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All India Test Series/IIT/FLT 1/ Paper : 1 - SOLUTIONS 1

THE ACE TUTORIALS

FLT - 1 (PAPER - 1) : SOLUTIONS
STANDARD ANSWER KEY
Q 1 2 3 4 5 6 7 8 9 10 11
A B B A D A C BD AC BC CD A
Q 12 13 14 15 16 17 18 19 20 21 22
A C B D B A C A D C B B
Q 23 24 25 26 27 28 29 30 31 32 33
A A C C D C A A BCD ABC ABD AC
Q 34 35 36 37 38 39 40 41 42 43 44
A A C C C D A A C A A C
Q 45 46 47 48 49 50 51 52 53 54 55

om
A A B B B B B D B AD AC ACD
Q 56 57 58 59 60 61 62 63 64 65 66

c
A ABD C D B C C B D A C D

g.
Q 67 68 69
ng
A B C B
Consider f (x) = ex – x
h h
(B). CD = h, tan θ = , tan2θ =
ye

(1) y
x L− x
C
.m

a=1
w
w

h
x
w

θ 2θ O
A x L–x B f ' (x) = ex – 1
://

D
L f ' (x) > 0 for x > 0 and f ' (x) < 0 for x < 0
Now, x tan θ = (L – x) tan 2θ ∴ f (x) is increasing ( ↑ ) for x > 0
tp

x (tan θ + tan 2θ) = L tan 2θ and decreasing ( ↓ ) for x < 0

ht

I I
 tan2θ 
2θ
 tan2θ   2 θ 
x=  L ; x =  tan θ tan2θ L
 tan θ + tan2θ  θ + 2θ 
 θ 2θ  x
x=0
2L y = ex always lies above y = x i.e. ex – x ≥ 1 for a > 1
limx= Hence never cuts = a = (0, 1] ⇒ B
θ→0 3
(2) (B). For 0 < a ≤ 1 the line always cuts y = ax . (3) (A). SS' = 2ae, where a and e are length of semi-major axis
and eccentricity respectively.
y
(9 − 3) 2 + (12 −4) 2 = 2ae ∴ ae = 5
∴ Centre is mid point of SS'
∴ Center ≡ (6, 8)
y=ax, a ? (0, 1] Let the equation of auxiliary circle be (x – 6)2 + (y – 8)2 = a 2
We know that the foot of the perpendicular from the focus
on any tangent lies on the auxiliary circle
x
O ∴ (1, – 4) lies on auxiliary circle.
i.e. (1 – 6)2 + (– 4 – 8)2 = a2 ⇒ a = 13
For a > 1, say a = e Q ae = 5 ⇒ e = 5/13
1

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2 All India Test Series/IIT/FLT 1/ Paper : 1 - SOLUTIONS

(4) (D). A is non singular ∴ det A ≠ 0 rr rr rr

(8) (AC). Clearly a.c = 0 & b.c = 0 . Also a.b = 0 ⇒ (A)
Given AB – BA = A, hence AB = A + BA = A(I + B)
det. A · det. B = det. A · det. (I + B) r r r
| a | | b | = | c |  | ar | | cr | r r r
det. B = det. (I + B) ....(1) (as A is non singular)
Again, r r  ⇒ r = r ⇒ | a |=|c|&|b|=1
r
again AB – A = BA | b | | c | = | a |  | c | | a |
A(B – I) = BA
r rr r r r r r
(det. A) · det.(B – I) = det. B · det. A ⇒ a × b.c = | a | | b | | c | = | a |2 = | c |2
⇒ det. (B – I) = det. (B) ....(2) r r r
From (1) and (2) (Student will assume a = iˆ , b = ˆj,c = kˆ but in this case all
det. (B – I) = det. (B + I) the four will be correct which will be wrong)
(5) (A). Solving line and circle n n −r
 1/2 1 −1/4  1
m2 x2 + (δ – lx)2 = m2 c2 (9) (BC).  x + x  ; Tr +1 = Cr x
n 2 . .x − r/4
x1  2 2r
(m2 + l2 ) x2 – 2lδx + (δ2 – m2 c2 ) = 0 2 2
x2 (l + m = 1)
n 1 1
Coefficient of the first 3 terms are C0 , n C1 , nC 2. 2
2 x1 x2 2 (δ − m c )
2 2 2 2 2
Given H = =
x1 + x 2 2lδ 1 1
n
C0 + n C2 . = 2. n C1.

