Automotive Fuels and Energy System
Automotive Fuels and Energy System
Automotive Fuels and Energy System
Introduction
An electric vehicle (EV) is operated by an electric motor, which draws electricity from a
battery bank. Different types of batteries for EVs and other applications are being developed for
better performance. Storage batteries store a fixed amount of chemical energy. The batteries can be
recharged when the electrochemically active materials in these batteries have been used up. Most
of the EVs at present use rechargeable lead acid batteries. Because of availability and low price, lead
acid batteries are more widely used than other batteries. The EVs should match comparable petrol
or diesel-driven vehicles in terms of performance, reliability, durability and cost. Therefore, the
manufacturers should develop these types of EVs. The battery pack used should be capable of
providing electricity to start the vehicle and also for auxiliary loads. Reliability, cost and useful life
of the batteries used in EVs are important.
Environmental and economic issues are the major driving force in developing EVs for urban
transportation. The exhaust emissions of the conventional internal combustion engine vehicles are
the major source of urban pollution that causes the greenhouse effect leading to global warming.
Electricity can be used as a transportation fuel to power battery electric and fuel cell vehicles. When
used to power electric vehicles, electricity is stored in an energy storage devices such as a battery.
EV batteries have a limited storage capacity and must be replenished by plugging the vehicle into a
recharging unit. The electricity for recharging the batteries can come from the existing power grid
or from distributed renewable sources such as solar or wind energy.
The battery operated electric vehicles (BEVs) are powered by motors, which draw electricity from
on-board storage batteries. The major components of a BEV system are the motor, controller,
power source, charger and drive train. The block diagram of an EV system is shown in following
figure.
Electric Vehicle Components
1. An electric motor
2. An electronic control module (ECM)
3. A traction battery ( a battery management system, a smart battery charger)
4. A cabling system
5. A regenerative braking system
6. A vehicle body, a frame, EV fluids for cooling, braking, etc. and lubricants.
Electric Motor:
Used for propelling the vehicle. There are two types of electric drive systems viz.,
alternating current (AC) and direct current (DC). DC motors are easier to control and are less
expensive, but they are often larger and heavier than AC motors. AC motors and controllers usually
have a higher efficiency over a large operational range, but due to complex electronics, the ECMs
are more expensive.
The controller
It takes signal form the vehicle`s accelerator pedal and controls the electrical
energy provided to the motor, causing the torque to turn the wheels.
Batteries
The batteries in an electric car are the energy storage device for the electric
motor. Unlike the gasoline in the fuel tank, which can only power the gasoline engine, the electric
motor can put energy into the batteries as well as draw energy from them.
EV Batteries
Power Density
Energy Density
The energy density is the energy obtainable per unit weight (gravimetric energy
density) or per unit volume (volumetric energy density). Energy capacity of the traction battery
determines the vehicle range. Specific energy determines battery weight for a given range, and
energy density determines battery size. In general terms, NiMH (nickel-metal hydride) batteries
have twice the energy density and specific energy compared to lead acid batteries. An EV with
NiMH batteries will have the same size and weight of battery, but twice the range. Two vehicles
with equal range, that is, the one with twice the efficiency but half the battery capacity, will spend
half as much time charging and use half as much electricity. Reducing energy consumption is often a
better way to increase EV range than increasing battery capacity. For a given charging power,
charge rate, measured in miles of range per hour of charge times is reduced as vehicle efficiency
increases. Energy costs are reduced in direct proportion to vehicle efficiency. For an efficient
vehicle, a lower capacity, lower cost battery may be a better choice for customer satisfaction.
Battery Efficiency
Battery efficiency is defined as energy released on discharge/energy required
for charge. Along with driving efficiency, battery efficiency also effects operating cost, charge
time, and emissions. NiMH batteries have a larger ratio between the open circuit voltage (VOC)
and voltage under load compared to PbA batteries. This translates into reduced efficiency over
the charge/discharge cycle. Battery losses translate directly into heat in the battery. Both NiMH
and PbA batteries can suffer from too much heat, but NiMH have higher losses and are more
sensitive to temperature. NiMH batteries may require active cooling, using the vehicle`s air
conditioning system to prevent overheating. This increases vehicle energy consumption and
reduces some of the range benefit of the NiMH battery.
