble) salt fOIm. viz.• morphine hydro- illegally in Afghanistan. Burma. Colombia. Guate-
chloride or heroin hydrochloride. by treating mala. Iran. Laos, Lebanon. Mexico, Pakistan and
with hydrochloric acid. Thailand.
opium pong
A bitter. yellowish-brown, strongly-addictive natu-
rally-occurring narcotic derived from the dried latex A standard unit of weight used in Southeast Asia for
juice of the opium poppy, Papaver somniferum. opium only. Equivalent to 0.375 kilogram (13.23
Source of morphine and heroin. Opium poppy is ounces). Thai-Shan-Lao term. See Figure 7.
cultivated legally in India. Turkey. China. Common-
wealth of Independent States (formerly the Soviet
Union). and Tasmania. Australia; and is cultivated
28
poppy (opium poppy) precipitation processes, and the process of chemi-
cally converting heroin base to a soluble salt fonn of
An annual plant, Papaver somniferum, originally of heroin, generally heroin hydrochloride. Heroin pro-
Asia Minor, having grayish-green leaves and vari- cessing can also include the extraction of morphine
ously colored flowers. The sole source of opium. from opium, and may include other operations, such
as fIltering, drying, pressing, and packaging the
finished heroin product.
poppy pod
29
soda ash lua
swidden agriculture
30
DisTRIBUTION
Department of Justice
Federal Bureau of Investigation/DIU
Federal Bureau of Prisons
Immigration and Naturalization Service
INTERPOL/USNCB
Organized Crime Drug Enforcement Task
Forces
U.S. Marshals Service
Department of Defense
Defense Intelligence Agency
National Security Agency
Department of State
DEA Headquarters
DEA Field Offices
DEA Laboratories
31