Thermal Conductivity of Food Products Using: A Correlation Analysis Based On Artificial Neural Networks (Anns)
Thermal Conductivity of Food Products Using: A Correlation Analysis Based On Artificial Neural Networks (Anns)
Email address:
ajasaaf@yahoo.com (Ajasa A. A.), adetokyom@yahoo.com (Adenowo A. A.), yogunlewe@yahoo.com (Ogunlewe A. O.),
comfortobolajoko@yahoo.com (Folorunso C. O.)
Abstract: This paper presents the correlation between the predicted and desired/targeted thermal conductivity of food
products as a function of moisture content, temperature and apparent density. The food products considered in this work are
the bakery products which include bread, bread dough, cake, and whole-wheat dough. Statistical data of results from
previous work in existing literatures were used in this work for a wide range of moisture contents, temperatures and
apparent densities resulting from baking conditions. The results of this work showed straight line curves when the predicted
values of thermal conductivity were plotted against the targeted values of thermal conductivity. This demonstrates
correlation between the predicted and targeted thermal conductivities when the points are joined together (best fit-points),
hence, a very good agreement between the predicted and the desired values of thermal conductivity. The two ANN models
that were finally selected, after several configurations had been considered and evaluated, are the optimal ANN model that
was found to be a network with two hidden layers and eight neurons and the simplest ANN model was equally found to be
a network with one hidden layer and ten neurons. The estimated errors between the predicted and desired (or targeted)
thermal conductivity values of the bakery products for both the optimal ANN and simplest ANN models are the MRE,
MAE and SE. Moreover, the results also showed that the optimal ANN model had an MRE of 0.04878%, an MAE of
0.0054W/mK and an SE of 0.0015W/mK while the simplest ANN model was estimated to have an MRE of 0.03388%, an
MAE of 0.0034W/mK and an SE of 0.0011W/mK. These errors are approximately equal to zero (i.e., 0 W/mK) and could,
therefore, be regarded as a good result for the prediction. Since the simplest ANN model had the least values of all three
errors (MRE, MAE and SE) when compared with other configurations, including the optimal ANN model, it is, however,
regarded as the best ANN model and is, thus, recommended.
Keywords: Thermo-Physical Properties of Biological Products, Thermal Conductivity of Bakery Products,
Back-Propagation, Artificial Neural Network, Mean Absolute Error, Mean Relative Error, Standard Error
Accordingly, heat is transferred mainly by convection ANN modelling differently for the prediction of food
from the heating media, and by radiation from oven walls quality. Recently, Sablani and Shayya in 2001 applied ANN
to the product surface and then by conduction to the modelling for the prediction of heat penetration parameters
geometric centre. At the same time, moisture diffuses in Stumbo’s method of thermal process calculations [20].
outward to the product surface [1, 5]. Rahman’s model [4] (data considered only above 0°C)
The problem of interest in the design of bakery ovens is predicted thermal conductivity with mean relative errors of
concerned with the promotion of the required rate of heat 24.3 and 81.6%, respectively. This model was able to
transfer with the minimum possible surface area and predict thermal conductivity with a mean relative error of
temperature difference. And from the engineer’s point of 12.6% and a mean absolute error of 0.081 W/mK. The
view, it is usually sufficient to know the total quantities of model can be incorporated in heat transfer calculations
energy emitted and absorbed by the material at various during food processing where moisture, temperature and
temperatures [16]. As such, it is frequently necessary to apparent porosity dependent thermal conductivity values
establish the rate at which heat will be conducted through a are required.
solid if a known temperature difference exists across the Shyam et al. (2002) optimal ANN model was found to be
solid. For such purposes, and especially if the process a network with 6 neurons in each of the 2-hidden layers.
