Physical Science11 - Q1 - 1 5
Physical Science11 - Q1 - 1 5
Physical Science11 - Q1 - 1 5
Physical Science
Quarter 1 – Module 1:
Formation of Heavy Elements
Personal Development
Alternative Delivery Mode
Quarter 1 – Module 1: Title
First Edition, 2020
Republic Act 8293, section 176 states that: No copyright shall subsist in any work of the
Government of the Philippines. However, prior approval of the government agency or office
wherein the work is created shall be necessary for exploitation of such work for profit. Such
agency or office may, among other things, impose as a condition the payment of royalties.
Borrowed materials (i.e., songs, stories, poems, pictures, photos, brand names, trademarks,
etc.) included in this module are owned by their respective copyright holders. Every effort
has been exerted to locate and seek permission to use these materials from their respective
copyright owners. The publisher and authors do not represent nor claim ownership over
them.
This module will walk you through the beginning of everything. It focuses on
how some elements known today were formed same as when stars were born right
after the universe existed. You will be provided with activities such as filling out
graphic organizer, reading story board and illustrations which make you remember
the lesson. Make sure to answer first the pretest before going through this module
and the posttest at the end of the module.
Have you also wondered what stars are made of? What keeps them shining so
bright? Are there also stars that do not spark? You might also be asking the same
questions ever since you were little that until now you still seek answers for. Well,
this module will help you understand some of the important concepts about stars.
Are you ready? Let’s go!
1
What I Know
Choose the letter of the best answer in each item and write it on a separate sheet of
paper.
1. Which of the following is the most accepted theory about the formation of the
universe that explains why it continues to expand?
a. big bang theory c. steady state theory
b. divine creation theory d. oscillating theory
5. Which element is the lightest and at the same time the most abundant in
outer space?
a. hydrogen c. lithium
b. helium d. iron
7. Which element can be formed when three atoms of helium are fused?
a. carbon c. oxygen b. hydrogen d. silicon
2
9. Which process is responsible for the formation of elements at the center of
star?
a. big bang nucleosynthesis c. stellar nucleosynthesis
b. nuclear fusion d. supernova nucleosynthesis
11. Which element will be formed when Carbon atom is combined with Helium
atom?
a. magnesium c. oxygen
b. neon d. silicon
12. Why do average stars have longer life span than massive star?
a. They have less fuel to burn c. They burn their fuel at faster rate
b. They have more fuel to burn d. They burn their fuel at slower rate
15. In which stage do massive stars explode and release large amount of
energy?
a. main sequence
b. protostar
c. super nova
d. white dwarf
3
Lesson
Stellar Nucleosynthesis:
1 Rise of the Stars!
The world where we live today is just a small part of our universe. In your
previous years, you have learned about the different theories of the origin of
the universe that eventually led to the formation of galaxies, solar system
and other heavenly bodies. This lesson will focus on one of those wonderful
things present in outer space, the stars. Although stars are millions of light
years away from us, we can still see them twinkling in the night sky. Let’s
find out how they emit light and what keeps them shining for a long time.
4
What’s In
Scientists believe that the formation of the universe began through the
explosion of a primordial atom which happened 13 billion years ago. It is
known as the Big Bang. It became a theory that also explains the
continuous expansion of the universe.
Right after Big Bang, protons and neutrons combined together and formed
light elements Hydrogen and Helium in the process of Big Bang
Nucleosynthesis. Other light elements such as Lithium and Beryllium
were also formed during this process.
5
What’s New
Stellar Nucleosynthesis
The word “stellar” means star and the formation of elements in the center of the
star is called stellar nucleosynthesis. Carl Sagan said that “We are made of star
stuff.” What did he mean by that? If we know how some important heavy elements
were formed same as stars, that maybe a clue.
Label the sequence of star life cycle. Use the hints/clues found in the table below
this diagram.
NEBULA
1. ______
PROTOSTAR
2. ______
9. _____ 5.SUPERNOVA
______
BLACK
DWARF
10. _____
NEUTRON BLACK HOLE
7. ______ 6. ______
STAR
6
Hints/ Clues
Average Star
1. The star is unable to generate heat when it runs out of
hydrogen in its core leading to its contraction and expansion.
It cools down and glows red. The Helium fused into Carbon.
The star is now RED GIANT
2. Red giant star becomes exhausted of nuclear fuel, the outer
material is blown off into space leaving the inert Carbon. The
remnant is known as WHITE DWARF.
3. Giant cloud of gas and dust known as NEBULA.
4. It is formed from nebula due to the gravity that pulled
Hydrogen gas together until it spins faster and faster and
becomes ignited. A PROTOSTAR rises.
5. MAIN SEQUENCE STAR starts to form when nuclear fusion
occurs at the core of the star, it begins to contract, glow and
become stable. Hydrogen is converted into Helium.
6. This is said to be the remain of the white dwarf that cooled
down and no longer emits light and heat. The hypothetical
BLACK DWARF.
Massive star
1. It is believed that a NEUTRON STAR is formed from supernova
explosion. This is also the smallest star
2. Explosion of star or SUPERNOVA releases large amount of
energy. Because of that, elements are dispersed into the space.
3. BLACK HOLE is a region in space where gravity is too strong
that no matter can escape from it.
4. A more massive main sequence star evolves, cools and expands
faster than low mass star and will turn into RED SUPER GIANT
star, the largest known star. Carbon fusion still occurs and
Oxygen formed.
7
What is It
TWAIN ASHLEY A. DEL ROSARIO 12-ADMIRABLE
Were you able to label all the stages of star? Review the hints/clues in the previous
activity. You will notice that following the sequence will reveal what happens in
each stage of star.
1. What element from space is pulled by gravity and turn into a protostar?
______________________________________________________________________
2. What will happen if a low massive main sequence star runs out of hydrogen
fuel?
_______________________________________________________________________
3. How are heavy elements such as Carbon, Oxygen and Neon formed during
star formation?
_______________________________________________________________________
4. Why is it impossible for any matter such as light and radiation to escape
from a black hole?
________________________________________________________________________
5. Why do you think massive star has shorter life span than average star?
________________________________________________________________________
1.Hydrogen gas in the nebula.
4. No, It cant. The velocity present from the surface of the sphere would equal to
the speed of light. that means the light becomes a black hole.
5.Massive stars are shorter lived than the average because while they have more
mass to burn through their fuel at a much higher rate as the temperature and
pressure in the core where fusion occurs is extremely high, than the average
star.
8
Look at the diagrams below. These will explain how stars are formed into
different stages because of nuclear fusion (combination of nuclei to form heavier
one) among heavy elements.
9
Tri alpha process happens in red giant star once they leave the stage of
main sequence star. This is how three Helium-4 are converted into Carbon.
A star accumulates more mass and continues to grow into red super
giant. Alpha particle fusion happens at its core and creates more heavy
elements until Iron. This is known as the Alpha ladder process.
10
How do elements heavier than Iron form? As the energy at the
core of the star decreases, nuclear fusion cannot produce
elements higher than Iron. Different pathway is needed for
heavier elements to be formed.
