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    Quiz 3 Ema 4324, Stability of Materials, Lecsec 3009 Monday, October 11, 2004

    Uploaded by

    Bryan de Barros
    This document provides electrochemical data and equations to calculate corrosion rates for a JRA-H2O system. It then asks the student to: 1) Calculate the corrosion potential and corrosion current assuming charge transfer control, giving the values as -0.392 V and 3.98x10-4 A. 2) Calculate the corrosion penetration rate (CPR) in mpy, giving the value as 245 mpy. 3) Predict the effects on corrosion current and potential of: a) increasing exposed area, b) increasing pH, c) increasing H2 pressure, d) increasing the cathodic Tafel constant, and e) introducing O2.

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    Quiz 3 Ema 4324, Stability of Materials, Lecsec 3009 Monday, October 11, 2004

    Uploaded by

    Bryan de Barros
    48 views2 pages
    This document provides electrochemical data and equations to calculate corrosion rates for a JRA-H2O system. It then asks the student to: 1) Calculate the corrosion potential and corrosion current assuming charge transfer control, giving the values as -0.392 V and 3.98x10-4 A. 2) Calculate the corrosion penetration rate (CPR) in mpy, giving the value as 245 mpy. 3) Predict the effects on corrosion current and potential of: a) increasing exposed area, b) increasing pH, c) increasing H2 pressure, d) increasing the cathodic Tafel constant, and e) introducing O2.

    Original Description:

    Jones solution Chapter 3

    Original Title

    Soluition Charpter 3_1

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    This document provides electrochemical data and equations to calculate corrosion rates for a JRA-H2O system. It then asks the student to: 1) Calculate the corrosion potential and corrosion current assuming charge transfer control, giving the values as -0.392 V and 3.98x10-4 A. 2) Calculate the corrosion penetration rate (CPR) in mpy, giving the value as 245 mpy. 3) Predict the effects on corrosion current and potential of: a) increasing exposed area, b) increasing pH, c) increasing H2 pressure, d) increasing the cathodic Tafel constant, and e) introducing O2.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    48 views2 pages

    Quiz 3 Ema 4324, Stability of Materials, Lecsec 3009 Monday, October 11, 2004

    Uploaded by

    Bryan de Barros
    This document provides electrochemical data and equations to calculate corrosion rates for a JRA-H2O system. It then asks the student to: 1) Calculate the corrosion potential and corrosion current assuming charge transfer control, giving the values as -0.392 V and 3.98x10-4 A. 2) Calculate the corrosion penetration rate (CPR) in mpy, giving the value as 245 mpy. 3) Predict the effects on corrosion current and potential of: a) increasing exposed area, b) increasing pH, c) increasing H2 pressure, d) increasing the cathodic Tafel constant, and e) introducing O2.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    Quiz 3

    EMA 4324, Stability of Materials, LecSec 3009 KEY


    Monday, October 11, 2004

    Electrochemical data for the JRA - H2O system are presented on the following table.

    Tafel
    equilibrium [Nernst] exchange current
    process constant,
    potential, volts SHE density, jo, A/cm2
    β, volts
    +2 - -5
    J + 2e = J -0.528 5x10 0.15
    + - -7
    2H + 2e = H2 -0.178 1x10 0.06
    O2 + 2H2O + 4e- = 4OH- 1.053 1x10-15 0.1
    o +2 +2 -6
    E [J /J] = -0.350 v; [J ] = 10 M; assume all jo values to have been determined at EN
    solution pH = 3

    1. [5 points] Assuming charge transfer [activation] control of all electrochemical processes, what
    values would you predict for the corrosion potential and corrosion current for JRA exposed to
    deaerated water of pH 3? [note: you may solve the problem using either analytical or
    graphical methods - I have provided a blank Evan’s diagram; the analytical expression[s]
    were in downloadable notes.]

    4.0
    log[current], log amperes

    2.0

    0.0

    -2.0
    icorr = 3.98x10-4
    -4.0

    -6.0
    Ecorr = -0.392v
    -8.0
    -0.40 -0.20 0.00 0.20 0.40
    applied potential, volts SHE

    Corrosion current, icorr = 3.98x10-4 A


    Corrosion potential, Ecorr = -0.392 v SHE
    2. [5 points] Calculate the corrosion penetration rate [CPR, in units of mpy] for JRA in the
    deaerated pH3 test solution.

    AW, g/mol atom radius, nm ion radius, nm density, g/cm3


    0.098 [JRA+2]
    JRA(c) 91.8 0.141 9.62
    0.077 [JRA+3]

    ***************************************************************************
    Had to have assume A = 1cm2 in order to use jo values - therefore, jcorr = icorr
    3.98x10-4 C/s*cm2*91.8/[2*96500*9.62] = 1.97x10-8 cm/s = 245 mpy

    3. [10 points] For 2 points each, predict the effects of the following changes on corrosion current
    and corrosion potential:

    a. An increase in area of JRA exposed to the environment. Ecorr unchanged


    icorr increased
    [jcorr unchanged]

    b. An increase in solution pH. Ecorr, icorr decrease

    c. An increase in H2 pressure. no change


    d. An increase in value of the Tafel constant for the
    cathodic reaction [βc]. Ecorr, icorr decrease

    e. Introduction of O2 [p = 1 atm]. Ecorr, icorr increase

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