Cost
Today, an EV battery will cost between $3,000 (PbA @$215/kWh) and $100,00
(NiMH @$3500/kWh). The low cost represents a deep-cycle PbA battery already in production
and in use by AC propulsion. The high cost represents advanced batteries made as prototypes for
evaluation in EVs. Some advanced batteries cost even more. Even the least expensive traction
battery today represents a marginally unacceptable cost compared to component costs.
Life
The conversion of electrical power to mechanical is the fundamental in making an electric vehicle
possible. DC motors were used to convert electrical energy to mechanical energy at the driving
wheels, since the power from the battery was immediately available in the direct form. The use of
AC machines shown considerable advantages in cost, size, weight and reliability.
The important characteristics of a motor for an EV or HEV include flexible drive control, fault
tolerance, high efficiency and low acoustic noise. The motor must be capable of handling voltage
fluctuations from the source. Another important requirement of the electric motor is acceptable
mass production costs, which is to be achieved through technological advancement. The
requirements of an EV or HEV motor, not necessarily in order of importance, are itemized in the
following:
Ruggedness
High torque – to – inertia ratio (Te/J); Large Te/J ratio results in good acceleration
capabilities.
Peak torque capability of about 200 to 300% of continuous torque rating.
High power – to – weight ratio.
High-speed operation, ease of control.
Low acoustic noise, low electromagnetic interference (EMI), low maintenance and low cost.
Extended constant power region of operation.
Types of DC Motors
The principle of the DC motor is well known. In the simplified two pole DC machine a rotor (or
armature) has a number of coils wound on its perpendicular axis and this is free to rotate between
the poles of either an electromagnet or a permanent magnet.
Electric current is supplied to the rotor coil from a DC supply through brushes on a commuter ring.
Series DC Motor
In the case of the series wound motor the field coil is in series connection with
the armature coil with the current limited by a resistor. With this arrangement it can be seen that
the series motor has one major advantage when used in an electric vehicle. This is its high torque at
near zero speed. In fact the torque would be infinite at aero speed if there was no limitation on the
current available and magnetic circuit has zero reluctance.
In real life the current is limited by the resistor Rs and the field coil and armature coil resistance to
the maximum that the field windings, rotor windings and brushes can withstand without
overheating.
Shunt DC Motor
In the case of the shunt wound the field coil is in parallel with the armature coil with its current
controlled by field resistor Rf. and the armature coil current is limited by series resistor Rs. With
this arrangement torque remains constant as speed rises until the maximum power point b on the
torque speed curve is reached if resistor Rf is then increased in value the field current will be
reduced and the no load speed will continue to increase.
Under load the speed of the shunt wound motors remains relatively constant, dropping by only a
few percent between no load and full load while the torque is directly proportional to the armature
current.
Compound DC Motor
It is possible to obtain a wide range of characteristics between the extremes of the series and shunt
wound motors by combining series and shunt field coils in a motor having a compound wound field.
In this motor configuration the majority of the field is provided by the shunt winding with series
field supplementing the shunt field. This is known as cumulative compounding.
With this arrangement the armature current in the series field increases with load causing the
torque to rise but also resulting in a large drop in speed that would be the case in a shunt motor.
The characteristics can therefore to some extent be tailored to the requirement of a particular
vehicle design.
Advantages of DC Machines
Disadvantages of DC Machines
Advantages of AC Machines
Maintenance free
Low-cost
High-speed of induction machines ( possible with a penalty in size and weight)
AC Motors
AC motors are suitable for use in electric vehicles are considered to fall into three categories, they
are induction motors, synchronous motor and switched or variable reluctance motors. Induction
motors and synchronous motors have been used for many years in constant speed industrial
applications but have only become possible for electric vehicle use with the advent of high power,
high efficiency variable frequency inverters.
Switched reluctance motors are only made possible by sophisticated electronic controls and their
use and utility in electric vehicles is still being investigated. Motors using permanent magnet rotors
such as synchronous motor with motor position feedback paradoxically such as the brushless DC
motor.