Neutron capture, a neutron is added to a seed nucleus.
Below is the representation of how neutron is captured
and heavier nucleus is formed.
Example:
11
What’s More
12
What I Have Learned
Read the paragraph then fill in the blanks with the correct word/s.
It all starts with 1. ____________, cloud of gas and dust particle in outer
space. Due to the force of gravity, the 2. ____________ gas is pulled together and
eventually became a protostar. Nebular fusion occurs at the center of the protostar
and becomes stable. During this time, hydrogen is converted into 3. _____________
forming main sequence star. The size of the star can be average or massive. A
massive main sequence star that runs out of hydrogen fuel will begin to expand
and cool down. This is 4. ________________, the biggest star in the universe. The red
super giant continues to fuse with heavy elements and stops when 5. ___________ is
converted in the core of the star. At this point, red super giant will become a
supernova after hundreds of years.
What I Can Do
Now, you have learned how stars are formed and evolve from one stage to another
and its connection with heavy elements from Carbon through Iron. There are many
processes that stars have to undergo before they evolve from one stage to another.
For your next task, you will write a story which relates the events of your life from
past, present and future to the life cycle of a star. Use also those elements which
could symbolize something or anything in your story. (Use another sheet of paper
for this task).
__________________________________________________________________________________
__________________________________________________________________________________
__________________________________________________________________________________
__________________________________________________________________________________
__________________________________________________________________________________
__________________________________________________________________________________
_________________________________________________________________________________-
__________________________________________________________________________________
13
Rubrics for Story of Your Life
14
Assessment
Multiple Choice. Choose the letter of the best answer. Write the chosen letter on a
separate sheet of paper.
3. Which phase of star will be created after the end of red giant?
a. black hole c. supernova
b. red super giant d. white dwarf
15
9. Which is the second most abundant element in the universe?
a. carbon c. hydrogen b. helium d. oxygen
10. What object is formed from gas and dust particles which are pulled together
by gravity and no nuclear fusion has happened yet?
a. nebula c. protostar
b. main sequence star d. red supergiant star
12. Which of the following is the sign that a protostar will transform into the
next stage?
a. When the it starts to spin faster
b. When it starts to glow
c. When Hydrogen nuclear fusion begins
d. When it increases temperature igniting the Hydrogen
15. Which is a huge luminous ball of hot gas such as Hydrogen and
Helium.
a. comet c. planet
b. moon d. star
16
Additional Activities
On this activity, you will see a star with the topic written on its center. Fill out the
parts of the stars with all the concepts you have learned in this module.
7 2
Star Formation
6 3
5 4
17
Answer Key
.15 D .15 C
.14 D .14 B
.13 A .13 A
.12 C .12 B
.11 A .11 C
.10 C .10 E .10 D
.9 B .9 F .9 C
.8 A .8 I .8 A
.7 B .7 C .7 A
.6 B .6 A .6 C
.5 D .5 G .5 A
.4 C .4 H .4 A
.3 D .3 J .3 C
.2 D .2 D .2 D
.1 D .4 B .1 A
Assessment What’s More What I Know
18
References
National Aeroautics and Space Administration. (2015, May 7).Imagine the Universe.
Retrieved from
https://imagine.gsfc.nasa.gov/educators/lifecycles/LC_main_p2.html
Strassler, M. (2013, March 4). What Holds Nuclei Together?. Retrived from
https://profmattstrassler.com/articles-and-posts/particle-physics-
basics/the-structure-of-matter/the-nuclei-of-atoms-at-the-heart-of-
matter/what-holds-nuclei-together/
19
Physical Science
Quarter 1 – Module 2:
Concept of Atomic Number
Led to the Synthesis of New
Elements in the Laboratory
Personal Development
Alternative Delivery Mode
Quarter 1 – Module 2: Concept of Atomic Number Led to the Synthesis of New
Elements in the Laboratory
First Edition, 2020
Republic Act 8293, section 176 states that: No copyright shall subsist in any work
of the Government of the Philippines. However, prior approval of the government agency or
office wherein the work is created shall be necessary for exploitation of such work for profit.
Such agency or office may, among other things, impose as a condition the payment of
royalties.
Borrowed materials (i.e., songs, stories, poems, pictures, photos, brand names,
trademarks, etc.) included in this module are owned by their respective copyright holders.
Every effort has been exerted to locate and seek permission to use these materials from
their respective copyright owners. The publisher and authors do not represent nor claim
ownership over them.
This module is especially designed for you. It will help you track the
development of your understanding on how the concept of atomic number led
to the synthesis of new elements in the laboratory.
To make learning easy for you, the module provides activities that will soon
develop your curiosity on how the concept of atomic number led to the
synthesis of new elements in the laboratory
1
What I Know
2
8. Process that can produce elements up to #83 - Bismuth.
a. Nuclear Fission c. S Process
b. R-Process d. S Process
12. In this process, there’s a buildup of a VERY heavy isotope, then as beta-
decays occur, you march up in atomic number and produce heavy
product.
a. S Process c. Nuclear Fission
b. R-Process d. Proton-Proton Reaction
3
Lesson
Physical Sciences: Concept of Atomic Number
that Led to the Synthesis
of New Elements in the Laboratory
Elements are made up of tiny particles, the neutron, proton and electron. H and
Helium are the elements that exist in the early beginning. Early in the Big
Bang, it was a tiny elementary particle. As the Universe expanded and cooled,
there was a period of proton-proton chain reaction wherein protons were fuse
into Helium. The Universe ran into a problem. Red giant cores get past this via
the Triple-Alpha process, but the Universe expands right through this
possibility and the density/temperature are quickly too low to synthesis any
additional elements.
What’s In
You learned earlier how all matter in the universe is made from tiny building
blocks called atoms. All modern scientists accept the concept of the atom, but
when the concept of the atom was first proposed about 2,500 years ago,
ancient philosophers laughed at the idea. It has always been difficult to
convince people of the existence of things that are too small to see. We will
spend some time considering the evidence (observations) that convince
scientists of the existence of atoms.
Do you have any idea how the different elements on the periodic table were
formed, known and identified? Let’s have a short review.
There is what we call Big Bang Theory that has some key stages: Singularity,
Inflation, Nucleosynthesis and Recombination: Let us differentiate them.
Singularity is a one-dimensional point which contains a huge mass in an
infinitely small space, where density and gravity become infinite and space-time
curves infinitely, and where the laws of physics as we know them cease to
operate. The basic homogeneity in distribution of matter in the universe was
established as a consequence of the first phase of inflation. Nucleosynthesis
was the nuclear fusion and the formation of new nuclei actions in the early
stages of development of the universe. Recombination - the formation of the
capture of free electrons by the cations in a plasma.
1. P and Pr both have one electron each. Pr has a bigger atomic size.
2. Od, Ri, and E are in the same series as P, C, and I. In terms of
atomic size, P is the biggest while C is the smallest. E is a metal while I is a
non-metal. Od is smaller than Ri in atomic size.
3. O has a bigger atomic size than E in the same group. Y is also a
bigger atom than C in the same group. R is more nonmetallic than Pe but
more metallic than Ti.
