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All India Test Series/IIT/FLT 1/ Paper : 2 - SOLUTIONS 1

THE ACE TUTORIALS

FLT - 1 (PAPER - 2) : SOLUTIONS
STANDARD ANSWER KEY
Q 1 2 3 4 5 6 7 8 9 10 11
A A A A D A A C B B ABC AC
Q 12 13 14 15 16 17 18 19 20 21 22
A AB C A C A B C D D A B
Q 23 24 25 26 27 28 29 30 31 32 33
A A D C B B C C C B AB ABC
Q 34 35 36 37 38 39 40 41 42 43 44
A ABCD B A C C A C B D D C
Q 45 46 47 48 49 50 51 52 53 54 55

om
A D B A C B B B C A ABC AC
Q 56 57 58 59 60 61 62 63 64 65 66
A BC B C D D D B B B C A

c
(1) (A). (3) g. (A). 9a + 3b + c = 90
ng
ak = (k2 + 1) k! = (k (k + 1) – (k – 1)) k !
= k (k + 1) ! – (k – 1) k ! c
3a + b + = 30
ye

So k (k + 1) ! – (k – 1) k ! 3
a1 = 1 . 2! – 0 Now using GM ≤ AM for 3 numbers 3a, b and c/3
.m

a2 = 2 . 3! – 1 . 2!
a3 = 3 . 4! – 2 . 3! c
1/3 3a + b +
 c
w

M ≤ 3
ak = k (k + 1) ! – (k – 1) k !  3a.b. 3 3
w

––––––––––––––––––––
w

a1 + a2 + ...... + ak = k (k + 1) ! 30
Hence b k = k (k + 1) ! (abc)1 / 3 ≤ = 10
3
://

a k (k2 + 1)k! (k 2 +1) k 2 +1 ∴ abc ≤ 1000

= = =
tp

∴
bk k(k + 1)! k(k +1) k2 + k log a + log b + log c ≤ 3
⇒ log a + log b + log c |max = 3
ht

a100 10001 m
∴ b = 10100 = n ∴ (n – m) = 99 (4) (D).
100
n
f(x)   π π   nπ n π
(2) (A). Consider a function g(x) = (1 + i 3)n =  2  cos +isin   =2n cos + 
isin
x   3 3   3 3
as f (x) and x are differentiable hence g (x) is also differen-
tiable. nπ
f ((1 + i 3) n ) =realpartof z =2n cos
f(a) f(b) 3
Now g(a) = and g(b) =
a b 6a
nπ 6a nπ
f(a) f(b) ∴ ∑ log2 2 n cos = ∑ n +log2 cos
Since = ∴ g (a) = g (b) n= 1 3 n =1 3
a b
Hence Rolle’s theorem is applicable for g (x) 6a(6a + 1)
∴ ∃ some x0 ∈ (a, b) where g ' (x) = 0 = + ( − 1 − 1 + 0 −1 −1 +0)
2 144424443
a suchterm
xf ′ (x) − f(x) x 0f ′ (x0 ) − f ( x 0 )
but g ′ (x) = , g ′ (x 0 ) = =0
x2 x 20 = 3a (6a + 1) – 4a = 18a 2 – a
∴ x0 f ' (x0 ) = f (x0 )
1

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2 All India Test Series/IIT/FLT 1/ Paper : 2 - SOLUTIONS

(5) (A). (8) (B). f (x) is increasing

π/ 2
  1 + cosx  1 −cosx
  x+ 1  x +1
 1 x +1 ln
I= ∫ e x cos(sinx)  2 
+sin(sinx)

 dx
2   g(x) = 1 +  =e  x 

0  x
π/ 2
1 x +1
∫e [{cos(sinx) + sin(sinx)} +cosx{cos(sinx) −sin(sinx)}]dx  x + 1 
x
= 2 14444244443 1444442444443  1  1 1 
f ′( x ) g ′ (x) =  1 +   (x +1)
 −  +ln    
 x
0
+1
f(x)
 x x x 
π/ 2 π/ 2
1 1  1 π/ 2
= ∫ e x [f(x) + f ′( x )]d x = e xf ( x ) =  e x {cos(sinx) sin(sinx)}
+  x +1
2 2 0 2 0
 1  x+ 1 x +1 
=  1+   ln  x  +1 − x 
0

