Chemistry PDF

AN ROINN OIDEACHAIS AGUS EOLAÍOCHTA
L EAVING C ERTIFICATE
CHEMISTRY
SYLLABUS
(O RDINARY L EVEL AND H IGHER L EVEL )
LEAVING CERTIFICATE PROGRAMMES
Aims and Principles The Leaving Certificate (Established)

1. The general aim of education is to contribute The Leaving Certificate (Established) programme
towards the development of all aspects of the offers students a broad and balanced education
individual, including aesthetic, creative, critical, while allowing for some specialisation.
cultural, emotional, expressive, intellectual, for Syllabuses are provided in a wide range of sub-
personal and home life, for working life, for liv- jects. All subjects are offered at Ordinary and
ing in the community and for leisure. Higher levels. In addition, Mathematics and Irish
are also offered at Foundation level.
2. Leaving Certificate programmes are presented
within this general aim, with a particular empha- The certificate is used for purposes of selection
sis on the preparation of students for the into further education, employment, training and
requirements of further education or training, for higher education.
employment and for their role as participative,
enterprising citizens. The Leaving Certificate Vocational
Programme (LCVP)
3. All Leaving Certificate programmes aim to pro-
vide continuity with and progression from the The Leaving Certificate Vocational Programme is
Junior Certificate programme. The relative an intervention within the Leaving Certificate
weighting given to the various components — (Established). LCVP students study a minimum
e.g. personal and social (including moral and of five subjects (at Higher, Ordinary or
spiritual) development, vocational studies and Foundation levels), including Irish and two sub-
preparation for further education and for adult jects from specified vocational subject groupings.
and working life — within the programmes may They are also required to take a recognised
vary. course in a Modern European language, other
than Irish or English. In addition LCVP students
4. Programmes leading to the award of the Leaving take three Link Modules on Enterprise Education,
Certificate are of two years duration and are Preparation for Work and Work Experience.
offered in three forms:
In particular, the LCVP aims to foster in students
i. The Leaving Certificate (Established) a spirit of enterprise and initiative and to devel-
op their interpersonal, vocational and technolog-
ii. The Leaving Certificate Vocational Programme ical skills.
iii. The Leaving Certificate Applied The Leaving Certificate Applied

The Leaving Certificate Applied is a distinct, self-
5. All Leaving Certificate programmes, in contribut- contained Leaving Certificate programme. It is
ing to a high quality education, emphasise the designed for those students who do not wish to
importance of : proceed directly to third level education or for
those whose needs, aspirations and aptitudes
• self-directed learning and independent are not adequately catered for by the other two
thought Leaving Certificate programmes. The Leaving
Certificate Applied is structured around three
• a spirit of inquiry, critical thinking, problem main elements – Vocational Preparation,
solving, self-reliance, initiative and enterprise Vocational Education and General Education -
which are interrelated and interdependent. This
• preparation for further education, for adult programme is characterised by educational expe-
and working life riences of an active, practical and student-cen-
tred nature.
• lifelong learning.
LEAVING CERTIFICATE
CHEMISTRY
(ORDINARY AND HIGHER LEVEL)

• L E AV I N G C E R T I F I C AT E C H E M I S T R Y S Y L L A B U S •
Preamble
Policy Context
Science education in the senior cycle should reflect The three components should be integrated within
the changing needs of students and the growing each science syllabus, with the first component
significance of science for strategic development in having a 70% weighting. The remaining 30% should
Ireland. be allocated to the other two components in the ratio
3 to 1.
Leaving Certificate science syllabuses are designed to
incorporate the following components: The syllabuses, which are offered at two levels,
Higher and Ordinary, will have approximately 180
• science for the enquiring mind, or pure science, to
hours of class contact time over a two-year period.
include the principles, procedures and concepts of
They should be practically and experimentally based
the subject as well as its cultural and historical
in their teaching.
aspects
• science for action, or the applications of science

and its interface with technology
• science, which is concerned with issues – political,

social and economic – of concern to citizens.
CONTENTS
Introduction . . . . . . . . . . . . . . . . . . . . . . . 2
Ordinary Level Syllabus . . . . . . . . . . . 5 Higher Level Syllabus . . . . . . . . . . . . 35
Ordinary Level Objectives . . . . . . . . . . . . 6 Higher Level Objectives . . . . . . . . . . . . . 36
Ordinary Level Core Higher Level Core
1. Periodic Table and Atomic Structure . . . . . . . 7 1. Periodic Table and Atomic Structure . . . . . . .37
2. Chemical Bonding . . . . . . . . . . . . . . . . . . .10 2. Chemical Bonding . . . . . . . . . . . . . . . . . . .42
3. Stoichiometry, Formulas and Equations . . . .12 3. Stoichiometry, Formulas and Equations . . . .45
4. Volumetric Analysis . . . . . . . . . . . . . . . . . . .14 4. Volumetric Analysis . . . . . . . . . . . . . . . . . . .47
5. Fuels and Heats of Reaction . . . . . . . . . . . . .15 5. Fuels and Heats of Reaction . . . . . . . . . . . . .49
6. Rates of Reaction . . . . . . . . . . . . . . . . . . . .18 6. Rates of Reaction . . . . . . . . . . . . . . . . . . . .53
7. Organic Chemistry . . . . . . . . . . . . . . . . . . .19 7. Organic Chemistry . . . . . . . . . . . . . . . . . . .54
8. Chemical Equilibrium . . . . . . . . . . . . . . . . .24 8. Chemical Equilibrium . . . . . . . . . . . . . . . . .61
9. Environmental Chemistry: Water . . . . . . . . .25 9. Environmental Chemistry: Water . . . . . . . . .62
Ordinary Level: Option 1 Higher Level: Option 1
1A. Additional Industrial Chemistry . . . . . . . . . .27 1A. Additional Industrial Chemistry . . . . . . . . . .65
1B. Atmospheric Chemistry . . . . . . . . . . . . . . . .29 1B. Atmospheric Chemistry . . . . . . . . . . . . . . . .67
Ordinary Level: Option 2 Higher Level: Option 2
2A. Materials . . . . . . . . . . . . . . . . . . . . . . . . . . .31 2A. Materials . . . . . . . . . . . . . . . . . . . . . . . . . . .69
2B. Additional Electrochemistry and 2B. Additional Electrochemistry and

the Extraction of Metals . . . . . . . . . . . . . . . .32 the Extraction of Metals . . . . . . . . . . . . . . . .70
Appendix 1 . . . . . . . . . . . . . . . . . . . . . . . . 33 Appendix 2 . . . . . . . . . . . . . . . . . . . . . . . . 72
Mathematical Requirements at Ordinary and Higher Level . . . . . . . . . . . . . . . 73
1
Introduction
Aims
The aims of the syllabus, common to both levels, The syllabus is presented in four columns, giving
are:
(i) the content
• To stimulate and sustain students’ interest in,
(ii) the depth of treatment
and enjoyment of, chemistry
(iii) suitable activities
• To provide a relevant course for those students
who will complete their study of chemistry at (iv) references to relevant social and applied aspects,
this level where appropriate.
• To provide a foundation course in chemistry for The third column includes mandatory experiments
those students who will continue their studies in (twenty-one for Ordinary level and twenty-eight for
chemistry or in related subjects Higher level). These are numbered in order, within
sections, and each experiment has the same number
• To encourage an appreciation of the scientific,
in the Ordinary level syllabus as in the Higher level
social, economic, environmental and
syllabus.
technological aspects of chemistry and an
understanding of the historical development of The format in which the syllabus is presented does
chemistry not imply any particular order of teaching. Teaching
strategies should promote, in a positive manner, the
• To illustrate generally how humanity has
aims and objectives of the syllabus.
benefited from the study and practice of
chemistry The syllabus consists of approximately 70% pure
chemistry; the remaining 30% deals with the social
• To develop an appreciation of scientific method
and applied aspects of chemistry. All material within
and rational thought
the syllabus is examinable.
• To develop skills in laboratory procedures and
The syllabus is designed for 180 hours of class
techniques, carried out with due regard for
contact time (the equivalent of 270 class periods of
safety, together with the ability to assess the uses
40 minutes each, or five class periods per week). A
and limitations of these procedures
specific number of class periods for each sub-section
• To develop skills of observation, analysis, of the syllabus is recommended. At Ordinary level,
evaluation, communication and problem- 187 class periods in total are recommended for all the
solving. specific sub-sections of the syllabus; the remaining 83
class periods may be used for supplementary work,
Structure of the Syllabus including revision. At Higher level, 258 class periods
The syllabus consists of a core and options. Each in total are recommended for all the specific sub-
option is an expansion of material that is contained in sections of the syllabus, including time for revision.
the core. The entire Ordinary level syllabus is The remaining 12 class periods may be used for
presented first, followed by the entire Higher level supplementary work, including further revision.
syllabus. In both cases, an expanded syllabus format These specifications are intended only to indicate the
has been adopted. approximate amount of time needed.
2
Practical Work Assessment

In all experimental work, safety should be a major The syllabus will be assessed in relation to its
concern. Safety equipment, such as fume cupboards, objectives. All material within the syllabus is
safety glasses and pipette fillers, should be used where examinable. Practical work is an integral part of the
appropriate. The mandatory experiments included in study of chemistry; it will initially be assessed through
the syllabus must be carried out by the students. An the medium of the written examination paper. An
adequate record of their practical work must be element of practical assessment may be included as
retained for the period of the course. In addition, the part of the overall assessment at a later stage.
students’ practical work should be supplemented by
teacher demonstrations where indicated throughout
the syllabus. There should be an appreciation of the
errors inherent in an experiment and of the
precautions that can be taken to reduce such errors.
Students will be given full recognition for carrying

out mandatory experiments using computer
interfacing and other modern methods of computer-
aided technology. However, this is not obligatory.
Differentiation between Ordinary level

and Higher level
There are two main differences between Ordinary
level and Higher level:
(i) Range of topics
All the Ordinary level material, except mandatory

experiment 4.2A in the Ordinary level syllabus
(see page 14), forms part of the Higher level
syllabus. The Higher level syllabus contains
additional material. Ordinary level students will
study one option from 1A, 1B, 2A, or 2B. Higher
level students must study, in their entirety, either
Option 1 or Option 2.
(ii) Depth of treatment
The Ordinary level syllabus provides an overview

of chemistry and its applications to everyday life.
At Higher level, a deeper and more quantitative
treatment of chemistry is required.
3
4
LEAVING CERTIFICATE CHEMISTRY
ORDINARY LEVEL
SYLL ABUS
5
• L E AV I N G C E R T I F I C AT E C H E M I S T R Y O R D I N A R Y L E V E L S Y L L A B U S •
Ordinary Level Syllabus Objectives

The objectives of the syllabus are:
1. Knowledge 4. Competence
Students should have a knowledge of Students should be able to
• basic chemical terminology, facts, principles and • translate scientific information in verbal, graphical
methods and mathematical form
• scientific theory • organise chemical ideas and statements
• social, historical, environmental, technological and • report experimental procedures and results in a
economic aspects of chemistry. concise, accurate and comprehensible manner
• use chemical facts and principles to make

2. Understanding
qualitative chemical predictions
Students should understand
• perform simple chemical calculations
• how chemistry relates to everyday life
• discuss public issues relating to chemistry.
• scientific information in verbal, graphical and
mathematical form
5. Attitudes
• basic chemical principles Students should appreciate
• how chemical problems can be solved • advances in chemistry and their influence on our
lives
• how the scientific method applies to chemistry.
• that the understanding of chemistry contributes to
3. Skills the social and economic development of society
Students should be able to • the range of vocational opportunities that use
• follow instructions given in a suitable form chemistry, and how chemists work.
• perform experiments safely and co-operatively
• select and manipulate suitable apparatus to

perform specified tasks
• make accurate observations and measurements
• interpret experimental data and assess the accuracy

of experimental results.
6
CORE
1. PERIODIC TABLE AND ATOMIC STRUCTURE

Content Depth of Treatment Activities Social and Applied Aspects
1.1 Periodic Table