om
4 2
δ 2 − m 2c 2
lH = ......... (1) n(n − 1) n(n − 1)
δ 1+ =n ; = (n − 1) ⇒ n = 8 ( a s n ≠ 1)

c
8 8

g.
lx+my = δ 8− r  3r 
1 1  4− 
B Tr +1 = 8 Cr x .x − r/4 = 8 Cr .
ng
2 . .x 4
( x2, y2 ) r r
A 2 2
Number of terms with integer power of x occur when r = 0,
ye

(x1,y1)
4, 8 ⇒ 3 terms. Hence B and C are correct.
δ2 − c 2l 2 (10) (CD). Given : (f '(x))2 + (g (x))2 = 1
mK =
.m

Similarly ......... (2)

δ x
f(x) + ∫ g ( t ) d t = sinx(cosx − sinx)
w

2δ 2 − c2 ( l2 + m 2 ) c2
(1) + (2) ⇒ lH + mK = = 2δ − 0
δ δ
w

Differentiating both sides

where (l2 + m2 = 1) f ' (x) + g (x) = cos 2x – sin 2x ....... (1)
w

(6) (C). Squaring (1)

://

Let z = a + i b ⇒ z = a − ib (f '(x))2 + (g (x))2 + 2 f '(x). g (x) = 1 – sin 4x

1 + 2 f '(x) . g (x) = 1 – sin 4x
tp

Hence, we have z2008 = z

∴ 2 f ' (x) g (x) = – sin 4x
∴ | z |2008 = | z | = | z |
ht

sin4x
Now, substituting g (x) = − in eq. (1)
2f ′(x)
| z | [ | z |2007 −1] = 0
| z | = 0 or | z | = 1, if | z | = 0 ⇒ z = 0 ⇒ (a, b) = (0, 0) sin4x
f ′ (x) − = cos2x − sin2x
if | z | = 1 ; z 2009 = zz = | z |2 = 1 2f ′ (x)

⇒ 2009 values of z ⇒ Total number of ordered pairs = 2010 Put f ' (x) = t
(7) (BD). As a > 2 hence a2 > 2a > a > 2 2t 2 – 2 (cos 2x – sin 2x) t – sin 4x = 0
Now (x – a)(x – 2a)(x – a2 ) < 0 ⇒ the solution set is as 2(cos2x − sin2x) ± 4 (1 − sin4x) + 8sin4x
shown ⇒ t=
4
∴ 4t = 2 (cos 2x – sin 2x) ± 4(1 − sin4x) + 8sin4x
0 a 2a a2
⇒ 2t = (cos 2x – sin 2x) ± 1 + sin4x
Between (0, a) there are (a – 1) positive integers
Between (2a, a2 ) there are (a 2 – 2a – 1) positive integers taking (+) ve sign, 2t = cos 2x – sin 2x + cos 2x + sin 2x
∴ a2 – 2a – 1 + a – 1 = 18 ⇒ a2 – a – 20 = 0 ⇒ t = cos 2x
(a – 5)(a + 4) = 0 taking (–) ve sign, t = – sin 2x
∴ a = 5 and a = –4 but a > 2∴ a = 5 ⇒ (B) and (D) Hence f ' (x) = cos 2x or f ' (x) = – sin 2x

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All India Test Series/IIT/FLT 1/ Paper : 1 - SOLUTIONS 3