 x  
1 π/ 2
= [e (cos1+ sin1) −1]
2 x +1
Let = u ∈ (1, ∞) as x > 0
dy x
(6) (A). − y = 1 −e − x , I.F. = e–x Consider h (u) = ln u + 1 – u
dx
1
∴ y . e–x = ∫ (e− x − e −2x ) dx h'(u) =
u
– 1 < 0 in (1, ∞)
Hence, g (u) is a decreasing function in (1, ∞)
1
y.e− x = −e− x + e− 2x +C

om
h (u) < h (1)
2 h (u) < 0
If x = 0, y = y 0 ∴ g ' (x) < 0 ⇒ g is decreasing
∴ f is increasing and g is decreasing

c
1 1
y0 = −1 + +C ⇒ =y 0 +

g.
C (9) (B). m = 5 . 5. 8. 7 = 1400
2 2
ng
−x −x 1 1
+ e− 2x +y0
5 5 8 7
∴ y.e = −e + n = 1400 – (5 . 8. 7) = 1400 – 280 = 1120
2 2
ye

If x → ∞ , then y 0 = –1/2 0
(7) (C). 1400 5
⇒k= =
.m

A = ((5 +2 6) ) 2 1/4
=(5 2+ 6) 1/2
[(= 3 +2) ]
21/2
1120 4
(10) (ABC).
w

8 6 16
A= 3 + 2 , B=8 3 + + + ,∞
Hence, ........ x x
f(x) = ∫ e sin(x −t)dt = ∫ e sin(t)dt
t x− t
w

3 3
0 0
w

8 6 21 8 3 (8 3) 3
r= . = ∴ B= = x
− 3 − 2
://

f(x) = ex ∫ e − t sintdt
3 8 3 3 1 ( 2 / 3)

B = 24( 3 + 2) 0
tp

Hence, quadratic equation is x 

f ' (x) = ex . e–x sin x +  ∫ e sin t d t e
−t
ht

2 4 ( 3 + 2) 0 
( 3 + 2 ) ( 3 − 2 ) x2 + x +C =0
( 3 + 2) f ' (x) = sin x + f (x) .......... (1)
x2 + 24x + C = 0 ........ (1) f '' (x) = cos x + f ' (x) = cos x + sin x + f (x)
[Using (1)]
Now, | α − β | =(6 6) k f '' (x) – f (x) = sin x + cos x .......... (2)

1 g (x) = sin x + cos x ⇒ g(x) ∈ [− 2, 2 ]

k = log6 10 – log6 5 + log6 ((log6 (18.72)) r r r
2 (11) (AC). ( r − a).n1 = 0
rr rr
1 r.n1 = a.n1
= log6 2 + log6 (log6 1296)
2 (xiˆ + yjˆ +zk).(i
ˆ ˆ +ˆj) =2
1 ^ ^
= log6 2 + log6 4 = 2 log6 2 = log6 4 n1 = i + j
2
∴ | α – β | = (6 6) log6 4 = ((6)3/2 )2log 6 2 =6log6 8 =8 P1 L
A
Hence (α – β)2 = 64
r=(1,1,1)+λ (1,–1,–1)
(α + β)2 – 4 αβ = 64 (1,1,1)
576 – 4C = 64 ⇒ 4C = 512 ⇒ C = 128
2

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All India Test Series/IIT/FLT 1/ Paper : 2 - SOLUTIONS 3