What is It
Key Points
5
3. Elements with atomic numbers greater than 92 (atomic number of
uranium) are called transuranium elements They were discovered in the
laboratory using nuclear reactors or particle accelerators.
Activity 1.1 Making Your Own Periodic Table shows how theoretical elements where
arrance accordiing to its atomic weight. For example, H has an atomic mass of
1.00794 amu, which makes hydrogen the lightest element on the periodic table.
Hydrogen, H, was named by Laviosier and is the most abundant element on the
periodic table. It is followed by He, Li, Be and so on and so fort because atomic
weight is used to arrange elements from lightest to heaviest.
By arranging the elements according to the square root of the frequency they
emitted, he was able to draw out an arrangement of elements that more
correctly predicted periodic trends.
6
Mention the experimental evidence he gave to an existing hypothesis: that
the elements’ atomic number, or place in the periodic table, was uniquely
tied to their “positive charge”, or the number of protons they had. This
discovery allowed for a better arrangement of the periodic table, and
predicted elements that were not yet discovered. His method of identifying
elements by shooting electrons and looking at x-rays became a very useful
tool in characterizing elements, and is now called x-ray spectroscopy.
When the elements were arranged according to their atomic numbers, there
were four gaps in the table. These gaps corresponded to the atomic numbers
43, 61, 85, and 87. These elements were later synthesized in the laboratory
through nuclear transmutations.
The first controlled nuclear chain reaction was carried out in a reactor at the
University of Chicago in 1942. One of the many reactions involved was:
235 +1 →87 +146 +31
92 0 35 57 0
The Discovery of the Missing Elements
Recall that in 1925, there were four vacancies in the periodic table
corresponding to the atomic numbers 43, 61, 85, and 87. Two of these
elements were synthesized in the laboratory using particle accelerators. A
particle accelerator is a device that is used to speed up the protons to
overcome the repulsion between the protons and the target atomic nuclei by
using magnetic and electrical fields. It is used to synthesize new elements. In
1937, American physicist Ernest Lawrence synthesized element with atomic
number 43 using a linear particle accelerator. He bombarded molybdenum
(Z=42) with fast-moving neutrons. The newly synthesized element was named
Technetium (Tc) after the Greek word "technêtos" meaning “artificial.” Tc was
the first man-made element.
The two other elements with atomic numbers 61 and 87 were discovered
through studies in radioactivity. Element-61 (Promethium) was discovered as
a decay product of the fission of uranium while element-87 (Francium) was
discovered as a breakdown product of uranium.
The invention of the device called cyclotron paved the way for transmuting
one element into another artificially. The high-energy particles that are
produced from the cyclotron upon hitting heavy target nuclei produce
heavier nuclei.
The Universe ran into the Be problem. Red giant cores get past this via the
Triple-Alpha process, but the Universe expands right through this possibility
and the density/temperature are quickly too low to synthesis any additional
elements.
8
Big Bang Nucleosynthesis
• The oldest stars in the Galaxy are deficient in the abundance of elements
heavier than Helium (but show the predicted amount of He)
• The current record holder has Fe/H about 130,000 times smaller than the
solar value.
• Not quite down to Big Bang abundances, but we are getting pretty close and
still looking.
Chemical Evolution
Chemical Evolution II
• For more massive stars, `equilibrium’ fusion reactions produce
elements all the way up to Fe.
• Freshly made elements are delivered via stellar winds or,
sometimes more spectacularly via supernova explosions
9
Neutron Capture Elements
Here a neutron
changed into a
proton by emitting
an electron
The R-process
10
• We see an overabundance of R-process elements in the oldest
stars. As the early chemical enrichment of the Galaxy was through
SNII, this is evidence of SNII as the source of r-process elements.
• If we look at the Crab Nebula or other SNII remnants we don’t see
r-process elements.
• We DO see regions of enhanced O, Si, Ne and He which appear to
reflect the `onion skin’ structure of the massive star progenitor.
Crab Nebula
1 https://www.nasa.gov/mission_pages/hubble/multimedia/crab_ nebula.html
D
i
a
The Transuranic
g Elements
r
a
In the 1930s, mthe heaviest element known was uranium, with an atomic
number 92. Early
(
in 1940, Edwin McMillan proved that an element having
an atomic number
H 93could be created. He used a particle accelerator to
bombard uranium
o with neutrons and created an element with an atomic
w
number 93 which he named neptunium.
Transuranic
R elements are synthetic elements with atomic numbers
-
higher than
P that of Uranium (Z = 92).
r 23892 + 10 → 23993 + −01
o
c
Plutonium (Z = 94)
e 238 2 239 + 21
s 92+ 1→ 93 0
s 23893→ 23994+1 + −10
O
At the cend of 1940, element-94 was synthesized by Seaborg,
McMillan,
c Kennedy, and Wahl. They bombarded uranium with
u
deuterons
r (particles composed of a proton and a neutron) in a
cyclotron. Element-94 was named plutonium.
)
11
Elements with atomic numbers greater than 92 (atomic number of uranium)
are called transuranium elements. Hence, neptunium and plutonium are
both transuranium elements. They are unstable and decay radioactively into
other elements. All these elements were discovered in the laboratory as
artificially generated synthetic elements. They are prepared using nuclear
reactors or particle accelerators. In the next lesson, you will learn the nuclear
reactions involved in the synthesis of these transuranium elements.
Stellar nucleosynthesis
This is the process by which elements are created within stars by combining
the protons and neutrons together from the nuclei of lighter elements. Fusion
inside stars transforms hydrogen into helium, heat, and radiation. Heavier
elements are created in different types of stars as they die or explode.
Superheavy elements are elements with atomic numbers beyond 103. These
are produced by bombarding heavy nuclear targets with accelerated heavy
projectiles.
Following are the equations of several nuclear reactions that have important
roles in the history of nuclear chemistry:
• The first naturally occurring unstable element that was isolated, polonium,
was discovered by the Polish scientist Marie Curie and her husband Pierre in
1898. It decays, emitting particles:
21284 → 20882 + 42
12
What’s More
13
Timeline Rubric
14
What I Can Do
Assessment
15
a. nuclear fission c. S Process
b. R-process d. S-Process
6. This is known as the origin of light elements.
a. Stellar Nucleosynthesis c. R-Process
b. Primordial Nucleosynthesis d. Supernova Nucleosynthesis
16
a
Additional Activities
17
Answer Key
b .15
c .14 266109Mt + 10n
c .13 5826Fe—> + 20983Bi .c
d .12 Mendeleev.
c .11 Dmitri after named
a .10 10n Mv is + 256101Mv
a .9 42He —> + En 25399 .b
b .8 radioactivity.
a .7 natural on research
b .6
extensive done
c .5
c .4
who had Curie Pierre
a .3 named after Marie and
c .2 is Cm 10n 24296Cm+
d .1 —> 42He + 23994Pu .a
a .15
c .14
d .13
b .12
a .11
a .10
c .9
c .8
b .7
a .6
b .5
c .4
c .3
d .2
c .1
What I Know
18
References
Coyne, Glynis L. (2012). Lead to Gold, Sorcery to Science: Alchemy and the
Foundations of Modern Chemistry. University of North Carolina PIT
Journal, 4. Retrieved October 10, 2015
http://pitjournal.unc.edu/article/lead-gold-sorcery-sciencealchemy-and-
foundations-modern-chemistry;
“The Synthesis of the Elements.” Lick Observatory. Accessed May 23, 2020.
http://www.ucolick.org/~bolte/AY4_04/class6_04bwd.pdf.