(Time needed: 4 class periods) Elements. Symbols of elements History of the idea of elements,
1–36. including the contributions of
the Greeks, Boyle, Davy and
Moseley.
The periodic table as a list of Arranging elements in order of History of the periodic table,
elements arranged so as to relative atomic mass; note including the contribution of
demonstrate trends in their differences compared with the Mendeleev.
physical and chemical modern periodic table. Comparison of Mendeleev's table
properties. with the modern periodic table.
Brief statement of the principal Demonstration of the reaction

resemblances of elements within with water of lithium, sodium
each main group, in particular and potassium.
alkali metals, alkaline earth
metals, halogens and noble gases.
1.2 Atomic Structure

(Time needed: 5 class periods) Matter is composed of particles, Very brief outline of the
which may be atoms, molecules historical development of atomic
or ions. theory (outline principles only;
mathematical treatment not
Atoms. Minute size of atoms. required): Dalton: atomic
Law of conservation of mass. theory; Thomson: negative
charge of the electron;
Rutherford: discovery of the
nucleus as shown by the
α–particle scattering
experiment; and Bohr: model of
the atom.
Properties of electrons, protons
and neutrons (relative mass,
relative charge, location within
atom).
Atomic number (Z ), mass number
(A), isotopes; hydrogen and
carbon as examples of isotopes.
Relative atomic mass (A r). The Use of the mass spectrometer

12C scale for relative atomic in determining relative atomic
masses. mass.
7
1. PERIODIC TABLE AND ATOMIC STRUCTURE (CONTINUED)

1.3 Radioactivity
(Time needed: 3 class periods) Alpha, beta and gamma Demonstration of properties – Historical outline of
radiation (nature and detection and penetrating radioactivity: work of Becquerel
penetrating ability). power (this can be shown using (discovery of radiation from
One example each of: an appropriate videotape, if uranium salts); Marie and
an α-emitter, e.g. 241Am desired). Pierre Curie (discovery of
a β-emitter, e.g. 14C (Principle of Geiger-Müller tube polonium and radium).
a γ-emitter, e.g. 60Co. not required.)
Widespread occurrence of
radioactivity.
Radioisotopes. Uses of radioisotopes (three

examples).
Half-life (non-mathematical 14C age determination

treatment). (calculations not required).
60Co for cancer treatment.

Food irradiation.
1.4 Electronic
Structure of Energy levels in atoms. Mandatory experiment 1.1* Sodium street lights, fireworks.
Atoms Organisation of particles in
(Time needed: 7 class periods) atoms of elements nos. 1–20
(numbers of electrons in each
main energy level).
Classification of the first twenty

elements in the periodic table
on the basis of the number of
outer electrons.
Atomic radii (covalent radii

only). Explanations for general
trends in values:
(i) down a group
(ii) across a period (covalent
radii of main group
elements only).
*Mandatory experiments are defined at the end of each section of the syllabus
8

1.4 Electronic Dependence of chemical

Structure of properties of elements on their
Atoms (continued) electronic structure.
Explanations in terms of atomic See mandatory experiment 1.2

radius, screening effect and below (reactivity of halogens).
nuclear charge for general
trends in properties of elements
in groups I and VII.
1.5 Oxidation and

Reduction Introduction to oxidation and Rusting of iron.
(Time needed: 7 class periods) reduction: simple examples only,
e.g. Na with Cl2, Mg with O2,
Zn with Cu2+. Oxidation and
reduction in terms of loss and
gain of electrons.
Oxidising and reducing agents. Swimming-pool water treatment.
The electrochemical series as a Mandatory experiment 1.2 Use of scrap iron to extract
series of metals arranged in (half equations only required, copper.
order of their ability to be e.g. 2Br– – 2e– → Br2).
oxidised (reactions, other than
displacement reactions, not
required).
Electrolysis of (i) copper sulfate Demonstration of ionic Electroplating.

solution with copper electrodes movement. Purification of copper.
and (ii) acidified water with Chrome and nickel plating.
inert electrodes. Cutlery.
Mandatory Experiments
1.1 Flame tests (Li, Na, K, Ba, Sr and Cu only).
1.2 Redox reactions of group VII elements: halogens as oxidising agents (reactions with bromides, iodides, Fe2+ and sulfites).
Displacement reactions of metals (Zn with Cu2+, Mg with Cu2+).
9
2. CHEMICAL BONDING
2.1 Chemical
Compounds Compounds. Simple chemical
(Time needed: 6 class periods) formulas.
Stability of noble gas electron Uses of helium and argon

configurations. related to their chemical
unreactivity.
Bonding and valency in terms Using the octet rule to predict
of the attainment of a stable the formulas of simple
electronic structure. Octet rule compounds – binary
and its limitations. compounds of the first 36
elements (excluding d-block
elements) and the hydroxides
and carbonates of these
elements (where such exist).
2.2 Ionic Bonding

(Time needed: 4 class periods) Positive and negative ions. Representation of ionic bonds
Minute size of ions. using dot and cross diagrams.
Ionic bonding as electron

transfer.
Sodium chloride crystal Examination of a model of the

structure. NaC1 crystal.
Characteristics of ionic Mandatory experiment 2.1 Ionic materials in everyday life

substances. (two uses, e.g. salt tablets to
replace salt lost by sweating).
2.3 Covalent Bonding

(Time needed: 4 class periods) Molecules. Minute size of
molecules.
Covalent bonding as the sharing Representation of covalent

of pairs of electrons. bonds using dot and cross
Single, double and triple diagrams.
covalent bonds.
Polar and non-polar covalent Polarity test for liquids (use of Polar and non-polar materials
bonding. charged plastic rod). in everyday life (two examples
of each).
Characteristics of covalent Testing solubility in different
substances. solvents of ionic and covalent
substances.
10
2. CHEMICAL BONDING (CONTINUED)

2.4 Electronegativity
(Time needed: 2 class periods) Electronegativity. Periodic
variation of electronegativity –
explanation for general trends
in values:
(i) down a group
(ii) across a period.
Electronegativity differences and Prediction of bond type using

polarity of bonds. electronegativity differences.
2.5 Shapes of
Molecules and Shapes of some simple Use of models or balloons to
Intermolecular molecules. illustrate molecular shapes.
Forces
(Time needed: 1 class period)
2.1 Tests for anions in aqueous solutions: chloride, carbonate, nitrate, sulfate.
11
3. STOICHIOMETRY, FORMULAS AND EQUATIONS

3.1 States of Matter

(Time needed: 1 class period) Motion of particles in solids,
liquids and gases.
Diffusion (Graham’s law not NH3 and HCl, ink and water,
required). smoke and air.
3.2 Gas Laws

(Time needed: 3 class periods) Boyle's law. Calculations not required. Boyle’s air pump.
Charles’s law. Calculations not required.
Combined gas law: Simple calculations, including

P1V1 P2V2 constant. correction of gas volumes to
= =
T1 T2 s.t.p. (units: Pa, cm3, K).
3.3 The Mole

(Time needed: 9 class periods) Avogadro constant. The mole as Calculation of relative molecular
the SI unit for amount of mass from relative atomic
substance containing the masses. Converting moles to
Avogadro number of particles. grams, litres and number of
Standard temperature and particles. Converting grams and
pressure (s.t.p.). Molar volume litres to moles.
at s.t.p., molar mass, relative
molecular mass (Mr).
Mandatory experiment 3.1
3.4 Chemical Formulas

(Time needed: 6 class periods) Empirical and molecular Calculations of empirical
formulas. formulas, given the percentage
composition by mass.
Calculation of molecular
formulas, given the empirical
formulas and the relative
molecular masses (examples
should include simple biological
substances, such as glucose and
urea).
Percentage composition by Calculations.

mass.
Structural formulas. Simple examples.
12
3. STOICHIOMETRY, FORMULAS AND EQUATIONS (CONTINUED)

3.5 Chemical
Equations Chemical equations. Balancing Simple examples.
(Time needed: 9 class periods) chemical equations.
Calculations based on balanced Calculations in g and kg rather

equations using the mole than tonnes. Calculations
concept (balanced equations will involving masses and volumes.
be given for all calculations).
3.1 Determination of the relative molecular mass of a volatile liquid (conical flask or gas syringe may be used).
13
4. VOLUMETRIC ANALYSIS
4.1 Concentration of
Solutions Solutions.
(Time needed: 6 class periods) Expression of solution Calculation of molarity from
concentration in mol l–1 concentration in grams per litre
(molarity), g l–1 and also in and vice versa. Calculation of
% (v/v). number of moles from molarity Use of % (v/v), e.g. wine.
and volume.
Colour intensity as a function
of concentration (simple
treatment only).
Primary standards.
Standard solutions. Mandatory experiment 4.1
4.2 Acids and Bases

(Time needed: 3 class periods) Acids, bases and salts. Household acids and bases (two
Neutralisation – formation of a examples of each). Everyday
salt from an acid and a base. examples of neutralisation, e.g.
use of lime in agriculture, use
Arrhenius theory of acids and of stomach powders for acid
bases (for aqueous solutions indigestion.
only).
4.3 Volumetric
Analysis Apparatus used in volumetric
(Time needed: 10 class periods) analysis.
Correct titrimetric procedure. Solving volumetric problems,
Acid-base titrations. using the formula method.
(Balanced equations will be
given in all volumetric
problems.)
Mandatory experiment 4.2A
4.1 Preparation of standard solution of sodium carbonate.
4.2 Standardisation of a hydrochloric acid solution using a standard solution of sodium carbonate.
4.2A A hydrochloric acid/sodium hydroxide titration, and the use of this titration in making the salt sodium chloride.
14
5. FUELS AND HEATS OF REACTION

5.1 Sources of
Hydrocarbons Coal, natural gas and petroleum Decomposition of animal waste
(Time needed: 1 class period) as sources of hydrocarbons. and vegetation as methane
sources. Hazards of methane
production in slurry pits, coal
mines and refuse dumps.
Methane as a contributor to
the greenhouse effect.
5.2 Structure of
Aliphatic Alkanes, alkenes and alkynes as
Hydrocarbons homologous series. For alkynes,
(Time needed: 5 class periods) only ethyne to be considered.
Systematic names, structural Use of models.
formulas and structural isomers
of alkanes to C-5.
Structures, but not isomers, of
hexane, heptane, octane,
cyclohexane and 2,2,4-
trimethylpentane (iso-octane) to
be considered.
of alkenes to C-4.
Physical properties [physical Demonstration of the solubility

state, solubility (qualitative properties of methane, ethene
only) in water and in non-polar and ethyne.
solvents].
5.3 Aromatic
Hydrocarbons Structure of benzene, Use of models. See aromatic compounds
(Time needed: 1 class period) methylbenzene and ethylbenzene (page 20).
as examples of aromatic
compounds.
state, solubility (qualitative properties of methylbenzene.
only) in water and in non-polar
solvents].
15
5. FUELS AND HEATS OF REACTION (CONTINUED)

5.4 Exothermic and

Endothermic Chemical reactions can result in Demonstration of an exothermic
Reactions a change in temperature. and an endothermic reaction.
(Time needed: 5 class periods) Exothermic and endothermic
reactions (and changes of
state).
Combustion of alkanes and

other hydrocarbons.
Heat of reaction (general term). Mandatory experiment 5.1
Sign of ∆H.
Heat of combustion. Bomb Use of the bomb calorimeter in

calorimeter as an instrument determining calorific values of
for accurately measuring heats foods.
of combustion. Heats of Kilogram calorific values of
combustion of different fuels. fuels, and their uses
(calculations not required).
5.5 Oil Refining and
its Products Fractionation of crude oil.
(Time needed: 4 class periods)
Production of the refinery gas, Uses of the refinery gas, light
light gasoline, naphtha, gasoline, naphtha, kerosene, gas
kerosene, gas oil and residue oil and residue fractions.
fractions.
Composition of natural gas and
liquid petroleum gas (LPG).
Addition of mercaptans to
natural gas for safety reasons.
Composition of petrol.
Auto-ignition. Octane numbers

as a measure of the tendency
of a fuel to cause knocking.
Lead in petrol.
Alternatives to lead:
improving octane number by
(i) isomerisation
(ii) dehydrocyclisation
(iii) catalytic cracking.
16