Induction Motors
Induction motors are a widely accepted commutator less motor type for EV
propulsion because of their low cost, high reliability and maintenance free properties. However,
due to the non-linearity of the dynamic model, conventional control of induction motors such as
variable-voltage variable-frequency (VVVF) cannot provide the desired performance.
Most of the PMSMs are found in small to medium power applications, although
there are some high-power applications for which PMSMs are used. PMSM and induction motors
have good performance in terms of torque response and have rugged motor structures, although
broken magnet chips in PM machines is a concern. With a higher power density, the PMSM is
smaller in size compared to an induction motor with the same power rating. PMSM is more efficient
and easier to cool, compared to the induction machines, due to the absence of rotor copper loss. The
induction motor has lower cost and cogging torque because of the absence of permanent magnets.
The electric motor is driven by a power-electronics-based power-processing unit that converts the
fixed DC voltage available from the source into a variable voltage, variable frequency source
controlled to maintain the desired operating point of the vehicle. The power electronics circuit
comprised of power semiconductor devices saw tremendous development over the past 3 decades.
The enabling technology of power electronics is a key driving force in developing efficient and high-
performance power-train units for EVs. High-power devices in compact packaging are available
today, enabling the development of lightweight and efficient power-processing units known as
power electronic motor drives. Advances in power solid state devices and very large-scale
integration (VLSI) technology are responsible for the development of efficient and compact power
electronics circuits. The developments in high-speed digital signal processors or microprocessors
enable complex control algorithm implementation with a high degree of accuracy. The controller
includes algorithms for the motor drive in the inner loop as well as system-level control in the outer
loop.
1. No Gas Required: Electric cars are entirely charged by the electricity you provide, meaning you
don’t need to buy any gas ever again. Driving fuel based cars can burn a hole in your pocket as
prices of fuel have gone all time high. With electric cars, this cost can be avoided as an average
American spends $2000 – $4 on gas each year. Though electricity isn’t free, an electric car is far
cheaper to run.
2. Savings: These cars can be fueled for very cheap prices, and many new cars will offer great
incentives for you to get money back from the government for going green. Electric cars can also be
a great way to save money in your own life.
3. No Emissions: Electric cars are 100 percent eco-friendly as they run on electrically powered
engines. It does not emit toxic gases or smoke in the environment as it runs on clean energy source.
They are even better than hybrid cars as hybrids running on gas produce emissions. You’ll be
contributing to a healthy and green climate.
4. Popularity: EV’s are growing in popularity. With popularity comes all new types of cars being
put on the market that are each unique, providing you with a wealth of choices moving forward.
5. Safe to Drive: Electric cars undergo same fitness and testing procedures test as other fuel
powered cars. In case an accident occurs, one can expect airbags to open up and electricity supply
to cut from battery. This can prevent you and other passengers in the car from serious injuries.
6. Cost Effective: Earlier, owing an electric car would cost a bomb. But with more technological
advancements, both cost and maintenance have gone down. The mass production of batteries and
available tax incentives have further brought down the cost, thus, making it much more cost
effective.
7. Low Maintenance: Electric cars runs on electrically powered engines and hence there is no need
to lubricate the engines. Other expensive engine work is a thing of past. Therefore, the maintenance
cost of these cars has come down. You don’t need to send it to service station often as you do a
normal gasoline powered car.
8. Reduced Noise Pollution: Electric cars put curb on noise pollution as they are much quieter.
Electric motors are capable of providing smooth drive with higher acceleration over longer
distances.
HEVs generate their own electricity onboard, so they do not have to carry the extra weight of
storage batteries. A hybrid`s electric motor is energized by a battery, which produces power
through a chemical reaction. A generator like the alternator of a conventional car is driven by the
ICE continuously recharges the battery. Hybrids can have a parallel design, a series design, or both
In a parallel design, the energy conversion unit and the electric propulsion system are connected
directly to the vehicle`s wheels. The primary engine is used for highway driving and the electric
motor provides added power during hill climbs, acceleration and other periods of high demand. The
parallel hybrid can utilize the engine to charge the battery pack during less intense power driving
cycles, such as cruising at freeway speeds. In a parallel hybrid, it is possible to turn the engine off
and run the electric motor from the battery pack for shorter in-town driving. In this case, the
parallel hybrid acts and a fully EV and becomes virtually emission-free. The driving range of a
parallel hybrid can achieve up to 400 miles or more.