1 cos2x 1 1 1 4 4 16 4
Integrating, f(x) = sin2x + C1 or f(x) = + C2 P ( A / B1 ) = . = , P ( A / B2 ) = . = =
2 2 6 6 36 6 6 36 9
f (0) = 0 ⇒ C1 = 0 and C2 = –1/2
1 1
1 cos2x − 1 .
∴ f (x) = sin2x or f(x) = P(B1 / A) = 2 36 =
1
2 2 1424 3 1 1 1 16 17
If f ' (x) = cos 2x then g (x) = – sin 2x E1 . + .
2 36 2 36
If f ' (x) = – sin 2x then g (x) = cos 2x
1 1 16
i.e. f(x) = sin2x and g (x) = – sin 2x ⇒ (C) .
16
E1
2 P(B2 / A ) = 2 36 = E
1424 3 1 16 1 1 17
cos2x − 1 E2 . + . E2
f(x) = and g (x) = cos 2x ⇒ (D) 2 36 2 36
2
(11) (A). y = | ln x | not differentiable at x = 1 E : third ball drawn is red
P (E) = P (E ∩ E1 ) + P (E ∩ E2 )
π 3π
,
y = | cos | x | | is not differentiable at x = 1 5 16 2 5 32 37
2 2 = . + . = + =
x ∈ (0, 2π) 17 6 17 6 102 102 102

om
y = cos–1 (sgn x) = cos–1 (1) = 0 differentiable
(18) (A). f (0) = 2,
1 1
(12) (C). Let ∫ f (t)dt = k , so f (x) = kx + 1, now ∫ (kt + 1) dt = k  x x 

c
0 0 f(x) = (ex + e− x )cosx − 2x −  x ∫ f ′ (t)dt − ∫ t{ {
f ′ (t)dt 

g.
 0 0 I II 
k
⇒ + 1 = k, so k = 2
ng
2 f(x) = (ex + e− x )cosx − 2x
∴ f (x) = 2x + 1,
ye

  x 
∫
3 x
−  xf(x) −xf(0) − t.f(t) 0 − f (t)dt 
Also ∫ f(x)dx = 12 ⇒ Option (C) is correct   
.m

0
0
(B). Let x1 , x2 , x3 ∈ R be the roots of f (x) = 0
f(x) = (ex + e− x )cosx − 2x − x f ( x ) + 2x
(13)
w

∴ f (x) = (x – x1 ) (x – x2 ) (x – x3 )
f (i) = (i – x1 ) (i – x2 ) (i – x3 )  
w

x
| f (i) | = | x1 – i | | x2 – i | | x3 – i | = 1 +  x f ( x ) − ∫ f (t)dt 
w

 0 
∴ x12 + 1 x22 + 1 x32 + 1 = 1
://

This is possible only if x1 = x2 = x3 = 0 x

⇒ f (x) = x3 ⇒ a = 0 = b = c ⇒ a + b + c = 0 f(x) = (e x + e− x )cosx − ∫ f(t)dt
tp

........... (1)
⇒/ all roots are zero. 0
ht

(14) (D). L1 and L2 are obviously non-parallel Differentiating eq. (1)

Consider the determinant f ' (x) + f (x) = cos x (e x – e–x ) – (e x + e–x ) sin x ........ (2)
2 −4 1 dy
Hence + y = ex (cosx − sinx) − e− x (cosx + sinx)
D= 2 4 −3 dx
= 2 (8 + 9) + 4 (4 + 3) + 1 (6 – 4)
1 3 2
(19) (D). f ' (0) + f (0) = –2 + 2 = 0
= 34 + 28 + 2 = 64 ⇒ D ≠ 0 ⇒ skew lines (20) (C). I.F. of DE (1) is ex .
Hence Statement-1 is false.
(15) (B)., (16) (A)., (17) (C). y.ex = ∫ e2x (cosx − sinx)dx − ∫ (cosx + sinx)dx
5R 2R
Urn-I ; Urn-II y.ex = ∫ e2x (cosx − sinx)dx − ∫ (sinx − cosx) + C
1B 4B
A : first two draws resulted in a blue ball.
Let I = ∫ e2x (cosx − sinx)dx = e 2x (Acosx + Bsinx)
1
B1 : urn-I is used P(B1 ) = Solving A = 3/5 and B = –1/5 and C = 2/5
2
x3 1  −x 2 −x
∴ y = e  cosx − sinx − (sinx − cosx)e + e
1
B2 : urn-II is used P(B2 ) = 5 5 5
2