5.6 Other Chemical

Fuels Ethyne: preparation, Mandatory experiment 5.2 Oxyacetylene welding and
(Time needed: 3 class periods) combustion, tests for (equations and structures of cutting.
unsaturation. products not required for the
tests for unsaturation).
Hydrogen: manufacture by Industrial uses. Potential as a

(i) electrolysis of water fuel.
(ii) steam reforming of natural
gas (simple treatment
only).
5.1 Determination of the heat of reaction of hydrochloric acid with sodium hydroxide.
5.2 Preparation and properties of ethyne [combustion, tests for unsaturation using bromine water and acidified potassium
manganate(VII) solution].
17
6. RATES OF REACTION
6.1 Reaction Rates

(Time needed: 3 class periods) Rate of reaction. Mandatory experiment 6.1
Plotting and simple

interpretation of reaction rate
graphs.
6.2 Factors Affecting

Rates of Reaction Concentration. Particle size. Demonstration of the effects on Dust explosions.
(Time needed: 7 class periods) reaction rate of
Temperature. (i) particle size
(ii) catalysts. Enzymes as catalysts produced
by living cells (two examples).
Nature of reactants. Catalysts. Catalytic converters:

(i) nature of catalysts
(ii) reactions catalysed
(iii) environmental benefits.
Catalyst poisons.
Demonstration of the oxidation

of methanol using a hot
platinum or nichrome catalyst.

of potassium sodium tartrate by
hydrogen peroxide, catalysed by
cobalt(II) salts.
6.1 Monitoring the rate of production of oxygen from hydrogen peroxide, using manganese dioxide as a catalyst.
6.2 Studying the effects on the reaction rate of (i) concentration and (ii) temperature, using sodium thiosulfate solution and hydrochloric
acid.
18
7. ORGANIC CHEMISTRY
7.1 Tetrahedral
Carbon Saturated organic compounds. Use of models, as appropriate.
Alkanes. Use as fuels.
Alcohols: structure and Comparison of structure with Ethanol as a solvent.

nomenclature up to C-4 water. Fermentation as a source of
(primary and secondary alcohols ethanol; use of fermentation in
only). Physical properties Solubility of (a) methanol and the brewing and distilling
[physical state, solubility (b) butan-1 -ol in industries.
(qualitative only) in water and (i) cyclohexane and (ii) water. Methanol as a denaturing
in non-polar solvents]. agent.
7.2 Planar Carbon

(Time needed: 9 class periods) Unsaturated organic compounds. Use of models, as appropriate.
Alkenes: non-polar double bond. Use in making plastics.

Structure and nomenclature up
to C-4.
Carbonyl compounds (aldehydes Solubility of ethanal in

only): polar double bond. (i) cyclohexane and (ii) water.
to C-4.
Physical properties [physical

state, solubility (qualitative
solvents].
Carboxylic acids: polar double Solubility of ethanoic acid in Methanoic acid in nettles and
bond. Structure and (i) cyclohexane and (ii) water. ants; ethanoic acid in vinegar.
nomenclature up to C-4.
Physical properties [physical Mandatory experiment 7.1

solvents].
Simple explanation of the use

of the circle to represent the
identical bonds in benzene,
intermediate between double
and single.
19
7. ORGANIC CHEMISTRY (CONTINUED)

7.2 Planar Carbon Aromatic compounds. Solubility of methylbenzene in Use of methylbenzene as an

(continued) (i) cyclohexane and (ii) water. industrial solvent.
An indication of the range and Inspect structural formulas of a Aromatic compounds form the
scope of aromatic chemistry range of consumer products to basis of dyestuffs, detergents,
(structures not required). show the presence of benzene herbicides and many
rings. pharmaceutical compounds (one
example in each case;
structures not required).
Aromatic acid-base indicators:
phenolphthalein, methyl orange
(structures not required).
Carcinogenic nature of some

aromatic compounds, e.g.
benzene. Not all aromatic
compounds are carcinogenic,
e.g. aspirin (structure of aspirin
not required).
7.3 Organic Chemical

Reaction Types Students are not, in general,
(Time needed: 14 class periods) required to know the conditions
(temperature, pressure, catalyst,
solvent) for these reactions,
except where specified
elsewhere in the syllabus. They
are required to be able to
write balanced equations for
the reactions, using structural
formulas, unless otherwise
indicated.
(a) Addition reactions

Alkenes – reactions with Industrial sources.
hydrogen, chlorine, bromine, Industrial importance of
water and hydrogen chloride. (i) products of the addition
reactions of ethene with
chlorine, bromine, water and
hydrogen chloride
(ii) hydrogenation of vegetable
oils.
20

7.3 Organic Chemical Polymerisation reaction (of Alkenes as raw materials in the
Reaction Types ethene and propene only – industrial manufacture of
(continued) reaction mechanism not plastics.
required).
Unreactivity of benzene with An indication of the range and

regard to addition reactions, scope of the petrochemical
relative to ethene. industry (two examples of
synthetic products of this
industry; structures not
required, unless specified
elsewhere in the syllabus).
(b) Substitution
reactions
Halogenation of alkanes.
Mandatory experiment 7.2 Soap manufacture.
(c) Elimination
reactions
Dehydration of alcohols. Mandatory experiment 7.3
(equations and structures of
products not required, unless
specified elsewhere in the
syllabus).
(d) Redox reactions

Alcohols:
Oxidation using KMnO4 or Mandatory experiment 7.4 Ethanal formation in the
Na2Cr2O7 to (i) aldehydes and metabolism of ethanol in the
(ii) acids (half equations only human body.
required).
Oxidation of aldehydes to acids Mandatory experiment 7.5

(half equations only required).
Combustion – a reaction
common to most organic
compounds.
Combustion of alcohols. Alcohols as motor fuels.
Non-flammability of fully Flame retardants, fire

halogenated alkanes. extinguishers.
21

7.3 Organic Chemical (e) Reactions as acids

Reaction Types Reactions of alcohols with
(continued) sodium.
Reactions of carboxylic acids

with magnesium, with sodium
hydroxide and with sodium
carbonate.
(f) Organic synthesis:

principles and
examples
Chemical synthesis involves Useful products of organic
(i) bond breaking and synthesis (two examples, e.g.
(ii) bond forming. aspirin, paracetamol; structures
and synthetic routes not
required).
Example of organic synthesis:
PVC from ethene (structures
and synthetic route required).
7.4 Organic Natural

Products Extraction techniques, e.g. Mandatory experiment 7.6 An indication of the range and
(Time needed: 4 class periods) solvent extraction, steam scope of organic natural
distillation. product chemistry (two
examples of useful organic
natural products; structures not
required).
7.5 Chromatography
and Instrumentation Chromatography as a separation Mandatory experiment 7.7 Use of thin-layer
in Organic Chemistry technique in which a mobile chromatography (TLC) in the
(Time needed: 3 class periods) phase carrying a mixture is separation of dyes taken from
caused to move in contact with fibres in forensic work.
a selectively absorbent GC and HPLC as more
stationary phase. advanced separation techniques.
22

7.5 Chromatography Instrumental methods of Examples of uses:

and Instrumentation separation or analysis, or both:
in Organic Chemistry
(continued) Mass spectrometry (cf.1.2, Analysis of (i) gases from a
(Time needed: 3 class periods) page 7). waste dump and (ii) trace
organic pollutants in water.
Gas chromatography (GC). Drug tests on athletes; blood

alcohol tests.
High-performance liquid Growth-promoters in meat;

chromatography (HPLC). vitamins in foods.
Brief reference to the principles

of each method. Interpretation
of spectra etc. not required. (It
should be noted that these
techniques are applicable not
only to organic chemistry but
also to many other areas of
chemistry.)
7.1 Recrystallisation of benzoic acid and determination of its melting point.
7.2 Preparation of soap.
7.3 Preparation and properties of ethene [combustion, tests for unsaturation using acidified potassium manganate(VII) solution and bromine
water].
7.4 Preparation and properties of ethanal [properties limited to reactions with (i) acidified potassium manganate(VII) solution, (ii) Fehling’s
reagent and (iii) ammoniacal silver nitrate].
7.5 Preparation and properties of ethanoic acid (properties limited to reactions with sodium carbonate and magnesium).
7.6 Extraction of clove oil from cloves (or similar alternative) by steam distillation.
7.7 Separation of a mixture of indicators using paper chromatography or thin-layer chromatography or column chromatography.
23
8. CHEMICAL EQUILIBRIUM
8.1 Chemical
Equilibrium Reversible reactions – dynamic
(Time needed: 4 class periods) equilibrium. At equilibrium, the
rate of the forward reaction
equals the rate of the reverse
reaction.
Equilibrium law and constant

(K c only).
8.2 Le Chatelier’s
Principle Le Chatelier’s principle. Mandatory experiment 8.1 Industrial application of Le
(Time needed: 5 class periods) Effect (if any) on equilibrium Chatelier’s principle in the
position of concentration, catalytic oxidation of sulfur
pressure, temperature and dioxide to sulfur trioxide and
catalyst. in the Haber process.
8.1 Simple experiments to illustrate Le Chatelier’s principle:
(i) CoC142– + 6H20 Co(H20)62+ + 4C1– (to demonstrate the effects of both temperature changes and concentration
changes on an equilibrium mixture).
(ii) Cr2O7 + H2O
2–
(iii) Fe3+ + CNS–

2CrO4 + 2H
2–
Fe(CNS)2+
+
} (to demonstrate the effects of concentration changes on an equilibrium mixture).
24
9. ENVIRONMENTAL CHEMISTRY: WATER

It is strongly recommended that students visit a water treatment plant – industrial or municipal.
9.1 pH Scale
(Time needed: 4 class periods) pH scale. Use of universal
indicator paper or solution.
Limitations of the pH scale –
usefulness confined to dilute
aqueous solutions.
Calculation of pH of dilute
aqueous solutions of strong
acids and bases (calculation of
pH of mixtures of strong acids
and bases not required).
9.2 Hardness in Water

(Time needed: 3 class periods) Hardness in water.
Causes of temporary and Tests on scale deposits in a Removal of hardness by boiling

permanent hardness. kettle. and ion exchange.
Deionisation.
9.3 Water Treatment

(Time needed: 4 class periods) Water treatment –
sedimentation, flocculation,
filtration, chlorination,
fluoridation and pH adjustment.
Sewage treatment (primary, e.g.

settlement, screening; secondary,
e.g. bacterial breakdown;
tertiary, i.e. reduction of level
of phosphates and nitrates).
Cost of tertiary treatment.
The role of nutrients in the Awareness that there are EU

eutrophication of water. limits for various chemical
species in water (two examples,
e.g. nitrates, phosphates,
specific metal ions).
25
9. ENVIRONMENTAL CHEMISTRY: WATER (CONTINUED)

