NALCO® 1720 Msds
NALCO® 1720 Msds
NALCO® 1720 Msds
PRODUCT
NALCO® 1720
2. COMPOSITION/INFORMATION ON INGREDIENTS
Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the
nature of the hazard(s).
3. HAZARDS IDENTIFICATION
**EMERGENCY OVERVIEW**
WARNING
Harmful if swallowed. Contains Sulfite. Causes asthmatic signs and symptoms in hyper-reactive individuals.
Irritating to respiratory system. May cause cancer by inhalation. Cobalt and cobalt compounds have been classified
as possible carcinogens to humans (Group 2B) by IARC. The ACGIH lists cobalt and inorganic compounds as an
animal carcinogen (A3). Contact with acids liberates toxic gas.
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. In case of contact with
eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with
plenty of water. Use a mild soap if available. Protect product from freezing.
Wear suitable protective clothing.
Not flammable or combustible. May evolve oxides of sulfur (SOx) under fire conditions.
NALCO® 1720
EYE CONTACT :
May cause irritation with prolonged contact.
SKIN CONTACT :
May cause irritation with prolonged contact.
INGESTION :
Harmful if swallowed. Contains Sulfite. May cause asthmatic-like attack.
INHALATION :
Irritant to respiratory system. Causes asthmatic signs and symptoms in hyper-reactive individuals. May cause cancer
by inhalation.
SKIN CONTACT :
Flush with large amounts of water. Use soap if available. If symptoms develop, seek medical advice.
INGESTION :
Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. Get medical
attention.
INHALATION :
Remove to fresh air, treat symptomatically. Get medical attention.
NOTE TO PHYSICIAN :
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and
clinical condition.
NALCO® 1720
EXTINGUISHING MEDIA :
Not expected to burn. Use extinguishing media appropriate for surrounding fire. Keep containers cool by spraying
with water.
ENVIRONMENTAL PRECAUTIONS :
Do not contaminate surface water.
STORAGE CONDITIONS :
Store the containers tightly closed. Store in suitable labeled containers. Store separately from acids. Store separately
from oxidizers. Amine and sulphite products should not be stored within close proximity or resulting vapors may form
visible airborne particles. Protect product from freezing.
NALCO® 1720
ENGINEERING MEASURES :
General ventilation is recommended. Use local exhaust ventilation if necessary to control airborne mist and vapor.
RESPIRATORY PROTECTION :
Where concentrations in air may exceed the limits given in this section or when significant mists, vapors, aerosols, or
dusts are generated, an approved air purifying respirator equipped with suitable filter cartridges is recommended.
Consult the respirator / cartridge manufacturer data to verify the suitability of specific devices. In event of emergency
or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory
protection is required, institute a complete respiratory protection program including selection, fit testing, training,
maintenance and inspection.
HAND PROTECTION :
When handling this product, the use of chemical gloves is recommended. The choice of work glove depends on work
conditions and what chemicals are handled. Please contact the PPE manufacturer for advice on what type of glove
material may be suitable. Gloves should be replaced immediately if signs of degradation are observed.
SKIN PROTECTION :
Wear standard protective clothing.
EYE PROTECTION :
Wear chemical splash goggles.
HYGIENE RECOMMENDATIONS :
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a
safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder
contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product
never eat, drink or smoke.
NALCO® 1720
ODOR Pungent
Note: These physical properties are typical values for this product and are subject to change.
HAZARDOUS POLYMERIZATION :
Hazardous polymerization will not occur.
CONDITIONS TO AVOID :
Freezing temperatures.
MATERIALS TO AVOID :
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen,
permanganate) may generate heat, fires, explosions and/or toxic vapors. Contact with strong acids (e.g. sulfuric,
phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapors. Contains
Sulfite. SO2 may react with vapors from neutralizing amines and may produce a visible cloud of amine salt particles.
NALCO® 1720
SENSITIZATION :
Sulfites can cause an allergic reaction in sensitive individuals.
CARCINOGENICITY :
This product contains cobalt compounds. The International Agency for Research on Cancer (IARC) has evaluated
cobalt and cobalt compounds and found it to be a possible human carcinogen.
MOBILITY :
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and
output. The level III model does not require equilibrium between the defined media. The information provided is
intended to give the user a general estimate of the environmental fate of this product under the defined conditions of
the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the
approximate respective percentages;
NALCO® 1720
BIOACCUMULATION POTENTIAL
The product will not bioaccumulate.
Hazardous wastes must be transported by a licensed hazardous waste transporter and disposed of or treated in a
properly licensed hazardous waste treatment, storage, disposal or recycling facility. Consult local, state, and federal
regulations for specific requirements.