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4 All India Test Series/IIT/FLT 1/ Paper : 1 - SOLUTIONS

(21) (B). Equation of normal in terms of slope is 1(main scale)

m3 x + (4 – y) m2 + 2 = 0 (25) (C). Least count =
N
point P(h, k) satisfies this equation
m1 1(main scale)
0.1 mm = ; 1 Main scale division = 2mm.
∴ m3 h + (4 – k) m2 + 2 = 0 m2 ....... (1) 20
m3 N
dN
t
(26) (D).
dN
= 50 −
N
; ∫ 50 − 2N ∫
= dt
k−4 dt 0.5 0 0
algebraic sum of slopes is m1 + m2 + m3 =
h N = (100 (1 – e–t/2) ) ; N = 25 ; t = 2 ln (4/3)
ur uur
∫ B.dl
(22) (B).
(27) (C). For loop B, µ0 (2i – i) = Ñ
If two normals are perpendicular then
ur uur
m1 m2 = – 1 and m1 m2 m3 = −
2 ∫ B.dl
For loop C, µ0 (i – 2i) = Ñ
h ur uur
2
For loop A, µ0 (3i – 3i) = Ñ∫ B.dl
substituting m3 = = m in (1) we get ur uur
h For loop D, µ0 (0 – i) = Ñ∫ B.dl

om
8 4(4 − k) So, B > A > C = D
+ +2= 0 (28) (A). At resonance XL = XC and Z = Zmin = R
h2 h2
4 + 2 (4 – k) + h 2 = 0 1

c
XL = ωL and = XC
x2 = 2 (y – 12) ωC
∴ latus rectum = 2
g. If ‘f’ is decreased then ω will decrease and hence XC will
ng
(23) (A). increase therefore at f < fr, circuit behaves as capacitative.
If the slopes are complementary then m1 m2 = 1 VL and VC always differ in phase by 180° at any frequency
(29) (A).
ye

2
∴ m3 = – 1 2 1
h = +
.m

F FL Fm
2
using m3 = – in (1) we get

////////////// ///
h
////////////////
w

8 4
w

− 2
+ (4 − k) +2=0
h h2
w

///

⇒ – 4 + 2 (4 – k) + h 2 = 0 ⇒ h 2 + 4 – 2k = 0
://

∴ x2 = 2 (y – 2)
x2 = 2Y R
Fm = ∞ Fm =
tp

where Y = y – 2 2
⇒ a = 1/2
ht

∴ directrix is Y = –1/2 or y – 2 = –1/2 1 n −1 1 n −1

= =
FL R FL R

R R
y= –a F1 = F2 =
2 ( n − 1) 2n
∴ 2y – 3 = 0
(24) (C).
F1 n
4S Ratio = =
P1 − P0 = ......... (1) F2 n − 1
2R
P2 (30) (BCD). Intensity increases no. of photon coming on plates
4S therefore it wouldn’t change stopping potential, work func-
P2 − P1 = ......... (2)
R P1 tion and maximum K.E.
Add (1) and (2) (31) (ABC). When return to same point displacement is zero
P0 therefore average velocity is also zero.
6S
P2 − P0 =
R Total distance 2 ( u2 /2g) u
Average speed = = =
Totaltime 2(u/g) 2
4

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All India Test Series/IIT/FLT 1/ Paper : 1 - SOLUTIONS 5

(32) (ABD). Equivalent circuit (38) (D).V1 + V2 = V0 (remains same st. line)
C
1 1 1
MV12 + MV22 + C1 = MV02
2 2 2
C
C K2 C1 is loss in kinetic energy
C On solving, V02 = V12 + V22 + C 2

