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    Chem 1220 Assignment 3

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    Kathi
    This document contains an assignment for a chemistry course covering electrochemistry and kinetics topics. It includes: 1) Showing that the potential measured by a pH electrode is proportional to pH using the Nernst equation. 2) Calculating the current from the silver deposition half reaction using the amount of silver deposited over time. 3) Summarizing the answers to several kinetics problems from the textbook involving zero, first, and second order reactions regarding rate constants and their relationships to concentrations and time.

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    Chem 1220 Assignment 3

    Uploaded by

    Kathi
    370 views3 pages
    This document contains an assignment for a chemistry course covering electrochemistry and kinetics topics. It includes: 1) Showing that the potential measured by a pH electrode is proportional to pH using the Nernst equation. 2) Calculating the current from the silver deposition half reaction using the amount of silver deposited over time. 3) Summarizing the answers to several kinetics problems from the textbook involving zero, first, and second order reactions regarding rate constants and their relationships to concentrations and time.

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    This document contains an assignment for a chemistry course covering electrochemistry and kinetics topics. It includes: 1) Showing that the potential measured by a pH electrode is proportional to pH using the Nernst equation. 2) Calculating the current from the silver deposition half reaction using the amount of silver deposited over time. 3) Summarizing the answers to several kinetics problems from the textbook involving zero, first, and second order reactions regarding rate constants and their relationships to concentrations and time.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    370 views3 pages

    Chem 1220 Assignment 3

    Uploaded by

    Kathi
    This document contains an assignment for a chemistry course covering electrochemistry and kinetics topics. It includes: 1) Showing that the potential measured by a pH electrode is proportional to pH using the Nernst equation. 2) Calculating the current from the silver deposition half reaction using the amount of silver deposited over time. 3) Summarizing the answers to several kinetics problems from the textbook involving zero, first, and second order reactions regarding rate constants and their relationships to concentrations and time.

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    Chem 1220

    Assignment 3

    Electrochemistry and Kinetics

    1. [6 points]

    a. Show with the aid of a form of the Nernst equation that when using a pH
    sensitive glass electrode and reference electrode that the measured
    potential is proportional to pH.

    The Nernst equatio:


    Xz = ion with charge z (ex: H3O+z = +1)
    E = EI +.0592/z log[Xz ]

    EI = sum of all other potential is measurement system, includes reference electrode and
    potentials inside ion sensor electrode and these should be kept constant

    With regards to pH,


    E = EI + 0.0592 log [ H3O+]
    measured
    E=EI -0.0592pH
    (y= b + m x)

    Thus, E is directly proportional to the pH of the solution because the -log[H3O+] is just the
    pH..

    b. Sketch a diagram of a pH sensitive glass electrode, label all parts and


    indicate the function of each part.

    Q3 constant

    Inner glass
    membrane- Charge separation (Cl-, H3O+ ions)
    charge
    separation Q
    constant
    Outer surface glass membrane – charge separation Q4
    2. [4 points]

    A constant electric current deposits 0.365 g of silver metal in 12960


    seconds(time) from a solution of silver nitrate.

    What is the half reaction for the deposition of silver. Molar mass of Ag is
    107.9

    AgNO3(aq) + e[-] = Ag(s) + NO3[-]


    Ag[+] + NO3[-] + e[-] = Ag(s) + NO3[-]

    Ag[+] + e[-] = Ag(s)

    What is the current?


    moles Ag = moles e-

    current (ampere)= C(coulombs)/time(sec)


    1 mole e- = 9.65 *104 coulombs

    moles Ag produced = 0.365 g Ag(s) * (1 mol Ag / 107.9 g Ag) = 0.00338 moles Ag


    So,

    0.00338 moles e- * (9.65 * 104 C ( coulombs ) / mole e-) = 326 C

    Current = 326 C / 12960 sec = 0.0252 amperes

    3. [ 5 points]

    Do Problems 14.25,14.29,14.31,14.33,14.39, 14.41, and 14.55 From BLB


    text.

    14.25:

    a. −Δ[O2]/Δt = 0.24 mol / s; Δ[H2O]/Δt = 0.48 mol / s


    b. Ptotal decreases by 28 torr / min

    14.29:

    a. Rate = k[N2O5]
    b. Rate = 1.16 ×10−4  M / s
    c. When the concentration of N2O5 doubles, the rate doubles.
    d. When the concentration of N2O5 is halved, the rate is halved.

    14.31:

    a. k = 1.7×102 M−1s−1
    b. If [OH−] is tripled, the rate triples.
    c. If [OH−] and [CH3Br] both triple, the rate increases by a factor of 9.

    14.33:

    a. Rate = k[OCl−][I−]
    b. k = 60  M−1s−1
    c. Rate = 6.0 × 10−5  M / s

    14.39:

    a. A graph of ln[A] versus time yields a straight line for a first-order reaction.
    b. On a graph of ln[A] versus time, the rate constant is the (–slope) of the straight line.

    14.41:

    a. k = 3.0 × 10−6 s−1


    b. t1/2 = 3.2 × 104 s

    14.55:

    a.
    Ea = 7 kJ

    ΔE = -66 kJ

    b. Ea (reverse) = 73 kJ

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