Chemistry BSC 1 Samester PDF

Department of Chemistry
University of Lucknow
Lucknow
B.Sc. Syllabus
Inorganic Chemistry
Semester I Paper – 1 Max Marks: 100 (80 + 20)
UNIT I
I. Atomic Structure: Quantum mechanics based structure of atom in
brief, shapes of s, p and d orbitals, aufbau and Pauli exclusion
principles, Hund's Multiplicity rules. Electronic configurations of the
elements, effective nuclear charge.
II. Periodic Properties and Classification based upon electronic
configuration: Diagonalrelationship, inert pair effect, atomic and ionic
radii, van der waal radii, ionizationenergy,
III. Electron affinity and electronegativity : definition, method of determination,
trends in periodic table and applications in predicting and explaining
chemical behaviour.
UNIT II
IV. Chemical Bonding
(a) Covalent bond: valence bond theory and its limitations,
directional characteristic of covalent bond. Hybridization
and shapes of simple molecules and ions. Valence Shell
Electron Pair Repulsion (VSEPR) theory to simple molecules
and ions. Molecular Orbital theory for homonuclearand
heteronuclear (CO and NO) diatomic molecules, multi-center
bonding in electron deficient molecules, bond strength and
the bond energy, % ionic character from dipole moment and
electro
negativity difference.
(b) Weak interactions: hydrogen bonding, van der Waals forces.
UNIT III
V. Ionic solid: ionic structures, radius ratio effect and coordination number,
limitation of ratio rule, Lattice defects, Lattice energy and Born-Haber
cycle, solvation energy and solubility of ionic solids, polarizing power
and polarizability of ions. Fajan's rule, Metallic bond free electron,
Valence bond and Band theories.
VI. s-Block elements: Comparative study, salient features of hydrides,
salvation and complexation tendencies of cations of alkali and
alkaline earth matter including their function in biosystems, an
introduction to alkyls and aryls of Li & Mg.
VII. Noble Gases: Chemical properties of the noble gases, discovery of
O2+PtF 6ˉ and O2XeF6.Chemistry of xenon, structure and bonding in
xenon compounds.
1
Lucknow
B.Sc. Syllabus
Inorganic Chemistry
UNIT IV
VIII. p-Block Elements:- Comparative study (including diagonal relationship)
physical and chemical behaviour of group 13-17 elements, compounds
like hydrides, oxides, oxyacids and halides ofgroup 13-16, diborane,
boronitride α, β forms, Fullerenes, silicates(structural principle)
andstructures of oxides and oxyacids of phosphorus and sulphur,
interhalogens and polyhalides.
Text Books (Theory Courses):

(a) Concise Inorganic Chemistry, J.D. Lee, Blackwell Science Ltd.
(b) Inorganic Chemistry, Puri, Sharma, Kalia and Kaushal.
(c) Pradeep's Inorganic Chemistry, K.K. Bhasin, Pradeep
Publication.
(d) Chemistry for degree students, R. L. Madan
Reference Books:
(a) Inorganic Chemistry, J.E.Huheey, Ellen A. Keiter, Richard
L. Keiter, Addison Wesley Longman (Singapore) Pvt. Ltd.
(b) Inorganic Chemistry, D.E.Shriver, P W. Atkins and C.H.L.
Langford, Oxford.
(c) Basic Inorganic Chemistry, F.A. Cotton, G. Wilkinson and P.L.
Gaus, Wiley.
(d) Concepts of Models of Inorganic Chemistry, B.Douglas,
D.McDaniel and J Alexander, John Wiley.
(e) Inorganic Chemistry, W.W. Porterfield, Addison - Wesley.
(f) Inorganic Chemistry, A.G. Sharpe, ELBS
(g) Inorganic Chemistry, G.L. Meissler and D.A. Tarr, Prentice-
Hall.
2
Lucknow
B.Sc. Syllabus
Organic Chemistry
UNIT I
I. Structure and bonding: Hybridization, bond lengths, bond angles, bond
energy, localised and delocalized π bonds, resonance, inductive and field
effects, hydrogen bonding, inclusion compounds, clathrates, charge transfer
complexes, van der Waals interaction, hyperconjugation, aromaticity.
II. Mechanism of Organic Reactions: Curved arrow notation, drawing
electron movements with arrows, half headed and double-headed arrows,
homolytic and heterolytic bond breaking Reactive intermediates-generation,
structure, stability and reactions of carbocation, carbanion, free radicals and
carbenes, Arynes, Nitrenes.
III. Types of organic reactions-addition, elimination, substitution,
rearrangement, condensation, methods of determination of reaction
mechanism (product analysis, intermediates, isotopic effects, kinetic and
stereochemical studies). Energy considerations.
UNIT II
IV. Stereoisomerism
Optical isomerism: Elements of symmetry, molecular chirality, optical
activity, stereogenic centres, enantiomers, properties of enantiomers,
chiral and achiral molecules with two stereogenic centres,
diastereomers, threo and erythro diastereomers, meso compounds,
resolution of enantiomers, inversion, retention and racemization.
Relative and absolute configurations. Sequence rules. D, L and R, S
nomenclature.
Geometrical isomerism: determination of configuration of geometric
isomers. E, Z system, geometrical isomerism in oximes and alicyclic
compounds. Conformatioal isomerism-Conformational analysis of
ethane and n-butane and cyclohexane, axial and equatorial bonds,
Saw-horse and flying wedge formulae, Fischer and Newman
projections formulae. Difference between conformation and
configuration.
UNIT – III
V. Alkanes And Cycloalkanes: Methods of formation with special
reference to Wurtz, Kolbe, Corey-House reactions and decarboxylation.
Physical properties and chemical reactions. Mechanism of free radical
halogenation of alkanes: orientation, reactivity and selectivity.
Cycloalkanes: Nomenclature, methods of preparation. Baeyer's strain theory
and its limitations. Ring strain in (cyclopropane and cyclobutane), theory of
strainless rings. The case of cyclopropane ring and banana bond.
VI. Alkenes, Cycloalkenes, Dienes: methods of formation. Mechanisms of
dehydration of alcohols and dehydrohalogenation of alkyl halides. Regio-
selectivity in alcohol-dehydration. Saytzeff's rule, Hofmann elimination.
Lucknow
B.Sc. Syllabus
Organic Chemistry
Physical properties and relative stabilities of alkenes. Chemical reactions of

