Rates and Energetics Mastery Booklet
Rates and Energetics Mastery Booklet
Rates and Energetics Mastery Booklet
Sybil places an iron nail in some water. After 5 minutes she says “My iron is not rusting as
it looks normal” Explain why she is wrong
10. For each of the diagrams list possible ways of measuring the rate of reaction.
There may be more than one possible answer.
a. b.
c. d.
Practical: Measuring the rate of reaction of marble chips and hydrochloric acid
• Place four marble chips into the conical flask and put the bung into the tube.
B 100
C 50
Lesson 2: How does changing the concentration affect the rate of reaction?
Collision theory is used to explain why chemical reactions occur. As mentioned before we
need the particles to collide with an energy above the activation energy.
Concentration is the number of particles in a given volume. In the box below there is a low
concentration of particles
23. In the empty box draw what a high concentration of particles would look like
Practical
The rate of the reaction between HCl and marble chips depends on the concentration
of the acid. We saw last lesson that the rate of a reaction varies as it progresses.
Hypothesis: The rate of a reaction between magnesium and hydrochloric acid depends
on the concentration of the hydrochloric acid.
24. Below is a worked example of how to write an accurate method for a different
practical. Use it to complete the blank table and then write your method up in a
paragraph in your book.
25. Calculate the mean time, making sure you ignore any anomalous results
26. Plot a line graph (X axis=concentration, Y axis=time to collect 30cm 3 )
27. Describe how changing the concentration affects the rate of reaction (Hint: say how it
changes, use numbers as evidence)
28. Explain why increasing the concentration increases the rate of reaction (Hint: use
collision theory)
29. Give one source of error from the practical.
30. Marjorie says “increasing the concentration of the acid speeds up the reaction
because there are less frequent collisions so more reactant is formed” There are two
mistakes. Re-write with the corrections.
Lesson 3 How does increasing the surface area increase the rate of reaction?
By increasing the surface area of a substance, you are increasing the number of particles
available to react
In this diagram, a lump of metal is being reacted with a solution. In image A, only the
particles at the very edge of the metal can collide with particles from solution. Particles
from inside the metal cannot collide.
Practical: Investigating how changing the surface area of rhubarb affects the rate of
reaction
Whole
Halved
Quartered
(________________) (___________________)
0 0 0 0
30 25 44 65
60 44 71 78
90 70 80 94
120 85 92 95
150 92 95 95
180 95 95 95
A different experiment was completed using different sized marble chips in similar method
to last lessons practical. The following data was collected.
38. In the two spaces on the table write small chips and big chips. Get this answered
checked before moving onto q below.
39. Plot the three lines on graph paper. Draw a smooth curve of best fit for each one.
40. Which reaction had the fastest rate? How
could you tell from the graph?
41. At what time did the medium surface area
chips finish reacting? How could you tell?
Lesson 4 Catalysts
A catalyst is something which is added to a reaction to increase its rate. It is not used up
as part of the reaction. It works by lowering the activation energy of the reaction, so
when particles with less energy collide a reaction can still occur.
Most of the chemical reactions that occur in the human body and in other living things are
high-energy reactions that would occur slowly, if at all, without the catalysis provided by
enzymes. For example, in the absence of catalysts, it takes several weeks for starch to
break down into glucose. Some enzymes increase reaction rates by a factor of one billion
or more.
Industrial Catalysts
Catalysts are very important in industry. Finely divided precious metals, such as platinum
and gold, or metal oxides are often used as catalysts. They are hugely expensive, but, as
they are not used up in the reaction, they can be used again and again. Other commonly
used surface catalysts are copper, iron, nickel and palladium.
Catalysts tend to be fairly specific; that is, they catalyze only one reaction of one
particular reactant (called the substrate). This means that very often, more than one
catalyst may be needed in a chemical plant.
Catalysts work by lowering the activation energy for a reaction, i.e., the minimum energy
needed for the reaction to occur. This is accomplished by providing a new mechanism or
reaction path through which the reaction can proceed. When the new reaction path has a
lower activation energy, the reaction rate is increased and the reaction is said to be
catalyzed. This very often results in lower temperature being used in industry, saving
money and cutting the use of fossil fuels and their subsequent emissions.
One example of everyday catalysts is the ones in a catalytic converter in a car. They have
a honeycomb construction inside, which contain precious metals like gold, platinum and so
on. As the exhaust gases pass through, the construction then removes all the harmfulness
in the gases.
