COMPLETE COURSE IN ORGANIC CHEMISTRY

BY VINEET KHATRI SIR

CLASS : XI TIME : 35 MIN. DPP. NO.1
Single Choice Questions :
1. Which of following is 3° (tertiary alcohol)

OH OH OH
(A) (B) (C) (D) All

2. Which of following is 1° amine ?

NH2 CH3
(A) (B) CH3 – C – NH2 (C) CH3 – NH2 (D) All
CH3

3. Which of following is 3° amine ?

CH3
(A) CH – N (B) CH3 – NH – Et (C) CH3 – NH – CH3 (D) CH3 – NH2
3

CH3

4. and

Number of secondary carbon atoms present in the above compounds are respectively:
(A) 6, 4, 5 (B) 4, 5, 6 (C) 5, 4, 6 (D) 6, 2, 1

5. Number of 1°, 2° and 3° hydrogen in isooctane is:

(A) 9,8,1 (B) 12,5,1 (C) 15,2,1 (D) None of these
Multiple Choice Question :
6. Which of the following compound contain all 1°, 2°, & 3° amine

N NH2
NH2
(A) H2.N NH (B)
N
H

NH2
N
N N
(C) (D)
N N
7. Which of the following compound contain only 1 type of carbon atom

(A) (B) (C) (D)

8. Which of the following compound contain only 2 types of carbon atom

N N

(A) (B) N N (C) (D)

N N

9. Which of the following is a 2° amine.

NH2
H
N
(A) C  C  C  C (B) (C) (D)
| N
NH 2
H

10. Classify the following alcohols as primary, secondary, or tertiary:

(a) (CH3)3CCH2OH (b) CH3CH(OH)CH(CH3)2

(c) (CH3)2C(OH)CH2CH3 (d)

(e)

11. Classify the following amines as primary, secondary, or tertiary:

(a) CH3NHCH(CH3)2 (b) CH3CH2CH(CH3)CH2NH2
(c) (CH3CH2)3N (d) (C6H5)2CHCH2NHCH3

(e) (f)

“A positive attitude brings much gratitude! Think positive,

be positive, speak positive and stay positive!
Do it every day and DO IT BIG!!!”
 COMPLETE COURSE IN ORGANIC CHEMISTRY
BY VINEET KHATRI SIR

CLASS : XI TIME : 35 MIN. DPP. NO.2

O
CH3
CH–2 CH=CH – C – Cl

1. N
O
CH–2 CH3
(a) Find out the total number of 1° hydrogen. (b) Find out the total number of 2° hydrogen.
(c) Find out the total number of 3° hydrogen. (d) Find out the total number of 1° carbon.
(e) Find out the total number of 2° carbon. (f) Find out the total number of 3° carbon.
(g) Find out the total number of 4° carbon.
(h) Find out the total number of functional groups.
(i) Find out the number of degree of unsaturation.

OH
H
2.
OO
NH2 NH2
NH
O
(a) Find out the total number of 1° hydrogen. (b) Find out the total number of 2° hydrogen.
(c) Find out the total number of 3° hydrogen. (d) Find out the total number of 1° carbon.
(e) Find out the total number of 2° carbon. (f) Find out the total number of 3° carbon.
(g) Find out the total number of 4° carbon. (h) Find out the total number of functional groups.
(i) Find out the number of degree of unsaturation.

3.
I IV
II III
Find out the number of 1°, 2° & 3° carbon atoms in the above compounds.
4. Match the column :
Column I Column II
CH3
(A) CH3—CH2—N (P) 1° Carbon
H
(B) CH2 = CH – CH3 (Q) 2° Carbon

(C) (R) 3° Carbon

OH
(D) (S) 4° Carbon

“Follow your dreams; they will give meaning to every step that you take.”
 COMPLETE COURSE IN ORGANIC CHEMISTRY
BY VINEET KHATRI SIR

CLASS : XI TIME : 35 MIN. DPP. NO.3

Calculate DBE value -
–
COO

1. 2. 3.

COOH
H OH
4. 5. 6. H OH
COOH

O
||
7. NH 8. 9.
||
O

10. 11. .. 12.

N
H

CN
CH3
H Br
13. 14. 15.
H Br
|| CH3
O

O O
OH
16. 17. 18.

19. 20. 21. C9H16 NOCl

COOH
COOH

“Set your goals where the sky is the beginning and if

you land anywhere in between, you are doing Great”
[1]
 COMPLETE COURSE IN ORGANIC CHEMISTRY
BY VINEET KHATRI SIR

CLASS : XI TIME : 35 MIN. DPP. NO.4

Calculate DBE value -

1. 2. N 3. HCOO

H2C
H3C

4. 5.