In a series design, the primary engine is connected to a generator that produces electricity. The
electricity charges the batteries which drive an electric motor that powers the wheels. A series
hybrid vehicle uses a high efficiency ICE or even a turbine to generate electrical power for the
electric motor. The engine is designed to charge a large battery pack, which in turn powers an
electric motor to provide power to the drive wheels. The ICE or turbine runs on and generates
electricity when the battery pack drops below a minimum charge level. The driving range of a series
hybrid vehicle can achieve ranges up to 400 miles without charging
A hybrid`s efficiency and emissions depend on the particular combination of subsystems, how these
subsystems are integrated into a complete system, and the control strategy that integrates the
subsystems.
Series and parallel hybrids come in a variety of types. The mission of the vehicle and the optimum
design for that mission dictate the choice. If the HEV is to be basically an EV with an ICE-assist for
achieving acceptable range, then the choice should be a series hybrid, with the ICE ensuring that the
batteries remain charged all the time. On the other hand, if the HEV is to be basically a vehicle with
almost all the performance characteristics and comforts of an ICEV but with lower emission and
fuel usage standards, then the choice should be a parallel configuration. Parallel HEVs have been
built with performance that is equal, in all aspects of normal operation, to that of a conventional car.
However, some series HEVs have also been built that perform nearly as well as ICEVs.
HEVs evolved out of two basic configurations: series and parallel. A series hybrid is one in
which only one energy converter can provide propulsion power. The heat engine or ICE acts as a
prime mover in this configuration to drive an electric generator that delivers power to the battery
or energy storage link and the propulsion motor. The component arrangement of a series HEV is
shown in Figure below.
Series HEV is the simpler type, where only the electric motor provides all the propulsion
power. A downsized heat engine on board drives a generator, which supplements the batteries and
can charge them when they fall below a certain state of charge. The power required to move the
vehicle is provided solely by the electric motor. Beyond the heat engine and the generator, the
propulsion system is the same as in an EV, making electric motor power requirements the same as
for in the EV.
A parallel hybrid is one in which more than one energy source can provide propulsion power. The
heat engine and the electric motor are configured in parallel, with a mechanical coupling that lends
the torque coming from the two sources. The component arrangements of a parallel hybrid are
shown in Figure below
In parallel HEV, the heat engine and the electric motor are connected to the driveshaft
through separate clutches. Power requirements of the electric motor in the parallel hybrid are
lower than that of an EV or series hybrid, because the heat engine complements for the total power
requirement of the vehicle. The propulsion power may be supplied by the heat engine, by the
battery-motor set, or by the two systems in combination.
Series and parallel hybrids come in a variety of types. The mission of the vehicle and the optimum
design for that mission dictate the choice. If the HEV is to be basically an EV with an ICE-assist for
achieving acceptable range, then the choice should be a series hybrid, with the ICE ensuring that the
batteries remain charged all the time. On the other hand, if the HEV is to be basically a vehicle with
almost all the performance characteristics and comforts of an ICEV but with lower emission and
fuel usage standards, then the choice should be a parallel configuration. Parallel HEVs have been
built with performance that is equal, in all aspects of normal operation, to that of a conventional car.
However, some series HEVs have also been built that perform nearly as well as ICEVs.
Use of the ICE to charge the batteries should be minimized when maximizing efficiency.
Energy is always lost while charging and discharging the battery and during the power flow
through the inverter. The vehicle should be operated off its engine or battery or both, until the
battery is at a minimum acceptable state of charge, say 20 to 40%. The battery should be charged
from the power grid when convenient.
