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    Mixer Reactor: 2. Reactor Feed 3. Product C2H4O, H2O

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    Inneke
    1. The document describes a chemical process involving the reaction of ethylene (C2H4) with oxygen. 2. It provides details on the fresh and recycled feed streams, reactor products and byproducts, and a purge stream. 3. Equations are given for the three main reactions that occur in the reactor and calculations are shown to determine the amounts and compositions of the various streams.

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    Mixer Reactor: 2. Reactor Feed 3. Product C2H4O, H2O

    Uploaded by

    Inneke
    47 views5 pages
    1. The document describes a chemical process involving the reaction of ethylene (C2H4) with oxygen. 2. It provides details on the fresh and recycled feed streams, reactor products and byproducts, and a purge stream. 3. Equations are given for the three main reactions that occur in the reactor and calculations are shown to determine the amounts and compositions of the various streams.

    Original Description:

    Robin Smith No.13

    Original Title

    13.11

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    1. The document describes a chemical process involving the reaction of ethylene (C2H4) with oxygen. 2. It provides details on the fresh and recycled feed streams, reactor products and byproducts, and a purge stream. 3. Equations are given for the three main reactions that occur in the reactor and calculations are shown to determine the amounts and compositions of the various streams.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    47 views5 pages

    Mixer Reactor: 2. Reactor Feed 3. Product C2H4O, H2O

    Uploaded by

    Inneke
    1. The document describes a chemical process involving the reaction of ethylene (C2H4) with oxygen. 2. It provides details on the fresh and recycled feed streams, reactor products and byproducts, and a purge stream. 3. Equations are given for the three main reactions that occur in the reactor and calculations are shown to determine the amounts and compositions of the various streams.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
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    3.

    Product
    C2H4O, H2O
    2. Reactor Feed
    Mixer Reactor
    1. Fresh Feed
    N2, O2, C2H4 4. Byproduct
    (A) N2, O2, C2H4,
    CO2
    5. Recycle (R) 6. Purge (P)
    Splitter
    C2H4 + 1/2 O2 → C2H4O 40%
    C2H4 + 3 O2 → 2 CO2 + 2 H2O 20%
    C2H4 → C2H4 (Unreacted) 40%
    C2H4 Fed Lost in Purge 8%

    Basis C2H4 Fed 100 kmol


    R C2H4 Estimation 50 kmol
    C2H4 Lost 8 kmol
    A5 A2 A4 error
    50 150 60
    52 152 60.8 0.04
    52.8 152.8 61.12 0.015385
    53.12 153.12 61.248 0.006061
    53.248 153.248 61.2992 0.00241
    53.2992 153.2992 61.31968 0.000962
    53.31968 153.3197 61.32787 0.000384
    53.32787 153.3279 61.33115 0.000154
    53.33115 153.3311 61.33246 6.145E-05
    P:R 0.150006 : 1
    N2 0.718182 790 kmol
    Fresh
    Feed O2 0.190909 210 kmol
    C2H4 0.090909 100 kmol
    N2 0.858423 6056.451 kmol SUM
    Reactor O2 0.112285 792.21 kmol
    Feed C2H4 7055.324
    0.021733 153.3311 kmol
    CO2 0.007559 53.33229 kmol kmol
    N2 6056.451 kmol
    O2 669.5451 kmol
    Byproduct
    C2H4 61.33246 kmol
    CO2 61.33246 kmol
    N2 5266.451 kmol
    O2 582.21 kmol
    Recycle
    C2H4 53.33115 kmol
    CO2 53.33229 kmol
    N2 790 kmol O2 Overall:
    O2 87.33508 kmol In - Out - Con = 0
    Purge Purge = Fresh Feed -
    C2H4 8 kmol Consumed in
    CO2 8.000171 kmol Reactor
    Splitter
    6. Hydrogen
    Recycle
    5. Unreacted
    Feed
    H2, CH4
    4. Effluent
    1. Hydrogen Feed C6H5CH3, H2,
    H2, CH4 CH4, C6H6, Se
    C12H10 pa
    Mixer Reactor ra
    3. Reactor Feed to
    2. Toluene Feed C6H5CH3, H2, CH4 r
    C6H5CH3