Physical Science
Quarter 1 – Module: 3
Physical Science
Alternative Delivery Mode
Quarter 1 – Module 3: Polarity of Molecules
First Edition, 2020
Republic Act 8293, section 176 states that: No copyright shall subsist in any work of
the Government of the Philippines. However, prior approval of the government agency or office
wherein the work is created shall be necessary for exploitation of such work for profit. Such
agency or office may, among other things, impose as a condition the payment of royalties.
Borrowed materials (i.e., songs, stories, poems, pictures, photos, brand names,
trademarks, etc.) included in this module are owned by their respective copyright holders. Every
effort has been exerted to locate and seek permission to use these materials from their
respective copyright owners. The publisher and authors do not represent nor claim ownership
over them.
This module was designed and written with you in mind. It is here to help you
determine if a molecule is polar or non-polar. The scope of this module permits it to be
used in many different learning situations. The language used recognizes the varied
vocabulary level of students. The lessons are arranged to follow the standard sequence
of the course. But the order in which you read them can be changed to correspond
with the textbook you are now using.
1
What I Know
Choose the letter of the best answer. Write the chosen letter on a separate sheet of
paper.
3. What type of chemical bond holds the atoms of water molecule together?
a. Hydrogen bond
b. Ionic bond
c. Polar covalent bond
d. Nonpolar covalent bond
2
7. What is the molecular shape of BeF3?
a. Linear
b. Trigonal
c. Tetrahedral
d. Trigonal bipyramidal
8. A molecule can have a polar bond and still be nonpolar overall. The statement
is ___
a. True
b. False
c. Maybe
9. A polar covalent bond would form in which of the following pairs of atoms?
a. Cl-Cl
b. Mg-O
c. N-H
d. C-S
True or False: Write TRUE if the statement is correct, otherwise write FALSE.
11. The general trend of electronegativity as you move from top to bottom of
the periodic table is increasing.
12. Flourine has the greatest electronegativity while cesium and francium have the
least electronegativity value.
13. Water, with a bent molecular shape, is classified as a polar molecule.
14. Sulfur hexafluoride (SF6) has six bonded electrons and no lone pair in its
central atom.
15. Hydrogen cyanide (HCN) exhibits a linear geometry.
3
Lesson
1 Polarity of Molecules
It is interesting to have a quick glance at the lessons you have learned about
compounds and chemical bonds when you were in Grades 8, 9 and 10. Can you still
recall them? Great!
Studying this module will certainly increase your understanding about the
polarity of molecules. This module is packed with interesting activities which will
make you enjoy your Chemistry lessons even more. So, are you ready to delve on an
exciting quest for chemistry learning? You may start now by doing the activity below.
Goodluck and happy learning!
What’s In
Chemical bonds are formed when atoms lose, accept or share electrons. An ionic bond
occurs when there is a transfer of one or more valence electrons form one atom to
another. It exists between metal and nonmetal atoms where metal loses electron/s
while nonmetal accepts the electron/s donated by metal. On the other hand, when two
nonmetal atoms combine, neither of them loses or gains electron Instead, electron
pairs are being shared by both atoms and the type of chemical bond formed is called
covalent bond.
4
Notes to the Teacher
Periodic Table is an indispensable tool in studying chemistry. In
order for the learners to answer the above activity, they must first
be familiar on how to use all the information written on the
periodic table. At this point, they should be able to effectively use
the periodic table in order to classify elements as to metal, non-
metal or semi-metals.
ANSWER: NaCl, CaCl2, Fe2O3,KBr, and AlCl3 are all ionic compound because the
atoms involved are combination of metal and nonmetal. On the other hand, CO2, CCl4,
N2O, PCl5 and HCl are covalent compounds because the atoms involved are both
nonmetals.
It’s good that you were able to recall the difference between ionic bond and covalent
bond.
You have learned that a covalent is a shared pair of electrons between two atoms. But
are the electrons equally shared by the combing atoms? How does a polar covalent
bond differ from a nonpolar covalent? Did you know that electronegativity of an atom
can be used to further classify covalent bond into polar and nonpolar?
As you perform the activity below, you will find out that substances have different
polarities, and this explains why there are substances that do not mix while others do.
5
What’s New
• Water
• Vinegar
• Oil
• Alcohol
• disposable glasses
• spoon
Procedure:
Guide Question:
Calculate the electronegativity difference and give the type of bond that exists
between the atoms in each of the following pairs.
6
What is It
The polarity of molecules is determined by the two factors: the polarity of bonds based
on the electronegativity difference of the atoms involved and the geometrical shape of
the molecules which can be predicted via valence shell electron pair repulsion (VSEPR)
theory.
7
Table 1. Type of bond based on electronegativity difference (∆EN) of bonded atoms
Electronegativity Difference
Type of Bond
(∆EN)
Ionic ≥1.7
Polar Covalent 0.5 to 1.6
Nonpolar Covalent ≤ 0.4
For example, you are asked to predict what type of bond is present between
the following pairs of atoms by determining their electronegativity difference.
4. Ca and Cl
5. Cl and Cl
6. H and Cl
7. S and O
8. C and N
Solution:
3. ENH = 2.1 (∆EN) = 2.1 – 3.0 = │-0.9│= 0.9 polar covalent bond
ENCl= 3.0
4. ENS= 2.5 (∆EN) = 2.5 – 3.5 = │-1.0│= 1.0 polar covalent bond
ENO = 3.5
5. ENC= 2.5 (∆EN) = 2.5 – 3.0 = │-0.5│= 0.5 polar covalent bond
ENN = 3.0
Using the above examples, let us know more about polar and nonpolar covalent
bonds. A polar covalent bond is formed when electrons are shared unequally by two
atoms in a compound. The bonded pair of atoms form an electric dipole (represented
by ). Dipole means “two poles” which means that a molecule has one positive
end and one negative end. In this type of bond, the atom with the higher EN value
becomes the partial negative pole (symbolized as ẟ-) while the atom with the lower EN
value becomes the partially positive (symbolized as ẟ+) pole. Always bear in mind that
the direction of the arrow is always pointing from a more electropositive pole to the
more electronegative pole. Take HCl for example, H is has higher EN than Cl, thus the
direction of the arrow is from H pointing to Cl and there is unequal electron density as
represented by a size of the circle (refer to figure 2). On the other hand, a nonpolar
covalent bond develops if both atoms equally share a pair of electrons between them.
8
This occurs when the bonding atoms have approximately equal EN value or equal
ability to attract electrons to each side. Nonpolar covalent bond is an example of bond
formed when two chlorine atoms combine.