alkenes- Mechanisms involved in hydrogenation, electrophilic and free-radical
additions. Markownikoff’s rule. Hydroboration-oxidation, oxymercuration-
reduction, epoxidation, ozonolysis, hydrations, hydroxylation and oxidation
with KMnO4, polymerization of alkenes. Substitutions at allylic and vinylic
positions of alkenes.
Methods of formation, conformation and chemical resections of cycloalkenes.
Nomenclature and classification of dienes: isolated, conjugated and
cumulated dienes, Structure of allenes and butadiene, methods of formation,
chemical reaction – 1, 2 and 1, 4 additions, Diels-Alder reaction.
VII. Alkynes: Structure and bonding in alkynes. Methods of formation,
chemical reactions and acidity of alkynes. Mechanism of electrophilic and
mucleophilic addition reactions, hydroboration-oxidation, reductions and
oxidation reactions.
UNIT IV
VIII. Arenes and Aromaticity: Nomenclature of benzene derivatives.
Structure of benzene: molecular formula and Kekule structure. Stability and
carbon carbon bond length of benzene, resonance structure, MO picture.
IX. Aromatic electrophilic substitution- general pattern of the mechanism,
Arrhenium ion intermediate. Mechanism of nitration, halogenation, sulfonation,
mercuration and Friedel-Crafts reaction. Energy profile diagrams. Activation
and deactivating substituents, orientation and ortho/para ratio. Side chain
reactions of benzene derivatives. Birch reduction.
X. Alkyl and Aryl Halides: Methods of formation, chemical reactions.
Mechanism of nucleophilic substitution reactions of alkyl halides, SN2 and
SN1 reactions with energy profile diagrams, chloroform. Aryl halides -
Methods of formation, nuclear and side chain reactions. Mechanisms of
nucleophilic aromatic substitutions. Synthesis and uses of DDT, BHC.
Text Books (Theory Courses):
a. Organic Chemistry, Vol. I, I.L. Finar, Pearson Education.
b. Organic Chemistry, M.K. Jain, Shoban Lal& Co.
c. Pradeep's Organic Chemistry, S.N. Dhawan, Pradeep
Publication.
Reference Books:
a. Organic Chemistry, Morrison and Boyd, Prentice Hall.
b. Organic Chemistry, L.G. Wade Jr. Prentice Hall.
c. Fundamentals of Organic Chemistry Solomons, John Wiley.
d. Organic Chemistry, Vol. I, II, III S.M. Mukherji, S.P. Singh
and R.P. Kapoor, Wiley Eastern Ltd. (New Age International)
e. Organic Chemistry, F.A. Carey, McGraw-Hill Inc.
f. Introduction to Organic Chemistry, Streitwiesser, Hathcock
and Kosover, Macmillan.

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Text Books (Theory Courses):

Physical properties and relative stabilities of alkenes. Chemical reactions of

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