9.4 Water Analysis

(Time needed: 6 class periods) Instrumental methods of Examples of uses:
analysis:
pH meter Analysis of river and lake

water.
Colorimetry Mandatory experiment 9.1 Analysis of (i) lead in water
and (ii) fertilisers.
Brief reference to principles of
each method.
Tests for anions (cf. mandatory Mandatory experiment 9.2

experiment 2.1).
Organic chemical pollutants, e.g.
sewage, industrial waste, silage,
milk.
9.1 Colorimetric experiment to estimate free chlorine in swimming-pool water or bleach (using a colorimeter or a comparator).
9.2 Determination of total suspended and total dissolved solids (expressed as p.p.m.) by filtration and evaporation respectively.
Determination of pH.
26
Options: Ordinary level students to choose ONE from

options 1A, 1B, 2A and 2B.
OPTION 1A: ADDITIONAL INDUSTRIAL CHEMISTRY

It is strongly recommended that students visit a particulat local chemical plant. This visit should be a structured one.
1A.1 General Principles

(Time needed: 4 class periods) Batch, continuous and semi-
continuous industrial chemical
processes.
Characteristics of effective and See above. Awareness of the contributions

successful industrial chemical of chemistry to society, e.g.
processes, such as provision of pure water, fuels,
metals, medicines, detergents,
(i) feedstock (raw materials, enzymes, dyes, paints,
preparation) semiconductors, liquid crystals
(ii) rate (temperature and and alternative materials such
pressure variables, catalyst) as plastics and synthetic fibres;
increasing crop yields by the
(iii) product yield (temperature
use of fertilisers, herbicides and
and pressure variables,
pesticides; food-processing.
catalyst)
(iv) co-products (separation,
disposal or sale)
(v) waste disposal and effluent
control (waste water
treatment, emission control)
(vi) quality control
(vii) safety (location of site, on-
site training, monitoring of
hazards, safety features)
(viii)costs (fixed costs, variable
costs; cost reduction by use
of heat exchangers,
catalysts, recycling and
selling of useful co-
products; costs of waste
disposal)
(ix) site location
(x) suitable materials for the
construction of chemical
plant (unreactive, resistant
to corrosion).
27
OPTION 1A: ADDITIONAL INDUSTRIAL CHEMISTRY (CONTINUED)
1A.2 Case Study

(Time needed: 5 class periods) A case study based on the Irish Awareness of the range and
chemical industry. ONE of the scope of the Irish chemical
three following processes should industry (two examples of
be studied, using the principles products produced by this
outlined in 1A.1 as far as they industry, other than those
are relevant to the process: referred to in the case study
chosen).
(a) Ammonia manufacture from
natural gas, water vapour and
air, and its conversion to urea.
Equation required for ammonia
formation.
(b) Nitric acid manufacture

from ammonia, and its use to
make fertilisers. Equation
required for oxidation of
nitrogen monoxide.
(c) Magnesium oxide Use of magnesium oxide as a

manufacture from sea water. heat-resistant material in the
Equation required for formation walls of furnaces.
of magnesium oxide.
28
OPTION 1B: ATMOSPHERIC CHEMISTRY

1B.1 Oxygen
(Time needed: 1 class period) Manufacture of oxygen using Uses of oxygen and of liquid
liquefaction and fractional nitrogen (two examples in each
distillation of air. case).
1B.2 Nitrogen
(Time needed: 1 class period) Structure and inertness. Any two uses, e.g. keeping
foods fresh, flushing out
Atmospheric abundance. dangerous vapours from oil
tankers.
Natural fixation of nitrogen;
nitrogen and oxygen in an
electric discharge.
Nitrogen cycle.
1B.3 Carbon Dioxide

(Time needed: 3 class periods) Combustion of carbon to give
carbon monoxide and carbon
dioxide.
Carbon monoxide as a neutral Carbon monoxide as a poison.

oxide. Carbon monoxide in cigarette
smoke and vehicle exhaust
fumes.
Carbon dioxide as an acidic Demonstration of the effect of
oxide. carbon dioxide on universal
indicator solution.
Fermentation in ethanol Carbon dioxide in carbonated
production as a source of drinks.
carbon dioxide.
The carbon cycle. The greenhouse effect and the

influence of human activity on
it.
Greenhouse gases and their
relative effects (especially
carbon dioxide and water
vapour).
Reduction of atmospheric
carbon dioxide levels by
dissolving in the ocean.
Possible implications of the
increased greenhouse effect.
29
OPTION 1B: ATMOSPHERIC CHEMISTRY (CONTINUED)

1B.4 Atmospheric
Pollution Oxides of nitrogen and sulfur:
(Time needed: 2 class periods) sources of pollution (natural,
domestic, industrial, internal
combustion engine).
Dissolving of nitrogen dioxide Demonstration of the effect of Acid rain and its effects on the
and sulfur dioxide to form sulfur dioxide on universal environment. Scrubbing of waste
acids. indicator solution. gases using limestone.
1B.5 The Ozone Layer

(Time needed: 2 class periods) Chloroalkanes: preparation from Chlorofluorocarbons and the
alkanes, e.g. chlorination of ozone layer.
methane.
Formation of ozone in the
stratosphere.
Beneficial effect of the ozone
layer.
CFCs and HCFCs. Uses of CFCs.
CFCs are believed to be the

main cause of damage to the
ozone layer.
Effects of damage to the ozone

layer.
30
OPTION 2A: MATERIALS

2A.1 Crystals
(Time needed: 3 class periods) Ionic, molecular, metallic and Use of models. Contributions of
covalent macromolecular crystals (i) Braggs: development of the
– physical properties related to X-ray technique for determining
the crystal binding forces. crystal structure;
Crystal structure is determined (ii) Dorothy Hodgkin:
by scattering of X-rays by the determination of the crystal
crystal (non-mathematical structure of complex organic
treatment only). molecules, e.g. vitamin B12,
penicillin (structures not
required).
The discovery of
buckminsterfullerene (structure
not required).
2A.2 Addition
Polymers Addition polymers. Monomers.
Polymerisation of alkenes: Demonstration of physical The industrial and domestic
poly(ethene) (low-density), properties (density, flexibility, importance and advantages of
poly(chloroethene), hardness) of poly(ethene), these polymers in plastics and
poly(phenylethene). poly(chloroethene) and fibres (two examples of uses of
poly(phenylethene). each polymer).
Brief history of the discovery of

low-density poly(ethene).
Recycling of plastics, exemplified

by the recycling of polystyrene
(stages: sorting, shredding,
washing, drying and re-extrusion).
2A.3 Metals
(Time needed: 1 class period) Comparison between metals and
non-metals (hardness, lustre,
malleability, ductility, heat
conductivity and electrical
conductivity).
Alloys. Carbon in steel and hardness.
31
OPTION 2B: ADDITIONAL ELECTROCHEMISTRY AND THE EXTRACTION OF METALS

2B.1 The Electrochemical

Series Different combinations of metals Contributions of Galvani, Volta,
(Time needed: 1 class period) produce different voltages in a Davy and Faraday.
simple cell.
The electrochemical series

(reactions of metals with acids,
water and oxygen not
required).
2B.2 Electrolysis of
Molten Salts Electrolysis of molten lead
(Time needed: 1 class period) bromide, using inert electrodes.
2B.3 Corrosion
(Time needed: 1 class period) Corrosion of metals. Relative Corrosion prevention
corrodibility of metals. (application of a protective
layer on a metal: galvanising
and surface coating).
2B.4 Strongly
Electropositive Extraction by electrochemical Uses (two examples in each
Metals (Na and methods. case).
Al)
(Time needed: 2 class periods) Recycling of aluminium.
2B.5 d-Block Metals

(Time needed: 4 class periods) Transition elements: general
chemical properties (colour, use
as catalysts).
Manufacture of iron (blast Uses of iron and steel (two

furnace – chemical aspects) examples in each case).
and steel. Steels as alloys of
iron.
Electric arc process for steel Environmental aspects of iron

manufacture (outline of main and steel production.
stages).
32
APPENDIX 1
Only the systematic names for organic compounds will be used on examination papers, except where the traditional
name continues to enjoy widespread use, particularly in industrial and everyday life. In these cases, the traditional
name will also be given in parentheses immediately after the systematic name. Knowledge of these traditional names
is not examinable. A representative list of such compounds follows: EAVING L C
ERTIFICATE
CHEMISTRY
Systematic Name Traditional Name

ethanal acetaldehyde
ethanoic acid acetic acid
ethyne acetylene
ethanol ethyl alcohol
ethene ethylene
2,2,4-trimethylpentane iso-octane
chloromethane methyl chloride
poly(ethene) polyethylene
poly(phenylethene) polystyrene
poly(chloroethene) polyvinyl chloride
methylbenzene toluene
The systematic names for inorganic compounds are not required.
33
34
LEAVING CERTIFICATE CHEMISTRY
HIGHER LEVEL
SYLL ABUS
35
• L E AV I N G C E R T I F I C AT E C H E M I S T R Y H I G H E R L E V E L S Y L L A B U S •
Higher Level Syllabus Objectives

The objectives of the syllabus are:
1. Knowledge 4. Competence
Students should have a knowledge of Students should be able to
• basic chemical terminology, facts, principles and • translate scientific information in verbal, graphical
methods and mathematical form
• scientific theories and their limitations • organise chemical ideas and statements and write
clearly about chemical concepts and theories
• social, historical, environmental, technological and
economic aspects of chemistry. • report experimental procedures and results in a
concise, accurate and comprehensible manner
2. Understanding
• explain both familiar and unfamiliar phenomena
Students should understand
by applying known laws and principles
• how chemistry relates to everyday life
• use chemical facts and principles to make chemical
• scientific information in verbal, graphical and predictions
mathematical form
• perform simple chemical calculations
• basic chemical principles
• identify public issues and misconceptions relating
• how chemical problems can be solved to chemistry and analyse them critically.
• how the scientific method applies to chemistry.

5. Attitudes
Students should appreciate
3. Skills
Students should be able to • advances in chemistry and their influence on our
lives
• follow instructions given in a suitable form
• that the understanding of chemistry contributes to
• perform experiments safely and co-operatively the social and economic development of society
• select and manipulate suitable apparatus to • the range of vocational opportunities that use
perform specified tasks chemistry, and how chemists work.
• make accurate observations and measurements
• interpret experimental data and assess the accuracy

of experimental results.
36
CORE
(Black text is for Higher level only.)
1. PERIODIC TABLE AND ATOMIC STRUCTURE

1.1 Periodic Table

(Time needed: 3 class periods) Elements. Symbols of elements History of the idea of elements,
1–36. including the contributions of
the Greeks, Boyle, Davy and
Moseley.
The periodic table as a list of Arranging elements in order of History of the periodic table,
elements arranged so as to relative atomic mass; note including the contributions of
demonstrate trends in their differences compared with the Dobereiner, Newlands,
physical and chemical modern periodic table. Mendeleev and Moseley.
properties. Comparison of Mendeleev’s table
with the modern periodic table.
Brief statement of the principal Demonstration of the reaction
resemblances of elements within with water of lithium, sodium
each main group, in particular and potassium.
alkali metals, alkaline earth
metals, halogens and noble
gases.
1.2 Atomic Structure

(Time needed: 6 class periods) Matter is composed of particles, Very brief outline of the historical
which may be atoms, molecules development of atomic theory
or ions. (outline principles only;
mathematical treatment not
Atoms. Minute size of atoms. required): Dalton: atomic theory;
Law of conservation of mass. Crookes: vacuum tubes, cathode
rays; Stoney: naming of the
electron; Thomson: negative
charge of the electron; e/m for
electrons (experimental details not
required); Millikan: magnitude of
charge of electrons as shown by
oil drop experiment (experimental
details not required); Rutherford:
Properties of electrons, protons discovery of the nucleus as shown
and neutrons (relative mass, by the α−particle scattering
relative charge, location within experiment; discovery of protons
atom). in nuclei of various atoms; Bohr:
model of the atom; Chadwick:
discovery of the neutron.
37

1.2 Atomic Structure Atomic number (Z ), mass

(continued) number (A ), isotopes; hydrogen
and carbon as examples of
isotopes.
Relative atomic mass (A r). The Calculation of approximate Use of the mass spectrometer
12C scale for relative atomic relative atomic masses from in determining relative atomic
masses. abundance of isotopes of given mass.
mass number (e.g. calculation Fundamental processes that
of approximate relative atomic occur in a mass spectrometer:
mass of chlorine). vaporisation of substance,
production of positive ions,
acceleration, separation,
detection (mathematical
treatment excluded).
1.3 Radioactivity
(Time needed: 2 class periods) Alpha, beta and gamma Demonstration of properties – Historical outline of
radiation (nature and detection and penetrating radioactivity: work of Becquerel
penetrating ability). power (this can be shown using (discovery of radiation from
One example each of: an appropriate videotape, if uranium salts); Marie and
an α-emitter, e.g. 241Am desired). Pierre Curie (discovery of
a β-emitter, e.g. 14C (Principle of Geiger-Müller tube polonium and radium).
a γ-emitter, e.g. 60Co. not required.)
Widespread occurrence of
radioactivity.
Distinction between chemical
reaction and nuclear reaction
(simple equations required –
confine examples to alpha and
beta emissions).
Radioisotopes. Uses of radioisotopes (three

examples).
Half-life (non-mathematical 14C age determination

treatment). (calculations not required).
60Co for cancer treatment.

