Solutions and Colligative Properties

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MAXIMA GROUP TUITIONS

SOLUTIONS (10 MARKS)

1. 1000 g of aqueous solution of Na2CO3 has 10 g of sodium carbonate. Concentration of solution is:
(a) 10,000 ppm (b) 1000 ppm
(c) 100 ppm (d) 10 ppm
2. The vapour pressure of pure benzene at 25 0C is 180 mm Hg. The vapour pressure lowering caused
by the addition of 25 g of a solute (molar mass = 342) to 250 g of benzene is ______.
(a) 1.4 mm Hg (b) 2.6 mm Hg
(c) 4.1 mm Hg (d) 3.2 mm Hg
3. A small amount of non-volatile solute is dissolved in 64.5 cm3 of acetone (density: 0.791 g/cm3).
The vapour pressure of this solution at room temperature is 260 mm Hg, while that of acetone is
285 mm Hg. What is the molality of the solution?
(a) 1.51 M (b) 2.51 M
(c) 1.05 M (d) 1.15 M
4. At 300 K, the vapour pressure of substance A is 0.95 atm and the vapour pressure of substance B is
0.15 atm. A solution of A and B is prepared and allowed to equilibriate with its vapour. The vapour
is found to have equal moles of A and B. What is the mole fraction of A in the original solution?

(a) 0.18 (b) 0.14


(c) 0.23 (d) 0.34
5. A solution has 1:3 ratio of cyclopentane to cyclohexane. The vapour pressures of the pure
compunds at 25 0C are 331 mm Hg for cyclopentane and 113 mm Hg for cyclohexane. What is the
mole fraction of cyclopentane in the vapour above the solution?
(a) 0.42 (b) 0.39
(c) 0.49 (d) 0.23
6. The depression of freezing point of a solvent (b.p. 303 K) for a particular solution is 0.153 K.
Calculate the molal elevation constant if the boiling point of the solution is constant is 304.52 K.
(Kf = 1.68 K kg mol-1)
(a) 1.68 K m-1 (b) 16.8 K m-1
(c) 0.68 K m-1 (d) 11.6 K m-1
7. The vapour pressure will be lowest for _____.
(a) 0.1 M sugar solution (b) 0.1 M NaCl solution
(c) 0.1 M Cu(NO3)2 solution (d) 0.1 M AgNO3 solution
8. A solution containing 500 g of protein per litre is isotonic with a solution containing 3.42 g of
sucrose per litre. The molar mass of protein is _____ g mol-1.
(a) 47500 (b) 14600
(c) 34200 (d) 50000
9. The osmotic pressure of a solution at 276 K is 2.5 atm. Its osmotic pressure at 546 K under similar
conditions will be _____.
(a) 0.5 atm (b) 1.0 atm
(c) 2.5 atm (d) 5.0 atm
10 Identify the compound amongst the following of which 0.05 m aqueous solution has the highest
. boiling point.
(a) Urea (b) Potassium chloride
(c) Sodium sulphate (d) Silver nitrate
MAXIMA GROUP TUITIONS
SOLUTIONS (10 MARKS)

ANSWER KEY

1. A 6. B

2. C 7. C

3. A 8. D

4. B 9. D

5. C 10. C

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