Electrical Properties of Solids

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Electrical Properties of Solids

We are aware of the physical properties of solids. Like the fact that they
have a definite shape and volume. But the electrical properties of solids
vary largely based on their composition and chemical structure. They
are divided into three groups – conductors, semiconductors,
and insulators. Let us study these further.

Electrical Properties of Solids


Now the electrical property of a substance is a reference to its
conductivity. Electric Conductivity of a substance is defined as its
ability to transmit heat energy or electric energy (and in some cases also
sound energy). So a good conductor of electricity is easily able to
transmit the energy without boiling or melting or changing its
composition in any way.

Solids have varying degrees of conductivity i.e. all solids do not have
uniform electrical properties. Actually, solids can be divided into three
broad categories based on their electrical conductivity. These three
groups are as follows,

Conductors
Broadly speaking, conductors are solids that have good electrical
conductivity. They allow heat energy and electric currents to transmit
through them with ease and speed. Conductors allow this transfer of
energy to happen via free flow of electrons from atom to atom. They
have the ability to carry this energy throughout themselves even when
the current is only applied to one part of their body.

All metals are known to be the best conductors. Their conductivity


depends on the number of valence electrons of their atoms. These
electrons are not closely bound together and can move
freely. Metals have such electrons in their atoms, and so they conduct
heat and electricity so well. Metals allow the electric field to transmit
through them in conductivities order of 106 – 108 ohm-1.

Insulators

Stark opposite to conductors, insulators are materials that absolutely do


not conduct any electric energy or currents. They do not let any (or very
little) electric charge flow through them. They have a significant band
gap which prevents the flow of electricity. Some examples are glass,
wood, plastics, rubber etc.

Since insulators are very bad conductors they have another use. We use
them to insulate conductors and semiconductors. For example, you must
have seen copper wires with a covering of plastic or some form of
polymers. They protect the wires and cables without allowing the
electric current to go through them. This is insulation of the wire.
Semiconductors
Semiconductors are the go-between conductors and insulators. These
are solids that have the ability to conduct electricity through them but
only under certain conditions. There are two such conditions that affect
the ability of semiconductors to conduct energy, heat, and impurities.

 Intrinsic Semiconductor: These are pure materials with no impurities


added, so they are known as undoped semiconductors. Here we
apply thermal energy to the material and create vacancies in the
valence bands. This allows the energy to pass through. And yet these
are not very good conductors and find very limited applications
 Extrinsic Semiconductors: These are doped semiconductors. We add
certain impurities to increase the conductivity of the materials.
There are two types of extrinsic semiconductor, namely n-type and
p-type. Examples are when we boost the conductivity of silicon and
germanium by this method.
One reason why semiconductors are an important material is that we
have control over their conductivity. This is why they find many
applications, especially in electronics.

Solved Question for You


Q: Conductivity of semiconductor increases with increase in
temperature. True or False?

Ans; The given statement is True.

 Intrinsic semiconductor; conductivity goes up or resistivity goes


down with temperature goes up.
 Heavily doped conductivity turns up again or resistivity goes down
with temperature goes up.

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