Food irradiation.
38

1.4 Electronic
Structure of Energy levels in atoms.
Atoms Organisation of particles in
(Time needed: 11 class periods) atoms of elements nos. 1–20
(numbers of electrons in each
main energy level).
Classification of the first twenty

elements in the periodic table
on the basis of the number of
outer electrons.
Emission and absorption spectra Mandatory experiment 1.1* Atomic absorption spectrometry
of the hydrogen atom – (AAS). Sodium street lights,
Balmer series in the emission fireworks.
spectrum as an example.
Line spectra as evidence for Viewing of emission spectra of

energy levels. elements using a spectroscope
or a spectrometer.
Energy sub-levels.
Heisenberg uncertainty principle.

Wave nature of the electron.
(Non-mathematical treatment in
both cases.)
Atomic orbitals. Shapes of s

and p orbitals.
Building up of electronic
structure of the first 36
elements.
Electronic configurations of ions

of s- and p-block elements
only. Arrangement of electrons
in individual orbitals of p-block
atoms.
*Mandatory experiments are defined at the end of each section of the syllabus.
39
1. PERIODIC TABLE AND ATOMIC STRUCTURE (C0NTINUED)

1.4 Electronic Atomic radii (covalent radii

Structure of only). Explanations for general
Atoms (continued) trends in values:
(i) down a group
(ii) across a period (covalent
radii of main group
elements only).
First ionisation energies.

Explanations for general trends
in values:
(i) down a group
(ii) across a period (main
group elements) and for
exceptions to the general
trends across a period.
Second and successive ionisation

energies.
Evidence for energy levels

provided by successive
ionisation energy values.
1.4 Electronic Dependence of chemical

Structure of properties of elements on their
Atoms (continued) electronic structure.
Explanations in terms of atomic See mandatory experiment 1.2

radius, screening effect and below (reactivity of halogens).
nuclear charge for general
trends in properties of elements
in groups I and VII.
40

1.5 Oxidation and

Reduction Introduction to oxidation and Rusting of iron.
(Time needed: 7 class periods) reduction: simple examples only,
e.g. Na with Cl2, Mg with O2,
Zn with Cu2+. Oxidation and
reduction in terms of loss and
gain of electrons.
Oxidising and reducing agents. Swimming-pool water treatment.
The electrochemical series as a Mandatory experiment 1.2 Use of scrap iron to extract
series of metals arranged in (half equations only required, copper.
order of their ability to be e.g. 2Br– – 2e– → Br2).
oxidised (reactions, other than
displacement reactions, not
required).
Electrolysis of (i) copper sulfate Demonstration of ionic Electroplating.

solution with copper electrodes movement. Purification of copper.
and (ii) acidified water with Demonstration of electrolysis of Chrome and nickel plating.
inert electrodes. (Half equations aqueous sodium sulfate (using Cutlery.
only required.) universal indicator) and of
aqueous potassium iodide (using
phenolphthalein indicator) with
inert electrodes. (Half equations
only required.)
1.1 Flame tests (Li, Na, K, Ba, Sr and Cu only).
1.2 Redox reactions of group VII elements – halogens as oxidising agents (reactions with bromides, iodides, Fe2+ and sulfites).
Displacement reactions of metals (Zn with Cu2+, Mg with Cu2+).
41
2. CHEMICAL BONDING
2.1 Chemical
Compounds Compounds. Simple chemical
(Time needed: 5 class periods) formulas.
Stability of noble gas electron Uses of helium and argon

configurations. related to their chemical
unreactivity.
Bonding and valency in terms Using the octet rule to predict
of the attainment of a stable the formulas of simple
electronic structure. Octet rule compounds – binary compounds
and its limitations. of the first 36 elements
(excluding d-block elements) and
the hydroxides, carbonates,
nitrates, hydrogencarbonates,
sulfites and sulfates of these
elements (where such exist).
Variable valency of transition
elements (Cu, Fe, Cr and Mn only).
2.2 Ionic Bonding
(Time needed: 4 class periods) Positive and negative ions. Representation of ionic bonds
Minute size of ions. using dot and cross diagrams.
Ionic bonding as electron transfer.
Sodium chloride crystal structure. Examination of a model of the

NaCl crystal.
Characteristics of ionic
substances. Mandatory experiment 2.1 Ionic materials in everyday life
(two uses, e.g. salt tablets to
replace salt lost by sweating).
2.3 Covalent Bonding
(Time needed: 4 class periods) Molecules. Minute size of
molecules.
Covalent bonding as the sharing Representation of covalent bonds

of pairs of electrons. Single, using dot and cross diagrams.
double and triple covalent
bonds. Distinction between
sigma and pi bonding.
Polar and non-polar covalent Polarity test for liquids (use of Polar and non-polar materials
bonding. charged plastic rod). in everyday life (two examples
of each).
Characteristics of covalent Testing solubility in different
substances. solvents of ionic and covalent
substances.
42

2.4 Electronegativity
(Time needed: 2 class periods) Electronegativity. Periodic
variation of electronegativity –
explanation for general trends
in values:
(i) down a group
(ii) across a period.
Electronegativity differences and Prediction of bond type using

polarity of bonds. electronegativity differences.
2.5 Shapes of
Molecules and Shapes of some simple Use of models or balloons to
Intermolecular molecules. illustrate molecular shapes.
Forces
(Time needed: 5 class periods) Using electron pair repulsion
theory to explain shapes of
molecules of type ABn for up
to four pairs of electrons
around the central atom (refer
to bond angles). (Shapes of
molecules with pi bonds not to
be considered.) Relationship
between symmetry and polarity
in a molecule (dipole moments
not required).
Distinction between
intramolecular bonding and
intermolecular forces.
Intermolecular forces: van der
Waals’, dipole-dipole, hydrogen
bonding. Effect of the Comparison of the boiling
intermolecular forces on the points of H2 and O2, of C2H4
boiling point of a covalent and HCHO, and of H2O and
substance. H2S.
43

2.6 Oxidation
Numbers Oxidation states and numbers. Calculation of oxidation
(Time needed: 5 class periods) Rules for oxidation numbers numbers of transition metals
(exclude peroxides, except for (in their compounds). Use of
hydrogen peroxide). oxidation numbers in
nomenclature of transition
metal compounds.
Calculation of oxidation
numbers of other elements.
Oxidation and reduction in Bleaches as examples of

terms of oxidation numbers. oxidising agents (e.g. NaOC1)
or reducing agents (e.g. SO2).
2.1 Tests for anions in aqueous solutions: chloride, carbonate, nitrate, sulfate, phosphate, sulfite, hydrogencarbonate.
44
3. STOICHIOMETRY, FORMULAS AND EQUATIONS

3.1 States of Matter

(Time needed: 1 class period) Motion of particles in solids,
liquids and gases.
Diffusion (Graham’s law not NH3 and HCl, ink and water,
required). smoke and air.
3.2 Gas Laws

(Time needed: 7 class periods) Boyle’s law. Calculations not required. Boyle’s air pump.
Charles’s law. Calculations not required.
Gay-Lussac’s law of combining

volumes.
Avogadro’s law.
Combined gas law: Simple calculations, including

P1V1 P2V2 constant. correction of gas volumes to
= =
T1 T2 s.t.p. (units: Pa, cm3, K).
The kinetic theory of gases Calculations involving

(non-mathematical treatment): PV = nRT (units: Pa, m3, K).
ideal gases; assumptions of
kinetic theory.
Equation of state for an ideal

gas:
PV = nRT (units: Pa, m3, K).
Reasons why gases deviate from

ideal gas behaviour.
3.3 The Mole
(Time needed: 9 class periods) Avogadro constant. The mole as Calculation of relative molecular M r determination using a mass
the SI unit for amount of mass from relative atomic spectrometer (simple treatment
substance containing the masses. Converting moles to only – interpretation of mass
Avogadro number of particles. grams, litres and number of spectra not required).
Standard temperature and particles. Converting grams and
pressure (s.t.p.). Molar volume litres to moles, and number of
at s.t.p., molar mass, relative particles to moles.
molecular mass (M r ). Converting moles to number of
atoms of a molecular species.
45
3. STOICHIOMETRY, FORMULAS AND EQUATIONS (CONTINUED)

3.4 Chemical Formulas

(Time needed: 6 class periods) Empirical and molecular Calculations of empirical
formulas. formulas, given the percentage
composition by mass.
Calculation of empirical
formulas, given the masses of
reactants and products.
Calculation of molecular
formulas, given the empirical
formulas and the relative
molecular masses (examples
should include simple biological
substances, such as glucose and
urea).
Percentage composition by Calculations.

mass.
Structural formulas. Simple examples.
3.5 Chemical
Equations Chemical equations. Balancing Simple examples.
(Time needed: 11 class periods) chemical equations.
Balancing redox equations (ionic
equations only – ignore
spectator ions).
Calculations based on balanced Calculations in g and kg rather

equations using the mole than tonnes. Calculations
concept (balanced equations will involving masses and volumes.
be given for all calculations).
Calculations involving excess of

one reactant.
Percentage yields. Calculation of percentage yields.
3.1 Determination of the relative molecular mass of a volatile liquid (conical flask or gas syringe may be used).
46
4. VOLUMETRIC ANALYSIS
4.1 Concentration of
Solutions Solutions.
(Time needed: 8 class periods) Expression of solution Calculation of molarity from
concentration in mol l–1 concentration in grams per litre
(molarity), g l–1 and also in and vice versa. Calculation of
% (w/v), % (v/v), % (w/w). number of moles from molarity Use of % (v/v), e.g. wine.
and volume. Simple calculations
involving percentage
concentrations.
Colour intensity as a function
of concentration (simple
treatment only). Calculation of the effect of
dilution on concentration.
Primary standards.
Standard solutions. Mandatory experiment 4.1
4.2 Acids and Bases

(Time needed: 4 class periods) Acids, bases and salts. Household acids and bases (two
Neutralisation – formation of a examples of each). Everyday
salt from an acid and a base. examples of neutralisation, e.g.
use of lime in agriculture, use
Arrhenius and Brønsted-Lowry of stomach powders for acid
theories of acids and bases (for indigestion.
aqueous solutions only).
Conjugate acid-base pairs.
47
4. VOLUMETRIC ANALYSIS (CONTINUED)

4.3 Volumetric
Analysis Apparatus used in volumetric Solving volumetric problems,
(Time needed: 22 class periods) analysis. Correct titrimetric using the formula method.
procedure. Acid-base titrations. Solving volumetric problems
from first principles, where the
formula method is not
applicable. (Either method may
be used when both methods
are applicable.)
Calculation of the relative

molecular mass of a compound
and of the amount of water of
crystallisation in a compound
from titration data. (Balanced
equations will be given in all
volumetric problems.)

