Lesson 11 Quality Management
Lesson 11 Quality Management
Lesson 11 Quality Management
1
Quantum Theory and Structure of Atoms and Electronic Structure and
Periodicity
Course Module
where; h = Planck’s constant
h = 6.63 x 10-34 Js (joule-seconds)
v = radiation frequency
E = always expressed in integral/whole number multiples
Photoelectric Effect
Shortly after 5 years Planck proposed the quantum theory, his hypothesis
was used by Albert Einstein (1879 – 1955), to explain another theory, the
photoelectric effect. This theory explains that when certain metals are
exposed to light of at least a certain minimum frequency (also called the
threshold frequency), electrons are ejected from its surface.
No matter how intense the light is, no electrons will be ejected, if below the
threshold frequency. If above the threshold frequency, the brightness of the
light is directly proportional to the number of electrons ejected, while the
energies of the electrons are directly proportional to its frequency.
Using Planck’s quantum theory, Einstein stated that energies are also possess
by each photon, described as:
E = hv
1
𝐸𝑛 = 𝑅𝐻 ( 2 )
𝑛
The farther away the electron is from the nucleus, the higher the excited
state is. However, Bohr’s model cannot explain the spectra of atoms which
are heavier than hydrogen.
Figure 2. The Rutherford-Bohr model of the hydrogen atom (Z=1) or a hydrogen-like ion (Z > 1);
https://en.wikipedia.org/wiki/Bohr_model; May 1, 2017
Course Module
Dual Nature of Electron
In 1924, Louis de Broglie (1892 – 1977), a French physicist, stated the if light
waves behave like a stream of particles, then electrons can have wave
properties. Electrons act like a standing or stationary wave. He also stated
that, if electrons in a hydrogen atom act like a standing wave, then the length
of the wave must exactly fit the circumference of the orbit.
Figure 3.De Broglie and the Bohr model: Waves on a String (a) Waves on a string have a wavelength
related to the length of the string, allowing them to interfere constructively. (b) If we imagine the
string bent into a closed circle, we get a rough idea of how electrons in circular orbits can interfere
constructively. (c) If the wavelength does not fit into the circumference, the electron interferes
destructively; it cannot exist in such an orbit.;
https://www.boundless.com/physics/textbooks/boundless-physics-textbook/atomic-physics-29/the-
early-atom-185/de-broglie-and-the-bohr-model-692-6303/images/waves-on-a-string/; May 1, 2017
Quantum Mechanics
Bohr’s theory was a significant finding with regard to the atomic model and
specific energies of electrons in particular, but it did not account for the
particle and wave-like properties of matter and atoms having more than one
electron.
The quantum mechanical model was then proposed by Erwin Schrödinger
(1887–1961), where he defied the previous suggestion that an electron
moves around the nucleus in a defined path. Instead, he focused on the idea
that an electron moves like a wave. Such behavior of electrons makes it
impossible to pinpoint its exact location and path, which was further defined
through the Heisenberg uncertainty principle. This principle explains that
it is uncertain to know both the momentum (p) and the position of a particle.
Mathematically:
ℎ
∆𝑥∆𝑝 ≥
4𝜋
General Chemistry
5
Quantum Theory and Structure of Atoms and Electronic Structure and
Periodicity
Quantum Numbers
Three quantum numbers are used to the size, shape, and orientation in
space of orbitals where electrons can be found:
The principal quantum number (n);
The angular momentum quantum number (l); and
The magnetic quantum number (m).
One quantum number explains electron behavior – the spin quantum number
(s).
All numbers combined complete the quantum number, describing a specific
electron.
The principal quantum number (n) describes the size of the orbital. It also
indirectly describes the energy of an orbital (true with hydrogen).
The angular quantum number (l) describes its shape. It can either be
spherical (l=0), polar (l=1) or cloverleaf (l=2). More complex shapes can
happen as this number goes higher. The value of l is designated by letters,
such as:
l 0 1 2 3 4 5
Name of orbital s p d f g h
(The name of orbital goes alphabetical after f)
The magnetic quantum number (m) describes its orientation. Unlike
spheres, orbitals with polar or cloverleaf shapes can point in any direction.
The spin quantum number (s) describes the electron spin, either clockwise
or counter-clockwise.