The presence of an RQ component (Reportable Quantity for U.S. EPA and DOT) in this product causes it to be
regulated with an additional description of RQ for road, or as a class 9 for road and air, ONLY when the net weight in
the package exceeds the calculated RQ for the product.
LAND TRANSPORT :
The presence of an RQ component (Reportable Quantity for U.S. EPA and DOT) in this product causes it to be
regulated with an additional description of RQ for road, or as a class 9 for road and air, ONLY when the net weight in
the package exceeds the calculated RQ for the product.
NALCO® 1720
N.O.S.
Technical Name(s) : SODIUM BISULFITE
UN/ID No : UN 3082
Hazard Class - Primary : 9
Packing Group : III
Reportable Quantity (per package) : 18,347 lbs
RQ Component : SODIUM BISULFITE
RQ Substance RQ
Sodium Bisulfite 18,347 lbs
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311,
312, AND 313 :
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370) :
Our hazard evaluation has found this product to be hazardous. The product should be reported under the following
indicated EPA hazard categories:
NALCO® 1720
- Fire Hazard
- Sudden Release of Pressure Hazard
- Reactive Hazard
Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely
hazardous substances and 10,000 pounds for all other hazardous chemicals.
FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act :
When use situations necessitate compliance with FDA regulations, this product is acceptable under : 21 CFR 173.310
Boiler Water Additives
NSF NON-FOOD COMPOUNDS REGISTRATION PROGRAM (former USDA List of Proprietary Substances &
Non-Food Compounds) :
NSF Registration number for this product is : 141556
This product is acceptable for treating boilers or steam lines where steam produced may contact edible products
and/or cooling systems where the treated water may not contact edible products in and around food processing areas,
excluding such use in areas where meat and poultry are processed (G9).
This product has been certified as KOSHER/PAREVE for year-round use INCLUDING THE PASSOVER SEASON by
the CHICAGO RABBINICAL COUNCIL.
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307, 40 CFR
116.4 / formerly Sec. 311 :
This product contains the following substances listed in the regulation. Additional components may be unintentionally
present at trace levels.
Substance(s) Citations
Sodium Bisulfite Sec. 311
CLEAN AIR ACT, Sec. 112 (Hazardous Air Pollutants, as amended by 40 CFR 63), Sec. 602 (40 CFR 82, Class I and
II Ozone Depleting Substances) :
This product may contain trace levels (<0.1% for carcinogens, <1% all other substances) of the following substance(s)
listed under the regulation. Additional components may be unintentionally present at trace levels.
Substance(s) Citations
Cobalt Sulfate Sec. 112
NALCO® 1720
CALIFORNIA PROPOSITION 65 :
This material contains trace amounts of chemicals known to the State of California to cause cancer.
AUSTRALIA
All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme
(NICNAS).
CHINA
All substances in this product comply with the Provisions on the Environmental Administration of New Chemical
Substances and are listed on the Inventory of Existing Chemical Substances China (IECSC).
EUROPE
The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.
JAPAN
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical
Substances and are listed on the Existing and New Chemical Substances list (ENCS).
KOREA
All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing
Chemicals List (ECL)
NEW ZEALAND
All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are
listed on or are exempt from the New Zealand Inventory of Chemicals.
NALCO® 1720
PHILIPPINES
All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory
of Chemicals & Chemical Substances (PICCS).
Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and
exposures of this product. Based on our recommended use of this product, we have characterized the product's
general risk. This information should provide assistance for your own risk management practices. We have evaluated
our product's risk as follows:
Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will
assist you to determine if your product application is consistent with our recommendations. Together we can
implement an appropriate risk management process.
This product material safety data sheet provides health and safety information. The product is to be used in
applications consistent with our product literature. Individuals handling this product should be informed of the
recommended safety precautions and should have access to this information. For any other uses, exposures should
be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace
operations. Please consult your local sales representative for any further information.
REFERENCES
Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American
Conference of Governmental Industrial Hygienists, OH., (Ariel Insight™ CD-ROM Version), Ariel Research Corp.,
Bethesda, MD.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS™ CD-ROM
Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health
Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS™
CD-ROM Version),
Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public
Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety
and Health Administration (OSHA), (Ariel Insight™ CD-ROM Version), Ariel Research Corp., Bethesda, MD.
NALCO® 1720
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati,
OH,
(TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Ariel Insight™ (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel
Insight™ CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS™ CD-ROM Version),
Micromedex, Inc., Englewood, CO.