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    Organic Chemistry PDF

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    Ankush Biswas
    The document outlines an organic chemistry course that covers basic principles, mechanisms of reactions, synthesis of compounds, therapeutic properties of heterocyclic compounds used in drugs, and stereochemistry. The course has 4 units that cover topics like electrophilic aromatic substitution reactions, aldol condensation, active methylene compounds and their uses in synthesizing acids and heterocycles, properties of important heterocycles, dye synthesis, and stereoisomerism. The objectives are to understand organic molecular structure, reactivity and transformations, and apply the knowledge to synthesis and drug activity.

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    Organic Chemistry PDF

    Uploaded by

    Ankush Biswas
    551 views4 pages
    The document outlines an organic chemistry course that covers basic principles, mechanisms of reactions, synthesis of compounds, therapeutic properties of heterocyclic compounds used in drugs, and stereochemistry. The course has 4 units that cover topics like electrophilic aromatic substitution reactions, aldol condensation, active methylene compounds and their uses in synthesizing acids and heterocycles, properties of important heterocycles, dye synthesis, and stereoisomerism. The objectives are to understand organic molecular structure, reactivity and transformations, and apply the knowledge to synthesis and drug activity.

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    The document outlines an organic chemistry course that covers basic principles, mechanisms of reactions, synthesis of compounds, therapeutic properties of heterocyclic compounds used in drugs, and stereochemistry. The course has 4 units that cover topics like electrophilic aromatic substitution reactions, aldol condensation, active methylene compounds and their uses in synthesizing acids and heterocycles, properties of important heterocycles, dye synthesis, and stereoisomerism. The objectives are to understand organic molecular structure, reactivity and transformations, and apply the knowledge to synthesis and drug activity.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    551 views4 pages

    Organic Chemistry PDF

    Uploaded by

    Ankush Biswas
    The document outlines an organic chemistry course that covers basic principles, mechanisms of reactions, synthesis of compounds, therapeutic properties of heterocyclic compounds used in drugs, and stereochemistry. The course has 4 units that cover topics like electrophilic aromatic substitution reactions, aldol condensation, active methylene compounds and their uses in synthesizing acids and heterocycles, properties of important heterocycles, dye synthesis, and stereoisomerism. The objectives are to understand organic molecular structure, reactivity and transformations, and apply the knowledge to synthesis and drug activity.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
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    The document discusses the content and objectives of an Organic Chemistry course, covering topics such as electron displacement effects, reaction mechanisms, active methylene compounds, heterocyclic compounds, stereochemistry, and dyes.

    The main topics covered in the course include electron displacement effects, reaction mechanisms, active methylene compounds, heterocyclic compounds, stereochemistry, and dyes.

    Some examples of named organic reactions discussed are the Fridel-Crafts reaction, Rimer-Tiemann reaction, Aldol condensation, Benzoin condensation, Perkins reaction, Cannizzaro reaction, and Pinacol-Pinacalone rearrangement.

    45

    ORGANIC CHEMISTRY

    Course Code: 13BC1104 L T P C


    4 0 0 3
    Course Educational Objectives:
    Course is intended to understand a basic principles relating to the nature
    reactivity properties, mechanisims, structures and chemical transformations
    of organic molecules.
    The course covers to the importance of synthetics reagents and their
    applications and also provide the information on theraputac activity on
    heterocyclic compounds which are used in drugs.
    Course Outcomes:
    The student shall be able to apply the knowledge of
    ✤ Basic principles of the Organic Chemistry
    ✤ Mechanisims of the Organic Reactions
    ✤ Synthetic Preparation of various commercially useful compounds.
    ✤ Therapeutic activity of heterocyclic compounds used in drugs.
    ✤ Synthetic Preparation of differents dies.
    ✤ Basic concepts of stereo chemistry usefull in the synthesis of
    biological active compounds.
    UNIT-1 ( 8 Lectures)
    ELECTRON DISPLACEMENT EFFECTS:
    Inductive effect-applications
    Inductomeric effect
    Mesomeric (or) Resonance effect-applications
    Electrometric effect
    Hyper conjugation-applications
    G V P College of Engineering (Autonomous) 2013
    46

    UNIT-II (14 Lectures)


