Safety Data Sheet

Sikadur®-52 Part A
Revision Date 06/19/2018 Print Date 06/19/2018

1. Identification

Product name : Sikadur®-52 Part A

Supplier : Sika Corporation

201 Polito Avenue

Lyndhurst, NJ 07071
USA
www.sikausa.com

Telephone : (201) 933-8800

Telefax : (201) 804-1076

E-mail address : ehs@sika-corp.com

Emergency telephone : CHEMTREC: 800-424-9300

INTERNATIONAL: 703-527-3887

Recommended use of the : For further information, refer to product data sheet.
chemical and restrictions on
use

2. Hazards identification

GHS Classification
Skin irritation, Category 2 H315: Causes skin irritation.
Eye irritation, Category 2A H319: Causes serious eye irritation.
Skin sensitization, Category 1 H317: May cause an allergic skin reaction.

GHS label elements

Hazard pictograms :

Signal Word : Warning

Hazard Statements : H315 Causes skin irritation.

H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.

Precautionary Statements : Prevention:

P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water

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for several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Warning : Reports have associated repeated and prolonged exposure to

some of the chemicals in this product with permanent
brain,liver, kidney and nervous system damage. Intentional
misuse by deliberate concentration and inhalation of vapors
may be harmful or fatal.

See Section 11 for more detailed information on health effects and symptoms.
There are no hazards not otherwise classified that have been identified during the classification
process.
There are no ingredients with unknown acute toxicity used in a mixture at a concentration >= 1%.

3. Composition/information on ingredients

Hazardous ingredients

Chemical name CAS-No. Concentration (%)

bisphenol-A-(epichlorhydrin) epoxy resin 25068-38-6 >= 50 - <= 100 %
1,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane 17557-23-2 >= 10 - < 20 %
[[(2-ethylhexyl)oxy]methyl]oxirane (2-ethylhexyl 2461-15-6 >= 10 - < 20 %
glycidyl ether)
solvent naphtha (petroleum), heavy arom. 64742-94-5 >= 2 - < 5 %
2-methylnaphthalene 91-57-6 >= 1 - < 2 %

There are no additional ingredients present which, within the current knowledge of the supplier
and in the concentrations applicable, are classified as hazardous to health or the environment
and hence require reporting in this section.

4. First aid measures

If inhaled : Move to fresh air.

Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.

In case of eye contact : Immediately flush eye(s) with plenty of water.

Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

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If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not induce vomiting without medical advice.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Obtain medical attention.

Most important symptoms : irritant effects

and effects, both acute and sensitizing effects
delayed
Allergic reactions
Excessive lachrymation
Erythema
Dermatitis
See Section 11 for more detailed information on health effects
and symptoms.

Causes skin irritation.

May cause an allergic skin reaction.
Causes serious eye irritation.

Protection of first-aiders : Move out of dangerous area.

Consult a physician.
Show this material safety data sheet to the doctor in
attendance.

Notes to physician : Treat symptomatically.

5. Fire-fighting measures

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Specific extinguishing : Collect contaminated fire extinguishing water separately. This

methods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters

6. Accidental release measures

Personal precautions, : Use personal protective equipment.

protective equipment and Deny access to unprotected persons.
emergency procedures
Environmental precautions : Do not flush into surface water or sanitary sewer system.
Local authorities should be advised if significant spillages
cannot be contained.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

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7. Handling and storage

Advice on safe handling : Do not breathe vapors or spray mist.

Avoid exceeding the given occupational exposure limits (see
section 8).
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Persons with a history of skin sensitization problems or
asthma, allergies, chronic or recurrent respiratory disease
should not be employed in any process in which this mixture is
being used.
Smoking, eating and drinking should be prohibited in the
application area.
Follow standard hygiene measures when handling chemical
products.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Store in accordance with local regulations.

Materials to avoid : No data available

8. Exposure controls/personal protection

Component CAS-No. Basis ** Value Exposure limit(s)* /

Form of exposure
2-methylnaphthalene 91-57-6 ACGIH TWA 0.5 ppm

*The above mentioned values are in accordance with the legislation in effect at the date of the
release of this safety data sheet.

**Basis
ACGIH. Threshold Limit Values (TLV)
OSHA P0. Table Z-1, Limit for Air Contaminat (1989 Vacated Values)
OSHA P1. Permissible Exposure Limits (PEL), Table Z-1, Limit for Air Contaminant
OSHA P2. Permissible Exposure Limits (PEL), Table Z-2
OSHA Z3. Table Z-3, Mineral Dust

Engineering measures : Use of adequate ventilation should be sufficient to control

worker exposure to airborne contaminants. If the use of this
product generates dust, fumes, gas, vapor or mist, use
process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure below any
recommended or statutory limits.

Personal protective equipment

Respiratory protection : Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk

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assessment indicates this is necessary.

The filter class for the respirator must be suitable for the
maximum expected contaminant concentration
(gas/vapor/aerosol/particulates) that may arise when handling
the product. If this concentration is exceeded, self-contained
breathing apparatus must be used.

Hand protection
Remarks : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is
necessary.

Eye protection : Safety eyewear complying with an approved standard should

be used when a risk assessment indicates this is necessary.

Skin and body protection : Choose body protection in relation to its type, to the
concentration and amount of dangerous substances, and to
the specific work-place.

Hygiene measures : Avoid contact with skin, eyes and clothing.

Wash hands before breaks and immediately after handling the
product.
Remove contaminated clothing and protective equipment
before entering eating areas.
Wash thoroughly after handling.