Course Module
In writing these numbers:
All quantum numbers are integers (0, 1, 2, 3, and so on)
Principal quantum number (n) – cannot be zero (1 above)
Angular quantum number (l) – any integer between 0 and n – 1
The magnetic quantum number (m) – any integer between -l and +l
The spin quantum number (s) – +½ or -½
Atomic Orbitals
With the three quantum numbers identified for any atom, we can now
determine the number and structure of orbitals it may have. The table below
details all possible combinations of the quantum numbers (n=1 to n=4):
sOrbital
All s orbitals are spherical in shape. They differ in sizes, becoming larger as
the principal quantum number increases.
pOrbital
All p orbitals are polar or dumbbell-like in shape. It has two lobes on
opposite sides of the nucleus. All p orbital look the same, except for their
orientations in space. They also become larger as the principal quantum
number increases.
dOrbital
All d orbitals, compared to s and p orbitals, have two different shapes. Four of
them assumes the cloverleaf shape, with four lobes. One is like the p orbital,,
but with a donut-shaped region in the xyplane.
All other orbitals of higher principal quantum numbers (f and above) have
more complex shapes and combinations.
Orbital Energies
Energy levels for orbitals determine the actual arrangement of electrons in
atoms. Electrons will first fill the most stable orbitals. This would depend not
only on the principal quantum number and the angular quantum number,
but also to certain properties such as repulsion between electrons in orbitals
and the total energy to use in order to fill an orbital. In summary, the figure
below details the order of orbitals to be filled with electrons:
Course Module
Figure 6. Order of atomic orbitals to be filled with electrons in a many-electron atom;
https://www.google.com.ph/url?sa=i&rct=j&q=&esrc=s&source=images&cd=&cad=rja&uact=8&ved=0ahUKEwi
3r9_5sNXTAhWITLwKHVuFBXwQjRwIBw&url=http%3A%2F%2Fwww.shmoop.com%2Fbonds-o ; May 2, 2017
Electron Configuration
With all four quantum numbers, we can now determine all orbitals possibly
being occupied by electrons in an atom, through the electron configuration.
The electrons fill the orbitals through a scheme called the Aufbau
(“building-up”) principle, which deals with increasing energy of subshells:
1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f
e.g., O: 1s 2s 2px 2py 2pz1
2 2 2 1
Course Module
Development of the Periodic Table
The development of the periodic table began during the nineteenth century.
The discovery of atomic masses of each element allowed chemists to
organize the different elements in a periodic table. Furthermore, chemists
believed that by grouping them on the basis of their atomic masses, they
were also able to cluster elements with the same chemical behaviour. This
was based on the rationale that chemical behaviour and atomic mass had a
strong correlation.
A few chemists had tried to decode the relationship of each element
according to their atomic mass and other relevant properties. John Newlands
in 1864 attempted to explain the relationship of the elements on his law of
octaves. The law of octaves explained that when the atomic masses of the
elements are arranged in ascending order, elements falling in every eight
position were deemed to have the same properties. The weakness of
Newland’s law of octave was its inapplicability to other elements beyond
calcium.
The work of Dimitri Mendeleev and Lothar Meyer provided a more
encompassing tabular arrangement of the elements in a periodic table. It was
in 1869 that the two chemists developed a classification system that
addressed the inadequacies of earlier methods of arranging the elements.
Mendeleev’s was able to enhance the law of octaves in two important ways.
Firstly, the new classification system of Mendeleev allowed the elements to
be grouped together in a much accurate manner. Secondly, it allowed the
prediction of the properties of unknown elements such as in the case of
Gallium (Ga).
The element Gallium, prior to its discovery, was called eka-alu,imu,.
Mendeleev, using his proposed classification system, had predicted a few of
the characteristics of Gallium. In the time Gallium was discovered, its
predicted properties was indeed very much similar to its actual element
properties.
Though Mendeleev’s work paved way to better classification system, several
inconsistencies were documented. This led to the discovery of other element
property that influencing the arrangement of the elements in the periodic
table. This essential property that affects arrangement of elements was the
atomic number. Henry Mosley elucidated the role of atomic number and how
it influenced the arrangement of the elements in a periodic table. Mosley
discovered that atomic number had the same pattern as atomic mass. It
increases in a similar manner with atomic mass. The contribution of Mosley
provided a way in reorganizing the elements in a more accurate and logical
manner such as in the case of argon.