x + y = 2 ⇒ (A) is correct ( | z | – 2) ( | z |2 – | z | – 2) = 0
uuur ( | z | – 2) ( | z | – 2) ( | z | + 1) = 0 ⇒| z | = 2
Now, AB = ˆi +kˆ
or | z | = – 1 (rejected)
ˆi ˆj kˆ
uuur r r 2
Now AB × V = n2 = 1 0 1 Now, if 0 < | z | < then equation (1) becomes
3
1 − 1 −1
| z |3 = 4 – 3 | z |2 ⇒ | z |3 + 3 | z |2 – 4 = 0
r | z |2 ( | z | – 1) + 4 | z | ( | z | – 1) + 4 ( | z | – 1) = 0
ˆ − 1) ⇒ rn = ˆi + 2jˆ − kˆ
n 2 = ˆi ( 0 + 1) − j(ˆ − 1− 1) + k( 2 ( | z | – 1) ( | z |2 + 4 | z | + 4) = 0
( | z | – 1) ( | z | + 2)2 = 0 ⇒| z | = +1 or | z | = – 2 (rejected)
n2 = AB × V Hence, | z | = {1, 2} where | z | = z1 + z2 + z3
2x + 2
(13) (C). f (x) = ln (2 + x) – is continuous in (–2, ∞)
x+3
^ ^ ^
V = i –j – k
^
B(j) 1 4 (x + 3) 2 − 4(x +2)
f ′ (x) = − =
P2 x + 2 (x + 3) 2
(x +2) ( x +3) 2

om
r x 2 + 2x +1 (x +1) 2
Hence equation of P2 is ( r − ˆj).(iˆ + 2jˆ −k)
ˆ =0
= >0 (f ' (x) = 0 at
=

c
r ˆ ˆ ˆ (x + 2)(x +3) 2 (x +2 ) ( x +3) 2
r . ( i + 2j − k) = 2 ⇒(B) is not correct.
If θ is the acute angle between P1 and P2 then
g. x = – 1)
⇒ f is increasing in (–2, ∞)
ng
r r Also, lim f(x) →−∞ and lim f ( x ) → ∞ ⇒ unique
(iˆ + ˆj).(iˆ +2ˆj −k)
ˆ x→ 2+
x→ ∞
ye

n1 .n 2 3 3
cos θ = r r = = =
| n1 | . | n 2 | 2. 6 2. 6 2 root
.m

π  1 −3 −4   1 −3 − 4  0 0 0
θ = cot − 1 3 = ⇒ (C) is correct
6 (14) (A). A =  −1 3
2
4   −1 3 4  = 0 0 0
w

    
As L is contained in P2 ⇒ θ = 0  1 −3 −4   1 −3 − 4  0 0 0
w

1 ⇒ A is nilpotent
(AB). Given | z1 | = | z2 | = | z3 | = 1 ⇒ z1 = z
w

(12)
1 (15) (C). If f (x) is odd, then f ' (x) is even but converse is not true
://

e.g. if f ' (x) = x sin x

z12 z22 z32 then f (x) = sin x – x cos x + C
tp

Also, + + +1 =0
z2 z3 z1z3 z1z2 f (–x) = – sin x + x cos x + C
ht

⇒ (z1 )3 + (z2 )3 + (z3 )3 + z1 z2 z3 = 0 ––––––––––––––––––––––

⇒ (z1 )3 + (z2 )3 + (z3 )3 – 3z1 z2 z3 = – 4z1 z2 z3 f (x) + f (–x) = constant which need not to be zero.
(z1 + z2 + z3 ) [(z1 )2 + (z2 )2 + (z3 )2 – Σ z1 z2 ] = – 4z1 z2 z3 x
Σ z1 [ (Σ z1 )2 – 3 Σ z1 z2 ] = – 4z1 z2 z3 For statement-1 : f(x) = ∫ 1 +t 2 dt, g(x) = 1 +
x2
Let z1 + z2 + z3 = z 0
z [z2 – 3 Σ z1 z2 ] = – 4z1 z2 z3
z3 = 3z Σ z1 z2 – 4z1 z2 z3 −x
f ( − x) = ∫ 1 +t 2 dt, t = y−
 1 1 1  0
z 3 = z1 z2 z3 3z  + +  −4
  z1 z2 z3   x

= z1 z2 z3 [3z(z1 + z2 + z3 ) − 4] f ( − x) = −∫ 1 +y 2 dy
0
z3 = z1 z2 z3 =[3 | z |2 – 4] ........... (1)
∴ f (x) + f (–x) = 0 ⇒ f is odd and g is obviously even.
2
Now, if | z | ≥ (16) (A). ∆ = 12 5 using Heroes formula.
3
then | z | = 3 | z |2 – 4 ⇒ | z |3 – 3 | z |2 + 4 = 0
3
21 5 Q R = abc 
R= 
| z |2 ( | z | – 2) – | z | ( | z | – 2) – 2 ( | z | – 2) = 0 10  4∆ 
3

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4 All India Test Series/IIT/FLT 1/ Paper : 2 - SOLUTIONS

(17) (B)., (18) (C)., (19) (D).