varies with time, sophisticated mathematical techniques are This optimal model was capable of predicting the thermal
required to establish this, the phenomenon being known as conductivity values of various bakery products (such as
transient-heat conduction. A knowledge of the product bread, bread dough, French bread, yellow cake, tortilla chip,
properties, including thermal conductivity as a function of whole wheat dough, baked chapatti and cup cake) for a
processing conditions is needed in order to predict the wide range of conditions with a mean relative error of 10%,
temperature and water distribution in the product during a mean absolute error of less than 0.02 W/m K and a
baking [5, 8]. The temperature and moisture distribution standard error of about 0.003 W/m K. The simplest ANN
within the porous product can be predicted using diffusion model, which had 1-hidden layer and 2 neurons, predicted
equations of heat and water. thermal conductivity values with a mean relative error of
less than 15% [3]. All these work were successfully carried
2. Literature Review out with satisfactory results obtained using ANN modelling.
In predicting thermal properties of a material at desired
Neural networks have been trained to perform complex conditions, several modelling approaches have been
functions in various fields including pattern recognition, proposed and none of them was found suitable for use over
identification, classification, speech, vision, and control a wide range of foods. According to Murakami and Okos
systems. Today, neural networks can be trained to solve (1989) the most promising approach is based on chemical
problems that are difficult for conventional computers or composition, temperature and physical characteristics [12].
human beings. Commonly, neural networks are adjusted (or More recently, Baik et al. in 2001 reviewed common and
trained) so that a particular input leads to a specific target new measurement techniques, prediction models and
output. Typically, many such input/target pairs are needed published data on thermo-physical properties of bakery
to train a neural network. products [2].
Linko and Zhu also stated that of all the various The series model of specific heat, density and thermal
modelling approaches of predicting the thermal diffusivity has been successfully applied to many food
conductivity of a wide range of foods, including bakery materials including porous materials such as baking
products, the neural network-based models have proven to products. However, for the prediction of thermal
be excellent. Amongst the major benefits of using ANN are conductivity of porous food, there is still some theoretical
excellent management of uncertainties, noisy data and non- argument for the use of the structural models [12].
linear relationships. Neural network modelling has Murakami and Okos (1989) evaluated nine different
generated increasing acceptance and is an interesting structural models with specific types of porous foods and
method in the estimation, prediction and control of found that parallel and perpendicular models showed 12–97%
bioprocesses [9]. and 18–61% standard errors respectively.
Review of past work showed that Ruan et al. applied Among the models, Keey’s model was found to be the
ANN modelling to predict the rheological properties of best prediction model for porous grains and powders. The
dough in 1995 [15]. Fang et al. also applied the ANN model produced standard errors of <28% for full fat dry
modelling to predict the physical properties of ground milk and <10% for other food materials. In addition, all
wheat in 1998 [18] while Hussain and Rahman, in 1999, structural models neglect interactions between components,
predicted the thermal conductivity of fruits and vegetables phase transition and distillation heat transfer, which may be
with the application of ANN modelling [6]. Similarly, ANN significant in the baking process [1]. Hence, most thermal
modelling was applied by Myhara et al. in 1998 for the conductivity models reported are usually empirical rather
prediction of isotherms of dates [11], Ni and Gunasekaran than theoretical.
in 1998 [7] and Xie and Xiong in 1999 [13] also applied
Advances in Bioscience and Bioengineering 2014; 2(2): 14-24 16
Average patent flour (first grade) is made up of the Thermal properties (thermal conductivity and diffusivity)
following: of gluten and glutenin were measured in the temperature
• Carbohydrates: 73.5%. This includes starch: 71%, range 60-175°typically used in extrusion processing.
soluble sugars 2.4% and cellulose 0.1%. Thermal conductivity and diffusivity of gluten decreased
• Proteins: 11.0 % :This includes gluten-forming with increasing temperature and increased with increasing
proteins 10% & water soluble proteins 1% moisture content. Thermal conductivity and diffusivity of
• Water:14% glutenin increased with temperature and moisture content.