Currently, Ford, Nissan, and Toyota use a power-split system. This system is the basis for many
series-parallel hybrid vehicles. This system is capable of instantaneously switching from one power
source to another or combining the two. The unit functions as a continuously variable transaxle,
although it does not use the belts and pulleys normally associated with CVTs. This transaxle also
does not have a torque converter or clutch. Rather, a damper is used to cushion engine vibration
and the power surges that result from the sudden engagement of power to the transaxle. The
power-split unit used here is basically comprised of a planetary gear set and two electric motors.
When used with high-output engines, the power-split unit also has an additional reduction
planetary gear set.
High power and energy density batteries
Desirable attributes of HEV batteries
High-peak and pulse-specific power
High specific energy at pulse power
High charge acceptance to maximize regenerative braking.
Long calendar and cycle life.
Lead -Acid Battery
Lead-acid batteries have been the most popular choice of batteries for EVs. Lead-acid
batteries can be designed to be high powered and are inexpensive, safe, and reliable. A recycling
infrastructure is in place for them. However, low specific energy, poor cold temperature
performance, and short calendar and cycle life are among the obstacles to their use in EVs and
HEVs.
The long existence of the lead-acid battery is due to the following:
• Relatively low cost
• Easy availability of raw materials (lead, sulfur)
• Ease of manufacture
• Favorable electromechanical characteristics
The battery cell operation consists of a cell discharge operation, when the energy is supplied from
the battery to the electric motor to develop propulsion power, and a cell charge operation, when
energy is supplied from an external source to store energy in the battery.
A highly porous structure is used for the positive electrode to increase the PbO2(s)/electrolyte
contact area, which is about 50 to 150 m2 per Ah of battery capacity. This results in higher current
densities, as PbO2 is converted to PbSO4(s). As discharge proceeds, the internal resistance of the
cell rises due to PbSO4 formation and decreases the electrolyte conductivity as H2SO4 is consumed.
PbSO4(s) deposited on either electrode in a dense, fine-grain form can lead to sulfatation. The
discharge reaction is largely inhibited by the buildup of PbSO4, which reduces cell capacity
significantly from the theoretical capacity.
The negative electrode equation during cell discharge is:
The electrons are released at the negative electrode during discharge operation. The production
of PbSO4(s) can degrade battery performance by making the negative electrode more passive.
Cell charge operation
The cell charge operation is the reverse of the cell discharge operation. During cell charging, lead
sulfate is converted back to the reactant states of lead and lead oxide. The electrons are consumed
from the external source at the negative electrode, while the positive electrode releases the
electrons. The current flows into the positive electrode from the external source, thereby delivering
electrical energy into the cell, where it gets converted into chemical energy.
The chemical reaction at the positive electrode during cell charging is:
The chemical reaction at the negative electrode during cell charging is:
Conventionally, lead-acid batteries are of flooded-electrolyte cells, where free acid covers all the
plates. This imposes the constraint of maintaining an upright position for the battery, which is
difficult in certain portable situations. Efforts in developing hermetically sealed batteries faced the
problem of buildup of an explosive mixture of hydrogen and oxygen on approaching the top-of-
charge or overcharge condition during cell recharging. The problem is addressed in the valve-
regulated-lead-acid (VRLA) batteries by providing a path for the oxygen, liberated at the positive
electrode, to reach the negative electrode, where it recombines to form lead-sulfate. There are two
mechanisms for making sealed VRLA batteries, the gel battery, and the AGM (absorptive glass
microfiber) battery. These types are based on immobilizing the sulfuric acid electrolyte in the
separator and the active materials, leaving sufficient porosity for the oxygen to diffuse through the
separator to the negative plate
Nickel – Cadmium Battery
Nickel – cadmium (NiCd) and nickel – metal hybrid (NiMH) batteries are examples of
alkaline batteries with which electrical energy is derived from the chemical reaction of a metal with
oxygen in an alkaline electrolyte medium. The specific energy of alkaline batteries is lowered due to
the addition of weight of the carrier metal. The NiCd battery employs a nickel oxide positive
electrode and a metallic cadmium negative electrode. The net reaction occurring in the potassium
hydroxide (KOH) electrolyte is:
The practical cell voltage is 1.2 to 1.3 V, and the atomic mass of cadmium is 112. The specific energy
of NiCd batteries is 30 to 50 Wh/kg, which is similar to that of lead-acid batteries. The advantages
of NiCd batteries are superior low-temperature performance compared to lead-acid batteries, flat
discharge voltage, long life, and excellent reliability. The maintenance requirements of the batteries
are also low.