CH2

CH3

O
O
O OH
HO
OH HO N(CH3)2

6. 7. O O
O
O O
O
O OCH3
O
erythromycin

8. 9.

“The future is my canvas. Now I

have to paint the right picture”
[2]
 COMPLETE COURSE IN ORGANIC CHEMISTRY
BY VINEET KHATRI SIR

CLASS : XI TIME : 35 MIN. DPP. NO.5

1. How many ether is/are possible for molecular formula C4H10O.
(A) 1 (B) 2 (C) 3 (D) 4
2. How many ketone is/are possible for molecular formula C4H8O
(A) 1 (B) 2 (C) 3 (D) 4
3. How many alcohol is/are possible for Molecular farmula C4H10O (only structural)
(A) 2 (B) 3 (C) 4 (D) 5

O
O–H
4.
O

Number of Functional group in above compound is

(A) 3 (B) 4 (C) 5 (D) 6

5. The functional groups in Cortisone are : HOH2C

(A) Ether, alkene, alcohol CH3 OCH3
O
(B) Alcohol, ketone, alkene, ether
(C) Alcohol, ketone, amine
(D) Ether, amine ketone

O O Cortisone
O
O–H
6. H SH
OH
OH
How many types of functional groups are present in given compound.
(A) 6 (B) 5 (C) 4 (D) 7

CH3 O

7. Present functional group is

O CH3

(A) ketone (B) ester (C) ether (D) alcohol

8. Present functional group is/ are
O O
||
OCCH3

O
(A) ketone (B) ester (C) ether (D) A and B both

"Histroy tells stories about great men from the past so

write your story now."
[3]
 COMPLETE COURSE IN ORGANIC CHEMISTRY
BY VINEET KHATRI SIR

CLASS : XI TIME : 35 MIN. DPP. NO.6

1. Circle the functional group & also find out the degree of unsaturation
O
H
N H
N
O H
(i) (ii) O
N O
Me
OH O
O
O Cl
(iii) H (iv)
H
O O O O
OH O
O
O O HO O
O
(v) (vi)
N
O
NH2
O O O NH2
O

2. Which of following is phenol ?

OH OH OH

(A) (B) (C) (D)

OH

NH2 OH
3. OH
O
H
O NH2

(i) Which functional group is not present in above compound ?

(A) Ketone (B) Carboxylic acid (C) Amine (D) Alcohol
(ii) Which functional group is present in above compound ?
(A) Ester (B) 2° amine (C) Alkyne (D) Amide
(iii) Types of functional group is present in above compound
(A) 5 (B) 6 (C) 7 (D) 8
(iv) Degree of unsaturation in above compound is
(A) 5 (B) 6 (C) 7 (D) 8
(v) Above compound is Bicyclo (A) Yes (B) No

(vi) Above compound is spiro (A) Yes (B) No

[4]
 O O

C–NH2

4.

NH2 OH

H O
(i) Which functional group is not present in above compound ?
(A) Ketone (B) Carboxylic acid (C) Amine (D) Alcohol
(ii) Which functional group is present in above compound ?
(A) Ester (B) 2° amine (C) Alkyne (D) Amide
(iii) Types of functional group is present in above compound
(A) 5 (B) 6 (C) 7 (D) 8
(iv) Degree of unsaturation in above compound is
(A) 5 (B) 6 (C) 7 (D) 8
(v) Above compound is Bicyclo (A) Yes (B) No
(vi) Above compound is spiro (A) Yes (B) No

Me
NH2 c
b
N S
5.
O N
H a– O
d Me O–H
e
(i) Which functional group is not present in above compound ?
(A) Ketone (B) Phenol (C) Amine (D) Alcohol
(ii) Which functional group is present in above compound ?
(A) Ester (B) 2° amine (C) Alkyne (D) Amide
(iii) Types of functional group is present in above compound
(A) 5 (B) 6 (C) 7 (D) 8
(iv) Degree of unsaturation in above compound is
(A) 5 (B) 6 (C) 7 (D) 8
(v) Above compound is Bicyclo (A) Yes (B) No
(vi) Above compound is spiro (A) Yes (B) No
Observe following compound and answer questions given below.