( )
2
V12 + V22 = V 02 −C 2 ; V1 + V2 = V02 −C2
2 2
K1
V

1 R = V02 − C2 (< V0 )
When K1 is closed energy stored = CV2
2
Therefore it yields circle of smaller radius.
5C (39) (A). In inelastic collision radius will be less but straight line
When K2 is also closed equivalent capacitance = of momentum conservation will be same.
3
(40) (A). Velocity of object I will always be less than object II,
2 therefore from above two solutions (0.5, 1.5) is correct.
1 1 5 C 2 5CV
Energy stored E = Ceq V2 = V =

om
2 2 3 6 V2
2 (0.5, 1.5)
5CV 2 CV2 2 1

c
Change = − = CV 2 = CV 2

g.
6 2 6 3 A
(1.5, 0.5)
(33) (AC). B
ng
V1
2
ye
.m

(1)
(41) (C). Just after closing, capacitor behaves as short circuit
(2)
and all current flows through it hence ammeter reads zero.
w

(42) (A). After long time capacitor behaves as open circuit and
w

no current flows through it.

Deviation, δ = i + e – A
w

dispersion, θ = (δV – δR) = (n V – n R) A V0 30

Therefore i = = = 2mA
δ1 = –δ2 R1 + R 2 10 + 5
://

δ1 + δ2 = 0
tp

(43) (A). Just after reopening, potential difference across R2

∴ Final ray will be parallel to initial ray. remains same initially as charge on capacitor does not
But θ1 ≠θ 2 ⇒ θ1 +θ 2 ≠ 0
ht

change initially, hence current remains same.

(34) (A). Statement 1 : I ∝ A 2 and I ∝ f2 (44) (C).
2 2 2 2
I1  A1   f1   2  1  a
= =     =1
I2  A2   f 2   1   2 E
mg
Statement 1 : Velocity amplitude : Aω ∝ I mg
therefore if velocity amplitude is same then intensity will
also be same. l  ml 2 
τ = mg + mgl =  + ml2  α
(35) (C). Increase in R deceases i, magnetic flux through ring, 2  3 
which is inside paper, decreases and by Lenz’s law, current
flows to produce flux in inward direction i.e. clockwise. 9g
α=
(36) (C). Electric field also depends upon charge distribution. 8l
(37) (C). In free expansion pressure outside is zero. So no work
is done by ideal gas but in real gas work may be done 9g 9g
a= ×l =
against internal force existing between molecules. 8l 8

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6 All India Test Series/IIT/FLT 1/ Paper : 1 - SOLUTIONS

(45) (A). (49) (B).

l 1  m l2 
EQl + mg + mgl =  + ml2  ω 2 O
–
2 2 3 
O O EtO O
– EtOOC
EtO – EtO EtO
+ EtO
OE t
E O O O EtO O OEt O
OEt OEt
Q
m
O O O
EtOOC EtOOC EtOOC
EtO –

COOEt COOEt
EtO COOEt
O O O OEt
–

(50) (B).
mgQ 3mgl 2ml 2 2 By replacement of 'c' by 'b' in the complex [Ma2 bcde]n± it
− l + = ω
2Q 2 3 becomes [Ma2 b 2 de]n±

om
Geometrical isomers of [Ma2 b 2 de]n±
2ml2 2 3gl
mgl = ω ; v=
3 2 b b a b d

c
a b a b b d a d a b

g.
M M M M M
4ml2 mgl 4ml2 3g a a a e b e a e a b
(B). EQl = α ; = α ; =α
ng
(46) e d a b e
3 2 3 8l cis cis
Total number of Trans
3g
ye