The biggest drawbacks of NiCd batteries are the high cost and the toxicity contained in cadmium.
Environmental concerns may be overcome in the long run through efficient recycling, but the
insufficient power delivered by the NiCd batteries is another important reason for not considering
these batteries for EV and HEV applications. The drawbacks of the NiCd batteries led to the rapid
development of NiMH batteries, which are deemed more suitable for EV and HEV applications.
NiMH batteries have a much longer life cycle than lead-acid batteries and are safe and abuse
tolerant. The disadvantages of NiMH batteries are the relatively high cost, higher self-discharge rate
compared to NiCd, poor charge acceptance capability at elevated temperatures, and low cell
efficiency. NiMH is likely to survive as the leading rechargeable battery in the future for traction
applications, with strong challenge coming only from lithium-ion batteries.
Manganese oxide-based positive electrodes (LiMn2O4 or LiMnO2) are also under research, because
manganese is cheaper, widely available, and less toxic. The cell discharge operation in a lithium ion
cell using LiCoO2 is illustrated in Figure below. During cell discharge, lithium ions (Li+) are released
from the negative electrode that travels through an organic electrolyte toward the positive
electrode. In the positive electrode, the lithium ions are quickly incorporated into the lithium
compound material. The process is completely reversible. The chemical reactions at the electrodes
are as follows:
At the negative electrode,
At positive electrode,
During cell charge operation, lithium ions move in the opposite direction from the positive
electrode to the negative electrode. The nominal cell voltage for a Li-ion battery is 3.6 V, which is
equivalent to three NiMH or NiCd battery cells. Lithium-ion batteries have high specific energy, high
specific power, high energy efficiency, good high-temperature performance, and low self-discharge.
The components of Li-ion batteries are also recyclable. These characteristics make Li-ion batteries
highly suitable for EV and HEV and other applications of rechargeable batteries.
Lithium-polymer evolved out of the development of solid state electrolytes, i.e., solids
capable of conducting ions but that are electron insulators. The solid state electrolytes resulted
from research in the 1970s on ionic conduction in polymers. These batteries are considered solid
state batteries, because their electrolytes are solids. The most common polymer electrolyte is
polyethylene oxide compounded with an appropriate electrolyte salt.
The most promising positive electrode material for Li-poly batteries is vanadium oxide V6O13.1
This oxide interlaces up to eight lithium atoms per oxide molecule with the following positive
electrode reaction:
Li-poly batteries have the potential for the highest specific energy and power. The solid polymers,
replacing the more flammable liquid electrolytes in other type of batteries, can conduct ions at
temperatures above 60°C. The use of solid polymers also has a great safety advantage in case of EV
and HEV accidents. Because the lithium is intercalated into carbon electrodes, the lithium is in ionic
form and is less reactive than pure lithium metal. The thin Li-poly cell gives the added advantage of
forming a battery of any size or shape to suit the available space within the EV or HEV chassis. The
main disadvantage of the Li-poly battery is the need to operate the battery cell in the temperature
range of 80 to 120°C. Li-poly batteries with high specific energy, initially developed for EV
applications, also have the potential to provide high specific power for HEV applications. The other
key characteristics of the Li-poly are good cycle and calendar life.
HEV Ultra-capacitors
In a hybrid EV, energy is constantly being stored and used; the repeated charging and discharging
puts a tremendous strain on the batteries. This reduces the lifetimes of batteries. Ultra-capacitors
eliminate many of the problems of batteries for hybrid EVs. The ultra-capacitors used in hybrid
electric traction batteries (HETB) are electrochemical capacitors, which have extremely high
volumetric capacitances because of large electrode surface areas and very small electrode
separations. Capacitors can have extremely long lives relative to those of batteries. Hence,
reliability of the HETB energy system is increased, the life-of-system cost is reduced, and adverse
environmental effects are diminished with the use of ultra-capacitors.