Redox titrations. Mandatory experiment 4.5
Calculations based on
mandatory experiments 4.5–4.8
4.1 Preparation of a standard solution of sodium carbonate.
4.2 Standardisation of a hydrochloric acid solution using a standard solution of sodium carbonate.
4.3 Determination of the concentration of ethanoic acid in vinegar.
4.4 Determination of the amount of water of crystallisation in hydrated sodium carbonate.
4.5 A potassium manganate(VII)/ammonium iron(II) sulfate titration.
4.6 Determination of the amount of iron in an iron tablet.
4.7 An iodine/thiosulfate titration.
4.8 Determination of the percentage (w/v) of hypochlorite in bleach.
48
5. FUELS AND HEATS OF REACTION

5.1 Sources of
Hydrocarbons Coal, natural gas and petroleum Decomposition of animal waste
(Time needed: 1 class period) as sources of hydrocarbons. and vegetation as methane
sources. Hazards of methane
production in slurry pits, coal
mines and refuse dumps.
Methane as a contributor to
the greenhouse effect.
5.2 Structure of
Aliphatic Alkanes, alkenes and alkynes as
Hydrocarbons homologous series. For alkynes,
(Time needed: 5 class periods) only ethyne to be considered.
of alkanes to C-5.
Structures, but not isomers, of
hexane, heptane, octane,
cyclohexane and 2,2,4-
trimethylpentane (iso-octane) to
be considered.
of alkenes to C-4.

state, solubility (qualitative properties of methane, ethene
only) in water and in non-polar and ethyne.
solvents].
5.3 Aromatic
Hydrocarbons Structure of benzene, Use of models. See aromatic compounds,
(Time needed: 1 class period) methylbenzene and ethylbenzene page 55.
as examples of aromatic
compounds.

state, solubility (qualitative properties of methylbenzene.
solvents].
49

5.4 Exothermic and

Endothermic Chemical reactions can result in Demonstration of an exothermic
Reactions a change in temperature. and an endothermic reaction.
(Time needed: 9 class periods) Exothermic and endothermic
reactions (and changes of
state).
Combustion of alkanes and

other hydrocarbons.
Heat of reaction (general term). Mandatory experiment 5.1
Sign of ∆H.
Bond energy (concept only – Illustrating bond energies by

no calculations except for the showing how the C–H bond
illustrative example indicated). energy in methane is
calculated.
Heat of combustion. Bomb Use of the bomb calorimeter in

calorimeter as an instrument determining calorific values of
for accurately measuring heats foods. Kilogram calorific values
of combustion. Heats of of fuels, and their uses
combustion of different fuels. (calculations not required).
Heat of formation.
Law of conservation of energy. Simple calculations of heat of

reaction, using heats of
Hess’s law. formation of reactants and
products. Simple calculations of
heat of formation, using other
heats of formation and one
heat of reaction. (Other kinds
of heat of reaction calculation
not required.)
50

5.5 Oil Refining and

its Products Fractionation of crude oil.
Production of the refinery gas, Uses of the refinery gas, light
light gasoline, naphtha, gasoline, naphtha, kerosene, gas
kerosene, gas oil and residue oil and residue fractions.
fractions.
Composition of natural gas and
liquid petroleum gas (LPG).
Addition of mercaptans to
natural gas for safety reasons.
Composition of petrol.
Auto-ignition. Octane numbers

as a measure of the tendency
of a fuel to cause knocking.
Internal combustion engine in

relation to auto-ignition.
Relationship between octane
number and
(i) chain length
(ii) degree of branching
(iii) cyclic structure.
Lead in petrol.
Alternatives to lead:
improving octane number by
(i) isomerisation
(ii) dehydrocyclisation
(iii) catalytic cracking.
Adding oxygenates (notably methyl
tert-butyl ether) to increase the
octane number and reduce
pollution (structure of methyl tert-
butyl ether not required).
51

5.6 Other Chemical

Fuels Ethyne: preparation, combustion, Mandatory experiment 5.2 Oxyacetylene welding and
(Time needed: 3 class periods) tests for unsaturation. (equations and structures of cutting.
products not required for the
tests for unsaturation).
Hydrogen: manufacture by Industrial uses. Potential as a
(i) electrolysis of water fuel.
(ii) steam reforming of natural
gas (simple treatment only).
5.1 Determination of the heat of reaction of hydrochloric acid with sodium hydroxide.
5.2 Preparation and properties of ethyne [combustion, tests for unsaturation using bromine water and acidified potassium manganate(VII)
solution].
52
6. RATES OF REACTION
6.1 Reaction Rates

(Time needed: 3 class periods) Rate of reaction. Mandatory experiment 6.1
Plotting and simple

interpretation of reaction rate
graphs.
Distinction between average and Calculation of instantaneous

instantaneous rate. rate from graphs.
6.2 Factors Affecting

Rates of Reaction Concentration. Particle size. Demonstration of the effects on Dust explosions.
(Time needed: 8 class periods) reaction rate of
Temperature. (i) particle size
(ii) catalysts. Enzymes as catalysts produced
by living cells (two examples).
Nature of reactants. Catalysts. Catalytic converters:

(i) nature of catalysts
(ii) reactions catalysed
(iii) environmental benefits.
Catalyst poisons.

of methanol using a hot
platinum or nichrome catalyst.
Activation energy and influence
of temperature on the rate of
reaction, using reaction profile
diagrams.
Surface adsorption and Demonstration of the oxidation

intermediate formation theories of potassium sodium tartrate by
of catalysis; the effect of hydrogen peroxide, catalysed by
catalysts on activation energy. cobalt(II) salts.
6.1 Monitoring the rate of production of oxygen from hydrogen peroxide, using manganese dioxide as a catalyst.
6.2 Studying the effects on the reaction rate of (i) concentration and (ii) temperature, using sodium thiosulfate solution and hydrochloric
acid.
53
7. ORGANIC CHEMISTRY
7.1 Tetrahedral
Carbon Saturated organic compounds. Use of models, as appropriate.
Alkanes. Use as fuels.
Chloroalkanes: structure and

nomenclature up to C-4.
Physical properties [physical Use as solvents.

solvents].
Alcohols: structure and Comparison of structure with Ethanol as a solvent.

nomenclature up to C-4 water. Fermentation as a source of
(primary and secondary alcohols ethanol; use of fermentation in
only). Physical properties Solubility of (a) methanol and the brewing and distilling
[physical state, solubility (b) butan-1 -ol in industries.
(qualitative only) in water and (i) cyclohexane and (ii) water. Methanol as a denaturing
in non-polar solvents]. agent.
7.2 Planar Carbon

(Time needed: 11 class periods) Unsaturated organic compounds. Use of models, as appropriate.
Alkenes: non-polar double bond. Use in making plastics.

to C-4.
Carbonyl compounds (aldehydes Solubility of ethanal in (i) Benzaldehyde in almond kernels

only): polar double bond. cyclohexane and (ii) water. (structure of benzaldehyde not
Structure and nomenclature up required).
to C-4.

solvents].
54

7.2 Planar Carbon Ketones: structure and

(continued) nomenclature up to C-4.
Physical properties [physical Solubility of propanone in

state, solubility (qualitative (i) cyclohexane and (ii) water.
only) in water and in non-polar Propanone as a solvent (e.g. in
solvents]. nail varnish remover).
Carboxylic acids: polar double Solubility of ethanoic acid in Methanoic acid in nettles and
bond. Structure and (i) cyclohexane and (ii) water. ants; ethanoic acid in vinegar.
nomenclature up to C-4. Use of ethanoic acid in the
manufacture of cellulose acetate
(structure of cellulose acetate
not required).
Use of propanoic acid and

benzoic acid and their salts as
food preservatives (structure of
benzoic acid not required).
Physical properties [physical Mandatory experiment 7.1
solvents].
Esters: structural formulas and Solubility of ethyl ethanoate in Fats as natural esters.
nomenclature up to C-4. (i) cyclohexane and (ii) water. Ethyl ethanoate as a solvent.
Aromas of esters.
solvents].
Simple explanation of the use

of the circle to represent the
identical bonds in benzene,
intermediate between double
and single. Sigma and pi
bonding in benzene.
Aromatic compounds. Solubility of methylbenzene in Use of methylbenzene as an

(i) cyclohexane and (ii) water. industrial solvent.
55

7.2 Planar Carbon An indication of the range and Inspect structural formulas of a Aromatic compounds form the
(continued) scope of aromatic chemistry range of consumer products to basis of dyestuffs, detergents,
(structures not required). show the presence of benzene herbicides and many
rings. pharmaceutical compounds (one
example in each case;
structures not required).
Aromatic acid-base indicators:
phenolphthalein, methyl orange
(structures not required).
Carcinogenic nature of some

aromatic compounds, e.g.
benzene. Not all aromatic
compounds are carcinogenic,
e.g. aspirin (structure of aspirin
not required).
7.3 Organic Chemical

Reaction Types Students are not, in general,
(Time needed: 21 class periods) required to know the conditions
(temperature, pressure, catalyst,
solvent) for these reactions,
except where specified
elsewhere in this syllabus. They
are required to be able to
write balanced equations for
the reactions, using structural
formulas, unless otherwise
indicated.
(a) Addition reactions
Alkenes – reactions with Industrial sources.

hydrogen, chlorine, bromine, Industrial importance of
water and hydrogen chloride. (i) products of the addition
reactions of ethene with
chlorine, bromine, water and
hydrogen chloride
(ii) hydrogenation of vegetable

oils.
56

7.3 Organic Chemical Mechanisms of ionic addition

Reaction Types (addition of HCl, Br2, C12, only
(continued) to ethene).
Evidence for this mechanism:

reaction of ethene with
bromine water containing
sodium chloride results in the
formation of 2-bromoethanol,
1 -bromo-2-chloroethane and
1 ,2-dibromoethane.
Polymerisation reaction (of Alkenes as raw materials in the

ethene and propene only – industrial manufacture of
reaction mechanism not plastics.
required).
Unreactivity of benzene with An indication of the range and

regard to addition reactions, scope of the petrochemical
relative to ethene. industry (two examples of
synthetic products of this
industry; structures not
required, unless specified
elsewhere in the syllabus).
(b) Substitution
reactions
Halogenation of alkanes.
Mechanism of free radical

substitution (monochlorination
of methane and ethane only).
Evidence for this mechanism:

(i) use of ultraviolet light even
for a very short period causes
a chain reaction
(ii) formation of trace
quantities of ethane and butane
in the monochlorination of
methane and ethane,
respectively
(iii) these reactions are speeded
up by the addition of a known
source of free radicals, such as
tetraethyllead.
57

7.3 Organic Chemical Esterification.

Reaction Types
(continued) Base hydrolysis of esters. Mandatory experiment 7.2 Soap manufacture (structures of
(structures of reactants and reactants and products
products required). required).
(c) Elimination
reactions
Dehydration of alcohols. Mandatory experiment 7.3

(equations and structures of
products not required unless
specified elsewhere in the
syllabus).
(d) Redox reactions
Alcohols:
Oxidation using KMnO4 or Mandatory experiment 7.4 Ethanal formation in the

Na2Cr2O7 to Calculation of percentage yield metabolism of ethanol in the
(i) aldehydes and (ii) acids (the balanced equation will be human body.
(half equations only required). given).
Oxidation of aldehydes to acids Mandatory experiment 7.5