(a) (b)
Figure 2. (a) Polar bond between H and Cl and (b) nonpolar bond between two
Cl atoms
You can predict the shape or molecular geometry of a substance using the following
steps:
Step 1: Determine the central atom of a molecule. The central atom is the least
electronegative element.
Step 2: Draw the appropriate Lewis dot structure for the molecule.
Step 3: Count the number of bonding pairs of electrons and non-bonding (or
lone pairs) around the central atom.
Step 4: Determine the electron pair orientation using the total number
of electron pairs.
9
Consider the examples below:
Step 1: ENB = 2.0 ENCl= 3.0 therefore, B will be the central atom and three Cl
atoms are attached to it. By looking at the chemical formula, you
will also have an idea that boron will be the central atom and three atoms of
choline are attached to it.
Step 2:
Step 3: The central atom has three electron pairs: 3 bonded pairs and
no lone pair
Step 4: The electron pair orientation for three electrons is trigonal planar.
Step 5: The molecular shape of BCl3 is trigonal planar.
Example 2: Predict the molecular geometry of CO2
Step 1: ENC= 2.5 ENO= 3.0 therefore, C will be the central atom and two
O atoms will be the attached to it. (Use may also use the chemical
formula to predict which atom will be the central atom
Step 2:
Step 3: For the purpose of determining the position of the bonding pairs,
let us count the double bonds as one bonding pair. Therefore, CO2
has two bonding pairs of electron.
Step 4: The electron pair orientation for two electron pairs is linear.
Step 5: The molecular shape of CO2 is linear.
Example 3: Predict the molecular geometry of CHCl3.
Step 1: ENC = 2.5, ENH= 2.1 and ENCl= 3.0. Because carbon is less
electronegative than chlorine and hydrogen is normally terminal atom,
C must be the central atom.
Step 2:
10
Now that you have learned how to determine the molecular geometry, let us now go
on to our discussion of polarity of molecules based on molecular shapes. You may
study the diagram below and we will use it as our guide.
Is the shape
NO YES
symmetrical
in 3D?
YES
Note: You must think about a molecule
in 3-D according to VSEPR Theory The molecule
is NONPOLAR
Going back to our previous examples, let us try to determine the polarity of
molecules of BCl3, CO2 and CHCl3.
For both BCl3 and CO2, the atoms are symmetrically arranged (trigonal
planar and linear) and the attached atoms to the central atom are also the
same. You must also take note that in a symmetrical molecule, the sum of the
bond dipole is equal to zero (because they cancel out) which leads to the
formation of nonpolar molecule. Therefore, both BCl3 and CO2 are nonpolar. On
the other hand, CHCl3, although it has a symmetrical arrangement
(tetrahedral), the atoms attached to the central atom are not all the same (3
chlorine atoms and 1 hydrogen atom). This causes CHCl 3 to become a polar
molecule.
Now, let us see if you fully understood our discussion. I want you to try
answering the exercises below.
11
Identify which molecule is polar and which is nonpolar given the Lewis structure and
molecular shapes of the following molecules.
1. NH3 Trigonal
pyramidal
3. CCl4
Tetrahedral
4. Linear
If you were able to answer that NH3 and H2O are polar molecules because the bond
dipole cannot be cancelled because of the presence of lone pairs on the central atom
and CCl4 and HBr are nonpolar molecules, you are correct. Job well done! You may
now proceed to the rest of this module.
What’s More
• PCl5
• BeCl2
• CH4
• OF2
• SF6
So far, we have discussed how polarity of molecules is being determined. At this point,
you will perform the activity below to find out if you fully understood our topic. If you
think you need to go back to the discussion part of this module while answering this
activity, please feel free to do so.
12
What I Have Learned
What I Can Do
Assessment
Multiple Choice. Choose the letter of the best answer. Write the chosen letter on a
separate sheet of paper.
1. The following molecules have polar covalent bonds EXCEPT?
a. NH3
b. CS2
c. BCl3
d. HBr
2. Which of the following bonds is the MOST polar?
a. H-Cl
b. C-Cl
c. H-H
d. N-F
13
3. What is the molecular shape of CHBr3?
a. Linear
b. Trigonal planar
c. Trigonal bipyramidal
d. Tetrahedral
4. A nonpolar covalent bond would form in which of the following pairs of atoms?
a. Na-Cl
b. Ca-O
c. P-N
d. C-S
5. From the given Lewis structure of NH3, how many nonbonding pair/s of
electron are around the central atom?
a. 0
b. 1
c. 2
d. 3
6. Which of the following statements is INCORRECT?
a. Polar covalent bonds can be present in a nonpolar molecule.
b. Polar covalent bond is present if the electronegativity difference between
atoms is equal or less than 0.4.
c. Polarity of bond and molecular geometry are the two factors that affect
the polarity of molecules.
d. Polar bond forms when electrons are unequally shared by two atoms in
a compound.
7. What do you call the relative ability of a bonded atom to attract shared
electron pairs?
a. Electron affinity
b. Electronegativity
c. Ionization energy
d. Metallic property
8. Which description below correctly describes polar molecules?
a. Have polar bonds present.
b. The polar bonds are arranged so that they do not cancel.
c. Lone pairs on the central atom are arranged so that they do not cancel.
d. Lone pairs on the central atom are arranged so that they can be
cancelled out.
14
9. Which of the following molecules is tetrahedral?
a. H2O
b. SF6
c. CH4
d. BF3
10. Which of the following is NOT TRUE about CO 2?
a. Has an electronegativity difference of 1.0
b. Polar bond is present
c. Has a linear molecular shape
d. Is a polar molecule
True or False: Write TRUE if the statement is correct, otherwise write FALSE.
11. S and O are bonded by a polar covalent bond because its
electronegativity difference value is 1.0.
12. Atoms with high electronegativity have a greater tendency to attract electrons
toward itself.
13. Polarity of molecules are determined both by polarity of bonds and molecular
geometry.
14. Among C-Cl, H-Cl, C-H and Cl-Cl, only Cl-Cl is polar.
15. Methyl alcohol, CH3OH, is a nonpolar molecule.
Additional Activities
______________________________________________________________________
______________________________________________________________________
________________________________________________________________________
________________________________________________________________________
________________________________________________________________________
________________________________________________________________________
15
Answer Key
F .15 .15 T
F .14 .14 T
T .13 .13 T
T .12 IC.10 .12 F
T .11 CC .9 .11 F
D .10 IC .8 .10 A
C .9 .7 CC C .9
C .8 CC .6 A .8
B .7 IC .5 B .7
B .6 .4 CC C .6
B .5 IC .3 C .5
D .4 .2 CC C .4
D .3 IC .1 C .3
D .2 D .2
B .1 What’s More B .1
Assessment What I Know
6
non-polar Octahedral Polar 7.1 SF .5
2
polar Bent Polar 5.0 OF .4
4
nonpolar Tetrahedral Non-polar 4.0 CH .3
2
nonpolar Linear Polar 5.0 BeCl .2
bipyramidal
polar polar 8.0 5
Trigonal PCl .1
16
.bond
of valence electrons that is not shared with another atom in a covalent
covalent bonds while lone pair (nonbonding electrons) refers to a pair
Answer: Bonding electrons are those electrons involved in the formation of
Differentiate bonding and non-bonding .electrons .4
molecular geometry satisfies the condition of VSEPR .theory
a nonpolar molecule as long as its bond but still be classified as
bond and molecular .geometry A molecule can have a polar covalent
Answer: .Yes Because polarity of molecule is determined both by polarity of
polarity of nonpolar?