• Fat: 1.0% Thermal conductivity of gluten was 0.06-0.35 W/m-C and
• Minerals: 0.5 % glutenin was 0.29-0.49 W/m-C for the temperature range
In terms of quantity, carbohydrates account for the 60-175°and moisture content range of 0-30%.
greatest portion in flour which incidentally forms the
greater part of bakery products. Starch essentially fulfills 3.2. Measurement of Thermal Conductivity
the following functions: (1) a source of nutrient for yeast Thermal conductivity of materials can be measured and
after enzymatic degradation, (2) absorption of free dough obtained through different materials. Depending on the
water during gelatinization, (3) contribution to crust, crumb measurement time these methods can be classified as either;
and coloration formation. • Steady State or
The content of soluble sugar substances in wheat flour • Transient or Unsteady
amounts to approximately 1.5 – 3%. The main soluble These two methods are explained below:
sugar substances are glucose, maltose and dextrin. They are A. Steady State Method
dissolved during dough production in the available dough In the steady state methods, the measurement time can be
liquid. Glucose and Maltose are available as yeast food much longer for poor thermally conductive samples than in
while Dextrin cannot be fermented by yeasts the transient methods. During testing, moisture migration
17 Ajasa, Abiodun Afis et al.: Thermal Conductivity of Food Products using: A Correlation Analysis Based
on Artificial Neural Networks (ANNs)
and property changes can occur due to long exposure to the capped column test device was operated horizontally.
high temperatures. Thus, this method may not be suitable Temperature distribution along the height of the test
for measurement of the thermal conductivity of bakery sample water stream was measured. The moisture content
products. The steady state methods include: distribution of test sample was determined by measuring
• Guarded hot plate moisture content of the sample cut into several section of
• Differential scanning calorimeter (DSC) attachment equal height. The k value can be determined by applying a
method heat and mass transfer equation to the experimental
• Capped column test device temperature and moisture gradient data. The measurement
(i) Guarded hot plate Method is fast (within several minutes), and there is no worry about
This method is a representative steady state method. A experimental deviation because of the moisture gradient,
time- independent heat flow is generated through the because the measurement device and data analysis are
sample between a heat source and a heat sink. This method designed to evaluate thermal and mass transfer properties
is mathematically simple to process, and it is easy to simultaneously.
control experimental conditions. The k values can be B. Transient Method
calculated as a mean value measures over the temperature The transient techniques are most suitable for bakery
interval used in the experiment using Fourier’s heat products because testing is very fast and it yields more
conduction equation. Experimental uncertainty in the accurate results. In the transient method, the sample is
measured thermal conductivity of biscuit dough was ≤ 7.4% subjected to a time-dependent heat flow and the
using a similar method, single-plate method [22]. This temperature is measured at one or more points within the
evaluation was based on combination of instrumentation sample or at its surface. The transient technique includes:
errors, geometrical uncertainties, and deviations from the • Line heat source probe method
assumed one-dimensional nature of heat flow. • Temperature history
(ii) DSC Attachment Method • Transient hot strip method (THS)
In order to alleviate the disadvantage of conventional (i) Line Heat Source Probe Method
steady state method, an attachment to a DSC was This method is recommended for most food applications,
constructed by Buhri and Singh [23]. The main innovations including bakery products. The method is simple and fast
are relatively rapid measurement (10 to 15 min), small (measuring times are between 3 and 600s) and requires
sample size, and no risk of drying of the samples. The relatively small samples, but it does require a fairly
thermocouple probe was inserted into the sample, and the sophisticated data acquisition system. The probe (0.66mm)
DSC heating pan temperature was kept at 40oC. After 5 consists of a constantan heater wire and chromel-
minutes the sample initial temperature was recorded. The constantan thermocouple wire.
pan temperature was then immediately increased by 10oC. A line heat source probe is embedded in the sample
After 10 to 15 minutes, a new steady state existed, and the (regarded as an infinite body), which is initially at a
final sample temperature was recorded. The k was obtained uniform temperature, resulting in a cylindrical temperature
using the following equation, which is based on Fourier’s distribution. Heating and temperature monitoring occur
heat conduction equation: simultaneously. The rate of temperature rise of the heater is
∆
directly related to the sample’s conductivity. The slope of
= (1) the linear portion of each data set was used to determine
(∆ ∆ )
effective thermal conductivity by equation (2)
where k = thermal conductivity, L = sample length,
∆Q = difference of energy required to maintain pan
= (2)
temperature, ( )
A = sample area perpendicular to heat flow,
where k = thermal conductivity of the sample,
∆t2 = final temperature difference between DSC heating
τ1 = initial time when probe heater was energized,
pan and sample
τ2 = final time since probe heater was energized,
∆t1 = Initial temperature difference between DSC heating
t1 = temperature of probe thermocouple at t1,
pan and sample
t2 = temperature of probe thermocouple at t2,
(iii) Capped column test device
Q = heat flux generated by probe heater.