(half equations only required). Calculation of percentage yield
(the balanced equation will be
given).
Ketones are not easily oxidised.
Reduction of carbonyl
compounds using H2/Ni catalyst.
Combustion – a reaction
common to most organic
compounds. Combustion of Alcohols as motor fuels.
alcohols.
Non-flammability of fully Flame retardants, fire

halogenated alkanes. extinguishers.
58

7.3 Organic Chemical (e) Reactions as acids and synthetic route required).
Reaction Types
(continued) Reactions of alcohols with
sodium.
Acidic nature of the carboxylic

acid group.
Reactions of carboxylic acids
with magnesium, with sodium
hydroxide and with sodium
carbonate.
(f) Organic synthesis:

principles and
examples
Chemical synthesis involves (i)

bond breaking and (ii) bond
forming.
Working out reaction schemes

of up to three conversions,
recalling familiar reactions.
Example of organic synthesis:
PVC from ethene (structures
7.4 Organic Natural

Products Extraction techniques, e.g. Mandatory experiment 7.6 An indication of the range and
(Time needed: 4 class periods) solvent extraction, steam scope of organic natural
distillation. product chemistry (two
examples of useful organic
natural products; structures not
required).
7.5 Chromatography
and Chromatography as a separation Mandatory experiment 7.7 Use of thin-layer
Instrumentation in technique in which a mobile chromatography (TLC) in the
Organic Chemistry phase carrying a mixture is separation of dyes taken from
(Time needed: 3 class periods) caused to move in contact with fibres in forensic work.
a selectively absorbent GC and HPLC as more
stationary phase. advanced separation techniques.
59

7.5 Chromatography Instrumental methods of Examples of uses:

and separation or analysis, or both:
Instrumentation in
Organic Chemistry Mass spectrometry (cf.1.2, Analysis of (i) gases from a
(continued) page 38). waste dump and (ii) trace
organic pollutants in water.
Gas chromatography (GC). Drug tests on athletes; blood

alcohol tests.
High-performance liquid Growth-promoters in meat;

chromatography (HPLC). vitamins in foods.
Infra-red absorption spectrometry Identification of organic

(IR) as a ‘fingerprinting’ technique compounds, e.g. plastics and
involving absorption of infra-red drugs.
radiation (reference to molecular
vibrations not required).
Ultraviolet absorption spectrometry Quantitative determination of

as a quantitative technique organic compounds (e.g. drug
involving the absorption of metabolites, plant pigments).
ultraviolet light.
Brief reference to the principles

of each method. Interpretation of
spectra etc. not required.
(It should be noted that these
techniques are applicable not only
to organic chemistry but also to
many other areas of chemistry.)
7.1 Recrystallisation of benzoic acid and determination of its melting point.
7.2 Preparation of soap.
7.3 Preparation and properties of ethene [combustion, tests for unsaturation using acidified potassium manganate(VII) solution and bromine
water].
7.4 Preparation and properties of ethanal [properties limited to reactions with (i) acidified potassium manganate(VII) solution, (ii) Fehling’s
reagent and (iii) ammoniacal silver nitrate].
7.5 Preparation and properties of ethanoic acid (properties limited to reactions with sodium carbonate, magnesium and ethanol).
7.6 Extraction of clove oil from cloves (or similar alternative) by steam distillation.
7.7 Separation of a mixture of indicators using paper chromatography or thin-layer chromatography or column chromatography.
60
8. CHEMICAL EQUILIBRIUM
8.1 Chemical
Equilibrium Reversible reactions – dynamic
(Time needed: 8 class periods) equilibrium. At equilibrium, the
rate of the forward reaction
equals the rate of the reverse
reaction.
Equilibrium law and constant Calculations involving

(K c only). equilibrium constants (K c ).
8.2 Le Chatelier’s
Principle Le Chatelier’s principle. Mandatory experiment 8.1 Industrial application of Le
(Time needed: 5 class periods) Effect (if any) on equilibrium Chatelier’s principle in the
position of concentration, catalytic oxidation of sulfur
pressure, temperature and dioxide to sulfur trioxide and
catalyst. in the Haber process.
8.1 Simple experiments to illustrate Le Chatelier’s principle:
(i) CoC142– + 6H20 Co(H20)62+ + 4C1– (to demonstrate the effects of both temperature changes and concentration
changes on an equilibrium mixture).
(ii) Cr2O7 + H2O
2–
(iii) Fe3+ + CNS–

2CrO4 + 2H
2–
Fe(CNS)2+
+
} (to demonstrate the effects of concentration changes on an equilibrium mixture).
61
9. ENVIRONMENTAL CHEMISTRY: WATER

It is strongly recommended that students visit a water treatment plant – industrial or municipal.
9.1 pH Scale
(Time needed: 6 class periods) Self-ionisation of water; K w;
pH scale. Use of universal
indicator paper or solution.
Limitations of the pH scale –
usefulness confined to dilute
aqueous solutions. Calculation of pH of dilute
aqueous solutions of strong
acids and bases (calculation of
pH of mixtures of strong acids
and bases not required).
pH of weak acids and bases. Approximate method of

calculation to be used –
assuming that ionisation does
not alter the total
Theory of acid-base indicators. concentration of the non-ionised
Choice of indicator. Titration form.
curves.
9.2 Hardness in Water

(Time needed: 3 class periods) Hardness in water.
Causes of temporary and Tests on scale deposits in a Removal of hardness by boiling

permanent hardness. kettle. and ion exchange.
Deionisation. Relative purity of

deionised and distilled water.
62

9.3 Water Treatment

(Time needed: 5 class periods) Water treatment –
sedimentation, flocculation,
filtration, chlorination,
fluoridation and pH adjustment.
Sewage treatment (primary, e.g.

settlement, screening; secondary,
e.g. bacterial breakdown;
tertiary, i.e. reduction of level
of phosphates and nitrates).
Cost of tertiary treatment.
The role of nutrients in the

eutrophication of water.
Pollution caused by uncontrolled
use of nitrate fertilisers.
Pollution by heavy metal ions Removal by precipitation.

in water – especially Pb 2+, Polluting potential of heavy
Hg 2+ and Cd 2+ metals from batteries in the
absence of recycling.
Awareness that there are EU

limits for various chemical
species in water (two examples,
e.g. nitrates, phosphates,
specific metal ions).
63

9.4 Water Analysis

(Time needed: 11 class periods) Instrumental methods of Examples of uses:
analysis:
pH meter Analysis of river and lake

water.
AAS [cf. flame tests Analysis of heavy metals in
(mandatory experiment water, e.g. lead, cadmium.
1.1), absorption spectra
(page 39)].
Colorimetry Mandatory experiment 9.1 Analysis of (i) lead in water

and (ii) fertilisers.
Brief reference to principles of
each method.
Tests for anions (cf. mandatory Mandatory experiment 9.2

experiment 2.1).
Biochemical oxygen demand Mandatory experiment 9.4 Organic chemical pollutants, e.g.
(BOD). sewage, industrial waste, silage,
milk.
9.1 Colorimetric experiment to estimate free chlorine in swimming-pool water or bleach (using a colorimeter or a comparator).
9.2 Determination of total suspended and total dissolved solids (expressed as p.p.m.) by filtration and evaporation respectively.
Determination of pH.
9.3 Estimation of total hardness using ethylenediaminetetraacetic acid (edta). (Balanced ionic equation required.)
9.4 Estimation of dissolved oxygen by redox titration.
64
Options: Higher level students to choose between

Option 1 and Option 2 in their entirety.
OPTION 1A: ADDITIONAL INDUSTRIAL CHEMISTRY

It is strongly recommended that students visit a particular local chemical plant. This visit should be a structured one.
1A.1 General
Principles Batch, continuous and semi-
(Time needed: 3 class periods) continuous industrial chemical
processes.
Characteristics of effective and See above. Awareness of the contributions
successful industrial chemical of chemistry to society, e.g.
processes such as provision of pure water, fuels,
metals, medicines, detergents,
(i) feedstock (raw materials, enzymes, dyes, paints,
preparation) semiconductors, liquid crystals
(ii) rate (temperature and and alternative materials, such
pressure variables, catalyst) as plastics and synthetic fibres;
(iii) product yield (temperature increasing crop yields by the
and pressure variables, use of fertilisers, herbicides and
catalyst) pesticides; food-processing.
(iv) co-products (separation,
disposal or sale)
(v) waste disposal and effluent
control (waste water
treatment, emission control)
(vi) quality control
(vii) safety (location of site,
on-site training, monitoring
of hazards, safety features)
(viii) costs (fixed costs, variable
costs; cost reduction by use
of heat exchangers,
catalysts, recycling and
selling of useful co-
products; costs of waste
disposal)
(ix) site location
(x) suitable materials for the
construction of chemical
plant (unreactive, resistant
to corrosion).
65
OPTION 1A: ADDITIONAL INDUSTRIAL CHEMISTRY (CONTINUED)

1A.2 Case Study

(Time needed: 5 class periods) A case study based on the Irish Awareness of the range and
chemical industry. ONE of the scope of the Irish chemical
three following processes should industry (two examples of
be studied, using the principles products produced by this
outlined in 1A.1 as far as they industry, other than those
are relevant to the process: referred to in the case study
chosen).
(a) Ammonia manufacture from
natural gas, water vapour
and air, and its conversion
to urea. Equations required
for
(i) hydrogen production
(ii) removal of carbon
dioxide
(iii) ammonia formation
(iv) urea synthesis. Use of urea as a fertiliser.
(b) Nitric acid manufacture

from ammonia, and its use
to make fertilisers.
Equations required for
(i) oxidation of ammonia
(ii) oxidation of nitrogen
monoxide
(iii) formation of nitric acid
(iv) formation of Use of ammonium nitrate as a
ammonium nitrate. fertiliser.
(c) Magnesium oxide

manufacture from sea
water. Equations required
for
(i) conversion of calcium
carbonate to calcium
oxide
(ii) conversion of calcium
oxide to calcium
hydroxide
(iii) formation of
magnesium hydroxide
(iv) formation of Use of magnesium oxide as a
magnesium oxide. heat-resistant material in the
walls of furnaces.
66
OPTION 1B: ATMOSPHERIC CHEMISTRY

1B.1 Oxygen
(Time needed: 1 class period) Manufacture of oxygen using Uses of oxygen and of liquid
liquefaction and fractional nitrogen (two examples in each
distillation of air. case).
1B.2 Nitrogen
(Time needed: 2 class periods) Structure and inertness. Any two uses, e.g. keeping
foods fresh, flushing out
Atmospheric abundance. dangerous vapours from oil
tankers.
Natural fixation of nitrogen;
nitrogen and oxygen in an
electric discharge.
Nitrogen cycle.
1B.3 Carbon Dioxide

(Time needed: 4 class periods) Combustion of carbon to give
carbon monoxide and carbon
dioxide.
Carbon monoxide as a neutral Carbon monoxide as a poison.

oxide. Carbon monoxide in cigarette
smoke and vehicle exhaust fumes.
Carbon dioxide as an acidic Demonstration of the effect of
oxide. carbon dioxide on universal
indicator solution.
Carbon dioxide in water – free
and combined as carbonate and
hydrogencarbonate.
Fermentation in ethanol Carbon dioxide in carbonated

production as a source of drinks.
carbon dioxide.
The carbon cycle. The greenhouse effect and the

influence of human activity on it.
Greenhouse gases and their relative
effects [especially carbon dioxide
and water vapour; also methane,
chlorofluorocarbons (CFCs)].
Reduction of atmospheric carbon
dioxide levels by dissolving in the
ocean.
Possible implications of the
increased greenhouse effect.
67
OPTION 1B: ATMOSPHERIC CHEMISTRY (CONTINUED)

1B.4 Atmospheric
Pollution Oxides of nitrogen and sulfur:
(Time needed: 2 class periods) sources of pollution (natural,
domestic, industrial, internal
combustion engine).
Dissolving of nitrogen dioxide Demonstration of the effect of Acid rain and its effects on the
and sulfur dioxide to form sulfur dioxide on universal environment. Scrubbing of waste
acids. indicator solution. gases using limestone.
1B.5 The Ozone Layer

(Time needed: 4 class periods) Chloroalkanes: preparation from Chlorofluorocarbons and the
alkanes, e.g. chlorination of ozone layer.
methane.
Formation of ozone in the
stratosphere (equation required).
Beneficial effect of the ozone
layer.
Photodissociation of ozone
(equation required).
CFCs and HCFCs. Uses of CFCs.