at = Geo. iso. = 6
8
Geometrical : Isomers of [Ma2 bcde]n±
.m

3g a a a
a r = ω2 r = e a e a d a
w

2
M M M
w

EQ c c d c
d e
w

2 2
 3g   3g  3g 1 3g b b b
a =   +  = +1 = 17
8  2
://

2 16 8 a a a
e a d a c a
tp

M M M
(47) (B). d b e b d b
ht

c c e
O O
..
H – O – S – O – H + H – .O. – N O cis
O base
a a a
acid e e b d b
H O M M M
– + d c c d e c
HSO 4 + H – O – N O H2O + NO2 a a
+ a
(48) (B). Trans
O2 – B.O. = 1.5 ; O2 2– B.O. = 1.0 ; F2 B.O. = 1.0 ; Total number of
O2 + B.O. = 2.5 Geometrical isomers = 9
O2 2– and F2 have same bond order and they are different Hence, decrease in number of Geometrical isomers = 3
molecular species, hence bond length is decided by size of
( −1) × 2 × 300
atoms bonded. (51) (D). − 190 = ∆E +
Bond length in O2 2– > Bond length in F2 because size of 1000
O– > size of F. ∆ E = – 189.4 kcal/mol

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All India Test Series/IIT/FLT 1/ Paper : 1 - SOLUTIONS 7

(52) (B). (56) (ABD).CH3 – CH2 – CH3

To convert FeO into Fe2 O3 otherwise FeO can combine It has 6 primary H = 44% given product and 2 secondary
with SiO2 present as gangue in the haematite ore. H = 56% given product.
FeO + SiO2  → FeSiO3 44 28.0 3.82 reactivitywith 2°H
So = 7.33 ; = =
gangue slag 6 7.33 1 reactivitywith1°H

∧m 200 × 10− 4 In CH3 − CH − CH3

(53) (AD). α = = = 0.1
∧∞m 0.2 |
CH3
Acid is 10% ionised so enthalpy of ionisation of It has 9 primary H = 66 % given product
2.7 It has 1 tertiary H= 33% given product
XOH = = 3kJ/mol
0.9 66 33 4.5 reactivitywith3° H
so = 7.33 ; = =
XOH (aq) ƒ X+(aq) + OH– (aq) 9 7.33 1 reactivitywith1°H
c–x x x
33
= 33
(0.1C)2 1
Kb = = 0.011
∴Reactivity ratio for monochlorination with

om
0.9C
1°H : 2°H : 3°H = 1 : 3.82 : 4.5
10−14
Ka = = 9.1 × 10− 13 H

c
0.011 |
(A) CH 3 − CH − CH − CH 2 − CH3
Due to cationic hydrolysis resultant solution is acidic
(AC). XY (aq) → X+ (aq) + Y– (aq) g. |
CH 2 − CH3
ng
(54)
X+ (aq) + H2 O (l) ƒ XOH (aq) + H+(aq)
At equilibrium : Cl
ye

C (1 – α) – Cα Cα |

→ CH3 − CH − CH − CH2 − CH3 (Major product)
.m

|
Kw 10−14 80 1
[H+] = Cα = ×C ; (10− 5 ) 2 = −5
× × CH 2 − CH3
Kb 4 × 10 M 2
w

1° H = 9 × 1 = 9
2° H = 6 × 3.82 = 22.92 (major) % of 2-chloro-3-ethyl pen-
w

Kh
M = 100 gm/mol; %α = × 100 ⇒ 2.5 × 10− 3 tane
w

C
22.92
3° H = 1 × 4.5 = 4.5 (minor) = = 62.93%
://

+ −
a for XY : 3a = 2 ( r + r ) 36.42
Total ⇒ 36.42 ≈ 63% ∴ X = 63
tp

1.732 × a = 2 (1.6 + 1.864)

a = 4Å = 4 × 10–8 cm. Cl
ht

Effective formula unit of XY = 1 |

(B) CH3 − CH 2 − C − CH2 − CH3 (minor)
Z.M 1 × 100 1 × 1000 |
d= = = = 2.6gm/cc
a 3 × NA (4 × 10−8 )3 × 6 × 1023 384 CH 2 − CH3
(55) (ACD). (A) At T1 and T2 the value of ∆Gf for MgO be- % of 3-chloro-3-ethyl pentane
comes more and more positive due to decrease in entropy 4.5
in the formation of MgO. = × 100 = 12.36% ≈ 12 ∴ Y = 12
36.42
T1
2 Mg (l) + O2 (g)  → MgO(s)
CH3 CHO
T2 (C) (i) O3
2 Mg (g) + O2 (g) → 2MgO(s) (ii) Zn, H2 O 2 H–C –C +
CHO
(C) Beyond T3 , ∆Gf of CO is more negative than that of O O
MgO
T3 CH3
Mg(g) + CO ↑ (i) O3 CHO
(D) MgO (s) + C(s) 144244 3 CH3 – C – C +2
gaseousproduct (ii) Zn, HO
2
CHO
↓ Rapidcooling O O
Mg(s)