Watch the demonstration the hydrogen peroxide (H2O2) decomposes to form water and
oxygen
23. Which catalyst was best? Give a reason for your choice
24. Write a word equation for the reaction
25. Write a balanced symbol equation for the reaction
26. Lloyd watches the demonstration and says “That was a waste of catalyst. Now it’s
used up we will need to throw it away.” Explain why Lloyd is wrong
27. Why is the reaction called a decomposition?
28. What was the independent variable?
29. Name 2 control variables for this investigation
30. How did we prove it was oxygen gas being released?
31. How could we have made sure the surface area of the liver was the same as the
powders?
32. Define ‘reactant’
33. Define ‘product’
34. How would the result be different if we cooked the liver first? Give reason for your
answer
35. Respiration ‘burns’ glucose at body temperature (37oC). In a lab glucose burns once
it reaches 144oC.
a) Why is the word ‘burns’ in inverted commas?
b) Calculate the percentage decrease in the temperature the reaction happens at
inside the body.
c) Why can the reaction happen at such a low temperature? Make sure you include
the words activation energy in your answer
The law for the conservation of energy states “Energy cannot be created or destroyed,
only transferred from one store to another”. In any substance there is a store of energy.
When chemical reactions occur the amount of energy in the chemical store of the products
is different to the reactants. Before we go into this in more detail we need to make two
things clear:
The chemicals (reactants or products) are very small and impossible to see
The test tube, water they are dissolved in, thermometer, air around them are
all part of the surroundings
In the case below the products have less energy in their chemical store. The excess
energy has been released and absorbed by the surroundings. This increases the thermal
store of the surroundings. Our thermometer will show a temperature rise. This is an
exothermic reaction because the surroundings have increased in temperature.
Exothermic means ‘releases heat’. Examples of exothermic reactions include
combustion, repisration, neutralisation, acids and metals.
In the second example the chemical store of the products is much larger than the
reactants. For this reaction to happen the reactants need to absorb energy from the
surroundings thermal store. This means the surroundings have less energy and the
thermometer shows a drop in temperature. This is an endothermic reaction. Endothermic
means ‘takes in heat’. Examples of endothermic reactions include thermal decomposition,
citric acid and sodium hydrogen carbonate, sports related cold-packs.
For each of the reactions below read the instructions carefully and complete the practical.
Make sure you wait at least 1 minute before adding the final reactant to get a reliable
starting temperature.
Exp Reaction Start temp (°C) End temp (°C) Temp
change (oC)
1 Demo: Measure out 10cm3 NaOH
into the polystyrene cup and
add 10cm3 HCl
2 Demo: Barium hydroxide and
ammonium chloride
3 Add 1 spatulas of iron filings to
5cm3 copper sulphate in a test
tube
4 Measure out 5cm3 water from
the tap into a test tube and add
a spatula of ammonium nitrate
5 Measure out 10cm3 NaOH into
A beaker and add 10cm3 HCl
6 Measure out 5cm3 of distilled
water into a test tube. Add a
spatula of sodium hydrogen
carbonate and stir, take the
temperature then add a spatula
of citric acid
Exothermic Endothermic
Energy
Temperature of
surroundings
Examples
40. Dora says “an exothermic reaction is a reaction where energy is taken into the
reactants causing a temperature change” she has made two mistakes. Re-write the
correct definition into your books
41. The following experiment was used to compare how much heat energy three
different fuels gave out when they were burnt.
Thermometer
Metal can
Fuel burner
100g water
Here are the results when 1.0 g of each fuel was burnt.
fuel temperature of water at start temperature of water at end
ethanol 19oC 36oC
paraffin 20oC 47oC
white spirit 18oC 41oC
Misreading
the thermometer
Thermometer only
reads to whole numbers
Lesson 6: Combustion
Fire is one of the most important discoveries in human history. Fire has provided warmth
through the cold winters of our ancestors. Fire has cooked our food and fired our clay
pots. Fire has allowed us to extract metals from the ground to make the machines of the
industrial revolution. Fire has allowed us to release energy from fuels like coal, oil and
natural gas. This energy was used to power steam and, more recently, the internal
combustion engine. It is safe to say that the story of human civilisation is the story of fire.