= (12 2 − 4 2) − (12 − 2) = 12 2 −4 2 −10 =8 2 −10
The parabolas will have their concavities in opposite di-
rection otherwise they can not touch. ∴Required area = 2 − [8 2 − 10] = 12 −8 2 =4 ( 3 2− 2 )
Method 2 :
y
2  3 y  3  
Directrix ∫  6 −  −
2   2
4− y  dy

y=23/8 0  
2 2
V1(0,4) 3 2 3/2  3 2 
= 6y − . y  + . (4 − y)3/2 
(0,23/8) S (6,9/8) 2 3  2 3 0
P(x1,y1) y 0
2
S
C x
O 3Q V(6,0)
2
Directrix V1(0,4)
y= –9/8
(3,2)

om
Let P1 : x2 = – λ (y – 4) (λ > 0) ..... (1)
and P2 : (x – 6)2 = λy .... (2)
Solving the two equation x
–3√2 O 3√ 2 V(6,0)

c
2
 (x − 6) 2 
x2 = −λ
 λ
−4 ⇒ x2 = −(x −6) 2 +4 λ
 g.
ng
x + (x – 6) – 4λ = 0 ⇒ 2x2 – 12x + 36 – 4λ = 0
2 2 = (12 − 2.2 2) − (0) + 2(2 2 −8)
b 2 – 4ac = 0 ⇒ 144 = 4 × 2 (36 – 4λ) ⇒ 18 = (36 – 4λ) = (12 – 4) + (4 − 8 2) = 12 −8 2 = 4(3 −2 2 )
ye

⇒ 4λ = 18 ⇒ λ = 9/2
Hence the parabolas are (20) (D)., (21) (A)., (22) (B).
.m

P(E) = p
9 9
x2 = − (y −4 ) ; ( x −6) 2 = λ ⇒ Latus rectum = 9/2 P (F) = P (E ∩ F) + P (E ∩ F)
2 2
w

P (F) = P (E) P (F/E) + P(E)P(F/E)

dy 
w

Again, must be same for both parabolas.

dx  P ( x , y ) E
F
w

1 1

dy dy  2x 9
://

2x = − λ ⇒  = − 1 (where λ = ) E
dx dx  ( x , y ) λ 2
1 1
tp

1 4p 1
= p.1 + (1 – p). = +
5 5 5
ht

dy dy  2(x1 − 6) 9
and 2(x − 6) = λ ⇒ = (where λ = ) (20) If p = 0.75
dx dx  ( x1 , y1 ) λ 2
1 1
∴ 2 (x1 – 6) = – 2x1 P (F) = (4p + 1) = (4) =0.8
4x1 = 12 ⇒ x1 = 3 5 5
when x1 = 3 then y 1 = 2 P ( E ∩ F) 0.75 15
∴ point of contact = (3, 2) ⇒ sum = 5 ∴ P (E/F) = = =
P(F) 0.80 16
(19) Method I :
5p
6 3 6 (21) Now P(E/F) = ≥p
2 2 ( x − 6) 2 (4p + 1)
A1 = ∫ (x −6) 2 dx =  = [0 (− 3)− ] =
3
2
3
9 9 3  3 27 Equality holds for p = 0 or p = 1
for all others value of p ∈ (0, 1), L.H.S. > R.H.S.
(A 1 ≡ Ar. PCV2 )
(22) If each question has n alternatives then
3 2
 2x2 2 3
3 2
1  1  1 (n − 1) p + 1
A2 = ∫ 

4 −
9 
dx = 4x − x
27 3
P(F) = p + (1 − p)
n
= p  1−  + =
 n n n
3
np
 2 × 54 2  2  ∴ P (E/F) = (n − 1) p + 1 which increases as n increases
= 12 2 −  −12 − 27 ×27 (A 2 ≡Ar.PCQ)
 27 
for a fixed p.
4

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All India Test Series/IIT/FLT 1/ Paper : 2 - SOLUTIONS 5

T “O” acts as focal point.