9. Physical and chemical properties

Appearance : liquid
Color : straw-like

Odor : aromatic

Odor Threshold : No data available

Flash point : > 212 °F (> 100 °C)

Ignition temperature : No data available

Decomposition temperature : No data available

Lower explosion limit (Vol%) : No data available

Upper explosion limit (Vol%) : No data available

Flammability (solid, gas) : No data available

Oxidizing properties : No data available

pH : Note: Not applicable

Melting point/range / : No data available

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Freezing point
Boiling point/boiling range : No data available

Vapor pressure : 4.000 mmHg (5.33288 hpa)

Density : 1.10 g/cm3

at 73 °F (23 °C)

Water solubility : Note: insoluble

Partition coefficient: n- : No data available

octanol/water
Viscosity, dynamic : No data available

Viscosity, kinematic : > 20.5 mm2/s

at 104 °F (40 °C)

Relative vapor density : No data available

Evaporation rate : No data available

Burning rate : No data available

Volatile organic compounds : 22 g/l

(VOC) content A+B Combined

10. Stability and reactivity

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : The product is chemically stable.

Possibility of hazardous : Stable under recommended storage conditions.

reactions
Conditions to avoid : No data available

Incompatible materials : No data available

11. Toxicological information

Acute toxicity
Not classified based on available information.
Ingredients:
bisphenol-A-(epichlorhydrin) epoxy resin:
Acute oral toxicity : LD50 Oral (Rat): > 5,000 mg/kg

Acute dermal toxicity : LD50 Dermal (Rabbit): > 20,000 mg/kg

Skin corrosion/irritation
Causes skin irritation.

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Serious eye damage/eye irritation

Causes serious eye irritation.
Respiratory or skin sensitization
Skin sensitization: May cause an allergic skin reaction.
Respiratory sensitization: Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Reports have associated repeated and prolonged exposure to some of the chemicals in this
product with permanent brain,liver, kidney and nervous system damage. Intentional misuse by
deliberate concentration and inhalation of vapors may be harmful or fatal.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.

Aspiration toxicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
IARC Not applicable

NTP Not applicable

12. Ecological information

Other information Do not empty into drains; dispose of this material and its
container in a safe way.
Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
May be harmful to the environment if released in large
quantities.
Water polluting material.

Component:

bisphenol-A- 25068-38-6 Toxicity to fish:

(epichlorhydrin) epoxy LC50
resin Species: Oncorhynchus mykiss (rainbow trout)
Dose: 2 mg/l
Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates:

EC50
Species: Daphnia magna (Water flea)
Dose: 1.8 mg/l
Exposure time: 48 h

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13. Disposal considerations

Disposal methods
Waste from residues : Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.

Contaminated packaging : Empty containers should be taken to an approved waste

handling site for recycling or disposal.

14. Transport information

DOT
Not regulated

IATA
UN number 3082
Description of the goods Environmentally hazardous substance, liquid, n.o.s.
(bisphenol-A-(epichlorhydrin) epoxy resin, 2,3-epoxypropyl o-
tolyl ether)
Class 9
Packing group III
Labels 9
Packing instruction (cargo 964
aircraft)
Packing instruction 964
(passenger aircraft)
Packing instruction Y964
(passenger aircraft)

IMDG
UN number 3082
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(bisphenol-A-(epichlorhydrin) epoxy resin, 2,3-epoxypropyl o-
tolyl ether)
Class 9
Packing group III
Labels 9
EmS Number 1 F-A
EmS Number 2 S-F

Marine pollutant yes

IMDG: For Limited Quantity special provisions reference IMDG Code Chapter 3.4

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Special precautions for user

No data available

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

15. Regulatory information

TSCA list : All chemical substances in this product are either listed on the
TSCA Inventory or are in compliance with a TSCA Inventory
exemption.

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

SARA304 Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Chronic Health Hazard

Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitization

SARA 302 : This material does not contain any components with a section
302 EHS TPQ.

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

Clean Air Act

Ozone-Depletion This product neither contains, nor was manufactured with a

Potential Class I or Class II ODS as defined by the U.S. Clean Air Act
Section 602 (40 CFR 82, Subpt. A, App.A + B).

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).

California Prop 65 WARNING: Cancer and Reproductive Harm -

www.P65Warnings.ca.gov

16. Other information

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HMIS Classification
Health * 2

Flammability 1

Physical Hazard 0

Personal Protection X

Caution: HMIS® rating is based on a 0-4 rating scale, with 0 representing minimal hazards or
risks, and 4 representing significant hazards or risks. Although HMIS® rating is not required
on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® rating
is to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the
National Paint & Coatings Association (NPCA). Please note HMIS® attempts to convey full
health warning information to all employees.

Notes to Reader
The information contained in this Safety Data Sheet applies only to the actual Sika
Corporation ("Sika") product identified and described herein. This information is not intended
to address, nor does it address the use or application of the identified Sika product in
combination with any other material, product or process. All of the information set forth herein
is based on technical data regarding the identified product that Sika believes to be reliable as
of the date hereof. Prior to each use of any Sika product, the user must always read and
follow the warnings and instructions on the product's current Product Data Sheet, product
label and Safety Data Sheet for each Sika product, which are available at web site and/or
telephone number listed in Section 1 of this SDS.

SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY

ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER
ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT
BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON
ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.

All sales of Sika products are subject to its current terms and conditions of sale available at
www.sikausa.com or 201-933-8800.

Revision Date 06/19/2018

Material number: 536773

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