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Safety Data Sheet

acc. to OSHA HCS
Printing date 04/30/2015 Reviewed on 04/27/2015

* 1 Identification
- Product identifier
- Trade name: Vibra-TITE® Retaining Compound
- Synonyms: 567 High Temperature - Large Gap Retaininng Compound
- Part number: VT567
- Relevant identified uses of the substance or mixture Part retaining
- Details of the supplier of the safety data sheet
- Manufacturer/Supplier:
ND Industries, Inc
1000 North Crooks Road
Clawson, MI 48017
USA
Telephone: +1-248-288-0000
Email: info@ndindustries.com
Website: www.ndindustries.com
- Information department: Product safety department
- Emergency telephone number:
United States: 1-800-424-9300
International: +1-703-527-3887
* 2 Hazard(s) identification
- Classification of the substance or mixture

GHS07

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
- Label elements
- GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
- Hazard pictograms

GHS07

- Signal word Warning

- Hazard-determining components of labeling:
Ethoxylated dimethacrylate
maleic acid
- Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
- Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P280 Wear protective gloves.
P280 Wear eye protection / face protection.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312 Call a poison center/doctor if you feel unwell.
P363 Wash contaminated clothing before reuse.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 2)

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(Contd. of page 1)
- Classification system:
- NFPA ratings (scale 0 - 4)
Health = 1
1 Fire = 1
1 0 Reactivity = 0
- HMIS-ratings (scale 0 - 4)
HEALTH *1 Health = *1
FIRE 1 Fire = 1
REACTIVITY 0 Reactivity = 0
- Other hazards
- Results of PBT and vPvB assessment
- PBT: Not applicable.
- vPvB: Not applicable.
* 3 Composition/information on ingredients
- Chemical characterization: Mixtures
- Description: Mixture of the substances listed below with nonhazardous additions.
- Dangerous components:
Ethoxylated dimethacrylate 60-70%
27813-02-1 Hydroxypropyl methacrylate 10-20%
80-15-9 Cumene hydroperoxide 1-5%
79-10-7 acrylic acid  1.00%
110-16-7 maleic acid  1.00%
* 4 First-aid measures
- Description of first aid measures
- After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
Supply fresh air; consult doctor in case of complaints.
- After skin contact: Immediately wash with water and soap and rinse thoroughly.
- After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
- After swallowing: If symptoms persist consult doctor.
- Information for doctor:
- Most important symptoms and effects, both acute and delayed No further relevant information available.
- Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
- Extinguishing media
- Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
- Special hazards arising from the substance or mixture No further relevant information available.
- Advice for firefighters
- Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
* 6 Accidental release measures
- Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Wear protective clothing.
- Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
- Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Dispose of the collected material according to regulations.
- Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
(Contd. on page 3)

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(Contd. of page 2)

7 Handling and storage

- Handling:
- Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
- Information about protection against explosions and fires: No special measures required.
- Conditions for safe storage, including any incompatibilities
- Storage:
- Requirements to be met by storerooms and receptacles: No special requirements.
- Information about storage in one common storage facility: Not required.
- Further information about storage conditions: Keep receptacle tightly sealed.
- Specific end use(s) No further relevant information available.
* 8 Exposure controls/personal protection
- Additional information about design of technical systems: No further data; see item 7.
- Control parameters
- Components with limit values that require monitoring at the workplace:
80-15-9 Cumene hydroperoxide
WEEL Long-term value: 6 mg/m³, 1 ppm
Skin
- Additional information: The lists that were valid during the creation were used as basis.
- Exposure controls
- Personal protective equipment:
- General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
- Breathing equipment:
Not required.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory
protective device that is independent of circulating air.
- Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
- Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can
not be calculated in advance and has therefore to be checked prior to the application.
- Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
- Eye protection:

Tightly sealed goggles

- Body protection: Protective work clothing

* 9 Physical and chemical properties
- Information on basic physical and chemical properties
- General Information
- Appearance:
- Form: Viscous
- Color: Green
- Odor: Characteristic
- Odour threshold: Not determined.
- pH-value: Not determined.
(Contd. on page 4)

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(Contd. of page 3)

- Change in condition
- Melting point/Melting range: Undetermined.
- Boiling point/Boiling range: 195 °C (383 °F)
- Flash point: 95 °C (203 °F)
- Flammability (solid, gaseous): Not applicable.
- Ignition temperature:
- Decomposition temperature: Not determined.
- Auto igniting: Product is not selfigniting.
- Danger of explosion: Product does not present an explosion hazard.
- Explosion limits:
- Lower: Not determined.
- Upper: Not determined.
- Vapor pressure: Not determined.
- Density: Not determined.
- Relative density Not determined.
- Vapour density Not determined.
- Evaporation rate Not determined.
- Solubility in / Miscibility with
- Water: Not miscible or difficult to mix.
- Partition coefficient (n-octanol/water): Not determined.
- Viscosity:
- Dynamic at 20 °C (68 °F): 10000 mPas
- Kinematic: Not determined.
- Solvent content:
- Organic solvents: 0.8 %
- Water: 0.1 %
- VOC content: 0.8 %
8.1 g/l / 0.07 lb/gl
- Solids content: 76.5 %
- Other information No further relevant information available.