1  1 1 1 1 1
60° = ( µ −1)  −  ; = ( µ −1)  + 
f  R1 R 2  40  10 10 
/2
(23) (A). 30° 1  2 9
T' = ( µ −1)   ⇒ µ =
2T 3 40  10  8
2 (30) (C).
Sum of heat current at C is zero.
(T − T ′) A ( 2T − T ′) A q
+ =0
ρ×l ρ× ( 3 l /2)

( 2T − T ′ )  2 2 + 3
⇒ (T − T ′ ) + 2 =0 ⇒T′ =  T 100 –q –50 +q
3  2+ 3 
(24) (D). In Case-I no horizontal external impulse on ball and –100 +q +50 –q
mass system while in Case-II friction is impulsive as normal

om
with ground is impulsive.
∴ both are wrong.
(25) (C).
3Q → P + energy (e)

c
g.
e = EP – 3EQ v2 100 − q 50 − q
(26) (B). −6
+ =0
v1 5 × 10 20 ×10−6
ng
2π 4
ω1 = rad/hr. 10 ⇒ q = 90 × 10–6 C
1 ∴ Final charge on 5µF top plate is 10µC.
ye

2π (31) (B).
ω2 = rad/hr.
8
.m

XL XC
2 3 tan θ1 = ; tan θ2 =
 T1  R 1 R R R
 T   =  R  ⇒ 2 =4 ⇒R2 =4 10
× 4 km
w

2 2 R1 X C − XL
tan θ =
w

R
2πR1
v1 = = 2π ×104 km/hr tan θ = tan θ2 – tan θ1
w

1h
(32) (AB).
://

2πR 2
v2 = = π × 104 km/hr
8h
tp

At closest separation
ht

vrel ⊥ to line joining π × 104 km/hr π

ω= = = rad/hr.
length of line joining 3 × 104 km 3
(27) (B). Initial velocity v 1 must be greater than v 0 if it has to A B
reach same height and finally while coming back it will i
approach a terminal velocity. Hence (B)
A1 + A2 A2 x − 1 G
(28) (C). A − A = x ; A = x + 1 C D
1 2 1
i
2
 x − 1
Energy ∝ A 2 ⇒ 
 x + 1 For null point current flows in the loop CD only.
(29) (C). 3V
i= =1A
2Ω + 1 Ω
VCD = 1V – 1 (1) = 0 ∴ option (A) is correct
O VA > VB
When Jockey touches B current flows from A to B to in-
crease the P.D. across the secondary circuit.
∴ option (B) is correct.
5

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6 All India Test Series/IIT/FLT 1/ Paper : 2 - SOLUTIONS

(33) (ABC). (42) (D).

m1
a2 mv 2m(KE)
(A) I = (m2 +m 3 ) r= =
4 qB qB

H 3H p+ α 2 + 6
Li2 + 12
C3 +
(B) H = I ω, ω = = 2 a/2 a/2
(Md 2 /3) Md m2 m3 m 1 4 6 12
m1 x1 + m 2 x 2 m1 y1 + m 2 y 2 q +1 +2 +2 3+
(C) xCM = m1 + m 2 ; yCM = m + m
1 2
m
r∝
m z + m 2z 2 q
z CM = 1 1
m1 + m2 r1 = r2 < r4 < r3
(D) According to Newton’s third law they exert equal and 2πmvcos θ m
(43) (D). P = ⇒P∝
opposite forces on each other in both (a) and (b). qB q
(34) (ABCD)
∴ P1 < P2 < P3 < P4
W iaf + Uif = Hiaf

om
20 + Uij = 50 mvsin θ 2mqv m
Uif = 30 and W ibf + W if = Hibf (44) (C). r = = sin θ ⇒ r ∝
qB qB q

c
W ibf + 30 = 36
r1 < r2 < r3 < r4

g.
W ipf = 6
(A) W ibf = 6 (45) (D).
ng
(B) Hfi = W fi + Ufi = 13 + 30 = 43
(C) Uif = 30, Ui = 10, Uf = 40 H
ye

(D) Hib = W ib + Uib = 6 + (22 – 10) = 18 N H

(A) H x N ; x = 1.46 Å
(35) (B). M = K L1L2 , K = 1 if rings are coplanar.. sp3
.m

H
(36) (A). Work done by action reaction force may be zero only
if disp. of both bodies are same.
w

y y +
(37) (C). (B) N N O N=N=O
w

Statement 1 : As net charge of dipole is zero.

