PRODUCT CONFORMITY CERTIFICATE

This is to certify that the

Model APNA 370 NOx Analyser

manufactured by:
Horiba Limited
Miyanohigashi
Kisshoin
Minami-Ku
Kyoto
Japan

has been assessed by Sira Certification Service

and for the conditions stated on this certificate complies with:

MCERTS Performance Standards for Continuous Ambient Air

Quality Monitoring Systems, Version 7 (October 2010)

Certification Ranges :
NO 0 to 1200 µg/m3
NO2 0 to 400 µg/m3
0 to 500 µg/m3

Project No: 674/0231A & 16A27831

Certificate No: Sira MC 070090/03
Initial Certification: 10 January 2007
This Certificate Issued 21 May 2012
Renewal Date: 20 May 2017
R Cooper I Eng MInst MC

MCERTS is operated on behalf of the Environment Agency by

Sira Certification Service
12 Acorn Industrial Park, Crayford Road, Crayford
Dartford, Kent, UK DA1 4AL
Tel: +44 (0)1322 520500 Fax: +44 (0)1322 520501

This certificate may only be reproduced in its entirety and without change
Registered Office: Rake Lane, Eccleston, Chester, UK CH4 9JN
To authenticate the validity of this certificate please visit www.siracertification.com/mcerts

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Approved Site Application

On the basis of these tests this certificate is valid when the instrument is used on urban air
quality and similar applications.

Any potential user should ensure, in consultation with the manufacturer, that the air monitoring
system is suitable for the process on which it will be installed.

Basis of Certification

This certification is based on the following Test Report(s) and on Sira’s assessment and
ongoing surveillance of the product and the manufacturing process:

TÜV Köln Report Number: 936/21204643/C dated 07/07/06

Product Certified

The APNA 370 measuring system consists of the following parts:

Horiba APNA 370 Oxides of Nitrogen analyser

This certificate applies to all instruments fitted with software version P1000878001C onwards
(serial number 432866-10021 onwards).

Certificate No: Sira MC 070090/03

This Certificate Issued: 21 May 2012

This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.siracertification.com/mcerts

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Certified Performance

The instrument was evaluated for use under the following conditions:

Ambient Temperature Range: +5°C to +40°C

Test Results expressed as % of Other results MCERTS

measured value specification
<0.5 <1 <2 <5
Repeatability at zero 0.16 nmol/mol <1nmol/mol

Repeatability at hourly limit value 1.70 nmol/mol <3 nmol/mol

Residual lack of fit at zero 1.20 nmol/mol <5 nmol/mol

Lack of fit (largest residual from the linear 1.1 <4%

regression line)

Sensitivity coefficient to sample gas 0.14nmol/mol/kPa <8 nmol/mol/kPa

pressure

Sensitivity coefficient to sample gas 0.23 nmol/mol/K <3 nmol/mol/K

temperature

Sensitivity coefficient to surrounding air Zero: <3nmol/mol/K

temperature
0.03 nmol/mol/K

Span: <3 nmol/mol/K

0.33 nmol/mol/K

Sensitivity coefficient to electrical supply 0.03 nmol/mol/V <0.3 nmol/mol/V

voltage

Converter efficiency 98.6% >95%

Interference by H2O (at concentration of 19 1.37 nmol/mol <5 nmol/mol

nmol/mol)

Certificate No: Sira MC 070090/03

This Certificate Issued: 21 May 2012

This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.siracertification.com/mcerts

Page 3 of 5
Test Results expressed as % of measured Other results MCERTS
value specification
<0.5 <1 <2 <5
Interference by NH3 (at concentration of 3.62 nmol/mol <5 nmol/mol
200 nmol/mol)
Interference by CO2 at concentration of 2.16 nmol/mol <5 nmol/mol
500µmol/mol
Interference by Ozone at concentration of 1.04 nmol/mol <2 nmol/mol
200 nmol/mol

Averaging effect 4.4 <7%

Short term zero drift (over 12h) 0.1 nmol/mol <2 nmol/mol

Short term span drift (over 12h) 0.2 nmol/mol <6 nmol/mol

Response time (rise) 87 s 180 s

Response time (fall) 87 s 180 s

Difference between rise and fall time 0 <10%

Reproducibility under field conditions Note 3.8 <5% averaged over

1
three month period

Long term zero drift (over 3months) Note 1 1.0 nmol/mol <5 nmol/mol

Long term span drift (over 3 months) Note 1 2.4 <5% of the max of
certification range

Period of unattended operation Note 1 3 months 3 months not less

than 2 weeks

Availability (data capture) Note 1 98% >90%

Combined performance characteristic 11.4% <15%

Note 1: Field test: The field test was performed at an urban site for 3 months.

Certificate No: Sira MC 070090/03

This Certificate Issued: 21 May 2012

This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.siracertification.com/mcerts

Page 4 of 5
Description

The APNA 370 ambient air analyser measures NOx using a combination of dual cross flow
modulation and the chemiluminescence (CLD) method. This monitor continuously measures
the concentrations of nitrogen oxides (NO, NO2, and NOx (NO + NO2) in the atmosphere.

The APNA 370 divides the sampled gas into two flows; one is used for NOx (NO + NO2)
concentration measurement by reducing NO2 to NO with a NOx converter; the other is used
for NO concentration measurement directly. An internal reference gas is also generated
internally. The NOx sample, NO sample and reference gas gases are switched to every 0.75s
with solenoid valves, and are introduced to the reaction chamber in turn. The concentrations
of NO2 are calculated from those of NO and NOx.

The detector used is silicon photodiode sensor to prolong working life.

The analyser also has internal data storage capacity for three different mean value periods.

An addition of an RS-232C port (optional) allows direct data communications to be performed.

General Notes

1. This certificate is based upon the equipment tested. The Manufacturer is responsible for
ensuring that on-going production complies with the standard(s) and performance
criteria defined in this Certificate. The Manufacturer is required to maintain an approved
quality management system controlling the manufacture of the certified product. Both
the product and the quality management system shall be subject to regular surveillance
according to ‘Regulations Applicable to the Holders of Sira Certificates’. The design of
the product certified is defined in the Sira Design Schedule for certificate
No. Sira MC 070090/03.

2. If certified product is found not to comply, Sira Certification Service should be notified
immediately at the address shown on this certificate.

3. The Certification Marks that can be applied to the product or used in publicity material
are defined in ‘Regulations Applicable to the Holders of Sira Certificates’.

4. This document remains the property of Sira and shall be returned when requested by
the company.

Certificate No: Sira MC 070090/03

This Certificate Issued: 21 May 2012

This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.siracertification.com/mcerts

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