The use of a capped column test device was introduced
In order to obtain correct results and avoid edge effects
by Zhou et al [24]. Experiments with the capped column
in a line heat source probe method, the following
test device were conducted with constant heat flux and no
constraints [25] should be considered:
net water loss. Constant heat flux was provided by
circulating hot cold water at constant temperatures at the Probe size: < 2/5 √( ) (3)
two ends of the cylindrical test sample (diameter 3cm,
height 5cm, and 2.5cm). The test sample was enclosed in where rp = probe radius, = thermal diffusivity of the
polystyrene foam to minimize heat loss to the surroundings. sample, ! = time, test duration
To eliminate the gravity-induced moisture migration effect,
Advances in Bioscience and Bioengineering 2014; 2(2): 14-24 18
Typically, many such input/target pairs are needed to train a compared. The mathematical representation of these error
neural network. parameters are defined in equations 8 to 10 as follow [10, 14]:
The back-propagation algorithm was utilized in model
1
∑ ( K D − K P )
n
training. A hyperbolic-tangent transfer function was also MAE = (8)
n i =1
used in all cases. Properly trained back-propagation networks
(Fig. 4) tend to give reasonable answers when presented with 1
∑ ( KD − KP ) / KD
n
MRE = (9)
unfamiliar inputs that have never been seen earlier. Typically, n i =1
a new input leads to an output similar to the correct output
for input vectors used in training that are similar to those 2
∑
n
(K D − K P )
being presented. This generalization properly makes it i =1
SE =
(10)
possible to train a network on a representative set of n −1
input/target pairs and get good results without training the
network on all possible input/output pairs.
The back-propagation algorithm uses the supervised where n is the number of data points, KD and KP are the
training technique where the network weights and biases desired and predicted values of thermal conductivity
are initialized randomly at the beginning of the training respectively.
phase. For a given set of inputs to the network, the response The optimum configuration of the network was chosen
to each neuron in the output layer is calculated and by selecting the lower value from the different
compared with the corresponding desired output response. configuration of the network. It was evidently based upon
The errors associated with desired output response are minimizing the difference between the neural network
adjusted in the way that reduces these errors in each neuron predicted values and the desired outputs. The datasets of 52
from the output to the input layer. cases obtained from other literature [1] were divided into
In order to avoid the potential problem of over-training two sets. The first set consisted of 36 (∼70%) cases for
or memorization while employing the back-propagation training/testing and 16 (∼30%) cases for validation
algorithm, the option of saving the best result is adopted (simulation), chosen randomly from the set of 52 cases.
during the selected number of training cycles of 2,000.
4. Simulation and Results
Neural network
Input including connections Output Compare Target 4.1. Simulation
(weights) between
No. of
No. of
neurons in MAE SE
hidden MRE (%)
each hidden (W/mK) (W/mK)
layers
layer
1 2 0.17 0.0199 0.0046
1 4 4.2 0.2212 0.0970
1 6 0.035077 0.0038 0.0011
Fig. 4. A back propagation network 1 8 0.18 0.0191 0.0050
1 10 0.03388 0.0034 0.0011
1 12 0.26 0.0297 0.0073
1 14 0.090897 0.0149 0.0041
1 16 0.12 0.0115 0.0038
2 2 0.24 0.0298 0.0075
2 4 0.41 0.0641 0.0125
2 6 0.37 0.0606 0.0121
2 8 0.048776 0.0054 0.0015
2 10 0.29 0.0441 0.0106
2 12 0.22 0.0382 0.0095
2 14 0.17 0.0166 0.0047
Fig. 5. Generalized multilayer neural network
2 16 0.22 0.0323 0.0072
1200
1000
800
MRE (%) X 10– 2
600 MAE (W/mK) X 10– 3
SE (W/mK) X 10– 4
400
Fig. 7. Corresponding chart showing the error values for 1-hidden layer
140
120
80
MAE (W/mK) X
10– 3
60
SE (W/mK) X 10–
40 4
0
4.4.2. Validating Dataset
1 2 3 4 5 6 7 8
The performance of the optimal neural network was
validated using a second dataset consisting of 16 cases not
Fig. 8. Corresponding chart showing the error values for 2-hidden layers previously used in the training. Thermal conductivity
values with an MRE of 0.0217 W/mK, MAE of 0.1544
4.4. Training, Validation and Prediction W/mK and SE of 0.0156 W/mK for 2-hidden layers with 8
4.4.1. Training Dataset neurons were predicted. The graph between the predicted
To reveal the credibility of prediction (with the training and the desired values of thermal conductivity for this
data set) from the optimal ANN, predicted values of model is shown in Fig. 11. There seemed to be no
thermal conductivity are plotted against the desired/targeted correlation between the predicted and the targeted thermal
values of thermal conductivity as shown in Fig. 9. Similarly, conductivities because of the few number of cases (16)
that of the simplest ANN model is shown in Fig. 10. These used for the validating dataset, as compared to that used for
two figures showed straight line curves, demonstrating the training set (36).