Is it possible for a molecule to have a polar bond but have an overall .3
∆EN is beyond .04 but less than 7,.1 the bond is .polar
or .nonpolar If the ∆EN is 4.0 or less, the bond is .nonpolar But if the
electronegativity can be used to predict whether the bond will be polar
of toward .itself The concept attract shared electrons to
Answer: Electronegativity measures the tendency of an atom in a molecule
polarity of molecules?
What is electronegativity and how can it be used in in determining the .2
there is equal sharing of electrons between .atoms
nonpolar bonds are formed when electrons between atoms, while
Answer: Polar bonds are formed when there is an unequal sharing of
.1 In your own words, differentiate polar and nonpolar covalent .bond
17
.nonpolar
configuration will exhibit a trigonal bipyramidal shape and therefore it is
3
Using the concept of VSEPR theory, a molecule with an AB E
E – lone pair (nonbonding electrons)
B - terminal atom
Note: A – corresponds to central atom,
the molecule is polar or nonpolar by determining its molecular .shape
3
E, a hypothetical molecule, is .discovered Predict whether Suppose that AB .2
central atom has no lone pair, making it .nonpolar
pairs of electron and has a trigonal planar geometry with three bonding
3
1 nonbonding pair/lone pair), this makes it .polar On the other hand, BF
has a trigonal pyramidal shape, with four electron pairs (3 bonding pairs and
3
Answer: Polarity of molecule is determined by its molecular .geometry Since NH
.molecule Explain the difference in the polarity of these .compounds
3 3
) is a nonpolar Ammonia (NH ) is polar molecule while boron trifluoride (BF .1
What I can do
Additional Activities:
18
References
19
Physical Science
Quarter 1 – Module 4:
Polarity of Molecules and
Its Properties
Personal Development
Alternative Delivery Mode
Quarter 1 – Module 4: Polarity of Molecules and Its Properties
First Edition, 2020
Republic Act 8293, section 176 states that: No copyright shall subsist in any work of the
Government of the Philippines. However, prior approval of the government agency or office
wherein the work is created shall be necessary for exploitation of such work for profit. Such
agency or office may, among other things, impose as a condition the payment of royalties.
Borrowed materials (i.e., songs, stories, poems, pictures, photos, brand names, trademarks,
etc.) included in this module are owned by their respective copyright holders. Every effort has
been exerted to locate and seek permission to use these materials from their respective
copyright owners. The publisher and authors do not represent nor claim ownership over them.
This module was designed and written with you in mind. It is here to help you master
the concept of polarity of molecules. The scope of this module permits it to be used in
different learning situations. The language used recognizes the varied vocabulary level
of students. The lessons are arranged to follow the standard sequence of the course.
But the order in which you read them can be changed to correspond with the textbook
you are now using.
1
What I Know
Choose the letter of the best answer. Write the chosen letter on a separate sheet of
paper.
2
8. Which of the following is NOT TRUE about water?
a. has high surface tension
b. has high boiling point
c. has low viscosity
d. becomes denser when freezes
3
Lesson
Properties of Molecules
1 based on its Polarity
From the previous module, you learned how to determine the polarity of bonds using
the concept of electronegativity. Also, you learned that polarity of molecules is affected
by both the polarity of bonds and its molecular shape or geometry.
What’s In
Let us have some warm up exercise for our nerve cells before we proceed to the
presentation of our lesson. You will perform a simple activity that will help you recall
some basic concepts related to polarity of molecules. Have some fun!
4
WORD CRYPTOGRAM
Directions: Unscramble the letters by placing the correct letter sequence in the
shaded boxes to come up with the correct answer for each number. Use the numbered
boxes to complete the answer to the riddle below.
1.
L E C M O U L E
1 5 6
2.
O P A L R O D N B
3 9
3.
O N L E A P I R
2 14 8 16
4.
N A R O P O L N B D O N
7 12
5.
A C E G T R O T L I Y E I T E N V
11 15 4 10 17
6.
M A T O
13
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17
Can you define the following words/terms that you have decoded?
5
What’s New
Analyze the lyrics of the song, “Tubig at Langis”, and answer the questions below.
TUBIG AT LANGIS
Sharon Cuneta
Chorus:
Tubig at langis
Idarang man sainit, ‘di rin tatamis
Dahil ang halo’y luha’t paghihinagpis
Ang kirot ay di maalis kung labis
Bakit nanaig ang dusa sa ligaya sa ‘ting daigdig ?
May dasal ba akong hindi N’ya narinig ?
Papel natin sa pag-ibig
Ako’y langis, ika’y tubig
Repeat Chorus:
Bakit nanaig ang dusa sa ligaya sa ‘ting daigdig ?
May dasal ba akong hindi N’ya narinig ?
Papel natin sapag-ibig
Ako’y langis, ika’y tubig
Ako’y langis, ika’y tubig
Guide Question:
1. What is the message of the song?
2. If you add oil to the water, what will happen? Will it create a single
homogenous phase or will it form two layers? Why?
3. Why do you think water and oil cannot be mixed even when heated? Support
your answer.
6
What is It
The general rule to remember about the solubility and miscibility of molecular
compounds can be summarized in a phrase, “like dissolves like” or “like mixes with
like”. This means that polar substances will only be dissolved or mixed with polar
substances while nonpolar substances will be soluble or miscible with another
nonpolar substance.
Now I want you to try the exercises below in order to assess how much you have
understood the solubility (and miscibility) rule of substances in relation to their
polarity.
Which of the following substances below will most likely mix with each other?
What chemistry concept did you used in answering the question above? If you
answered polarity of molecules, then you are on the right track. Great job! Benzene
and chloroform are both nonpolar compounds while water and vinegar are both polar
compounds, thus they are miscible to each other. However, the rest is a combination
of polar and nonpolar molecules and therefore will not mix and instead will form two
layers even if shaken or carefully stirred.
From the previous module, you learned the intramolecular forces of attraction, the
attractive force that binds atoms together. In this module, you will learn another type
of attractive force, the intermolecular forces of attraction (IMFA) which exists between
molecules.
7
In this lesson, we will not discuss IMFA in so much detail because it will be tackled to
you in the next module. We will just focus on the following salient points of IMFA and
its effect on the physical properties of covalent compounds:
1. There are several types of IMFA and below they are arranged from
STRONGEST to WEAKEST.
Ion-dipole → H-bonding→ dipole-dipole→dipole-induced dipole→
London forces of attraction
2. The strength of IMFA greatly affects the physical properties of substances
such as boiling point, melting point, vapor pressure, surface tension, etc.
Before we move further, try to perform the exercise below to test your ability to
analyze concepts and principles that you have learned from the discussion.
