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    Tarea #3: Difusión en Estado Estacionario y Pseudoestacionario Sin Reacción Química

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    Diego Fidel Gonzalez Contreras
    This document provides two diffusion problems to solve involving: 1) Determining the gas diffusivity of benzene in air using data from a pseudo-steady state experiment in a tube. 2) Calculating the steady-state molar flux and concentration profile of ethanol diffusing through a stagnant film of water or air using given conditions and equations.

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    Tarea #3: Difusión en Estado Estacionario y Pseudoestacionario Sin Reacción Química

    Uploaded by

    Diego Fidel Gonzalez Contreras
    125 views8 pages
    This document provides two diffusion problems to solve involving: 1) Determining the gas diffusivity of benzene in air using data from a pseudo-steady state experiment in a tube. 2) Calculating the steady-state molar flux and concentration profile of ethanol diffusing through a stagnant film of water or air using given conditions and equations.

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    This document provides two diffusion problems to solve involving: 1) Determining the gas diffusivity of benzene in air using data from a pseudo-steady state experiment in a tube. 2) Calculating the steady-state molar flux and concentration profile of ethanol diffusing through a stagnant film of water or air using given conditions and equations.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    125 views8 pages

    Tarea #3: Difusión en Estado Estacionario y Pseudoestacionario Sin Reacción Química

    Uploaded by

    Diego Fidel Gonzalez Contreras
    This document provides two diffusion problems to solve involving: 1) Determining the gas diffusivity of benzene in air using data from a pseudo-steady state experiment in a tube. 2) Calculating the steady-state molar flux and concentration profile of ethanol diffusing through a stagnant film of water or air using given conditions and equations.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    of 8

    Tarea #3: Difusión en estado estacionario y pseudoestacionario sin r

    Transferencia de Masa: Daniel Felipe Borda Lopez, Diego Fidel Gonzalez Contreras, Anny Carolin

    Contacto: dborda@unal.edu.co, dgonzalezco@unal.edu.co, anpaezr@unal.edu.co

    1. An Arnold cell is to be operated as a pseudo-steady-state cell to determine the gas diffusivity of benzene i
    cm-long tube, with an inner diameter of 1.0 cm, is initially loaded with liquid benzene to a depth of 1.0 cm from
    and the liquid are maintained at a constant temperature of 308 K. At this temperature, benzene exerts a va
    continually blown over the top of the tube, removing any of the vaporized benzene vapor; the gas space with
    At 308 K, liquid benzene’s density is 0:85 g/cm3.

    Parte A
    It was determined that 72.0 h were required to completely evaporate the benzene initially loaded into the tu
    diffusion coefficient for benzene in air using these data.

    Condiciones e Información Proporcionada

    Masa Molecular del benceno, MMA (g/mol)


    Masa Molecular del aire, MMB (g/mol)
    Constante universal de los gases ideales, R (atm cm 3/mol K)

    Presión, P (atm)
    Presión vapor del benceno, PA(atm)
    Temperatura, T (K)
    Tiempo, t (h)
    Longitud del tubo, LT(cm)
    Altura inicial del benceno, Li(cm)
    Densidad del benceno liquido, ρAliq(0.85g/cm3)

    CALCULOS

    K
    Difusividad, DAB (cm2/s)
    Difusividad, DAB (m2/s)

    Parte B

    Compare your evaluated diffusivity with the value reported


    in Appendix J.1. What is a possible reason for any difference
    in these values?

    Difusividad Apendice, 298 k J.1, D* AB (cm2/s)


    Difusividad Apendice, 308 k J.1, D* AB (cm2/s)
    Diferencia relativa (Dato Apendice J.1, reff)

    2. Ethanol is diffusing through a 4-mm stagnant film of water. The ethanol concentrations of the entran
    maintained at 0.1 and 0.02 mol/m3, respectively. If the water film temperature is 283 K, determine the stea
    and the concentration profile as a function of the position z within the liquid film. Compare these results with
    K and 1 atm at the same entrance and exit ethanol concentrations.

    Condiciones e Información Proporcionada

    Masa Molecular del Etanol, MMA (g/mol)


    Masa Molecular del agua, MMB (g/mol)
    Masa Molecular del aire, MMc (g/mol)
    Constante universal de los gases ideales, R (atm cm 3/mol K)

    Presión, P (atm)
    Temperatura, T (K)
    Concentracion entrada, Cin (mol/m3)
    Concentracion salida, Cout (mol/m3)
    Pelicula, L (mm)

    Datos
    Parametro de asociación, ΦB
    Viscosidad de la solución, µB (cp)
    Volumen atomico del Carbono, (cm3/mol)
    Volumen atomico del Hidrogeno, (cm3/mol)
    Volumen atomico del Oxigeno, (cm 3/mol)

    Volumen del etanol, VA (cm3/mol)(C2H5OH)


    Difusividad, DAB (cm2/s), calculada
    Difusividad, DAB (m2/s), calculada
    Difusividad, DAc (m2/s), (Dato Apendice J.1, reff)
    Flux de etanol en agua, NAZ
    Flux de etanol en aire, NAZ

    Perfil de densidad molar


    z (mm) cA
    0 0.100
    Perfil de densidad molar 0.4 0.092
    0.120 0.8 0.084
    0.100
    f(x) = − 0.02 x + 0.1
    0.080
    Axis Title

    0.060
    0.040
    0.020
    Perfil de densidad molar
    0.120
    0.100 1.2 0.076
    f(x) = − 0.02 x + 0.1
    0.080 1.6 0.068

    Axis Title
    0.060
    2 0.060
    0.040
    2.4 0.052
    0.020
    0.000 2.8 0.044
    0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 3.2 0.036
    Axis Title 3.6 0.028
    4 0.020
    y pseudoestacionario sin reacción química.
    ego Fidel Gonzalez Contreras, Anny Carolina Páez Rocha.

    u.co
    Consideraciones
    ermine the gas diffusivity of benzene in air at 308 K and 1.0 atm. The 20-
    quid benzene to a depth of 1.0 cm from the bottom of the tube. The tube Consideramos estado seudoestacionario
    this temperature, benzene exerts a vapor pressure of 0.195 atm. Air is
    zed benzene vapor; the gas space within the tube is essentially stagnant.
    e’s density is 0:85 g/cm3.

    the benzene initially loaded into the tube. Estimate the binary gas-phase
    nzene in air using these data.

    78.112
    28.945
    82.057

    1
    0.195
    308
    72.0
    20.0
    1.0
    0.85

    0.001
    0.0954
    9.54E-06

    ported
    erence

    0.0962 ++++++++
    0.1011 ++++++++
    5.64%

    e ethanol concentrations of the entrance and the existing planes are


    mperature is 283 K, determine the steady-state molar flux of the ethanol
    iquid film. Compare these results with a 4-mm stagnant film of air at 283
    e and exit ethanol concentrations.

    Consideraciones
    Consideramos flujo unimolecular, est
    46.070
    18.015
    28.945
    82.057

    1
    283
    0.10
    0.02
    4.00

    2.26
    1.3
    14.8
    3.7
    7.4

    59.20
    8.88E-06
    8.88E-10
    1.22E-05
    1.78E-08
    2.44E-04

    Perfil de densidad molar


    z (mm) cA
    0 0.100
    0.4 0.092
    0.8 0.084
    1.2 0.076
    1.6 0.068
    2 0.060
    2.4 0.052
    2.8 0.044
    3.2 0.036
    3.6 0.028
    4 0.020
    estado seudoestacionario
    mos flujo unimolecular, estado estacionario.

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