Advantages of Ultra capacitors
They can function at power densities greater than those of batteries.
They can provide high power levels during acceleration.
They have excellent low-temperature characteristics.
They do not require maintenance.
They can provide consistent performance over time.
They are safe in EVs because of their relative ease of discharge.
Fuel Cell
Fuel cells produce electricity, employing reaction between hydrogen and oxygen gases,
electrochemically. Fuels cells are efficient, environmentally benign, compact, modular and reliable
for power generation. Different type of fuel cells currently under development are the protons
exchange membrane fuel cells (PEMFCs), phosphoric acid fuel cells (PAFCs), molten carbonate fuel
cells (MCFCs), solid oxide fuel cells (SOFCs), direct methanol fuel cells (DMFCs), and alkaline fuel
cells (AFCs).
Fuel cell operate on hydrogen gas and oxygen from air. Hydrogen gas can be obtained from a
variety of fuels. Fuel cell power plants can be operated with overall system efficiencies of about 45
% - 60% or even higher. They offer high efficiency and low emissions even at part load and in small
sizes. Because of high fuel utilization efficiencies, fuel cells help in carbon dioxide emission
reduction. Owing to their noiseless operation, fuel cells can be installed in densely populated areas
as well. Fuel cells can be used for stationary/portable power generation and automotive
applications. High-conversion efficiency, extremely low or no emissions, noiseless opearion, high-
current density and compactness are some of the advantages that make fuel cells an ideal power
option for automobile application. The use of batteries in combination with the fuel cell system
provides starting power as well as the surge power requirement of the electric motor.
Challenges
Cost reduction.
Increased reliability and durability.
Hydrogen generation, distribution, dispensing and onboard storage.
Availability and affordability of hydrogen refueling.
Codes and standards development.
Scalability for mass manufacture.
Basics of Fuel Cells
A fuel cell is galvanic cell (that is, a battery), which converts chemical energy into electrical
energy by means of an electrochemical process. As with a battery, a fuel cell is a device in which
electron transfer is forced to take place through an external pathway rather than directly between
reactants. A fuel cell operates by taking in fuel and an oxidant (usually pure oxygen or oxygen in
air) at separate electrodes and converting the excess chemical energy into DC electricity. The fuel
source is typically either hydrogen or a hydrogen carrier such as natural gas or methanol.
Fuel cells produce minimal pollution while fueled with a hydrogen carrier and has zero pollution
when operated on hydrogen. In the case of a H2O2 fuel cell, water and heat are the only by-products.
Unlike conventional batteries, a fuel cell does not utilize the material that it is composed of as a fuel
source. A fuel cell takes fuel from outside and converts it into chemical energy. Thus, fuel cell do not
suffer from some of the limitations of the conventional batteries in that they do not have to be
discarded, as in the case of non – rechargeable batteries, or recharged, as in the case of
rechargeable batteries. A fuel cell consists of two porous electrodes where energy conversion
process takes place, and a solid or liquid electrolyte, which conducts the ions to form a closed
circuit. A generalized fuel cell is shown in figure below.
The fuel molecules, that is hydrogen, are introduced on the anode side of fuel cell. At the anode,
which is sometimes called the fuel electrode, the hydrogen molecules give up their electrons,
resulting in the formation of positively charged hydrogen ions by reaction H 2 => 2H+ + 2e-. These
electrons are subsequently drawn to the cathode by the oxidizing agent, O2, resulting in the
formation of negatively charged oxygen ions. As the electrons move through the external circuit
connecting the anode and the cathode, electrical energy is created which can be used as a source of
power. Such a process would be slowed considerably if there was no mechanism to redistribute the
ions formed at the electrodes. To allow the migration of ions from one electrode to another, an
electrolyte is introduced between the two electrodes. The electrolyte provides the pathway for the
hydrogen ions to pass from the anode to the cathode side of the cell. There, the hydrogen ions
combine catalytically with oxygen, which has diffused to the membrane-catalyst interface through
the porous cathode and the electrons from the adjacent cell to form water, according to the reaction
4H+ + O2 +4e- => 2H2O. Thus, the overall reaction in the fuel cell is simply described as follows.