A common type of fuel is an alkane. These saturated hydrocarbons are found in the ground
as crude oil. They are made of only carbon and hydrogen and they release huge amounts
of energy when they combust. Examples include natural gas (methane) which is used for
cooking and heating
Complete combustion
Complete combustion is when there is an excess of oxygen present. A roaring blue Bunsen
flame is an example of complete combustion. As there is more than enough oxygen every
single atom of carbon and hydrogen can bond with oxygen. Complete combustion forms
carbon dioxide and water. Because so many new bonds are made it releases the most
amount of heat. Carbon dioxide is a greenhouse gas and rising levels have been thought to
be the main cause of climate change through global warming
Incomplete combustion
53. Complete the table below to summarise the differences in the types of combustion
Oxygen supply
Colour of flame
Energy released
Smoke/soot
produced
Environmental issue
54. Use the venn diagram below to compare complete and incomplete combustion
Complete Incomplete
combustion combustion
55. (Extended response) Compare complete and incomplete combustion
Hint: Compare means mention how they are the same and different
Useful vocab: Contrastingly, however, similarities
Keywords: oxidation, energy, flame, products, oxygen, smoke, soot, greenhouse,
toxic
56. This apparatus can collect the products of a combustion reaction. Label the
diagram using words from the box.
57. Which two gases rise from the candle and enter the delivery tube?
58. What collects in the U-tube?
59. Why is the U-tube cooled?
60. Blue cobalt chloride paper is placed in the U-tube. What is seen and what does it
prove?
61. What happens to the limewater? What does this prove?
62. Candle wax contains the hydrocarbon pentacosane. What is meant by the term
hydrocarbon?
63. Write the word equation for the combustion of pentacosane:
Balancing complete combustion equations is easier than it seems if you follow these
simple rules:
If the fuel has an odd number of carbons (e.g., CH4, C3H8) you need one molecule of
fuel in the equation.
If the fuel has an even number of carbons (e.g., C2H6) you need two molecules of
fuel in the equation.
Each carbon in the reactants makes one molecule of CO2 in the products.
Every two hydrogens in the reactants make one molecule of H2O in the products.
Then all you need to do is count up the oxygen atoms in the products
and balance this in the reactants.
Note: this only works for complete combustion of alkanes.
64. Try writing balanced equations for combustion of:
A. Propane (C3H8)
B. Ethane (C2H6)
C. Pentane (C5H12)
D. Decane (C10H22)
E. Pentacosane – candle wax (C25H52)
65. When carbon burns it combines with oxygen to form carbon dioxide. The diagram
shows some carbon atoms reacting with some oxygen molecules.
a) Finish the diagram by drawing the correct number of carbon dioxide molecules.
One has been done for you.
b) Write ‘reactants’ and ‘products’ under the correct sides of the diagram.
12 g 24 g 32 g 44 g 64 g
66. This diagram below shows the reaction between marble chips and acid.
b) What would you expect the balance to read when the reaction has finished? Circle
the correct answer. 179 g 180 g 181 g
67. If you heat a piece of copper, it combines with oxygen from the air to form a black
layer of copper oxide.
b) How would the mass of your piece of copper change as you heated it?
c) Why would this happen?
While the reaction completes: Draw and label your equipment in a correct scientific
diagram. Calculate the mass of copper carbonate you started with.
7. Write the equation for the reaction and the masses you’ve worked out underneath
each substance.
I. What mass of carbon dioxide is given off in this reaction? Give the unit.
(b) The pupils then heated some magnesium in another crucible. They worked
carefully and did not lose any of the magnesium oxide which formed. They recorded
the mass of the crucible and contents before and after heating.
Thermal decomposition
Combustion
77. For each reaction, identify the type of reaction (the equations are not balanced).
a) CH4 + O2 CO2 + H2O
b) Mg + O2 MgO
c) CaCO3 CaO + CO2
78. Explain why combustion is also an oxidation reaction
79. In the following reaction:
CuCO3 CuO + CO2
247g of copper carbonate was heated and 88g of carbon dioxide was given off.
Calculate the mass of copper oxide produced
81. Describe two ways to measure the rate of a reaction involving a gas being given off
91. What would you expect to see happen to the temperature during an exothermic
reaction?
92. Why does the rate of reaction increase when the concentration is increased?
2 control variables when testing the effect
of surface area on the rate of reaction
between HCl and calcium carbonate are:
The amount of carbonate
The amount of acid
The test for carbon dioxide is to put a lit
splint inside it and if the flame goes out,
it’s carbon dioxide
When investigating endothermic reactions
a polystyrene cup is better because it stops
energy being lost to the environment