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8 All India Test Series/IIT/FLT 1/ Paper : 1 - SOLUTIONS

(59) (B). 4S + 6NaOH  → 2Na 2 S + Na 2 S2 O3 + 3H2 O

i.e. Initially H2 S and H2 S2 O3 are formed which react with
(i) O3 CHO NaOH and final products are Na 2 S and Na 2 S2 O3 .
2 CH3 – C – C H +
(ii) Zn, H2O (60) (C). (CO)5 Mn – Mn (CO)5
CHO
O O Total number of electrons in both Mn atoms
= 2 [Atomic number of Mn + 5 × number of electrons con-
tributed by CO] = 2 [25 + 5 × 2] = 70
(i) O3 It can not act as an oxidising agent.
2 CH 3 – C – CH + CHO (61) (C).
(ii) Zn, H2O
O O CHO Cr2O 3(s) + N2 + H2 O (g)
(NH4) 2C r2 O7
(A) (B) (C) (D)
C2 H5 Orange solid Green solid
Mg CoCl 2
Conc.
HCl
(i) O3 C2H5 – C – C H CHO Mg3N2
+2 CrCl3 (I)
(ii) Zn, H2 O (F) CoCl.6H 2O
O O CHO 2
Green sol. Pink
H2 O (E)

om
So we obtain four types of product (given in bracket)
∴Z=4 H2O2/OH
(D) X + Y + Z = 63 + 12 + 4 = 79 NH 3
(J)

c
2–
CrO4
NiCl 2

g.
(G)
(55) (A) p, q, r, (B) – p, q, s, (C) – r, (D) – p, q, r Yellow sol. sol.
For 2s : Number of radial node = 1, number of maxima in 2+
ng
[Ni(NH3) 6]
radial probability distribution curve = 2, No. of angular Et2 O H2 O2 /H + Deep blue
node = 0 (K)
ye

For 4d : Number of radial node = 1, number of maxima in CrO.OEt

5 2
radial probability distribution curve = 2, No. of angular (H)
.m

node = 0 Blue
(56) (A) r, s; (B) – r ; (C) p, r, s ; (D) p, q
Mn 2+ + NH3 + 2H 2O 
→ Mn(OH) 2 ↓ +2NH +4
w

∆
(A) CuS + 2O2 
→ CuSO4
w

∆ H2O2
CuS + CuSO4 
→ 2Cu + 2SO2 ↑
w

∆ MnO.(OH) 2 ↓ orMnO 2
PbS + 2O2 
→ PbSO 4
://

Brownishblack
∆
PbSO4 + PbS  → 2Pb + 2SO 2 ↑ (62) (B). Ni2+ in [Ni(NH3 )6 ]2+
tp

(B) During smelting step of extraction of Cu copper (I)

3d
ht

sulphide is not reduced, while other metal oxides can be

reduced to respective metals during carbon reduction i.e.
smelting process.
(C) Main ores of Ag, Pb and Cu occur as sulphides hence 4s 4p 4d
they are concentrated by froth floatation process.
1
(D) (p) 2Ag + 4CN − + O 2 + H 2 O ƒ 2[Ag(CN) 2 ]− + 2OH −
2 Hyb. sp3d2
(Impure) [Soluble]
µeff = 2.8 B.M.
2[Ag(CN) 2 ] − + Zn 
→[Zn(CN) 4 ] 2− + 2Ag ↓ (63) (D).
O
(q) 2Au + 4CN − + 1 O 2 + H 2 O ƒ 2[Au(CN)2 ]− + 2OH − O O
2 2– + + 3H2O
(Impure) [Soluble] CrO4 + 2H2O2 + 2H Cr
O O
2[Au(CN) 2 ]− + Zn  →[Zn(CN) 4 ]2− + 2Au ↓ deep blue
(unstable in the absence
(57) (C). Victor Meyer test is a identification test. of organic solvent)
(58) (D). Nitrobenzene is a deactivated ring & deactivated rings
do not give F.C. reaction. → CrO5 is stabilized in presence of ether, Amyl alcohol,
amylacetate.
8