correlation between the predicted and targeted thermal This data set was also used with the simplest ANN
conductivities when the points are joined together (best fit- configuration of one hidden layer consisting of ten neurons.
points). The results demonstrate a very good agreement The model predicted thermal conductivity with a 4.73% (or
between the predicted and the desired values of thermal 0.0473 W/mK) MRE, 25.6% (or 0.2559 W/mK) MAE and
conductivity. Considering the inherent variation in the input 11.6% (or 0.1163 W/mK) SE. The graph between the
dataset, the simplest ANN configuration can be considered. predicted and the targeted values of thermal conductivity
The simplest ANN model with 1-hidden layer and 10 for the simplest ANN model is shown in Fig. 12. Similar
neurons predicted thermal conductivity with a 0.34% reasons could also be given for the non-correlation between
(0.0034 W/mK) MAE, 3.386 X 10-4 W/mK MRE and the predicted and targeted thermal conductivities for the
0.0011 W/mK SE being the least of all values of the error validating dataset, that is, fewer numbers of cases (16) were
measures. used.
Advances in Bioscience and Bioengineering 2014; 2(2): 14-24 22
Fig. 17. Thermal conductivities vs. Moisture content (1 hidden layer with
10 neurons)
Fig. 20. Thermal conductivities vs. Moisture content (2 hidden layers with
12 neurons)
5. Conclusion
In this paper, an ANN model was developed for
calculating the thermal conductivity of a variety of bakery
products under a wide range of conditions of moisture
content, temperature and apparent density. The optimal
model consisted of 2-hidden layers with eight neurons in
each hidden layer, and was able to produce thermal
conductivity values with a MAE of 54 X 10-4W/mK, MRE
Fig. 18. Thermal conductivities vs. Apparent density (1 hidden layer with of 4.878 X10-4W/mK and a SE of 15 X 10-4W/mK (see
10 neurons)
Table 3). However, the simplest ANN model has 1-hidden
Finally, there is a great disagreement or deviation layer with 10 neurons. This also showed a good prediction
between the predicted values of thermal conductivity and with a MRE of about 3.388 X 10-4 W/mK, MAE of 34 X
the targeted values when plotted against density for an 10-4 W/mK and SE of 11 X10-4 W/mK (see Table 4).
ANN model that has 1 hidden layer with 4 neurons, as From these values, it can be deduced and concluded that
shown in Fig. 19. Similarly, when the predicted and the simplest ANN model (with 1-hidden layer and 10
targeted values of thermal conductivity are plotted against neurons), when compared with the optimal ANN model
moisture content for an ANN model that has 2 hidden (with 2-hidden layers and 8 neurons in each hidden layer)
layers with 12 neurons, there was no agreement, as shown has smaller mean relative error,smaller mean absolute error
in Fig. 20. These ANN models are said to be inefficient and lesser standard error. Therefore, this model performs
models because of the non-intersection of most of their better accordingly.
triangles and stars points.
Advances in Bioscience and Bioengineering 2014; 2(2): 14-24 24
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