How well did you perform in this exercise? Continue reading for you to find out the
correct answers for this activity.
From the above discussion you learned that there are several types of IMFA and their
relative strength as compared to other types. Strong intermolecular forces tend to yield
solids and liquids while weak intermolecular forces favor formation of gases.
Table 1 shows the comparison of the various types of IMFA while table 2 shows the
physical properties of polar and nonpolar molecules as affected by the type of
IMFA present.
8
Table 2. General Properties of polar and nonpolar molecules
In the simplest sense, boiling point, melting point, viscosity and surface tension
increase as the strength of intermolecular forces increases. On the other hand, vapor
pressure and volatility decrease with increasing strength of IMFA. London dispersion
forces increase as the molecular mass of a substance increases. Unlike in H-bonding,
as the molar mass increases, the boiling point, melting point, viscosity and surface
tension decrease.
9
What’s More
BP MPV ST VP
10
What I Have Learned
3. Compare and contrast polar and non-polar molecules based on its physical
properties.
4. What relationship can you derive between the strength of IMFA and the
physical properties of covalent molecules?
What I Can Do
A. Using the concept of bond polarity and solubility, explain why water (H2O) and
vinegar are miscible, but vinegar and oil are immiscible.
11
Assessment
Multiple Choice: Choose the letter of the best answer. Write the chosen letter on a
separate sheet of paper.
2. The boiling point of water is greater than dihydrogen sulfide because of ______.
a. Dipole-dipole bond
b. H-bonding
c. London dispersion
d. Ion-dipole
5. ______ refers to the energy required to increase the surface area by a unit
amount.
a. Viscosity
b. Surface tension
c. Vapor pressure
d. Density
12
7. Which of the following substances is miscible in hexane (C 6H14)?
a. Acetone (C3H6O)
b. Vinegar (CH3COOH)
c. Chloroform (CHCl3)
d. Methanol (CH3OH)
9. Which of the following properties has indirect relationship with the strength of
IMFA?
a. Boiling point
b. Melting point
c. Surface tension
d. Vapor pressure
10. In which of the following solvents would molecular iodine (I2) be most soluble?
a. Vinegar
b. Water
c. Ethyl alcohol
d. Carbon tetrachloride
13
Additional Activities
H2 O 100 0
14
Answer Key
F .15 F .15
T .14 T .14
F .13 F .13
T .12 T .12
F .11 F .11
D .10 A .10
D .9 B .9
C .8 D .8
C .7 C .7
C .6 B .6
B .5 D .5
A .4 A .4
C .3 C .3
B .2 CRYPTOGRAM A .2
D .1 WORD C .1
Assessment What's More What I Know
17 16 15 14 13 12 11 10 9 8 7 6 5 4 3 2 1
Y R T E M O E G R A L U C E L O M
RIDDLE
13
M O T A
.6
17 10 4 15 11
Y T I V I T A G E N O R T C E L E
.5
12 7
D N O B R A L O P N O N
.4
16 8 14 2
R I A P E N O L
.3
9 3
D N O B R A L O P
.2
6 5 1
E L U C E L O M
.1
What's More
15
3 3 3
acetone, CH OCH COOH Acetic acid, CH
acid
molar mass than acetic
however acetone has lower
Both have H-bonding
3 3
CH3COOH
OCHCH 2 3 3
OH CHethanol, CH Methanol, CH OH
ethanol
molar mass than
but methanol has lower
Both have H-bonding
2 3 3
CH CH OH OHCH 2 2
dipole Owater, H SDihydrogen sulfide, H
which is stronger than dipole-
2
and IMFA type is H-binding
S H Because it is polar molecule
2
O H
4 4
carbon tetrachloride, CCl Methane, CH
London forces
4 dipole which is stronger than
CH 11. a
n
d
I
M
F
A
t
y
p
e
i
s
d
i
p
o
l
e
B
e
c
a
u
s
e
i
t
i
s
p
o
l
a
r
m
o
l
e
c
u
l
e
4
CCl
VP ST V MP BP
What’s More
16
is inversely proportional to the strength of .IMFA and ST are
directly proportional to the strength of IMFA while VP increases
with decreasing strength of .IMFA Therefore, BP, MP, V increase
with increasing strength of .IMFA Vapor pressure Answer: Boiling
point, melting point, viscosity and surface tension
molecules? covalent of properties physical the and
.4 What relationship can you derive between the strength of IMFA
Answer:
physical .properties
.3 Compare and contrast polar and non-polar molecules based on its
What I Can Do
17
membrane .effectively
membrane can perform its function of being selectively permeable
water while its hydrophobic part is oriented .inward In this way, the cell
it forms a micelle wherein its hydrophilic part has a close contact with
loving) end and hydrophobic (water-fearing) .end When placed in water,
hand, are present in the cell .membrane It has a hydrophilic (water-
it can no longer perform its basic .function Phospholipids, on the other
polar and nonpolar .groups Once its shape has been altered or modified,
The shape of proteins is affected by attraction and repulsion among its
a long chain and it also has the ability to bend to form various .shapes
nonpolar ends which are essential for life processes to .occur It can form
Possible answer: Proteins are macromolecules having polar and
processes such as in the structure of proteins and .phospholipids
.C Explain the importance polarity of molecules to biological
What I Can Do
18
References
19
Physical Science
Quarter 1 – Module 5:
General Types of
Intermolecular Forces
Physical Science
Alternative Delivery Mode
Quarter 1 – Module 5: General Types of Intermolecular Forces
First Edition, 2020
Republic Act 8293, section 176 states that: No copyright shall subsist in any work
of the Government of the Philippines. However, prior approval of the government agency or
office wherein the work is created shall be necessary for exploitation of such work for profit.
Such agency or office may, among other things, impose as a condition the payment of
royalties.
Borrowed materials (i.e., songs, stories, poems, pictures, photos, brand names,
trademarks, etc.) included in this module are owned by their respective copyright holders.
Every effort has been exerted to locate and seek permission to use these materials from
their respective copyright owners. The publisher and authors do not represent nor claim
ownership over them.
This module was designed and written with you in mind. It is here to help you
master the General Types of Intermolecular Forces. The scope of this module
permits it to be used in different learning situations. The language used recognizes
the varied vocabulary level of students. The lessons are arranged to follow the
standard sequence of the course. But the order in which you read them can be
changed to correspond with the textbook you are now using.
1
What I Know
Choose the letter of the best answer. Write the chosen letter on a separate
sheet of paper.
3. The ease with which the electron distribution in the atom or molecule
can be distorted
a. Diffusion
b. Polarizability
c. dipole moment
d. induced dipole
2
6. The strongest among the intermolecular forces
a. ion-dipole
b. h-bonding
c. dipole-dipole
d. dipole-induced dipole
3
12. The strength of ion-dipole interaction depends on the ions present.
with ions of the same magnitude, which is true about this
interaction?
a. a. Cations interact more strongly that anions because their charges
are less concentrated.
b. b. Cations interact more strongly that anions because their charges
are more concentrated.
c. c. Anions interact more strongly that anions because their charges
are less concentrated.
d. d. Anions interact more strongly that anions because their charges
are more concentrated.