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All India Test Series/IIT/FLT 1/ Paper : 1 - SOLUTIONS 9

(64) (A), (65) (C), (66) (D).

CH3 Br Br

Et CH CH = CH2 CH – CH2Br CH CH COCH3

NBS alc. KOH Br2 alc. KOH HgSO4

CCl4 NaNH 2 dil. H2S O 4
(A) (B) (C) (D) (E)

HOCl
excess

OH O OH
OH Cl
CH– COOK CO – CHO C – CHCl2 C – CH
Cl
Intramolecular KOH
Cannizaro

om
(G) (F)
(67) (B).

c
(I) eg
dx2– y2 dz2

g.
0
t2g
ng
dxy dyz dzx
In d 1 , d 2 , d 3 system for octahedral ligand field, electronic distribution of any metal cation does not change, whatever may be
ye

ligands.
(II) eg
.m

dx2– y2 dz2
0
t2g
w

dxy dyz dzx

w

5d6
w

Due to increased Zeff value for 3rd transition series metal cation, ∆0 value gets increased, and P < ∆0 , therefore electronic
distribution for d 6 will not change, whatever may be the ligands.
://
tp

(III) eg
dx2– y2 dz2
0
ht

t2g
dxy dyz dzx
Electronic distribution for d8 system for any octahedral ligand field does not change, hence, hybridization and magnetic
moment do not change.
(IV)
4s 4p 4d 4s 4p 4d

eg eg
dx 2– y 2 dz2 dx 2– y 2 dz2
0 0
t2g t2g
dxy dyz dzx dxy dyz dzx

P> 0 P< 0
d7 d7
Hybridisation : sp3d2 Hybridisation : d2 sp3
µeff : 3.89 B.M. µeff : 1.732 B.M.

Hence for d 7 system hybridisation and µeff value changes according to strong or weak field ligand.
9

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10 All India Test Series/IIT/FLT 1/ Paper : 1 - SOLUTIONS

(68) (C).
(III) eg
dx2– y2 dz2
0
(I) eg t2g
dx2– y2 dz2 dxy dyz dzx
0
t2g
d3
dxy dyz dzx
For given P < ∆0
d5 Hybridisation : d 2 sp 3
For given P > ∆0 Inner orbital complex
Hybridisation : sp3 d 2 µeff : 3.89 B.M.
µeff : 5.9 B.M.
Outer orbital complex/high spin complex. (IV) eg
dx2– y2 dz2
0
4d t2g
4s 4p
dxy dyz dzx
(II) d6
For given P > ∆0

om
eg Hybridisation : sp3 d 2
dx2– y 2 dz 2
0 Outer orbital/high spin/spin free complex.
t2g (69) (B).

c
dxy dyz dzx (A) Due to higher oxidation state of Cobalt in

g.
d7
III
[Co(H 2O) 6 ]3+ , P < ∆0 , also H2 O lies towards stronger
ng
For given P < ∆0
Hybridisation : d 2 sp 3 ligand side in spectrochemical series.
(B) Due to high value of Zeff in Ir+3 , which belongs to IIIrd
ye

µeff : 1.732 B.M.

Inner orbital complex/low spin complex/spin paired com- transition series (P < ∆0 )
(C) CO is a strong field ligand hence P < ∆0
.m

plex
(D) Due to high value of Zeff of Pd 2+, which belongs to
2nd transition series, [P < ∆0 ]
w
w
w
://
tp
ht

10

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