HO
Statement 2 : Gauss law is valid for all charge distributions.
w

N
(38) (C). i = i0 (1 −e− t/ τ ) at t = 0, i = 0 z
://

(C)
N
OH
tp

di i0 L − t / τ
e = −L = e at t = 0, e ≠ 0
dt τ O
ht

(39) (A). A 1 v 1 = A 2 v 2 O
4cm2 × 1m/s = 1mm2 × 2m/s N v N sp ²
(D)
400mm2 × v = 1 mm2 × 2m/s O O
v=1.64 Å
2 20
v= = mm/s = 5mm/s v>x>z>y
400 4
N2 H4 exists in gauche conformation hence repulsion be-
(40) (C). Height of syringe = V/A = 5cm
tween l.p. and l.p. is reduced while in N 2 O4 all atoms being
Work done = ∆ KE of water + gain in PE of water + gain in
is same plane there is repulsion between two bonds hav-
1 ing B.O. = 1.5 each, hence N–N bond length in N2 O4 is
PE of piston = (Vρ)v 2 + m1 gh 1 + m2 gh 2 greater than N – N bond length in N2 H4 .
2

1 H
= [(20 × 10–6 ) 1000]22 + [20 × 10–3 × 10 × 2.5 × 10–2 ]
2 O
O N H
+ [0.1 × 10 × 0.05] = 0.04 + 0.005 + 0.05 = 0.095 J H
N N
N
(41) (B). Force exerted by external agent on the piston will O O H
continuously decrease
6

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All India Test Series/IIT/FLT 1/ Paper : 2 - SOLUTIONS 7

(46) (B). (49) (B). (A) Hydrolysis by SN2 for both

H
+
N N N
– SN2 +

OH (B) Cl Cl + H2O Cl Cl OH 2 Cl Cl – OH
H Cl Cl Cl
–HOCl
CH3 – CH – CH – CH3 CH3 – CH = CH – CH3 (Cis/trans)
Trans is major N 2H 2O
Br H H + HOCl N
Br 2/CCl4 Cl H
H
Cl

CH3 Antiaddition at
H 3 0 0° C
H3C H Br trans obtained NF3 + 2H2 O → HNO2 + 3HF
Br Br
H Br erythreo product Mechanism by S N1 :
H
CH3 CH3 Step I :

k′ E  1
300°C
N+ + F–
1 N
(47) (A). ln 1 = 1  −  ........ (1) F F slow F F

om
k1 R  T1 T2 
F
k2′ E 2  1 1  Step II
=  − 

c
ln ........ (2)
k2 R  T1 T2 

Solving we get eq. (2) – eq. (1) : g. N+ + H 2O

Fast
N + –H+ N
ng
F F OH2
F F OH
F F
k′ k′  E − E1  1 1
ln 2 − ln 1 =  2   − 
ye

k2 k1  R   T1 T2  H 2O
.m

H2 O H2O
HON=O N NF(OH) 2unstable
k1 2k'1 F– F O
Q for 2 : 1 molar ratio =
k2 k '2
w

(C) Hydrolysis by SN2 for both

(D) Hydrolysis by SN2 for both
w

 k′ k   8314 (T2 − 300)

ln  2 × 1 =  
 k1′ k2   8.314 300 × T2
w

(50) (B).
://

 T2 − 300 0.7 × 3  300 CH2 – I

= 1 −  + –
tp

ln 2 = (1000)   ;
 300 × T2  10  T2  CH3 – C C – H
NaH –
CH3 – C C
ht

(X)
300  0.7 × 3
= 1 − 
T2  10  O

CH 2 – C C– CH3 CH 2 – C – OH
300 × 10 O3
T2 = = 379.746 K = 379.75 K O
(10 − 0.7 × 3) H2 O2
+ CH3 – C – OH
(48) (C).Serpeck’s process is used when bauxite contains SiO2
(51) (B). ∆Tf = Kf.m.i
as impurity.
0.2406 = 1.86 × 0.1 (1 + α) ; α = 0.1
∆
Al2O3 + 3C +N 2 
→2AlN +3CO ↑ HCOOH(aq) ƒ H+(aq) + OH– (aq)