Residence times of CFCs.
Breakdown of CFCs in the

stratosphere.
Removal of ozone by Cl atoms

(equations required), O atoms
and NO molecules. Role of
methane in absorbing Cl atoms.
CFCs are believed to be the

main cause of damage to the
ozone layer.
Effects of damage to the ozone

layer.
Replacements for CFCs.
68
OPTION 2A: MATERIALS

2A.1 Crystals Ionic, molecular, metallic and Use of models. Contributions of

(Time needed: 3 class periods) covalent macromolecular crystals (i) Braggs: development of the
– physical properties related to X-ray technique for determining
the crystal binding forces. crystal structure;
Crystal structure is determined (ii) Dorothy Hodgkin:
by scattering of X-rays by the determination of the crystal
crystal (non-mathematical structure of complex organic
treatment only). molecules, e.g. vitamin B12,
penicillin (structures not
required).
The discovery of
buckminsterfullerene (structure
not required).
2A.2 Addition
Polymers Addition polymers. Monomers.
Polymerisation of alkenes: Demonstration of physical The industrial and domestic
poly(ethene) (low-density and properties (density, flexibility, importance and advantages of
high-density), poly(chloroethene), hardness) of poly(ethene), these polymers in plastics and
poly(phenylethene), poly(chloroethene) fibres (two examples of uses of
poly(tetrafluoroethene), and poly(phenylethene). each polymer).
poly(propene).
Structural differences between Brief history of the discovery of

low-density and high-density low-density poly(ethene) and of
poly(ethene). high-density poly(ethene). Brief
history of the discovery of
poly(tetrafluoroethene).
Recycling of plastics, exemplified
by the recycling of polystyrene
(stages: sorting, shredding,
washing, drying and re-extrusion).
2A.3 Metals
(Time needed: 1 class period) Comparison between metals and
non-metals (hardness, lustre,
malleability, ductility, heat
conductivity and electrical
conductivity).
Alloys. Carbon in steel and hardness.
69

2B.1 The
Electrochemical Different combinations of metals Contributions of Galvani, Volta,
Series produce different voltages in a Davy and Faraday.
(Time needed: 1 class period) simple cell.
The electrochemical series

(reactions of metals with acids,
water and oxygen not
required).
2B.2 Electrolysis of
Molten Salts Electrolysis of molten lead
(Time needed: 1 class period) bromide, using inert electrodes.
(Half equations only required.)
2B.3 Corrosion
(Time needed: 2 class periods) Corrosion of metals. Relative Corrosion prevention
corrodability of metals. (application of a protective
layer on a metal: galvanising
and surface coating).
Protective layers on Al, Cr.
Sacrificial anodes.
2B.4 Strongly
Electropositive Extraction by electrochemical Uses (two examples in each
Metals (Na and methods. case).
Al)
(Time needed: 4 class periods) Sodium in Downs cell. Chlorine is an important by-
product.
Aluminium from bauxite: Environmental aspects of

bauxite → pure alumina – aluminium production.
electrolysis to aluminium.
Economics of cheap electricity
in the extraction of Al.
Anodising. Porous nature of the oxide

layer formed by anodising
allows dyeing.
Recycling of aluminium.
70

2B.5 d-Block Metals

(Time needed: 4 class periods) Transition elements: general
chemical properties (colour,
variable valency, use as
catalysts).
Manufacture of iron (blast Uses of iron and steel (two

furnace – chemical aspects) examples in each case).
and steel. Steels as alloys of
iron.
Electric arc process for steel Environmental aspects of iron

manufacture (outline of main and steel production.
stages).
71
APPENDIX 2
Only the systematic names for organic compounds will be used on examination papers, except where the traditional
name continues to enjoy widespread use, particularly in industrial and everyday life. In these cases, the traditional
name will also be given in parentheses immediately after the systematic name. Knowledge of these traditional names
is not examinable. A representative list of such compounds follows:
Systematic Name Traditional Name

ethanal acetaldehyde
ethanoic acid acetic acid
propanone acetone
ethyne acetylene
ethyl ethanoate ethyl acetate
ethanol ethyl alcohol
ethene ethylene
methanal formaldehyde
methanoic acid formic acid
2,2,4-trimethylpentane iso-octane
methanol methyl alcohol
chloromethane methyl chloride
poly(ethene) polyethylene
poly(phenylethene) polystyrene
poly(chloroethene) polyvinyl chloride
methylbenzene toluene
The systematic names for H4edta and methyl tert-butyl ether are not required.
The systematic names of inorganic compounds are not required, except for compounds of transition metals (cf.
section 2.6).
72
Mathematical Requirements for Ordinary and Higher levels

Black text is for Higher level only.
1. Use of calculators • make approximate evaluations of numerical

Students will be expected to have an electronic expressions and use such approximations to check
calculator conforming to the examination regulations calculator calculations.
for the duration of the course and when answering
the examination paper. It is recommended that Algebra
students have available the following keys: Students should be able to
x
Ordinary level: +, –, x, ÷, 1/x , log10 x, 1 0 , EE or EXP, • change the subject of an equation
memory.
• solve simple algebraic equations
y
Higher level: as above, and x2, x, x .
• substitute for physical quantities in physical
In carrying out calculations, students should be advised to equations using consistent units
show clearly all expressions to be evaluated using a calculator.
• formulate simple algebraic equations as
The number of significant figures given in the answer to a
mathematical models of physical situations
numerical problem should match the number of significant
figures given in the question. • comprehend and use the symbols >, <, ∝ ,=, x, ∆x.
Graphs
2. Mathematical requirements
Students should be able to
The chemistry syllabus does not require Higher level
mathematics. There is no requirement for the use of • translate information between numerical,
calculus techniques. algebraic, verbal and graphic forms
• select appropriate variables and scales for graph

Arithmetic
plotting
Students should be able to
• understand the concept of significant figures • determine the slope of a linear graph and allocate
appropriate physical units to it
• recognise and use significant figures as appropriate
• choose by inspection a straight line that will serve
• recognise and use expressions in decimal and
as the best straight line through a set of data
standard form (scientific) notation
represented graphically
• recognise and use prefixes indicating
-3 3
• choose by inspection a curve that will serve as the
multiplication by 10 , 10
best curve through a set of data presented
• find weighted means graphically
• use an electronic calculator for addition, • determine the slope of a curve at a point and
subtraction, multiplication and division, for allocate appropriate physical units to it.
reciprocals, squares, square roots, logarithms and
their inverses
73
Procedures for drawing up
National Syllabuses
The NCCA’s Course Committees for the Leaving Certificate
(Established) have the following membership:
• Association of Secondary Teachers, Ireland

• Teachers’ Union of Ireland
• Joint Managerial Body
• Association of Community and Comprehensive Schools
• Subject Association
• Irish Vocational Education Association
• National Council for Educational Awards
• Conference of Heads of Irish Universities
• Department of Education and Science (Inspectorate).
On the basis of a brief provided by Council, the NCCA’s

Course Committees prepare the syllabuses.
Recommendations of Course Committees are submitted

to the Council of the NCCA for approval. The NCCA, hav-
ing considered such recommendations, advises the
Minister for Education and Science accordingly.
Further information may be obtained by contacting the

NCCA at 24 Merrion Square, Dublin 2.
Published by The Stationery Office
To be purchased directly from:
Government Publications Sales Office,
Sun Alliance House,
Molesworth Street, Dublin 2.
Or by mail order from:
Government Publications, Postal Trade Section,
4-5 Harcourt Road, Dublin 2.
Tel: 01-647 6834/5 Fax: 01-475 2760
Or through any bookseller.
Designed by: Langley Freeman Design Group Limited

© 1999 Government of Ireland

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AN ROINN OIDEACHAIS AGUS EOLAÍOCHTA

Aims and Principles The Leaving Certificate (Established)

iii. The Leaving Certificate Applied The Leaving Certificate Applied

(ORDINARY AND HIGHER LEVEL)

• science for action, or the applications of science

• science, which is concerned with issues – political,

Ordinary Level Syllabus . . . . . . . . . . . 5 Higher Level Syllabus . . . . . . . . . . . . 35

Ordinary Level Objectives . . . . . . . . . . . . 6 Higher Level Objectives . . . . . . . . . . . . . 36

Ordinary Level Core Higher Level Core

2. Chemical Bonding . . . . . . . . . . . . . . . . . . .10 2. Chemical Bonding . . . . . . . . . . . . . . . . . . .42

4. Volumetric Analysis . . . . . . . . . . . . . . . . . . .14 4. Volumetric Analysis . . . . . . . . . . . . . . . . . . .47

6. Rates of Reaction . . . . . . . . . . . . . . . . . . . .18 6. Rates of Reaction . . . . . . . . . . . . . . . . . . . .53

7. Organic Chemistry . . . . . . . . . . . . . . . . . . .19 7. Organic Chemistry . . . . . . . . . . . . . . . . . . .54

8. Chemical Equilibrium . . . . . . . . . . . . . . . . .24 8. Chemical Equilibrium . . . . . . . . . . . . . . . . .61

9. Environmental Chemistry: Water . . . . . . . . .25 9. Environmental Chemistry: Water . . . . . . . . .62

Ordinary Level: Option 1 Higher Level: Option 1

1B. Atmospheric Chemistry . . . . . . . . . . . . . . . .29 1B. Atmospheric Chemistry . . . . . . . . . . . . . . . .67

Ordinary Level: Option 2 Higher Level: Option 2

2A. Materials . . . . . . . . . . . . . . . . . . . . . . . . . . .31 2A. Materials . . . . . . . . . . . . . . . . . . . . . . . . . . .69

2B. Additional Electrochemistry and 2B. Additional Electrochemistry and

Mathematical Requirements at Ordinary and Higher Level . . . . . . . . . . . . . . . 73

Practical Work Assessment

Students will be given full recognition for carrying

Differentiation between Ordinary level

(i) Range of topics

All the Ordinary level material, except mandatory

(ii) Depth of treatment

The Ordinary level syllabus provides an overview

Ordinary Level Syllabus Objectives

• scientific theory • organise chemical ideas and statements

• use chemical facts and principles to make

• perform experiments safely and co-operatively

• select and manipulate suitable apparatus to

• make accurate observations and measurements

• interpret experimental data and assess the accuracy

1. PERIODIC TABLE AND ATOMIC STRUCTURE

1.1 Periodic Table

Brief statement of the principal Demonstration of the reaction

1.2 Atomic Structure

Relative atomic mass (A r). The Use of the mass spectrometer

1. PERIODIC TABLE AND ATOMIC STRUCTURE (CONTINUED)

Radioisotopes. Uses of radioisotopes (three

Half-life (non-mathematical 14C age determination

60Co for cancer treatment.

Classification of the first twenty

Atomic radii (covalent radii

1. PERIODIC TABLE AND ATOMIC STRUCTURE (CONTINUED)

1.4 Electronic Dependence of chemical

Explanations in terms of atomic See mandatory experiment 1.2

1.5 Oxidation and

Oxidising and reducing agents. Swimming-pool water treatment.

Electrolysis of (i) copper sulfate Demonstration of ionic Electroplating.

Stability of noble gas electron Uses of helium and argon

2.2 Ionic Bonding

Ionic bonding as electron

Sodium chloride crystal Examination of a model of the

Characteristics of ionic Mandatory experiment 2.1 Ionic materials in everyday life

2.3 Covalent Bonding

Covalent bonding as the sharing Representation of covalent