13. At any certain time the shift in the position of the electrons in an
atom will likely create a temporary positive and negative poles. This is
known as
a. dipole forces
b. dipole moment
c. dispersion forces
d. instantaneous dipole
14. The force/s of attraction present between the species I2 and NO-3
a. London dispersion forces
b. H-bonding and ion-induced dipole interaction
c. Van der Waals interaction and dipole-dipole interaction
d. London dispersion forces and ion-induced dipole interaction
4
Lesson
Types of
Intermolecular
Forces
Atoms in molecules and ionic substances are attracted to each other either by
sharing or complete transfer of electrons. These attractions keep the molecules
and their identities intact.
But, say, how do molecules or substances stay together and exhibit properties
that are unique to them? This is known as bulk properties.
In this lesson, you will learn how the different forces of attraction known as
intermolecular forces keep substances together. You will also be able to identify the
intermolecular forces present between and among substances, thus their bulk
properties can be predicted.
What’s In
This simple activity will help you recall what you understood about Lewis electron
dot structure and polarity of molecules. The polarity of substances will guide you
in identifying the intermolecular forces present between and among molecules.
5
Directions:
1. Use a clean sheet of paper to answer this part.
1. CCl2F2
2. N2
3. CH4
4. H2O
5. CO
6
What’s New
Activity 1:
Using the illustrations below, describe what happens in each of the attractions
between substances by completing each sentence with the correct words. Tell
what kind of attractive forces keep the substances together.
1.
This attraction happens between polar molecules. The charges align so that the
________________ pole of one molecule is attracted to the ____________ end of the
other molecule. Kind of interaction: __________________
2.
The ____________ sodium ion is attracted to the partially ___________ end of water
molecules. Kind of attraction: ____________________
3.
4.
5.
7
Activity 2: Identify the intermolecular forces present among the following
species.
e. Fe2+ and O2
8
What is It
This section gives brief and thorough discussion of the concepts of intermolecular
forces. The different types of intermolecular forces are described to be congruent
with the first objective of this module. The second discussion is about the strategies
to identify the intermolecular forces present between and among molecules.
Activity 1:
Atoms are held together in molecules by strong intramolecular forces, like covalent
and ionic bonds. On the other hand, other forms of attractive forces are present to
keep these molecules together giving rise to the different states of matter, which,
then exhibit their own bulk properties such as boiling, melting, and freezing points,
and viscosity among others.
There are three general types of intermolecular forces (IMF), namely, van der
Waals forces, ion-dipole interaction, and H-bonding.
Van der Waals forces, after the Dutch chemist Johannes van der Waals
(1837-1923) consist of dipole-dipole interaction, dipole-induced dipole interaction,
and dispersion forces. Dipole-dipole attraction is present among polar molecules.
Through constant movement, the charges of the molecules align in such a way that
the positive (+) end of one molecule is attracted to the negative (-) end of the other
molecule. This happens due to the shift of electron density towards the more
electronegative element in the molecule resulting to (+) and (-) ends. The measure of
this electron shift is known as dipole moment, represented by crossed arrow, .
Dispersion forces (London dispersion forces), were named after the German
physicist Fritz London (1900-1954). The electron cloud of a neutral substance can
be normally distributed around the nucleus. At any given time, the electron
distribution may be uneven resulting to an instantaneous dipole. This temporary
dipole will then influence the neighbouring atoms through attractive and repulsive
forces. Eventually, the substances will gain instantaneous dipoles, too. Attraction
between opposite charges will happen among the species present. These are true
for ion-induced dipole and induced dipole-induced dipole interactions.
Ion-dipole interaction results from the attraction between either a cation (+)
or an anion (-) with permanent polar molecules. The ions will be attracted to the
opposite charges present in the dipole resulting to this type of attraction.
9
H-bonding is a special type of dipole-dipole interaction between the H-atoms
in a polar bond. It requires that the H-atoms in the molecules be bonded with more
electronegative atoms such as O, N, or F to form H-bonds with other molecules.
With the presence of an ion (cation or anion), the charged ends of polar
molecules will be attracted to the dipole. This is true in the case of Na+ and
formaldehyde. The positive (+) sodium ion will be attracted to the partially-negative
oxygen in formaldehyde, resulting to an ion-dipole interaction.
In both NH3 and H2O, the hydrogen atoms are bonded to more
electronegative atoms, nitrogen and oxygen, respectively. This permits them to form
H-bonds with other molecules with the same condition. Thus, H-bond is present
between NH3 and H2O.
Ion-induced dipole forces of attraction are present among Fe2+ ions together with
oxygen molecules. The charge in iron will distort the electron distribution in O2
resulting to temporary poles in oxygen. The oppositely-charged particles, Fe2+ and
partially-negative end of O2 will then be attracted to form the above-mentioned force
of attraction.
In all of the examples above, London dispersion forces are also present.
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What’s More
Column A Column B
4. Dichloromethane (CH2Cl2)
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What Have I Learned
c. H-bonding
b. CS2
c. C2H6
d. CH3COOH
e. Br2
What I Can Do
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Assessment
Choose the letter of the best answer. Write the chosen letter on a separate sheet of
paper.
3. Why are dispersion forces high in molecules with great number of electrons?
a. The electron distribution of big molecules is easily polarized.
b. The nucleus in the molecules has greater effective shielding effect.
c. The electrons move freely around the nucleus resulting to greater energy.
d. The electrons in the molecules can easily jump from one orbital to
another.
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6. How does dipole-dipole interaction happen?
a. Polar molecules shift electron density that gives rise to
neutral substances.
b. The electron distribution in the polar molecules is distorted
that results to (-) and (+) poles.
c. Polarization of big nonpolar molecules brings about
the formation of permanent (+) and (-) charges.
d. The (-) and (+) ends of one polar molecule align themselves
to the (+)and (-) ends of another polar molecule and attract
each other.
10. CH4
11. CH3COOH
12. O3
13. N2
14. NH3
15. PCl5
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Additional Activities
This part will test whether you fully understand what intermolecular
forces are present between and among species. You can answer this by
recalling the strategies discussed earlier in this module. Remember also that
there may be more than one IMF present in the given substances.
2. Acetone, CH2O
4. Methane, CH4
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Answer Key
What’s In
4. H2O (Water)
Bent
Nonpolar
5. CO (Carbon
monoxide) Linear Polar
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What’s New
London dispersion forces, ion-induced dipole .5
.Act 2
1. Act
.molecules
be either repulsive or attractive depending on the distance of the
2a) van der Waals forces are interactions between molecules that can
Additional Activities
London dispersion forces , dipole-dipole interaction .5
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References
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Nutrients Review.com. “Glycerin (Glycerol).” Accessed May 22, 2020.
http://www.nutrientsreview.com/carbs/edible- glycerin.html
Quora. “What is the formula and structure of water?” Accessed May 24, 2020.
https://www.quora.com/What-is-the-formula-structure-of-water
Study.com. “Ether: Preparations and Reactions.” Accessed May 20, 2020.
https://study.com/academy/lesson/ether-preparation-reactions.html
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