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    Spectroscopy Flashcards

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    Lej
    This document provides an overview of various spectroscopy techniques used in organic chemistry, including infrared spectroscopy (IR), ultraviolet-visible spectroscopy (UV), and nuclear magnetic resonance spectroscopy (NMR). It lists the characteristic functional groups observed in IR spectroscopy and their typical absorption ranges. It also outlines the general chemical shift ranges seen for common proton environments in 1H NMR spectroscopy and how the number of adjacent protons affects peak splitting.

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    Spectroscopy Flashcards

    Uploaded by

    Lej
    74 views66 pages
    This document provides an overview of various spectroscopy techniques used in organic chemistry, including infrared spectroscopy (IR), ultraviolet-visible spectroscopy (UV), and nuclear magnetic resonance spectroscopy (NMR). It lists the characteristic functional groups observed in IR spectroscopy and their typical absorption ranges. It also outlines the general chemical shift ranges seen for common proton environments in 1H NMR spectroscopy and how the number of adjacent protons affects peak splitting.

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    This document provides an overview of various spectroscopy techniques used in organic chemistry, including infrared spectroscopy (IR), ultraviolet-visible spectroscopy (UV), and nuclear magnetic resonance spectroscopy (NMR). It lists the characteristic functional groups observed in IR spectroscopy and their typical absorption ranges. It also outlines the general chemical shift ranges seen for common proton environments in 1H NMR spectroscopy and how the number of adjacent protons affects peak splitting.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    74 views66 pages

    Spectroscopy Flashcards

    Uploaded by

    Lej
    This document provides an overview of various spectroscopy techniques used in organic chemistry, including infrared spectroscopy (IR), ultraviolet-visible spectroscopy (UV), and nuclear magnetic resonance spectroscopy (NMR). It lists the characteristic functional groups observed in IR spectroscopy and their typical absorption ranges. It also outlines the general chemical shift ranges seen for common proton environments in 1H NMR spectroscopy and how the number of adjacent protons affects peak splitting.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 66

    Organic Chemistry – Spectroscopy

    Infrared Spectroscopy (IR)


    Measures molecular vibrations of characteristic functional
    groups
    Organic Chemistry – Spectroscopy
    IR Alkanes
    C-H 2800-3000
    C-C 1200
    Organic Chemistry – Spectroscopy
    IR Alkenes
    =C-H 3080-3140
    C=C 1645
    Organic Chemistry – Spectroscopy
    IR Alkynes
    C≡C 2200
    ≡C-H 3300
    Organic Chemistry – Spectroscopy
    IR Aromatic
    C-H 2900-3100
    C-C 1475-1625
    Organic Chemistry – Spectroscopy
    IR Alcohols
    O-H 3100-3500 (broad)
    Organic Chemistry – Spectroscopy
    IR Ethers
    C-O 1050-1150
    Organic Chemistry – Spectroscopy
    IR Aldehydes
    (O)C-H 2700-2900
    C=O 1700-1750
    Organic Chemistry – Spectroscopy
    IR Ketones
    C=O 1700-1750
    Organic Chemistry – Spectroscopy
    IR Carboxylic Acids
    C=O 1700-1750
    O-H 2800-3200 (broad)
    Organic Chemistry – Spectroscopy
    IR Amines
    N-H (sharp) 3100-3500
    Organic Chemistry – Spectroscopy
    UV Spectroscopy
    Involves passing UV light through a chemical sample and
    plotting absorbance vs. wavelength. It is most useful for
    studying compounds containing double bonds and
    heteroatoms with lone pairs
    Organic Chemistry – Spectroscopy
    Nucleus Magnetic Resonance (NMR)
    H-NMR is a form of NMR, only looking at proton shifts
    Organic Chemistry – Spectroscopy
    NMR RCH3
    Approximate shift: 0.9
    Organic Chemistry – Spectroscopy
    NMR RCH2
    Approximate shift: 1.25
    Organic Chemistry – Spectroscopy
    NMR R3CH
    Approximate shift: 1.5
    Organic Chemistry – Spectroscopy
    NMR –CH=CH
    Approximate shift: 4.6-6
    Organic Chemistry – Spectroscopy
    NMR –C≡CH
    Approximate shift: 2-3
    Organic Chemistry – Spectroscopy
    NMR Ar–H
    Approximate shift: 6-8.5
    Organic Chemistry – Spectroscopy
    NMR –CHX
    Approximate shift: 2-4.5
    Organic Chemistry – Spectroscopy
    NMR –CHOH/–CHOR
    Approximate shift: 3.4-4
    Organic Chemistry – Spectroscopy
    NMR RCHO
    Approximate shift: 9-10
    Organic Chemistry – Spectroscopy
    NMR RCHCO–
    Approximate shift: 2-2.5
    Organic Chemistry – Spectroscopy
    NMR –CHCOOH/–CHOOR
    Approximate shift: 2-.2.6
    Organic Chemistry – Spectroscopy
    NMR –CHOH–CH2OH
    Approximate shift: 1-5.5
    Organic Chemistry – Spectroscopy
    NMR ArOH
    Approximate shift: 4-12
    Organic Chemistry – Spectroscopy
    NMR –COOH
    Approximate shift: 10.5-12
    Organic Chemistry – Spectroscopy
    NMR –NH2
    Approximate shift: 1-5
    Organic Chemistry – Spectroscopy
    NMR –CHOH–CH2OH
    Approximate shift: 1-5.5
    Organic Chemistry – Spectroscopy
    NMR Types of Protons
    Corresponds to the number of peaks seen in the spectrum
    Organic Chemistry – Spectroscopy
    Position of peaks
    The further left-shifted (downfield) the peak, the more
    deshielded the proton. Usually this corresponds to more
    electron-withdrawing groups
    Organic Chemistry – Spectroscopy
    Integration of peaks
    The larger the integration, the more protons contained
    under the peak
    Organic Chemistry – Spectroscopy
    Splitting
    Hydrogens on adjacent carbons will split a peak into a n +
    1 subpeaks, where n is the number of hydrogens on the
    adjacent carbon

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