1 8 0 0° C Cα 2 0.1 × (0.1) 2 1
SiO2 + 2C 
→Si +2CO Ka = = × −2
= 10
(1− α ) 0.9 9
AlN + 3H2O 
→Al(OH) 3 + NH3 ↑
Kw 10− 14
steam Kh = = × −12
=9 10
1
1 4 7 0° K
Ka × 10−2
2Al(OH)3 
→ Al2 O3 + 3H2 O 9
7

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8 All India Test Series/IIT/FLT 1/ Paper : 2 - SOLUTIONS

AquaRegia
(52) (C). (A) Ag + [Cl]  →Noreaction
AquaRegia
Au + 3[Cl] 
→AuCl3
soluble

(B) Ca 2 + + Na 2 CrO4 
→Noppt.asCaCrO 4 is soluble (Ksp of SrCrO4 > 10–5 )

Sr 2+ + Na 2CrO 4 
→ SrCrO 4 ↓ +2Na +
Yellowppt.
(K sp = 10− 5 ) both Sr2+ and Ba2+
give yellow ppt.
Ba 2 + + Na 2 CrO 4 
→ BaCrO 4 ↓ +2Na + with Na2 CrO4
Yellowppt.
(K sp = 10− 10 )
∆
(C) Cl− + H2SO4  →HCl ↑+ HSO−4 
→ Whitefumes

Br − + H2SO4 
∆
→ HBr ↑ + HSO−4  with Br–


om
− ∆ −
2Br + 3H2SO4 → Br2 ↑ +2HSO4 + SO2 ↑ +2H2 O Reddish
(Reddishbrown)  Brown vapour


c
∆
I − + H2SO4 
→HI ↑+ HSO −4

g.
with I–
violet
∆
2I − + 3H2SO4  →I 2 ↑+ 2HSO−4 + SO2 ↑+ 2H 2O
ng
vapours
(violetvapours)
(D) Only NO2 is decomposed by dil. H2 SO4 , while dil. H2 SO4 has no action on NO3 – .
–
ye

NO −2 + H + 
→HNO2 ↑ ; 3HNO 2 
→ HNO 3 + 2NO ↑ + H 2 O
.m

↓ air
NO 2 ↑
w

Reddish-Brown
w

NO3− + dil.H2SO4 
→noreaction
w

(53) (A).
://

H
tp

O
O O OH N
NaOH
ht

+ NH3
OH
–H2O
+
O O O O O NH2
+
NH2 O

NH2 NH2

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All India Test Series/IIT/FLT 1/ Paper : 2 - SOLUTIONS 9

(55) (AC).
Me Me σ – C3 H5 can exist in two structures :

(B) CH2 = CH OH CH2 = CH – CH (i) H C = CH – CH

2 2
+
O–H
H H
S C
O Cl
Cl
(ii) H2C H2C

(56) (BC). When base is (1/5)th neutralized

Me RNH2 + HCl → RNH3 Cl
a x
Cl – CH2 – CH = CH – Me CH2= CH – CH
a a
O 4 –
Cl 5 5
S

O  a / 5
pOH = pKb + log  
4 a / 5

om
O O O
5 = pKb + log (1/4) [Q pDH = 14 – pH = 14 – 9 = 5]
pKb = 5.6

c
(C) Me – C NaOH/I 2
Me – C Me – C

g.
CH 2 CI 2 CI2
Me – C Me – C Me – C 1
OH pH = [pKw – pKb – log C]
O O O 2
ng
4.5 × 2 = (14 – 5.6 – log C)
O– O O O
log C = – 0.6
ye

– I2 –
OH
+
C = 0.25
OH
Let V ml. of HCl is used
.m

O O
0.5 × V
= 0.25
– –
w

+ CHI3
V + 100
w

V = 100 ml.
(D) CH3 − CH − CH3 
NH 4OH/I2
→ no reaction M. Moles of acid = M. Moles of base = 0.5 × 100 = 50
w

|
OH
50 × 10−3 × 45
://

NaOH + I2 is a good oxidising agent but NH4 OH + I2 is Wt. % of base in sample = × 100 = 90
2.5
not.
tp

