(MP PET 1999) (NCERT 1989) : Chemical Kinetics

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Chemical Kinetics 489

1. The temperature coefficient of most of the reactions lies between [MP PET 1999]
6. The minimum energy necessary to permit a reaction is
(a) 1 and 3 (b) 2 and 3 [NCERT 1989]
(c) 1 and 4 (d) 2 and 4 (a) Internal energy
2. The influence of temperature on the rate of reaction can be found (b) Threshold energy
out by [AFMC 2001]
(c) Activation energy
(a) Clapeyron–Claussius equation
(d) Free energy
(b) Gibbs–Helmholtz equation
7. The formation of gas at the surface of tungsten due to adsorption is
(c) Arrhenius equation the reaction of order [AIEEE 2002]
(d) Vander Waal's equation (a) 0
3. The mechanism for the reaction is given below (b) 1
2P  Q  S  T (c) 2
P  Q  R  S (slow) (d) insufficient data
P  R  T (fast) 8. The time of completion of 90% of a first order reaction is
approximately [MP PET 2002]
The rate law expression for the reaction is
(a) 1.1 times that of half life
[Kurukshetra CEE 2002]
(b) 2.2 times that of half life
(a) r  k[P]2 [Q] (b) r  k[P][Q]
(c) 3.3 times that of half life
(c) r  k[ A][R] (d) r  k[P]2 (d) 4.4 times that of half life
4. Consider the following energy profile for the reaction. 9. In a photochemical reaction, the ratio of number of dissociate
X  Y  R  S . Which of the following deductions about the molecules and number of quanta of absorbed energy is called
reaction is not correct
(a) Einstein
100
80 (b) Quantum efficiency
60
(c) Quantum constant
40
20 x+y (d) Planck constant
0
(a) The energy of activation for the backward reaction is 80 kJ
Reaction Pathway 10. A reaction rate constant is given by

(b) The forward reaction is endothermic k  1.2  10 14 e (25000 / RT ) sec 1


(c) H for the forward reaction is 20 kJ It means [MP PET 1995]

(d) The energy of activation for the forward reaction is 60 kJ (a) logk versus log T will give a straight line with slope as –
5. The minimum energy required for molecules to enter into the 25000
reaction is called
(b) logk versus T will give a straight line with slope as –
[KCET 1986; EAMCET 1992; MP PMT 1993; MP PET 1994] 25000
(a) Potential energy
(c) logk versus log1 / T will give a straight line with slope as –
(b) Kinetic energy
25000
(c) Nuclear energy
(d) logk versus 1 / T will give a straight line
(d) Activation energy

(SET -11)
Chemical Kinetics 487

K 35 o C
1. (b) Temperature coefficient = = between 2 and 3. 7. (a) The order of reaction for the formation of gas at the surface of
K 25 o C
tungsten due to adsorption is zero .
2. (c) Arrihenius equation is : K  Ae  Ea / RT 8. (c) For a first order reaction
2 .303 a
3. (b) The rate law expression for the reaction is r  k[P][Q] . K log
t (a  x )
4. (a) Ea of backward reaction  80  40  40kJ
2 .303 100 2 .303  t1 / 2 100
t log   log
Hence (a) statement is wrong. k (100  90) 0 .593 10
5. (d) The energy necessary for molecules to undergoes chemical  3.3  t1 / 2  log 10  3.3 t1 / 2
reaction is known as Activation energy.
9. (b) It is also known as Quantum yield and indicated by  .
6. (b) Molecules undergoing reaction should cross over the minimum
energy barrier or energy level known as threshold energy. 10. (d) According to the Arrihenius equation a straight line is to be
`obtained by plotting the logarithm of the rate constant of a
chemical reaction (log K) against 1/T.
***

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