Figure below shows the periodic table of elements. Below are the key points
in understanding the periodic table of elements. Elements can be divided into
General Chemistry
11
Quantum Theory and Structure of Atoms and Electronic Structure and
Periodicity
four on the basis of the filled subshell type. These four categories are the
representative elements, the noble gases, the transition metals, the
lanthanides and actinides. The chemical reactivity of the four types of
elements are determined by their valence electron. The valence electrons of
an atom are also referred to as the outermost electrons. On the other hand,
core electrons are all nonvalence electrons in an atom.
Representative Elements
Also known as the main group elements
Belong to Group 1A to 7A
Elements in this group have s or p shells that are not completely filled
Valence electrons occupy highest n shell
Valence electrons pattern showed similarity among this group of
elements. It can be observed that all representative elements have the
same number and type of electrons
Noble Gases
Group 8A elements
Characterized by a completely filled p subshell except for helium
Elements in this group has an electron configuration of ns2np6,
whereas n is the principal quantum number
Course Module
Only helium has a different configuration compared to other noble
gases. Its electron configuration is 1s2
Noble gases exhibited almost similar behaviour. These elements such
as in the case of helium and neon are fairly stable that can be
attributed to their completely filled ns and np subshells
Transition Metals
Also known as the d-block transition elements
Elements in Group 1B and 3B through 8B
This group of elements can be differentiated from other elements in
the periodic table by observing their d subshells. Transition elements
have incompletely filled d subshells as well as readily produce cations
with incompletely filled d subshells
Another characteristic is that valence electron configuration is not
always similar within the group
Zeff = Z – σ
Where,
Z = actual nuclear charge
σ = shielding constant
Atomic Radius
Basis in defining the size of an atom
Referred to as one-half the distance between the two nuclei in two
adjacent metal atoms or in a diatomic molecule
Figure below shows the periodic trend of atomic radii of each element
Ionic Radius
Referred to as the radius of a cation or an anion
The size of an ionic compound is influenced by the sizes of its cation or
anion
When an atom acquires an additional electron, and forms an anion, the
electron cloud sphere expands. This happens when nuclear charge stay
the same and the repulsion leads to the expansion of the electron cloud.
On the contrary, the reduction in the number of the electrons in an atom
leads to a decreased in the size of the electron cloud domain, resulting to
a smaller cation. Figure below shows the sizes of the cations and anions
of some elements.
Course Module
Figure 10.Comparison of radii of neutral atoms and their ions;
http://wps.prenhall.com/wps/media/objects/3311/3391006/blb0803.html; April 23, 2017
Ionization Energy
The minimum energy required to remove an electron from a gaseous
atom in its ground state
Expressed in kJ/mol
Ionization energy is a reflection of how stable an atom’s outermost
electrons is
As ionization energy becomes higher, the harder for it for an electron
of an atom to be removed
An electron is more difficult to remove in a positively charged ion
Ionization energy is classified into first (I1), second (I2)and third
ionization energy (I3)
Ionization energy is derived from an endothermic process hence it is
expressed in a positive value
Ionization energies of elements have an increasing trend across a
period. The ionization energy increases as atomic number becomes
larger. This is attributed also to the nuclear charge of an atom
wherein as atomic number increases nuclear charge become stronger
and more effective. Hence, electrons are being held tightly
General Chemistry
15
Quantum Theory and Structure of Atoms and Electronic Structure and
Periodicity
Electron Affinity
Electron affinity is the ability of an atom to receive additional
electrons.
It is also defined as the negative of the energy change that occurs
when an electron is accepted by an atom in the gaseous state to form
an anion
It should be noted that an electron affinity is positive if the reaction
that happens is an exothermic in nature. Consequently, the electron
affinity is negative if the reaction is endothermic.
Expressed in kJ/mol
A positive electron affinity denotes that greater capacity of an atom of
a particular element to accept an electron
Course Module
In general, the electron affinity increases from left to right across a
period. Group 7A has the highest electron affinities. However, when
comparing the electron affinities of metals and non-metals, electron
affinity is higher among the non-metals.