(54) (ABC). (57) (B). There is large δ– charge developed (due to F-atom) on
ht

∆ the periphery of C 2 F6 molecule, hence fluoro-carbons have

(A) PO34− + 3HNO3  →H3PO4 +3NO3−
higher boiling point than corresponding hydrocarbons.
∆
H 3 PO 4 + 12(NH 4 ) 2 MoO 4 +21HNO3 → (58) (C). Froth floatation method is used for benefication of
°
Notexceeding40C
sulphide ore like PbS, Cu 2 S etc.
(NH 4 ) 3 PO 4 .12MoO 3 ↓ +21NH 4 NO3 +12H 2 O NaCN or KCN solution is very good depressant to sup-
press the floating property of ZnS not for PbS.
or (NH 4 ) 3[P(Mo3O10 ) 4 ] ↓ (59) (D).
Amm.Phosphomolybdate
(Canaryyellowppt. (Pyrolysis of ester)

− +
H + 
R.T.
(B) NO 2 + (dil.) →HNO2 O ∆ major

R.T.
3HNO2 
→ 2NO ↑+ HNO3 + H2 O O

Hoffmann alkene is major product.

2+ (D). According to spectrochemical series CN– is stronger
SO 24 −
R.T. (60)
FeSO4 (aq) + NO ↑
→ [Fe(H2 O)5 (NO)] +
field ligand, so it has more ∆0 value,
Brown ring complex
so correct order of ∆0 for these complex ions.
(C) 3HgCl2 + SO 24− +2H 2 O 
→HgSO 4 .2HgO ↓ +4H + +6Cl − [CrCl6 ]3– < [Cr(C2 O4 )3 ]3– < [Cr(CN)6 ]3–
Yellowppt.
9

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10 All India Test Series/IIT/FLT 1/ Paper : 2 - SOLUTIONS

(61) (D). x 3x 0 H
CO + 2H2 ƒ CH3 OH CH3 − C = C −CH3 
2 → CH − CH − CH − CH
3 3
| | Ni | |
x–y 3x – 2y y CH3 CH3 CH3 CH3
y 2 2
= ; y = x = 103 mol/sec.
x 3 3 CH3 CH3
| |
3 CH3 − C − CH = CH2 
H2
→ CH3 − C − CH2 − CH3
x= ×103 mol/sec. ; x = 1500 mol/sec | Ni
2 |
CH3 CH 3
(CO, β) = 1500 mol/sec.
(H2 , β) = 4500 mol/sec. (C) Neopentane cannot be prepared.
(62) (B). (CO, γ) = 1500 – 1000 = 500 mol/sec.
D
(H2 , γ) = 4500 – 2000 = 2500 mol/sec. H2
(63) (B). (D)
Ni
CO + 2H2 ƒ CH3 OH
D
q = ∆H × 1000 × 60 = 6 × 104 × 100 × 2 = 12 × 106 cal
q = 12000 kcal

om
CH3 CH3
(64) (B).
CH3
H D D H
H2 CH3 H2 CH2
CH – CH = CH2 CH – CH2 – CH 3 C – CH2 – CH3 +

c
CH3 CH3 CH3
H2 D H H D

g.
CH3
C = CH – CH3 CH3 CH3
ng
CH3

(65) (C). Racemic mixture (optically inactive)

ye

(A) Methane can not prepared by catalytic hydrogena- (66) (A).

tion of alkene
.m

(B) CH3 − CH 2 − CH 2 − CH2 − CH = CH 2

(A)
→ CH3 − CH 2 − CH2 − CH2 − CH2 − CH3
H2

w

Chiral so optically active

Ni
w

CH3 − CH − CH 2 − CH = CH 2
w

H |Pd
| 
2 →
CH3 BaSO4 cis trans
://

Chiral so optically active

(B)
tp

H
2 → CH − CH − CH − CH − CH
 3 2 2 3
Ni |
ht

CH3
H (excess)

2 →
CH3 − CH 2 − CH − CH = CH2 Ni Achiral so optically inactive
| (C)
CH3

H
2 → CH − CH − CH − CH − CH
 3 2 2 3
Ni |
CH3

10

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