OH (d)
OH (c)
O
(e) O
HO
6. O
N N
Me
OH H
(a) (b)
(i) Total number of different types of functional groups in this compound are
(A) 5 (B) 6 (C) 7 (D) 8

"Let your mind lead you and let your heart guide you."
[5]
 COMPLETE COURSE IN ORGANIC CHEMISTRY
BY VINEET KHATRI SIR

CLASS : XI TIME : 35 MIN. DPP. NO.7

1. Find - D.B.E. of the following
(Write your answer in box)

(1) C4 H10 (2) C4H8

(3) C4H6 (4) C5H12O

(5) C5H10O (6) C5H8O

(7) C6H12 (8) C4H8Cl2

(9) C4H8Br2 (10) C4H10O

(11) C10H20 (12) CNH5

(13) C3H6O (14)

O
(15) (16)

(17) (18)

(19) (20)

CH2 CH2
O

(21) (22)

CH2 CH2 O

O
O
C–O–H
(23) (24) CH –C–O–H
3

(25) CH3 – NH2 (26) C2H3N

[6]
2. Match the column :
Column I Column II
(Compound) (Double bond equivalent)

(A) (P) 4
H
CH3
C—N S
O
O N
COOH
(penicillin)

(B) (Q) 5

(Hexahelicene)
(C) (R) 7

(Prismane)
O
C OH
(D) C (S) 19
C OH
O
(Ninhydrin)

3. Match the column :

Column I Column II
(Compound) (Double bond equivalent)

(A) (P) 5

(Limonene)

(B) (Q) 4

(Zingiberene)

(C) (R) 3

(Pyrene)

(D) (S) 12

(Cubane)
[7]
 ANSWER-KEY
Answers of DPP No.-1
1. D 2. D 3. A 4. A 5. C 6. BC
7. CD 8. ABCD 9. BD 10. (a) 1°, (b) 2°, (c) 3°, (d) 3°, (e) 2°
11. (a) 2°, (b) 1°, (c) 3°, (d) 2°, (e) 2°, (f) 3°
Answers of DPP No.-2
1. a-9, b-12, c-1, d-5, e-9, f-1, g-1, h-4, i-6 2. a-9, b-11, c-3, d-5, e-9, f-3, g-0, h-7, i-5
1°
2° 1° 3° 2°
3° 4° 3° 4° 3° 3° 1° 3° 3° 1°
2° 1° 1°
2° 3° 3° 2° 2° 2° 3° 3°
3. 2° 1° 2° 3° 2°
2° 3° 3° 4° 1° 3° 2° 2° 3° 1°
2° 3° 3° 2°
1°
(I) (II) (III) (IV)
4. (A) P; (B) P, Q; (C) P, Q, R, S; (D) Q,R

Answers of DPP No.- 3

1. 4 2. 2.5 3. 7 4. 10 5. 10 6. 2 7. 7
8. 2 9. 10 10. 3 11. 3 12. 3 13. 4 14. 6
15. 0 16. 4 17. 3 18. 5 19. 4 20. 4 21. 2
Answers of DPP No.- 4
1. 5 2. 0 3. 1.5 4. 2 5. 11 6. 21 7. 5
8. 16 9. 5
Answers of DPP No.- 5
1. C 2. A 3. C 4. B 5. B 6. B 7. C
8. D

Answers of DPP No.- 6

1. Function group DBE
(i) ene, yne, ketone 5
(ii) aldehyde, 2° amine, 3° Amine, Amide, ene, ketone 6
(iii) ene, yne, anhydride, ketone and aldehyde 8
(iv) alcohol, naphthol, acid chloride, aldehyde 9
(v) ketone, alkene, anhydride 5
(vi) ketone, aldehyde, ene, yne, alcohol, amide, 1° amine, ester 11

2. C 3. (i) B, (ii) D, (iii) B, (iv) B, (v) A, (vi) B

4. (i) B, (ii) D, (iii) B, (iv) B, (v) B, (vi) B 5. (i) A, (ii) D, (iii) C, (iv) C, (v) B, (vi) B 6. (i) C
Answers of DPP No.- 7
1.
(1) 0 (2) 1 (3) 2 (4) 0 (5) 1 (6) 2 (7) 1
(8) 0 (9 0 (10) 0 (11) 1 (12) 0 (13) 1 (14) 4
(15) 2 (16) 5 (17) 2 (18) 3 (19) 7 (20) 7 (21) 17
(22) 4 (23) 5 (24) 1 (25) 0 (26) 2
2. A  Q ; B  S ; C  P ; D R 3. A  R ; B  Q ; C  S ; D P