Electron
Group Configurat Variations/ Characteristics
ion
Hydrogen 1s1 Has single valence electron
Traditionally shown in Group 1A
Forms uninegative ions
Group 1A ns1 , n≥2 Alkali metals
Elements Low ionization energy
Very reactive in nature
Rarely can be found in its pure form
Group 2A ns2 , n≥2 Alkaline earth metals
Elements Less reactive than alkali metals
Metallic character increases from top to
bottom
Reactivity with water varies depending on
the element and form of water
Reactivity towards oxygen increases from Be
to Ba
Group 3A ns2np1 , n≥2 All elements except for boron (metalloid) are
Elements metals
Metallic elements from both unipositive and
tripositive ions
Unipositive ions fromed by metals from this
group are more stable than tripositive ions
Group 4A ns2np2 , n≥2 Carbon- non-metal
Elements Silicon and germanium – metalloids
Metallic elements of this group do not react
with water but react with acids
General Chemistry
17
Quantum Theory and Structure of Atoms and Electronic Structure and
Periodicity
In summary, the figure below shows the general trends of elements in terms
of their physical and chemical properties. These tips will help you remember
easily the general trends of the different physical as well as chemical
characteristics of the elements.
Course Module
Glossary
angular momentum quantum number: describes the shape of orbital
atomic orbital: wave functions which mathematically describe the position
and energy of electron in an atom
atomic radius: defines the size of an atom; e-half the distance between the
two nuclei in two adjacent metal atoms or in a diatomic molecule
electron:located outside the atom’s nucleus; negatively charged (-1)
electron affinity: ability of an atom to receive additional electrons
electron configuration: how electrons are distributed among many orbitals
of an atom
free electron: electron which is infinitely located far from the nucleus;
energy is zero
ionization energy: minimum energy required to remove an electron from a
gaseous atom in its ground state
ionic radius: radius of a cation or an anion
magnetic quantum number: describes the orientation of orbital
metalloids: possess properties of both metals nonmetals
orbital energy: energy level of orbital which describes the arrangement of
electrons in an atom
principal quantum number: describes size of orbital
photons: light particles
quantum: smallest quantity of energy that can be absorbed through
electronic radiation
spin quantum number: describes electron spin
threshold frequency: minimum frequency of light which causes
photoelectric effect
valence electrons: outermost electrons
Brown, T.L., LeMay Jr., H.E., Bursten, B.E., Murphy, C.J., Woodward, P.M.,
Stoltzfus, MW; 2015; Chemistry – The Central Science (13th Edition); Upper
Saddle River, NJ; Pearson Education, Inc.
Chang, R.; 2010; Chemistry (10th Edition); New York; McGraw-Hill
Companies, Inc.
Petrucci, R.H., Herring, F.G., Madura, J.D., Bissonnette, C. (2011). General
Chemistry: Principles and Modern Applications (10th edition). Toronto:
Pearson Canada
General Chemistry
19
Quantum Theory and Structure of Atoms and Electronic Structure and
Periodicity
Electron Configurations;
https://www.youtube.com/watch?v=RJlEH5Jz80w&list=PL166048DD75B05
C0D&index=6; May 1, 2017
Electron Configurations 2;
https://www.youtube.com/watch?v=YURReI6OJsg&list=PL166048DD75B05
C0D&index=7; May 1, 2017
Orbitals;
https://www.youtube.com/watch?v=yBrp8uvNAhI&list=PL166048DD75B0
5C0D&index=4; May 1, 2017
Course Module
More on orbitals and electron configuration;
https://www.youtube.com/watch?v=FmQoSenbtnU&list=PL166048DD75B0
5C0D&index=5; May 1, 2017
Valence electrons;
https://www.youtube.com/watch?v=1TZA171yxY4&list=PL166048DD75B0
5C0D&index=10; May 1, 2017
The Periodic Table; https://www.youtube.com/watch?v=0RRVV4Diomg;
May 1, 2017
Groups of the Periodic Table;
https://www.youtube.com/watch?v=LDHg7Vgzses&list=PL166048DD75B0
5C0D&index=11; May 1, 2017
Periodic Table Trends: Ionization Energy;
https://www.youtube.com/watch?v=ywqg9PorTAw&list=PL166048DD75B
05C0D&index=12; May 1, 2017
Other Periodic Table Trends; https://www.youtube.com/watch?v=XMLd-
O6PgVs&list=PL166048DD75B05C0D&index=13; May 1, 2017
Atomic Radius, Ionization Energy and Electonegativity,
https://www.youtube.com/watch?v=hePb00CqvP0, April 21, 2017
The Periodic Table; https://www.youtube.com/watch?v=hePb00CqvP0,
April 21, 2017
General Trends of Elements in a Periodic Table;
https://www.youtube.com/watch?v=aFnOVch8gIA; April 22, 2017
The periodic table - classification of elements;
https://www.youtube.com/watch?v=t_f8bB1kf6M; April 26, 2017