    8. Product
    C6H5CH3,
    C6H6, C12H10

    9. Toluene
    Recycle

    H2 𝑆=1−0,0036/(1−𝑋)^1,544
    0.95
    Stream 1
    CH4 0.05
    Mr Value Fuel Value
    kg/kmol $/kg $/kg
    H2 2 1.06 0.53
    C6H5CH3 92 0.21 -
    C6H6 78 0.34 -
    CH4 16 - 0.22
    C12H10 154 - 0.17
    a. b.
    Stream 10 300 kmol/h P= 300 kmol/h
    H2 0.35 337,5/𝑆+162,5
    Stream 7 Stream 1
    CH4 0.65
    Stream 2 P/S In - Con = 0 𝑃/𝑆=300/𝑆
    Stream 2
    Stream 9 R
    Stream 3 P/S + R 487,5/𝑆+12,5
    Stream 7
    (𝑃/𝑆+𝑅)𝑋
    Consume
    Stream 10 P = 300
    C6H5CH3 𝑃/𝑆−(𝑃/𝑆+𝑅)𝑋=0
    Balance In - Con = 0
    Stream 11
    𝑅𝑋=𝑃/𝑆 𝑋−𝑃/𝑆 𝑃/2 (1/𝑆−1)=150(1/𝑆−1)

    𝑅=𝑃/𝑆 (1−1/𝑋)

    Stream 3 P/S + R
    𝑃/𝑆−𝑃/2 (1/𝑆−1)
    Consume

    H2
    Balance
    𝑅+𝑃/2 (1/𝑆−1)
    H2 Stream 4
    Balance (𝑅+𝑃/2 (1/𝑆−1))𝛼
    Stream 7
    𝑃/𝑆−𝑃/2 (1/𝑆−1)+(𝑅+𝑃/2 (1/𝑆−1))𝛼
    Stream 1 In - Out -
    Con = 0
    Generate P/S
    0,65/0,35 (𝑅+𝑃/2 (1/𝑆−1))𝛼
    CH4 Stream 7
    Balance
    0,65/0,35 (𝑅+𝑃/2 (1/𝑆−1))𝛼−𝑃/𝑆
    Stream 1 In - Out +
    Gen = 0
    1)+(𝑅+𝑃/2 (1/𝑆−1))𝛼)/(0,65/0,35 (𝑅+𝑃/2 (1/𝑆−1))𝛼−𝑃/𝑆 " " )=0,95/0,05

    𝑃/𝑆−𝑃/2 (1/𝑆−1)+(𝑅+𝑃/2 (1/𝑆−1))𝛼=19(0,65/0,35 (𝑅+𝑃/2 (1/𝑆−1))𝛼−𝑃/𝑆 " " )

    𝑃/𝑆−1/2 𝑃/𝑆+𝑃/2+19 𝑃/𝑆=19 0,65/0,35 (𝑅+𝑃/2 (1/𝑆−1))𝛼−(𝑅+𝑃/2 (1/𝑆−1))𝛼

    𝑃/2 (1/𝑆−1))𝛼=(19,5 𝑃/𝑆+𝑃/2)/(19 0,65/0,35−1)

    1/0,05 (0,65/0,35 (𝑅+𝑃/2 (1/𝑆−1))𝛼−𝑃/𝑆)


    Stream 1

    1/0,05 (0,65/0,35 ((19,5 𝑃/𝑆+𝑃/2)/(19 0,65/0,35−1))−𝑃/𝑆)

    20 𝑃(0,65/0,35 ((19,5 1/𝑆+1/2)/(19 0,65/0,35−1))−1/𝑆)

    P= 300 kmol/h
    6000((19,5 1/𝑆+1/2)/(19−0,35/0,65)−1/𝑆)

    6000((19,5 1/𝑆+1/2−19 1/𝑆+0,35/0,65 1/𝑆)/(19−0,35/0,65))

    6000(((0,5+0,35/0,65) 1/𝑆+0,5)/(19−0,35/0,65))

    325/𝑆 (0,5+0,35/0,65)+162,5
    337,5/𝑆+162,5

    1/0,35 (𝑅+𝑃/2 (1/𝑆−1))𝛼


    Stream 7

    1/0,35 ((19,5 𝑃/𝑆+𝑃/2)/(19 0,65/0,35−1))

    𝑃((19,5 1/𝑆+1/2)/(19×0,65−0,35))

    P= 300 kmol/h
    25(19,5 1/𝑆+1/2)

    487,5/𝑆+12,5
    tter
    7. Purge

    5. Unreacted
    Feed
    H2, CH4

    10. Pure Product


    C6H6

    11.
    Se Byproduct
    pa C12H10
    ra Furnace
    to
    r

    Substance Comp Mr Value Calc 1 Calc 2 Calc 3


    H2 0.95 2 -1.06 -1009.456 -1738.863 -3874.934
    CH4 0.05 -
    C6H5CH3 1 92 -0.21 -5816.941 -12036.58 -30250.81

    H2 0.35 2 0.53 186.1535 380.2355 948.6052


    CH4 0.65 16 0.22 1148.03 2344.956 5850.158
    C6H6 1 78 0.34 7956 7956 7956
    C12H10 1 154 0.17 14.18828 4228.22 16569.02

    Estimate X 0 0.96 0.97


    S 0.9964 0.481532 0.191598
    Total Value ($/h) 2477.975 1133.968 -2801.96

    Profitable Conversion Range


    X= 0 - 0.96

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