    Mechanism and applications of the following named reactions
    i) Fridel-Crafts reaction
    ii) Rimer-Tiemann reaction
    iii) Aldol condensation,
    iv) Benzoin condensation
    v) Perkins’s reaction,
    vi) Cannizaro’s reaction,
    vii) Pinacol-Pinacalone rearrangement
    viii) Beckmann rearrangement
    UNIT-III (14 Lectures)
    ACTIVE METHYLENE COMPOUNDS:
    Preparation of Malonic ester, isomerism- Acid hydrolysis of malonic ester.
    Synthetic uses of malonic ester with reference to synthesis of mono
    carboxylic acids( n-butyric acid isobutyric acid, and isovaleric acid),
    dicarboxylic acids ( succinic acid, á,-methylsuccinic acid and adipic acid),
    á, â- unsaturated acid(crotonic acid), amino acid(glycine), ketocarboxylic
    acid(acetoacetic acid) ketones (ethylmethylketone),alicyclic
    acids(cyclopropanecarboxylic acid) and heterocyclics(Barbituric acid).
    Preparation of Acetoacetic ester, isomerism-tautomerism, and Ketonic
    and Acid hydrolysis. Synthetic uses of acetoacetic ester with reference
    to synthesis of mono carboxylic acids ( n-butyric acid isobutyric acid and
    á,-methyl n-butyric acid and â-methyl n-butyric acid ), dicarboxylic acids
    ( succinic and adipic acids) , á, â- unsaturated acid(crotonic acid), amino
    acid(glycine), ketones (3-methyl-2-pentanone), 1, 3 & 1, 4diketones
    (acetylacetone and acetonylacetone) and alicyclic acids (acetylcyclohexane)
    and heterocyclics (4-methyluracil).
    UNIT-IV (14 Lectures)
    HETEROCYCLIC COMPOUNDS:
    Nomenclature, preparation, structure, properties and uses of Furan,
    Pyrrole, Thiophene, Pyridine, Quinoline, Isoquinoline

    G V P College of Engineering (Autonomous) 2013


    47

    DYES:
    Definition of dye, Classification based on chemical structure and method
    of application.Witt’s theory of color and chemical constitution. Synthesis
    and uses of the following dyes- Cong red, Bismark brown, Malachite
    green, Rosaniline and Fluorescein.
    UNIT-V (10 Lectures)
    STEREO CHEMISTRY:
    Configurational isomerism: Optical isomerism, Conditions for an optically
    active compound, Optical activity of Lactic acid and Tartaric acid.
    Diastereomerism, Relative and Absolute configuration- Sequence rules,
    Geometrical isomerism-E & Z system of nomenclature.
    Conformational Isomerism: Conformations of ethane, n-butane and 1,2-
    dihaloethane.Bayer’s strain theory-limitations, Sachey and Mohr theory,
    conformations of cyclohexane
    TEXT BOOKS:
    1. Arun Bahl & B.S. Bahl “Advanced Organic Chemistry” –,
    Rev. Editiopn S.Chand & Company Ltd, New Delhi 2012
    2. T. Morrison and Robert.N. Boyd “Text book of Organic
    Chemistry”, 6th Edition 1992
    3. Paula Yurkanis “Bruice Organic chemistry”, 3rd Edition
    ,Pearson publishers,2010
    REFERENCES:
    1. I.L Finar, “Organic Chemistry”, Volume I6th Edition, Pearson
    Education Publishers, New Delhi, 2004.
    2. Peter Skyes, “Reaction mechanism”, 6th Edition, Orient
    Longman Ltd. New Delhi, 1997.
    3. O.P. Agrawal, “Reaction and Reagents”, Rev.Edition, Goel
    Publishing house, Meerut, 2005
    4. Gaurikar and others, “Polymer science”, Ist Edition, New Age
    International Ltd, NewDelhi 1986.

    G V P College of Engineering (Autonomous) 2013


    48

    5. O.P. Agrawal, “Synthetic Organic Chemistry”, 14th Edition,


    Goel Publishing house,Meerut, India,2006.
    6. C.N.Pillai, “Organic chemistry”, University Press, New Delhi,
    2009.
    7. B.Mehata& M.Mehata, “Organic chemistry”, PHI Learning
    Pvt. Ltd., 2005.
    8. P.Bahadur & N.V.Sastry, “Principles of polymer science”,
    Narosa Publishing house, New Delhi 2002.

    pqr

    G V P College of Engineering (Autonomous) 2013

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