10 Stability and reactivity

- Reactivity
- Chemical stability
- Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
- Possibility of hazardous reactions No dangerous reactions known.
- Conditions to avoid No further relevant information available.
- Incompatible materials: No further relevant information available.
- Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
- Information on toxicological effects
- Acute toxicity:
- LD/LC50 values that are relevant for classification:
80-15-9 Cumene hydroperoxide
Oral LD50 382 mg/kg (rat)
Dermal LD50 500 mg/kg (rat)
Inhalative LC50/4 h 220 mg/l (rat)
79-10-7 acrylic acid
Oral LD50 250 mg/kg (rat)
Dermal LD50 280 mg/kg (rabbit)
Inhalative LC50/4 h 11 mg/l (ATE)
110-16-7 maleic acid
Oral LD50 708 mg/kg (rat)
Dermal LD50 1560 mg/kg (rabbit)
(Contd. on page 5)

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Trade name: Vibra-TITE® Retaining Compound

(Contd. of page 4)
- Primary irritant effect:
- on the skin: Irritant to skin and mucous membranes.
- on the eye: Irritating effect.
- Sensitization: Sensitization possible through skin contact.
- Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
- Carcinogenic categories
- IARC (International Agency for Research on Cancer)
79-10-7 acrylic acid 3
- NTP (National Toxicology Program)
None of the ingredients is listed.
- OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.

12 Ecological information
- Toxicity
- Aquatic toxicity: No further relevant information available.
- Persistence and degradability No further relevant information available.
- Behavior in environmental systems:
- Bioaccumulative potential No further relevant information available.
- Mobility in soil No further relevant information available.
- Ecotoxical effects:
- Remark: Harmful to fish
- Additional ecological information:
- General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Harmful to aquatic organisms
- Results of PBT and vPvB assessment
- PBT: Not applicable.
- vPvB: Not applicable.
- Other adverse effects No further relevant information available.

13 Disposal considerations
- Waste treatment methods
- Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
- Uncleaned packagings:
- Recommendation: Disposal must be made according to official regulations.

14 Transport information
- UN-Number
- DOT, ADN, IMDG, IATA not regulated
- UN proper shipping name
- DOT, ADN, IMDG, IATA not regulated
- Transport hazard class(es)
- DOT, ADN, IMDG, IATA
- Class not regulated
- Packing group
- DOT, IMDG, IATA not regulated
- Environmental hazards:
- Marine pollutant: No
- Special precautions for user Not applicable.
- Transport in bulk according to Annex II of MARPOL73/78
and the IBC Code Not applicable.
- UN "Model Regulation": -
(Contd. on page 6)

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(Contd. of page 5)

15 Regulatory information
- Safety, health and environmental regulations/legislation specific for the substance or mixture
- Sara
- Section 355 (extremely hazardous substances):
None of the ingredients is listed.
- Section 313 (Specific toxic chemical listings):
80-15-9 Cumene hydroperoxide
79-10-7 acrylic acid
- TSCA (Toxic Substances Control Act):
Hydroxypropyl methacrylate
Cumene hydroperoxide
Propylene glycol
Saccharin
acrylic acid
2'-phenylacetohydrazide
maleic acid
Polyethylene glycol dimethacrylate
1,4-naphthoquinone
Deionized water
- Proposition 65
- Chemicals known to cause cancer:
None of the ingredients is listed.
- Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
- Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
- Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
- Carcinogenic categories
- EPA (Environmental Protection Agency)
None of the ingredients is listed.
- TLV (Threshold Limit Value established by ACGIH)
79-10-7 acrylic acid A4
- NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
- Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and
shall not establish a legally valid contractual relationship.
- Department issuing SDS: ND Industries, Inc. - Safety, Health and Environmental Affaires
- Contact: Safety, Health and Environmental Affaires
- Date of preparation / last revision 04/30/2015 / 8
- Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A
Skin Sens. 1: Sensitisation - Skin, Hazard Category 1
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
- * Data compared to the previous version altered.
(Contd. on page 7)

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Trade name: Vibra-TITE® Retaining Compound

(Contd. of page 6)

- Disclaimer
The information set forth is based on information that ND Industries, Incorporated believes to be accurate. No warranty, expressed or
implied, is intended. The information is provided solely for your information and consideration and ND Industries Inc. assumes no legal
responsibility for use or reliance thereon. In the event of a discrepancy between the information on the non-English document and its
English counterpart, the English version shall supersede.

®ND and ND Industries, Inc. are registered trademarks of ND Industries Incorporated,

®Vibra-TITE is a registered trademark of ND Industries, Inc.

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